(3) summary of the invention
The present invention is in order to remedy the deficiencies in the prior art, and a kind of wide spectrum, efficient, environmental protection, herbicidal effect is good, usage amount the is little Herbicidal combinations that contains cloransulammethyl and imazamox are provided.
The present invention is achieved through the following technical solutions:
A kind of Herbicidal combinations that contains cloransulammethyl and imazamox, its active ingredient consists of cloransulammethyl and imazamox, and the weight ratio of described cloransulammethyl and imazamox is 4: 0.2-20.
This contains the Herbicidal combinations of cloransulammethyl and imazamox, and the weight ratio that its preferred scheme is described cloransulammethyl and imazamox is 4: 1-10.
This contains the Herbicidal combinations of cloransulammethyl and imazamox, and its active ingredient cloransulammethyl and imazamox account for the 20%-60% of Herbicidal combinations gross weight, and all the other are operable auxiliary element in the agricultural chemicals.Described auxiliary element can be in emulsifier, wetting agent, dispersant, thickener, defoamer, filler, synergist, solvent, antifreezing agent, the methyl oleate several, or be of value to the material of active ingredient stable and drug effect performance in preparation for other.This auxiliary element is conducive to that Herbicidal combinations is made suitable agricultural and goes up the formulation of using, and preferred formulation is wetting powder, water dispersible granules, aqueous emulsion, aqueous suspension or oil suspending agent.
Described emulsifier is one or more in polyoxyethylene nonylphenol ether, Nonoxynol-9, Bian Ji phenol polyethenoxy ether, styryl phenol APEO, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, the alkyl benzene calcium sulfonate; Described wetting agent is one or more in sldium lauryl sulfate, neopelex, fatty alcohol-polyoxyethylene ether, the OPEO; Described dispersant is one or more in lignin and derivative sulfonate, naphthalene and alkylnaphthalene sulfonate formaldehyde condensation products, the alkylphenol polyoxyethylene phosphate; Described thickener is one or more in xanthans, aluminium-magnesium silicate, bentonite, PAA, the gum Arabic; Described defoamer is one or more in silicone defoaming agent, polymerization glycerine, the polyether-modified silicon defoaming agent; Described filler is one or more in atlapulgite, kaolin, montmorillonite, diatomite, attapulgite, the white carbon.
The percentage by weight of each constituent of described wetting powder in wetting powder is respectively: cloransulammethyl and imazamox 35%-60%, wetting agent 1%-8%, dispersant 1%-10%, synergist 4%-6%, surplus is filler.
The percentage by weight of each constituent of described water dispersible granules in water dispersible granules is respectively: cloransulammethyl and imazamox 35%-60%, wetting agent 1%-8%, dispersant 1%-10%, synergist 4%-6%, surplus is filler.
The percentage by weight of each constituent of described aqueous emulsion in aqueous emulsion is respectively: cloransulammethyl and imazamox 20%-30%, solvent 10%-20%, emulsifier 5%-15%, dispersant 5%-10%, antifreezing agent 5%-10%, surplus is water.
The percentage by weight of each constituent of described oil suspending agent in oil suspending agent is respectively: cloransulammethyl and imazamox 30%-50%, emulsifier 10%-20%, dispersant 1%-8%, defoamer 0.1%-1%, thickener 1%-3%, surplus is methyl oleate.
The percentage by weight of each constituent of described aqueous suspension in aqueous suspension is respectively: cloransulammethyl and imazamox 20%-35%, dispersant 10%-20%, wetting agent 5%-15%, thickener 0.1%-1%, antifreezing agent 1%-10%, surplus is water.
The beneficial effect that the present invention contains the Herbicidal combinations of cloransulammethyl and imazamox is: can prevent and kill off grassy weed and can prevent and kill off broad leaved weed again, solve cloransulammethyl and the agent of imazamox list and killed the narrow problem of grass spectrum in the soybean field, can improve herbicidal effect effectively, enlarged and killed the grass spectrum, slowed down the drug-fast generation of weeds, reduce cost and agricultural chemicals usage amount, reduced the pollution to environment, be mainly used in the control of soybean Tian Miaohou weeds.
(4) embodiment
The invention will be further described below in conjunction with embodiment, but the present invention is not limited thereto, and the formulation preparation method among the embodiment is conventional preparation method, no longer describes in detail.
Embodiment 1:40% cloransulammethyl imazamox oil suspending agent (4: 1) comprises the following component of following weight: (in double centner, as follows)
32 kilograms of cloransulammethyls, 8 kilograms of imazamox, 15 kilograms of fatty alcohol-polyoxyethylene ether, 4 kilograms of alkylphenol polyoxyethylene phosphates, 0.5 kilogram of silicone defoaming agent, 1 kilogram of gum Arabic, methyl oleate is supplied double centner.
Pour each component of above-mentioned weight in sand cylinder sand milling, filter, remove bead, namely make 40% cloransulammethyl imazamox oil suspending agent.Methyl oleate no longer describes in detail as the usual auxiliaries of oil suspending agent.
Using method: be applicable to the processing of soybean Tian Miaohou cauline leaf, every mu of ground consumption 8 grams are converted 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 2-6:
Emulsifier is selected one or more in polyoxyethylene nonylphenol ether, Nonoxynol-9, Bian Ji phenol polyethenoxy ether, styryl phenol APEO, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, the alkyl benzene calcium sulfonate for use among the embodiment 2-6; Dispersant is selected one or more in lignin and derivative sulfonate, naphthalene and alkylnaphthalene sulfonate formaldehyde condensation products, the alkylphenol polyoxyethylene phosphate for use; Defoamer is selected for use, in the polymerization glycerine, polyether-modified silicon defoaming agent one or more; Thickener is selected one or more in xanthans, aluminium-magnesium silicate, bentonite, PAA, the gum Arabic for use.
The preparation method of embodiment 2-6 is with embodiment 1.
Embodiment 2-6 using method: be applicable to that all soybean Tian Miaohou cauline leaf handles, every mu of ground consumption is respectively 10 grams, 6.6 grams, 9.3 grams, 6 grams, 6.25 grams, converts 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 7:50% cloransulammethyl imazamox water dispersible granules (4: 16) comprises the following component of following weight:
10 kilograms of cloransulammethyls, 40 kilograms of imazamox, 5 kilograms of sldium lauryl sulfates, naphthalene and 4 kilograms of alkylnaphthalene sulfonate formaldehyde condensation products, 4 kilograms of synergist organosilicons, 2 kilograms of white carbons, kaolin is supplied double centner.
With each component dry pulverization process of above-mentioned weight, send Squeezinggranulator then to, carry out granulation, namely make 50% cloransulammethyl imazamox water dispersible granules by dry, screening.
Using method: be applicable to the cauline leaf processing of soybean field, every mu of ground consumption 6 grams are converted 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 8-12:
Wetting agent is selected one or more in sldium lauryl sulfate, neopelex, fatty alcohol-polyoxyethylene ether, the OPEO for use among the embodiment 8-12; Dispersant is selected one or more in lignin and derivative sulfonate, naphthalene and alkylnaphthalene sulfonate formaldehyde condensation products, the alkylphenol polyoxyethylene phosphate for use.
The preparation method of embodiment 8-12 is with embodiment 7.
Embodiment 8-12 using method: be applicable to that all soybean Tian Miaohou cauline leaf handles, every mu of ground consumption is respectively 7 grams, 8.5 grams, 6.6 grams, 5 grams, 5.2 grams, converts 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 13:60% cloransulammethyl imazamox wetting powder (4: 10) comprises the following component of following weight:
17.15 kilograms of cloransulammethyls, 42.85 kilograms of imazamox, 3 kilograms of OPEOs, 8 kilograms of sodium lignin sulfonates, 5 kilograms of synergist organosilicons, 3 kilograms of atlapulgites, kaolin is supplied double centner.
Enter in the blender after each component coarse crushing with above-mentioned weight and mix, pulverize through air-flow again and namely make 60% cloransulammethyl imazamox wetting powder.
Using method: be applicable to the cauline leaf processing of soybean field, every mu of ground consumption 5 grams are converted 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 14-18:
Constituent |
42% wettable powder |
35% wettable powder |
45% wettable powder |
50% wettable powder |
57% wettable powder |
? |
Agent (4: 0.2) |
Agent (4: 1) |
Agent (4: 5) |
Agent (4: 12) |
Agent (4: 15) |
Cloransulammethyl |
40 |
28 |
20 |
12.5 |
12 |
Imazamox |
2 |
7 |
25 |
37.5 |
45 |
Wetting agent |
1 |
5 |
4 |
6 |
8 |
Dispersant |
7 |
5 |
10 |
1 |
8 |
The synergist organosilicon |
4 |
4.5 |
5 |
4 |
6 |
Atlapulgite |
4 |
2 |
3 |
2 |
1 |
Kaolin |
Supply 100kg |
Supply 100kg |
Supply 100kg |
Supply 100kg |
Supply 100kg |
Wetting agent is selected one or more in sldium lauryl sulfate, neopelex, fatty alcohol-polyoxyethylene ether, the OPEO for use among the embodiment 14-18; Dispersant is selected one or more in lignin and derivative sulfonate, naphthalene and alkylnaphthalene sulfonate formaldehyde condensation products, the alkylphenol polyoxyethylene phosphate for use.
The preparation method of embodiment 14-18 is with embodiment 13.
Embodiment 14-18 using method: be applicable to that all soybean Tian Miaohou cauline leaf handles, every mu of ground consumption is respectively 7 grams, 8.5 grams, 6.6 grams, 6 grams, 5.2 grams, converts 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 19:20% cloransulammethyl imazamox aqueous emulsion (4: 0.2) comprises the following component of following weight:
19.05 kilograms of cloransulammethyls, 0.95 kilogram of imazamox, 15 kilograms of solvent xylenes, 8 kilograms of Nonoxynol-9s, 5 kilograms of alkylphenol polyoxyethylene phosphates, 8 kilograms of antifreeze glycols, deionized water is supplied double centner.
Cloransulammethyl, imazamox are mixed with Nonoxynol-9, alkylphenol polyoxyethylene phosphate, ethylene glycol after with xylene soluble again, add deionized water then and shear, namely make 20% cloransulammethyl imazamox aqueous emulsion.
Using method: be applicable to the cauline leaf processing of soybean field, every mu of ground consumption 15 grams are converted 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 20-24:
Emulsifier is selected one or more in polyoxyethylene nonylphenol ether, Nonoxynol-9, Bian Ji phenol polyethenoxy ether, styryl phenol APEO, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, the alkyl benzene calcium sulfonate for use among the embodiment 20-24; Dispersant is selected one or more in lignin and derivative sulfonate, naphthalene and alkylnaphthalene sulfonate formaldehyde condensation products, the alkylphenol polyoxyethylene phosphate for use.
The preparation method of embodiment 20-24 is with embodiment 19.
Embodiment 20-24 using method: be applicable to that all soybean Tian Miaohou cauline leaf handles, every mu of ground consumption is respectively 13 grams, 10.7 grams, 13.6 grams, 10 grams, 15 grams, converts 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 25:30% cloransulammethyl imazamox aqueous suspension (4: 20) comprises the following component of following weight:
5 kilograms of cloransulammethyls, 25 kilograms of imazamox, 4 kilograms of sodium lignin sulfonates, 8 kilograms of alkylphenol polyoxyethylene phosphates, 6 kilograms of neopelexes, 0.5 kilogram of xanthans, 5 kilograms of antifreeze glycols, water is supplied double centner.
Each component of above-mentioned weight is mixed, namely make 30% cloransulammethyl imazamox aqueous suspension after the shearing.
Using method: be applicable to the processing of soybean Tian Miaohou cauline leaf, every mu of ground consumption 10 grams are converted 30 kilograms in water, even spraying under calm, fine condition.
Embodiment 26-30:
Dispersant is selected sodium lignin sulfonate and alkylphenol polyoxyethylene phosphate for use among the embodiment 26-30; Wetting agent is selected one or more in sldium lauryl sulfate, neopelex, fatty alcohol-polyoxyethylene ether, the OPEO for use; Thickener is selected one or more in xanthans, aluminium-magnesium silicate, bentonite, PAA, the gum Arabic for use.
The preparation method of embodiment 26-30 is with embodiment 25.
Embodiment 26-30 using method: be applicable to that all soybean Tian Miaohou cauline leaf handles, every mu of ground consumption is respectively 12.5 grams, 8.5 grams, 15 grams, 10.7 grams, 9 grams, converts 30 kilograms in water, even spraying under calm, fine condition.
Biologicall test test A:
I) test objective: under the room temperature condition, adopt the pot experiment method, research cloransulammethyl and imazamox are mixed the synergy of weeds are measured.
II) test material: grassy weed (barnyard grass grass, green foxtail) field is collected seed and is preserved, and broad leaved weed (dayflower, Siberian cocklebur, Amaranthus retroflexus) field is collected seed and preserved, and germination rate is more than 90%.
III) test apparatus: 3WT-II type spray tower, BS124S type ten thousand/electronic balance, the biochemical incubator of SPX type intelligence.
IV) test method: earlier take by weighing a certain amount of cloransulammethyl and the former medicine of imazamox respectively with electronic balance, adding acetone, fully to dissolve the back be that 0.1% the Tween 80 aqueous solution dilutes with mass fraction, makes single agent mother liquor respectively;
Weed seed that will vernalization shows money or valuables one carries unintentionally in biochemical incubator evenly is placed in the flowerpot, 100 of every basin sowings are cultured to the 2-4 leaf phase, evenly spray soup with 3WT-II type spray tower, every processing repeats 4 times, takes by weighing in 10 days behind the spray medicine and respectively handles weeds acrial part fresh weight.
Calculate the theoretical fresh weight inhibiting rate (E that respectively handles hybrid combining with the Gowing method
0=X+Y-X*Y/100), compare with actual measurement inhibiting rate (E) then, estimate the two and use synergy type to weeds with, work as E-E
0Value is greater than 10% for synergistic effect, less than-10% be antagonism, is addition between-10%~10%.
V) statistics sees Table 1:
Table 1 cloransulammethyl, imazamox are used the synergy effect (Gowing method) to weeds with
As can be seen from Table 1, after cloransulammethyl and imazamox are mixed, be 4 in weight ratio particularly: in the time of between the 1-10, to broad leaved weed and grassy weed E-E
0Value illustrates that the synergy that cloransulammethyl and imazamox are mixed to soybean weeds belongs to addition all between-10%~10%.
Biologicall test test B: field control effectiveness test
I) reagent agent: prepared herbicidal composition in above-described embodiment:
Embodiment 1:40% cloransulammethyl imazamox oil suspending agent (4: 1);
Embodiment 2:30% cloransulammethyl imazamox oil suspending agent (4: 4);
Embodiment 3:45% cloransulammethyl imazamox oil suspending agent (4: 8);
Embodiment 7:50% cloransulammethyl imazamox water dispersible granules (4: 16);
Embodiment 13:60% cloransulammethyl imazamox wetting powder (4: 10);
Embodiment 17:50% cloransulammethyl imazamox wetting powder (4: 12);
Embodiment 19:20% cloransulammethyl imazamox aqueous emulsion (4: 0.2);
Embodiment 25:30% cloransulammethyl imazamox aqueous suspension (4: 20);
Embodiment 28:20% cloransulammethyl imazamox aqueous suspension (4: 6).
Ii) contrast medicament: 84% cloransulammethyl water dispersible granules, 4% imazamox aqua.
Iii) for studying thing: soybean, wherein soybean back second trifoliolate leaf of emerging launches, and grows fine, and robust plant does not have other damage by disease and insect.
Iv) prevent and kill off object: soybean weedses such as dayflower, corn sow thistle, field thistle, Siberian cocklebur, piemarker, Amaranthus retroflexus, black nightshade, barnyard grass grass, green foxtail, lamb's-quarters.
V) test method: the experimental field is located in the farmland, the Sun Louzhen of Jiangsu Province one place, and soil property is that sandy loam two closes soil, and PH is 8, and middle fertility was in dispenser on June 11 in 2012.According to the area of experimental plot, the accurate good various medicaments of weighing, and after converting the water dilution, utilize knapsack sprayer, and carrying out even spraying, shower nozzle is selected the Fan spray head of weed killer herbicide special use for use.Spray medicine weather on the same day is fine, calm.During spraying soup is evenly sprayed application in the experimental plot, do not leak the phenomenon of spray, many sprays.
Vi) the results are shown in Table 2:
Table 2 Herbicidal combinations of the present invention and single agent weed killer herbicide preventive effect contrast table
The result of the test of table 2 shows that Herbicidal combinations of the present invention has significant preventive effect to soybean weeds, and effect significantly is better than single agent and uses.
Determine that by above-mentioned test the synergy of preventing and kill off soybean weeds that is mixed of cloransulammethyl and imazamox belongs to summation action, can prevent and kill off broad leaved weed and grassy weed simultaneously, effect significantly is better than single agent and uses, and cloransulammethyl and imazamox weight ratio are 4: during 1-10 to the integrated control effects of weeds greater than 90%, weight ratio is 4: during 0.2-20 to the integrated control effects of weeds more than 80%, and to soybean safety, cloransulammethyl and imazamox are mixed not only to have enlarged and kill the grass spectrum, and reduced cost, reduced the agricultural chemicals usage amount, slow down the drug-fast generation of weeds, reduced the pollution to environment.