CN103320019A - Novel biologic mouldproof shoe polish and preparation method thereof - Google Patents
Novel biologic mouldproof shoe polish and preparation method thereof Download PDFInfo
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- CN103320019A CN103320019A CN2013102540847A CN201310254084A CN103320019A CN 103320019 A CN103320019 A CN 103320019A CN 2013102540847 A CN2013102540847 A CN 2013102540847A CN 201310254084 A CN201310254084 A CN 201310254084A CN 103320019 A CN103320019 A CN 103320019A
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Abstract
The invention relates to novel biological mouldproof shoe polish and a preparation method thereof. The novel biological mouldproof shoe polish comprises the following components in mass percent according to a formula: 0-10 parts of pigment paste, 2-5 parts of oxidized polyethlene wax, 5-10 parts of brazil buttonwood wax, 2-10 parts of surfactant, 10-20 parts of liquid paraffin, 1-2 parts of oleic acid, 1-3 parts of stearic acid, 0-3 parts of SG-9, 0-3 parts of paraffin emulsifier, 0.1-2 parts of biological compound antiseptic, 10-20 parts of turpentine and the balance of deionized water.
Description
Background technology
The raw material of leather shoes is leather, and leather is to make with the skin of the animals such as ox, pig, sheep, and its main component is protein and fat, these materials all are the good nutrition bases of microorganism, animal skin is processed finished leather, pass through tens procedures such as kneading, stuffing, covering with paint, last tens of days.Wherein, the boots leather is with containing a large amount of sugars and tannin in the vegetable extract.What stuffing technique was used is vegetables oil or animal oil.Contain protein ingredient milk casein in the finishing agent.All these also all are the nutritious prod of microorganism.In addition, suitable temperature and humidity is again the essential condition of mould-growth and breeding.Because temperature can be accelerated the carrying out of cell metabolism, nutritive substance and meta-bolites only have and just can be absorbed or be excreted to external by moisture.According to statistics, on mouldy leather shoes, the bacterium number of every sq is more than 10,000,000.Identify it mostly is the bacterium of Aspergillus and Penicillium through classification, such as: aspergillus niger, flavus, aspergillus oryzae, Penicillium citrinum, Penicillium islandicum, grey green mold etc.
Mould is caused by meta-bolites corrosion and the destruction of leather shoes.After mould spores stain leather surface, in case envrionment conditions is suitable, spore just can germination and growth.Simultaneously, secrete the materials such as multiple lytic enzyme and organic acid, thus the corrosion leather.For example proteolytic enzyme can resolve into the leather protein matter of long-chain the constituents of peptone, albumen Shi and the amino acid of short chain, then obtains the nutrition of oneself, and the green ramp of bacterium is reached maturity, and produces the sporophore that makes new advances.So circulation goes down constantly to breed the offspring of oneself, constantly decomposes leather protein matter, and its result tarnishes leather, crowfoot cracks or catabiosis occur, therefore says that the process of mould Growth and reproduction on leather shoes is exactly the process that leather shoes go mouldy and corroded.
Prevent that leather shoes are mouldy, must add safely and effectively sterilant, to support antimycotic growth.Also should carry out the use custodianship of leather shoes, wipe away mildew-resistant shoe polish as often being coated with, like this, even can be not mouldy under the wet heat condition of yellow plum weather yet.
The natural biological antiseptic agent is with safety non-toxic, good water solubility, thermostability advantages of higher, in addition being rooted in the hearts of the people of " green food " theory, people to natural biological antiseptic agent more and more pay close attention to.At present, main biological preservative that generally acknowledge in the world, safety, the employing Production by Microorganism Fermentation and that use in developed country has: nisin (Nisin), tennecetin (Natamycin) and epsilon-polylysine (ε-poly-lysine) etc.Epsilon-polylysine (a kind of amino acid homopolymer with broad spectrum antibiotic activity of ε-poly-lysine), have good sterilizing ability and thermostability, fungistatic effect is good in neutral and acid range, various gram positive bacteriums, gram negative bacterium and heat-resistant bacillus are had remarkable restraining effect, are the antiseptics for natural food with superior antiseptic property and huge business potential.Tennecetin (Natamycin) is a kind of secondary metabolite that Natal streptomycete (Streptomyces Nataleois) obtains by fermentation, be in a kind of polyene macrocyclic lipoid substance it can narrow spectrum inhibition yeast and mould; And dosage is low, and efficient is high, and its minimal inhibitory concentration (MIC) is generally 1-10 μ g/mL; Add it and be difficult to be assimilated by the stomach of human body or animal, finally discharge with ight soil, thereby be used widely.
Compound preservative is to be applied in the shoe polish among the present invention, be used for leather shoes mildew resistant, fully analyze the kind of various microorganisms, growth characteristics are taked effectively, safe and reliable composite the forming of monomer sanitas, be not the stack of simple sanitas, accomplish effective, economical, mutual collaborative the replenishing of each monomer simultaneously, complementary consumption is few, safe.Composite biological preservative has improved the monomer effect, the effect of each monomer is fully played, mutually collaborative additional, the usage quantity of sanitas is controlled in the lowest range, thereby guarantee to adopt less consumption and reach desirable effect, the security of guaranteeing food is improved, and reduces simultaneously use cost.
By examining element, find that the patent publication us relevant with present patent application mainly contains:
1, mildew-resistant shoe-blacking:
On November 21st, 2011 by the Decree of Patent Office of China " mildew-resistant shoe-blacking ", application number 201110322957.4 is characterized in that: the component that comprises following parts by weight: oil of mirbane 5-10 part, oxidized polyethlene wax 2-5 part, crude montan wax 5-10 part, turps 20-30 part, oil black nigrosine 1-5 part, ceresine 10-20 part, mould inhibitor 5-10 part.Mildew-resistant shoe-blacking provided by the invention be coated on the leather shoes volatilization very fast, be difficult for dying ash, glossiness is good and can prevent that leather shoes are mouldy.The mould inhibitor that adopts in the prescription is phenol or Pentachlorophenol, all has higher preservative property, can prevent effectively that vamp is mouldy.But phenol or Pentachlorophenol have than severe corrosive, and be poisonous, and cortex is had certain harm, reduces cortex work-ing life.
2, a kind of blast shoe-blacking
On October 24th, 2011 by the Decree of Patent Office of China " a kind of blast shoe-blacking ", application number 201110325166.7, it is characterized in that: the component that comprises following parts by weight: oil of mirbane 5-10 part, oxidized polyethlene wax 2-5 part, crude montan wax 5-10 part, silicone oil 5-10 part, turps 20-30 part, oil black nigrosine 1-5 part, ceresine 10-20 part, mould inhibitor 5-10 part, the method can increase certain light to leather shoes, but employed mould inhibitor is phenol or Pentachlorophenol, stronger corrodibility is arranged, not only affect the life-span of cortex, also may cause accidental injury to the people.
3, a kind of high-performance is nourished waterproof shoe polish and preparation method thereof
On September 18th, 2012 by the Decree of Patent Office of China " a kind of high-performance is nourished waterproof shoe polish and preparation method thereof ", application number 201210344732.3, it is characterized in that it is formulated by certain mass ratio by tensio-active agent, oleic acid, animal tallow leather fat, brightening agent, tasteless kerosene, trolamine, mould inhibitor, essence, deionized water that high-performance is nourished waterproof shoe polish, the preparation method comprises preparation of raw material, oil phase mixing, water mixing, oil mixing with water and filtration canned-matter step.This high-performance is nourished waterproof shoe polish and is added fluorine containing silicone oil and multiple auxiliary agent, can effectively improve the antistatic and mildew-resistant effect of leather shoes, strengthens anti-the circumnutating property of leather, gives simultaneously the characteristics such as leather is smooth, soft, elasticity is good.But the selected mould inhibitor of this kind method is nano phase ag_2 o leather fungicide, methyl p-hydroxybenzoate, 1, at least a in the 2-benzisothiazole-3-ketone, but these several sanitass are comparatively responsive to pH, and therefore the pH that obtains of above-mentioned prescription may affect the sterilizing ability of sanitas.
Summary of the invention
The objective of the invention is that (it is composite that ε-poly-lysine) etc. carries out science with natural biological antiseptic agent tennecetin (Natamycin) and epsilon-polylysine, the preparation composite biological preservative, this compound preservative antimicrobial spectrum is wide, stability is high, green safety, pollution-free to ecology, in addition, in shoe polish, add the materials such as tensio-active agent, can effectively increase glossiness and the brightness of footwear.The present invention improves the prescription of shoe polish: pigment paste 0～10,2～5 parts of oxidized polyethlene wax, 5～10 parts in Brazilian paulownia wax, 2～10 parts in tensio-active agent, 10～20 parts of whiterusss, 1～2 part of oleic acid, 1～3 part of stearic acid, SG-90-3 part, paraffin emulsifier 0-3 part, 0.1～2 part of biological compound preservative, 10～20 parts in turps, the deionized water surplus.
Embodiment
The invention will be further described below by specific embodiment, and following examples are descriptive, is not determinately can not limit protection scope of the present invention with this.
Pigment paste, oxidized polyethlene wax, Brazilian paulownia wax, tensio-active agent, whiteruss, oleic acid, stearic acid, turps, SG-9, paraffin emulsifier and a small amount of deionized water are heated to 80-85 ℃, stir into paste with stirrer 100-200r/min stand-by; In epsilon-polylysine and the tennecetin one or both are put in a small amount of deionized water, stir 1-2min with agitator 500-1000r/min stand-by; With above-mentioned both mix, get final product with the clarifixator homogeneous again after stirring evenly with stirrer.
Embodiment 1:
5 parts of oxidized polyethlene wax, 5 parts in Brazilian paulownia wax, 3 parts of Arlacel-60s, 3 parts of tween-80s, 10 parts of whiterusss, 2 parts of oleic acid, 3 parts of stearic acid, SG-93 part, paraffin emulsifier part, 0.01 part of tennecetin, 0.5 part of epsilon-polylysine, 20 parts in turps, the deionized water surplus.Oxidized polyethlene wax, Brazilian paulownia wax, Arlacel-60, tween-80, whiteruss, oleic acid, stearic acid, turps, SG-9, paraffin emulsifier and a small amount of deionized water are heated to 80-85 ℃, stir 30min with stirrer 100r/min stand-by; Epsilon-polylysine and tennecetin are put in a small amount of deionized water, stir 1min with agitator 1000r/min stand-by; With above-mentioned both mix, get final product with the clarifixator homogeneous again after stirring evenly with stirrer.
Embodiment 2:
5 parts of mineral black cream, 2 parts of oxidized polyethlene wax, 10 parts in Brazilian paulownia wax, 5 parts of tween-80s, 10 parts of whiterusss, 2 parts of oleic acid, 3 parts of stearic acid, SG-91 part, 1 part of paraffin emulsifier, 0.8 part of epsilon-polylysine, 15 parts in turps, the deionized water surplus is heated to 80-85 ℃ with pigment paste, oxidized polyethlene wax, Brazilian paulownia wax, tween-80, whiteruss, oleic acid, stearic acid, turps, SG-9, paraffin emulsifier and a small amount of deionized water, stirs 30min with stirrer 200r/min and becomes paste stand-by; Epsilon-polylysine is put in a small amount of deionized water, stirs 1min with agitator 500/min stand-by; With above-mentioned both mix, get final product with the clarifixator homogeneous again after stirring evenly with stirrer.
Embodiment 3:
5 parts of palm fibre pigment pastes, 2 parts of oxidized polyethlene wax, 8 parts in Brazilian paulownia wax, 5 parts of tween-80s, 15 parts of whiterusss, 1 part of oleic acid, 1 part of stearic acid, 0.5 part of epsilon-polylysine, 15 parts in turps, deionized water surplus.With brown pigment paste, oxidized polyethlene wax, Brazilian paulownia wax, tween-80, whiteruss, oleic acid, stearic acid, turps, and deionized water is heated to 80-85 ℃ on a small quantity, stirs 30min with stirrer 200r/min and becomes paste stand-by; Epsilon-polylysine is put in a small amount of deionized water, stirs 1min with agitator 500/min stand-by; With above-mentioned both mix, get final product with the clarifixator homogeneous again after stirring evenly with stirrer.
Above demonstration and described ultimate principle of the present invention, principal character.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification sheets just illustrates principle of the present invention; do not breaking away under the spirit and scope of the present invention prerequisite; the present invention also has various changes and modifications, and these changes and improvements fall in the claimed scope of the invention.
Claims (4)
1. new bio mildew-resistant shoe polish and preparation method thereof, its prescription quality per-cent is: pigment paste 0～10,2～5 parts of oxidized polyethlene wax, 5～10 parts in Brazilian paulownia wax, 2～10 parts in tensio-active agent, 10～20 parts of whiterusss, 1～2 part of oleic acid, 1～3 part of stearic acid, SG-90-3 part, paraffin emulsifier 0-3 part, 0.1～2 part of biological compound preservative, 10～20 parts in turps, the deionized water surplus.
2. new bio mildew-resistant shoe polish claimed in claim 1 and preparation method thereof, it is characterized in that: described biological compound preservative is one or both mixtures in epsilon-polylysine and the tennecetin, and mass percent is tennecetin 0-0.3 part, epsilon-polylysine 0-1.7 part.
3. new bio mildew-resistant shoe polish claimed in claim 1 and preparation method thereof, it is characterized in that: described tensio-active agent is one or more mixtures in Arlacel-60, Tegin 55G, the tween-80, and content is 2～10 parts.
4. new bio mildew-resistant shoe polish claimed in claim 1 and preparation method thereof, it is characterized in that the preparation method is: pigment paste, oxidized polyethlene wax, Brazilian paulownia wax, tensio-active agent, whiteruss, oleic acid, stearic acid, turps, SG-9, paraffin emulsifier and a small amount of deionized water are heated to 80-85 ℃, stir into paste with stirrer 100-200r/min stand-by; In epsilon-polylysine and the tennecetin one or both are put in a small amount of deionized water, stir 1-2min with agitator 500-1000r/min stand-by; With above-mentioned both mix, get final product with the clarifixator homogeneous again after stirring evenly with stirrer.
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| CN2013102540847A CN103320019A (en) | 2013-06-25 | 2013-06-25 | Novel biologic mouldproof shoe polish and preparation method thereof |
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| CN2013102540847A CN103320019A (en) | 2013-06-25 | 2013-06-25 | Novel biologic mouldproof shoe polish and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040087667A1 (en) * | 2002-11-06 | 2004-05-06 | Mercurio Anthony Fred | Aerosol delivery systems |
| CN101606745A (en) * | 2009-06-26 | 2009-12-23 | 广东省微生物研究所 | Composite biological preservative and its production and application |
| CN102352189A (en) * | 2011-08-03 | 2012-02-15 | 罗程耀 | Shoe polishing brightener |
| EP1438363B1 (en) * | 2001-10-22 | 2013-03-13 | S. C. Johnson & Son, Inc. | Furniture polish composition |
| CN103013349A (en) * | 2012-12-14 | 2013-04-03 | 吴江市利达上光制品有限公司 | Atomizing type stain removal leather lustering agent and preparation method thereof |
-
2013
- 2013-06-25 CN CN2013102540847A patent/CN103320019A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1438363B1 (en) * | 2001-10-22 | 2013-03-13 | S. C. Johnson & Son, Inc. | Furniture polish composition |
| US20040087667A1 (en) * | 2002-11-06 | 2004-05-06 | Mercurio Anthony Fred | Aerosol delivery systems |
| CN101606745A (en) * | 2009-06-26 | 2009-12-23 | 广东省微生物研究所 | Composite biological preservative and its production and application |
| CN102352189A (en) * | 2011-08-03 | 2012-02-15 | 罗程耀 | Shoe polishing brightener |
| CN103013349A (en) * | 2012-12-14 | 2013-04-03 | 吴江市利达上光制品有限公司 | Atomizing type stain removal leather lustering agent and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 印度SBP技术咨询委员会: "《工业蜡及其配方》", 31 March 1988, article "鞋油用蜡", pages: 50-100 * |
| 王志明: "《精细化学品配方1000例》", 30 September 2001, article "鞋油", pages: 81 * |
| 胡国华: "《复合食品添加剂》", 30 November 2012, article "聚赖氨酸复合" * |
| 顾学斌，等: "《抗菌防霉技术手册》", 31 October 2011, article "聚赖氨酸" * |
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Application publication date: 20130925 |