CN103319807A - Reinforced modifier for PVC (Poly Vinyl Chloride) waterproof rolling material - Google Patents

Reinforced modifier for PVC (Poly Vinyl Chloride) waterproof rolling material Download PDF

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Publication number
CN103319807A
CN103319807A CN2013102457799A CN201310245779A CN103319807A CN 103319807 A CN103319807 A CN 103319807A CN 2013102457799 A CN2013102457799 A CN 2013102457799A CN 201310245779 A CN201310245779 A CN 201310245779A CN 103319807 A CN103319807 A CN 103319807A
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CN
China
Prior art keywords
reinforced modifier
rolling material
pvc
modifier
pvc waterproof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013102457799A
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Chinese (zh)
Inventor
邓丽
邓军
邓忠权
陈绪煌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhong Plastic Union New Material Technology Hubei Co Ltd
Original Assignee
Zhong Plastic Union New Material Technology Hubei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhong Plastic Union New Material Technology Hubei Co Ltd filed Critical Zhong Plastic Union New Material Technology Hubei Co Ltd
Priority to CN2013102457799A priority Critical patent/CN103319807A/en
Publication of CN103319807A publication Critical patent/CN103319807A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a reinforced modifier for a PVC (Poly Vinyl Chloride) waterproof rolling material. The reinforced modifier comprises the following components in parts by weight: 2 to 3 parts of chlorcosane, 0.2 to 0.3 part of antioxidant, 2 to 3 parts of rubber-plastic modifier, 2 to 3 parts of tribasic lead sulfate and 1 to 2 parts of dibasic lead phosphite. A preparation process of the reinforced modifier comprises the following steps of: compounding, mixing, stirring, heating, cooling, discharging and packaging the components. The reinforced modifier has the characteristics of being novel in conception, standard in process, simple and convenient to operate, low in cost, free of pollution and the like. When applied to the PVC waterproof rolling material, the reinforced modifier has the beneficial effects that the brittleness of the PVC waterproof rolling material is decreased, the toughness and the strength of the PVC waterproof rolling material are improved, the product quality is improved, the production cost is lowered, the reinforced modifier can be produced in batch and the like. The reinforced modifier can be widely applied to the fields of PVC waterproof rolling material processing and the like.

Description

The reinforced modifier that is used for PVC waterproof roll
Technical field
The present invention relates to a kind of reinforced modifier of plastics, particularly relate to a kind of reinforced modifier for PVC waterproof roll.
Background technology
Up to now, the auxiliary materials such as the PVC waterproof roll fragility of producing with existing method is large, easily rhegma, second-rate, and interpolation chlorinatedpolyethylene are more, cause high expensive, are difficult to adapt to the demand in market.How to reduce cost, improve quality, become problem puzzled in the waterproof roll production industry always.
Summary of the invention
The objective of the invention is in order to overcome the deficiency of above-mentioned background technology, develop a kind of new modified additive as auxiliary material, in order to reduce the fragility of waterproof roll, improve toughness and intensity, and a kind of reinforced modifier for PVC waterproof roll is provided.
To achieve these goals, the technical scheme of the reinforced modifier for PVC waterproof roll of the present invention is such:
Reinforced modifier of the present invention comprises following component and weight part: clorafin 2~3; Oxidation inhibitor 0.2~0.3; Rubber plastic modified agent 2~3; Tribasic lead sulfate 2~3; Dibasic lead phosphite 1~2.
Described reinforced modifier comprises following component and weight part: clorafin 2.2~2.9; Oxidation inhibitor 0.22~0.28; Rubber plastic modified agent 2.1~2.8; Tribasic lead sulfate 2.2~2.9; Dibasic lead phosphite 1.2~1.8.
Described reinforced modifier comprises following component and weight part: clorafin 2.6; Oxidation inhibitor 0.25; Rubber plastic modified agent 2.5; Tribasic lead sulfate 2.6; Dibasic lead phosphite 1.5.
Described rubber plastic modified agent is to be composited by ethene ethyl acetate and vinyl chloride copolymer and Aluminate coupling agent, and its proportioning is: ethene ethyl acetate and vinyl chloride copolymer: Aluminate coupling agent=1.5~2.5:0.05~0.1.
The proportioning of described rubber plastic modified agent is: ethene ethyl acetate and vinyl chloride copolymer: Aluminate coupling agent=2:0.08.
The reinforced modifier that is used for PVC waterproof roll that the present invention is alleged, have following beneficial effect: reasonable idea, technological specification, making are simple, cheap, non-environmental-pollution: be used for that PVC waterproof roll processing can reduce fragility, improves intensity, the advantage such as reduce production costs, can form very soon industrialized mass production.The present invention can be widely used in the PVC waterproof roll processing industry.
Embodiment
The present invention is described in further detail below in conjunction with embodiment, but this embodiment should not be construed as limitation of the present invention.
Embodiment 1
Reinforced modifier of the present invention is joined by following processing sequence system:
One, the preparation of each component of reinforced modifier and weight part
1, the preparation of rubber plastic modified agent:
Get ethene ethyl acetate and vinyl chloride copolymer 1.5 by described rubber plastic modified agent proportioning, Aluminate coupling agent 0.05 is inserted in the agitator together, stirs under normal temperature condition, gets final product discharging, for subsequent use after stirring.
2, the preparation of described each component and weight part:
Get clorafin 2; Oxidation inhibitor 0.2; Rubber plastic modified agent 2; Tribasic lead sulfate 2; Dibasic lead phosphite 1, for subsequent use.
Two. the preparation of described reinforced modifier:
1, batch mixing: above-mentioned each ingredients weight parts for preparing is mixed, drop into together mixing and stirring in the kneader, heating to 135 ℃~140 ℃ can stop to heat, for subsequent use;
2, discharging is packed: can discharging packing, i.e. finished product---described reinforced modifier packing after the above-mentioned batch mixing that processes is cooled to normal temperature.
Embodiment 2
The present embodiment is substantially the same manner as Example 1, and its difference is:
The preparation of each component auxiliary agent of reinforced modifier and weight part:
1, auxiliary agent rubber plastic modified agent preparation:
Get ethene ethyl acetate and vinyl chloride copolymer 2 by described rubber plastic modified agent proportioning, Aluminate coupling agent 0.08 is inserted in the agitator together, stirs under normal temperature condition, gets final product discharging, for subsequent use after stirring.
2, the preparation of described each component and weight part:
Get clorafin 2.2; Oxidation inhibitor 0.22; Rubber plastic modified agent 2.1; Tribasic lead sulfate 2.2; Dibasic lead phosphite 1.2, for subsequent use.
Embodiment 3
The present embodiment is substantially the same manner as Example 1, and its difference is:
The preparation of each component auxiliary agent of reinforced modifier and weight part:
1, auxiliary agent rubber plastic modified agent preparation:
Get ethene ethyl acetate and vinyl chloride copolymer 2.5 by described rubber plastic modified agent proportioning, Aluminate coupling agent 0.1 is inserted in the agitator together, stirs under normal temperature condition, gets final product discharging, for subsequent use after stirring.
2, the preparation of described each component and weight part:
Get clorafin 2.6; Oxidation inhibitor 0.25; Rubber plastic modified agent 2.5; Tribasic lead sulfate 2.6; Dibasic lead phosphite 1.5, for subsequent use.
Embodiment 4
The present embodiment is substantially the same manner as Example 1, and its difference is:
The preparation of each component auxiliary agent of reinforced modifier and weight part:
1, auxiliary agent rubber plastic modified agent preparation:
Get ethene ethyl acetate and vinyl chloride copolymer 2.5 by described rubber plastic modified agent proportioning, Aluminate coupling agent 0.1 is inserted in the agitator together, stirs under normal temperature condition, gets final product discharging, for subsequent use after stirring.
2, the preparation of described each component and weight part:
Get clorafin 2.9; Oxidation inhibitor 0.28; Rubber plastic modified agent 2.8; Tribasic lead sulfate 2.9; Dibasic lead phosphite 1.8, for subsequent use.
Embodiment 5
The present embodiment is substantially the same manner as Example 1, and its difference is:
The preparation of each component auxiliary agent of reinforced modifier and weight part:
1, auxiliary agent rubber plastic modified agent preparation:
Get ethene ethyl acetate and vinyl chloride copolymer 2.5 by described rubber plastic modified agent proportioning, Aluminate coupling agent 0.1 is inserted in the agitator together, stirs under normal temperature condition, gets final product discharging, for subsequent use after stirring.
2, the preparation of described each component and weight part:
Get clorafin 3; Oxidation inhibitor 0.3; Rubber plastic modified agent 3; Tribasic lead sulfate 3; Dibasic lead phosphite 2, for subsequent use.
Obviously, those skilled in the art can carry out various changes and modification to the present invention and not break away from the spirit and scope of the present invention.Like this, if of the present invention these are revised and modification belongs within the scope of claim of the present invention and equivalent technologies thereof, then the present invention also is intended to comprise these changes and modification interior.
The content that is not described in detail in this specification sheets belongs to the known prior art of this area professional and technical personnel.

Claims (5)

1. reinforced modifier that is used for PVC waterproof roll, it is characterized in that: described reinforced modifier comprises following component and weight part:
Clorafin 2~3; Oxidation inhibitor 0.2~0.3; Rubber plastic modified agent 2~3; Tribasic lead sulfate 2~3; Dibasic lead phosphite 1~2.
2. the reinforced modifier for PVC waterproof roll according to claim 1, it is characterized in that: described reinforced modifier comprises following component and weight part:
Clorafin 2.2~2.9; Oxidation inhibitor 0.22~0.28; Rubber plastic modified agent 2.1~2.8; Tribasic lead sulfate 2.2~2.9; Dibasic lead phosphite 1.2~1.8.
3. the reinforced modifier for PVC waterproof roll according to claim 1, it is characterized in that: described reinforced modifier comprises following component and weight part:
Clorafin 2.6; Oxidation inhibitor 0.25; Rubber plastic modified agent 2.5; Tribasic lead sulfate 2.6; Dibasic lead phosphite 1.5.
4. the described reinforced modifier for PVC waterproof roll of arbitrary claim in 3 according to claim 1, it is characterized in that: described rubber plastic modified agent is to be composited by ethene ethyl acetate and vinyl chloride copolymer and Aluminate coupling agent, and its proportioning is: ethene ethyl acetate and vinyl chloride copolymer: Aluminate coupling agent=1.5~2.5:0.05~0.1.
5. the reinforced modifier for PVC waterproof roll according to claim 4, it is characterized in that: described proportioning is ethene ethyl acetate and vinyl chloride copolymer: Aluminate coupling agent=2:0.08.
CN2013102457799A 2013-06-20 2013-06-20 Reinforced modifier for PVC (Poly Vinyl Chloride) waterproof rolling material Pending CN103319807A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013102457799A CN103319807A (en) 2013-06-20 2013-06-20 Reinforced modifier for PVC (Poly Vinyl Chloride) waterproof rolling material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013102457799A CN103319807A (en) 2013-06-20 2013-06-20 Reinforced modifier for PVC (Poly Vinyl Chloride) waterproof rolling material

Publications (1)

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CN103319807A true CN103319807A (en) 2013-09-25

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103524947A (en) * 2013-10-23 2014-01-22 潍坊市晨鸣新型防水材料有限公司 Reinforced root resistant waterproof roll and production process thereof
CN105128371A (en) * 2015-09-15 2015-12-09 安庆越球建筑防水材料有限公司 Process for manufacturing roof waterproof coiled material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336983A (en) * 2011-05-27 2012-02-01 湖北众联塑业有限公司 Processing modifier for polyvinyl chloride waterproof coiled material
CN102719035A (en) * 2012-06-15 2012-10-10 中塑联新材料科技湖北有限公司 Special reinforcing composite calcium carbonate for polyvinyl chloride pipes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336983A (en) * 2011-05-27 2012-02-01 湖北众联塑业有限公司 Processing modifier for polyvinyl chloride waterproof coiled material
CN102719035A (en) * 2012-06-15 2012-10-10 中塑联新材料科技湖北有限公司 Special reinforcing composite calcium carbonate for polyvinyl chloride pipes

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
山西省化工研究所 编: "《塑料橡胶加工助剂》", 31 October 2002, 化学工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103524947A (en) * 2013-10-23 2014-01-22 潍坊市晨鸣新型防水材料有限公司 Reinforced root resistant waterproof roll and production process thereof
CN103524947B (en) * 2013-10-23 2015-07-29 潍坊市晨鸣新型防水材料有限公司 A kind of enhancement type root resistant waterproof roll and production technique thereof
CN105128371A (en) * 2015-09-15 2015-12-09 安庆越球建筑防水材料有限公司 Process for manufacturing roof waterproof coiled material

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Application publication date: 20130925