CN103304954A - Polyoxymethylene plastic plate - Google Patents
Polyoxymethylene plastic plate Download PDFInfo
- Publication number
- CN103304954A CN103304954A CN2013101710130A CN201310171013A CN103304954A CN 103304954 A CN103304954 A CN 103304954A CN 2013101710130 A CN2013101710130 A CN 2013101710130A CN 201310171013 A CN201310171013 A CN 201310171013A CN 103304954 A CN103304954 A CN 103304954A
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- CN
- China
- Prior art keywords
- accounts
- agent
- plastic plate
- high temperature
- acetal plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920006324 polyoxymethylene Polymers 0.000 title abstract 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 68
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 8
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims abstract description 8
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical group C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 claims abstract description 4
- 239000004642 Polyimide Substances 0.000 claims abstract description 4
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001721 polyimide Polymers 0.000 claims abstract description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical group N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004033 plastic Substances 0.000 claims description 39
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 37
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 6
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical group OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 6
- 229950002083 octabenzone Drugs 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000003431 cross linking reagent Substances 0.000 abstract 3
- 239000000945 filler Substances 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- LEVJVKGPFAQPOI-UHFFFAOYSA-N phenylmethanone Chemical compound O=[C]C1=CC=CC=C1 LEVJVKGPFAQPOI-UHFFFAOYSA-N 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 description 11
- 230000003245 working effect Effects 0.000 description 3
- 230000009970 fire resistant effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a polyoxymethylene plastic plate. The polyoxymethylene plastic plate comprises polyoxymethylene plastic and additives, wherein the additives comprise an antioxidant, a weather resistant agent, a crosslinking agent, a wear resistant agent, a high temperature resistant agent and a filling agent, the antioxidant is triphenyl phosphite, the weather resistant agent is [2-4-hydroxy-(octyloxy)phenyl]phenyl-methanone, the crosslinking agent is hexahydrophthalic anhydride, the wear resistant agent is silicon nitride, the high temperature resistant agent is polyimide, and the filling agent is talcum powder. A modified polyoxymethylene plastic plate product is all improved in high temperature resistance, oxidation resistance and weather resistance, so that the polyoxymethylene plastic plate has less possibility of being eroded in a use process, and is prolonged in service life; in addition, the crosslinking agent can be used for promoting the product production in a production process, so that the mechanical strength and wear resistance of the polyoxymethylene plastic plate are both improved.
Description
Technical field
The present invention relates to a kind of finishing material, be specifically related to a kind of acetal plastic plate.
Background technology
In use heat-proof aging and resistance to weathering are relatively poor for existing acetal plastic on the Vehicles Collected from Market, so that all greatly reduce the work-ing life of product, simultaneously because difficulty relatively during melt-processed, cause the wear resistance of subsequent product, physical strength all relatively poor, can't produce on a large scale.
Summary of the invention
The object of the present invention is to provide a kind of anti-oxidant, high temperature resistant, acetal plastic plate that weather burn into physical strength is high.
Technical scheme of the present invention is, a kind of acetal plastic plate, comprise acetal plastic and additive, described additive comprises antioxidant, weather resisting agent, linking agent, anti-wear agent, high temperature resistant dose and weighting agent, and described antioxidant is triphenyl phosphite, and described weather resisting agent is Octabenzone, described linking agent is hexahydrophthalic anhydride, described anti-wear agent is silicon nitride, and described high temperature resistant dose is polyimide, and described weighting agent is talcum powder.
In a preferred embodiment of the present invention, the weight proportion scope of each composition is that described acetal plastic accounts for 74%-81% in the described acetal plastic plate, described antioxidant accounts for 2.6%-3.2%, described weather resisting agent accounts for 1.8%-2.5%, described linking agent accounts for 3.3%-4.1%, described anti-wear agent accounts for 2.8%-3.7%, and described high temperature resistant dose accounts for 2.1%-2.8%, and described weighting agent accounts for 6.4%-9.7%.
In a preferred embodiment of the present invention, the concrete weight proportion of each composition is that described acetal plastic accounts for 78.3% in the described acetal plastic plate, described antioxidant accounts for 3%, described weather resisting agent accounts for 2.3%, described linking agent accounts for 3.8%, described anti-wear agent accounts for 3.5%, and described high temperature resistant dose accounts for 2.6%, and described weighting agent accounts for 6.5%.
In a preferred embodiment of the present invention, the concrete weight proportion of each composition is that described acetal plastic accounts for 76.7% in the described acetal plastic plate, described antioxidant accounts for 2.8%, described weather resisting agent accounts for 2.1%, described linking agent accounts for 3.5%, described anti-wear agent accounts for 3.1%, and described high temperature resistant dose accounts for 2.2%, and described weighting agent accounts for 9.6%.
Of the present invention is a kind of acetal plastic plate, after this acetal plastic plate modification so that fire-resistant oxidation resistant performance and the weather-resistant property of product itself be improved, so that the acetal plastic plate in use is not easy to be corroded, greatly increase work-ing life, in addition, linking agent can promote the production of product in process of production, so that the physical strength of acetal plastic plate, wear resisting property all get a promotion.
Embodiment
The below is described in detail preferred embodiment of the present invention, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
Of the present invention is a kind of acetal plastic plate, comprise acetal plastic and additive, described additive comprises antioxidant, weather resisting agent, linking agent, anti-wear agent, high temperature resistant dose and weighting agent, described antioxidant is triphenyl phosphite, described weather resisting agent is Octabenzone, and described linking agent is hexahydrophthalic anhydride, and described anti-wear agent is silicon nitride, described high temperature resistant dose is polyimide, and described weighting agent is talcum powder.
Further, the weight proportion scope of each composition is that described acetal plastic accounts for 74%-81% in the described acetal plastic plate, described antioxidant accounts for 2.6%-3.2%, described weather resisting agent accounts for 1.8%-2.5%, described linking agent accounts for 3.3%-4.1%, described anti-wear agent accounts for 2.8%-3.7%, and described high temperature resistant dose accounts for 2.1%-2.8%, and described weighting agent accounts for 6.4%-9.7%.
Further, the concrete weight proportion of each composition is that described acetal plastic accounts for 78.3% in the described acetal plastic plate, described antioxidant accounts for 3%, described weather resisting agent accounts for 2.3%, described linking agent accounts for 3.8%, described anti-wear agent accounts for 3.5%, and described high temperature resistant dose accounts for 2.6%, and described weighting agent accounts for 6.5%.
Further, the concrete weight proportion of each composition is that described acetal plastic accounts for 76.7% in the described acetal plastic plate, described antioxidant accounts for 2.8%, described weather resisting agent accounts for 2.1%, described linking agent accounts for 3.5%, described anti-wear agent accounts for 3.1%, and described high temperature resistant dose accounts for 2.2%, and described weighting agent accounts for 9.6%.
Of the present invention is a kind of acetal plastic plate, after this acetal plastic plate modification so that fire-resistant oxidation resistant performance and the weather-resistant property of product itself be improved, so that the acetal plastic plate in use is not easy to be corroded, greatly increase work-ing life, in addition, linking agent can promote the production of product in process of production, so that the physical strength of acetal plastic plate, wear resisting property all get a promotion.
The above only is the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (4)
1. acetal plastic plate, it is characterized in that: comprise acetal plastic and additive, described additive comprises antioxidant, weather resisting agent, linking agent, anti-wear agent, high temperature resistant dose and weighting agent, described antioxidant is triphenyl phosphite, described weather resisting agent is Octabenzone, and described linking agent is hexahydrophthalic anhydride, and described anti-wear agent is silicon nitride, described high temperature resistant dose is polyimide, and described weighting agent is talcum powder.
2. acetal plastic plate according to claim 1, it is characterized in that: the weight proportion scope of each composition is that described acetal plastic accounts for 74%-81% in the described acetal plastic plate, described antioxidant accounts for 2.6%-3.2%, described weather resisting agent accounts for 1.8%-2.5%, described linking agent accounts for 3.3%-4.1%, described anti-wear agent accounts for 2.8%-3.7%, and described high temperature resistant dose accounts for 2.1%-2.8%, and described weighting agent accounts for 6.4%-9.7%.
3. enhancing AS plastic plate according to claim 2, it is characterized in that: the concrete weight proportion of each composition is that described acetal plastic accounts for 78.3% in the described acetal plastic plate, described antioxidant accounts for 3%, described weather resisting agent accounts for 2.3%, described linking agent accounts for 3.8%, described anti-wear agent accounts for 3.5%, and described high temperature resistant dose accounts for 2.6%, and described weighting agent accounts for 6.5%.
4. enhancing AS plastic plate according to claim 2, it is characterized in that: the concrete weight proportion of each composition is that described acetal plastic accounts for 76.7% in the described acetal plastic plate, described antioxidant accounts for 2.8%, described weather resisting agent accounts for 2.1%, described linking agent accounts for 3.5%, described anti-wear agent accounts for 3.1%, and described high temperature resistant dose accounts for 2.2%, and described weighting agent accounts for 9.6%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310171013.0A CN103304954B (en) | 2013-05-10 | 2013-05-10 | Polyoxymethylene plastic plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310171013.0A CN103304954B (en) | 2013-05-10 | 2013-05-10 | Polyoxymethylene plastic plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103304954A true CN103304954A (en) | 2013-09-18 |
| CN103304954B CN103304954B (en) | 2014-11-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310171013.0A Expired - Fee Related CN103304954B (en) | 2013-05-10 | 2013-05-10 | Polyoxymethylene plastic plate |
Country Status (1)
| Country | Link |
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| CN (1) | CN103304954B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709597A (en) * | 2013-12-24 | 2014-04-09 | 苏州华东橡胶工业有限公司 | Formula of modified urea-formaldehyde resin |
| CN103709600A (en) * | 2013-12-26 | 2014-04-09 | 苏州市涵信塑业有限公司 | Modified melamine formaldehyde resin composition |
| CN103709598A (en) * | 2013-12-26 | 2014-04-09 | 苏州市涵信塑业有限公司 | Modified urea-formaldehyde resin composition |
| CN108638598A (en) * | 2018-04-10 | 2018-10-12 | 安徽宏志建材科技有限公司 | The preparation method of high-ductility high wear resistance composite board |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995130A (en) * | 2006-12-28 | 2007-07-11 | 深圳市科聚新材料有限公司 | Halogen-free environment-friendly flame-proof polyoxymethylene resin and its preparation method |
| CN101619155A (en) * | 2009-08-07 | 2010-01-06 | 苏州工业园区富事达塑业有限责任公司（苏州塑料一厂） | Wear-resistant and heat-resistant acetal resin |
| CN103044852A (en) * | 2013-01-18 | 2013-04-17 | 云南云天化股份有限公司 | Polyacetal resin composition |
-
2013
- 2013-05-10 CN CN201310171013.0A patent/CN103304954B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995130A (en) * | 2006-12-28 | 2007-07-11 | 深圳市科聚新材料有限公司 | Halogen-free environment-friendly flame-proof polyoxymethylene resin and its preparation method |
| CN101619155A (en) * | 2009-08-07 | 2010-01-06 | 苏州工业园区富事达塑业有限责任公司（苏州塑料一厂） | Wear-resistant and heat-resistant acetal resin |
| CN103044852A (en) * | 2013-01-18 | 2013-04-17 | 云南云天化股份有限公司 | Polyacetal resin composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709597A (en) * | 2013-12-24 | 2014-04-09 | 苏州华东橡胶工业有限公司 | Formula of modified urea-formaldehyde resin |
| CN103709600A (en) * | 2013-12-26 | 2014-04-09 | 苏州市涵信塑业有限公司 | Modified melamine formaldehyde resin composition |
| CN103709598A (en) * | 2013-12-26 | 2014-04-09 | 苏州市涵信塑业有限公司 | Modified urea-formaldehyde resin composition |
| CN103709598B (en) * | 2013-12-26 | 2015-09-16 | 太仓市天合新材料科技有限公司 | A kind of formula of modified urea-formaldehyde resin |
| CN108638598A (en) * | 2018-04-10 | 2018-10-12 | 安徽宏志建材科技有限公司 | The preparation method of high-ductility high wear resistance composite board |
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| Publication number | Publication date |
|---|---|
| CN103304954B (en) | 2014-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: TAICANG TIANHE NEW MATERIAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SUZHOU INDUSTRIAL PARK FANGYUAN METAL PRODUCTS CO., LTD. Effective date: 20141008 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 215000 SUZHOU, JIANGSU PROVINCE TO: 215400 SUZHOU, JIANGSU PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20141008 Address after: 215400 Suzhou City, Taicang Province Economic Development Zone, Beijing West Road, No. 1, building 6, No. Applicant after: Taicang Tian He new material Science and Technology Ltd. Address before: 215000 Jiangsu Province, Suzhou City Industrial Park Tong Gong Village Applicant before: Suzhou Industrial Park Fangyuan Metal Products Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170824 Address after: 215000 Jiangsu Province, Suzhou City Industrial Park Tong Gong Village Patentee after: Suzhou Industrial Park Fangyuan Metal Products Co., Ltd. Address before: 215400 Suzhou City, Taicang Province Economic Development Zone, Beijing West Road, No. 1, building 6, No. Patentee before: Taicang Tian He new material Science and Technology Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141105 Termination date: 20170510 |