CN103304918A - PVC (Polyvinyl Chloride) sole material with high conductivity - Google Patents
PVC (Polyvinyl Chloride) sole material with high conductivity Download PDFInfo
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- CN103304918A CN103304918A CN2013102137998A CN201310213799A CN103304918A CN 103304918 A CN103304918 A CN 103304918A CN 2013102137998 A CN2013102137998 A CN 2013102137998A CN 201310213799 A CN201310213799 A CN 201310213799A CN 103304918 A CN103304918 A CN 103304918A
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- pvc
- sole
- shoe
- pvc material
- conduction performance
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Abstract
The invention discloses a PVC (Polyvinyl Chloride) sole material with high conductivity. The PVC sole material comprises the following components in percentage by weight: 60-70% of PVC, 1-3% of HSt, 1-3% of three salts, 10-30% of DOP (Dioctyl-Phthalate) and 10-15% of nanometer conductive fiber. The PVC sole material with high conductivity, disclosed by the invention, is high in electromagnetic shielding efficiency, low in electrical resistivity, strong in conductivity, free of influence from temperature and humidity and capable of effectively releasing static electricity and guiding the static electricity from a human body to the ground, thus the static electricity is eliminated; and meanwhile, dust generated when a person walks in a dust free room is also effectively inhibited, and the PVC sole material is suitable for all occasions with static hazards such as combustion, explosion and the like possibly caused by the static electricity carried by the human body.
Description
Technical field:
The present invention relates to a kind of footwear material technical field, relate in particular to the PVC material for sole of shoe.
Background technology:
The PVC material is large, the inexpensive commodity polymer material of a kind of output, can be widely used in chemical industry, coal, electronics, computer, cableless communication and shoe industry etc., yet PVC is isolator as material for sole of shoe, and normal conditions lower volume resistivity is 10
13Ω .cm, the tangent of the dielectric loss angle value is large, surface resistivity is high, in case be with static, just be difficult to eliminate, and easily adsorb dust, be difficult to clean, when static electric charge runs up to a certain degree, easily produce spark, can cause the place blasts on fire such as Chemicals storehouse, oil depot, colliery.So the preparation of conduction PVC material for sole of shoe becomes important trend and the direction of macromolecular material research and development.
Summary of the invention:
In order to overcome defects, the purpose of this invention is to provide a kind of PVC material for sole of shoe of high conduction performance.
Purpose of the present invention is achieved through the following technical solutions:
A kind of PVC material for sole of shoe with high conduction performance comprises following component by weight percentage:
Described PVC content is 60-65%.
Described HSt is a kind of stearic acid material.
Described three salt are tribasic lead sulfates, and chemical formula is 3PbOPbSO
4H
2O.。
Described DOP is dioctyl phthalate (DOP), and main raw material is Tetra hydro Phthalic anhydride and 2-Ethylhexyl Alcohol.
Described nano-conductive fiber is to be fibrous product by a kind of microscopic pattern that Products of Acetylene Polymerization Over Nano-cu Particles makes behind phase transition of vacuum.
The PVC sole electromagnetic shielding efficiency that nano-conductive fiber provided by the invention is made is high, resistivity is little, electroconductibility is strong, and be not subjected to the impact of temperature and humidity, effective release electrostatic, with static from the human body the earth that leads, thereby eliminate static, also effectively suppressed simultaneously the dust that personnel walk about and produce in dust free chamber.Be applicable to prevent that there is the place (such as the operation place of the industries such as oil, chemical industry, colliery, printing, rubber, medical treatment, purification, electronics) of static hazard in all because human body may cause burning, blast etc. with static.
Embodiment:
In order to deepen the understanding of the present invention, the invention will be further described below in conjunction with embodiment, and this embodiment only is used for explaining the present invention, does not consist of the restriction to protection domain of the present invention.
Embodiment 1:
Take by weighing PVC material 65g, HSt 2g, three salt 2g, DOP 20g rises to 150-170 ℃ with two roll temperatures of mill, puts into kneaded PVC, adds nano-conductive fiber 11g and HSt, three salt and DOP behind the bag roller, turns refining, and descends sheet after thin-pass 10-15 time.Use the dull and stereotyped combization machine of 25t to carry out compressing tablet, hot pressing temperature 160-180 ℃, 10-15min colds pressing behind the hot pressing 8-10min.
Embodiment 2:
Take by weighing PVC material 65g, HSt 1g, three salt 1g, DOP 20g rises to 150-170 ℃ with two roll temperatures of mill, puts into kneaded PVC, adds nano-conductive fiber 13g and HSt, three salt and DOP behind the bag roller, turns refining, and descends sheet after thin-pass 10-15 time.Use the dull and stereotyped combization machine of 25t to carry out compressing tablet, hot pressing temperature 160-180 ℃, 10-15min colds pressing behind the hot pressing 8-10min.
Embodiment 3:
Take by weighing PVC material 70g, HSt 3g, three salt 3g, DOP 10g rises to 150-170 ℃ with two roll temperatures of mill, puts into kneaded PVC, adds nano-conductive fiber 14g and HSt, three salt and DOP behind the bag roller, turns refining, and descends sheet after thin-pass 10-15 time.Use the dull and stereotyped combization machine of 25t to carry out compressing tablet, hot pressing temperature 160-180 ℃, 10-15min colds pressing behind the hot pressing 8-10min.
Embodiment 4:
Take by weighing PVC material 70g, HSt 2g, three salt 3g, DOP 10g rises to 150-170 ℃ with two roll temperatures of mill, puts into kneaded PVC, adds nano-conductive fiber 15g and HSt, three salt and DOP behind the bag roller, turns refining, and descends sheet after thin-pass 10-15 time.Use the dull and stereotyped combization machine of 25t to carry out compressing tablet, hot pressing temperature 160-180 ℃, 10-15min colds pressing behind the hot pressing 8-10min.
Claims (6)
1. PVC material for sole of shoe with high conduction performance is characterized in that: comprise by weight percentage following component:
2. a kind of PVC material for sole of shoe with high conduction performance according to claim 1, it is characterized in that: described PVC content is 60-65%.
3. a kind of PVC material for sole of shoe with high conduction performance according to claim 1, it is characterized in that: described HSt is a kind of stearic acid material.
4. a kind of PVC material for sole of shoe with high conduction performance according to claim 1, it is characterized in that: described three salt are tribasic lead sulfates, chemical formula is 3PbOPbSO
4H
2O.
5. a kind of PVC material for sole of shoe with high conduction performance according to claim 1, it is characterized in that: described DOP is dioctyl phthalate (DOP), main raw material is Tetra hydro Phthalic anhydride and 2-Ethylhexyl Alcohol.
6. a kind of PVC material for sole of shoe with high conduction performance according to claim 1 is characterized in that: described nano-conductive fiber is to be fibrous product by a kind of microscopic pattern that Products of Acetylene Polymerization Over Nano-cu Particles makes behind phase transition of vacuum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102137998A CN103304918A (en) | 2013-05-31 | 2013-05-31 | PVC (Polyvinyl Chloride) sole material with high conductivity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102137998A CN103304918A (en) | 2013-05-31 | 2013-05-31 | PVC (Polyvinyl Chloride) sole material with high conductivity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103304918A true CN103304918A (en) | 2013-09-18 |
Family
ID=49130661
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102137998A Pending CN103304918A (en) | 2013-05-31 | 2013-05-31 | PVC (Polyvinyl Chloride) sole material with high conductivity |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103304918A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670162A (en) * | 2016-01-20 | 2016-06-15 | 苏州市景荣科技有限公司 | Preparation method of high-toughness antistatic PVC (polyvinyl chloride) composite sole material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088228A (en) * | 1992-12-17 | 1994-06-22 | 莱阳市塑料一厂 | Method for making high-polymerization degree modified polyvinyl-chloride shoe material |
| JP2005048062A (en) * | 2003-07-29 | 2005-02-24 | Nippon Chem Ind Co Ltd | Stabilizer composition for chlorine-containing resin and chlorine-containing resin composition |
| CN101397387A (en) * | 2008-10-16 | 2009-04-01 | 韩燕� | Method for manufacturing coiled material floor for computer room |
| JP2012146430A (en) * | 2011-01-11 | 2012-08-02 | Innovation & Infinity Global Corp | Transparent conductive structure utilizing mixed nanoparticle and method for producing the same |
-
2013
- 2013-05-31 CN CN2013102137998A patent/CN103304918A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088228A (en) * | 1992-12-17 | 1994-06-22 | 莱阳市塑料一厂 | Method for making high-polymerization degree modified polyvinyl-chloride shoe material |
| JP2005048062A (en) * | 2003-07-29 | 2005-02-24 | Nippon Chem Ind Co Ltd | Stabilizer composition for chlorine-containing resin and chlorine-containing resin composition |
| CN101397387A (en) * | 2008-10-16 | 2009-04-01 | 韩燕� | Method for manufacturing coiled material floor for computer room |
| JP2012146430A (en) * | 2011-01-11 | 2012-08-02 | Innovation & Infinity Global Corp | Transparent conductive structure utilizing mixed nanoparticle and method for producing the same |
Non-Patent Citations (1)
| Title |
|---|
| 陈克正等: "纳米导电纤维与导电炭黑填充PVC复合材料的电性能研究", 《高分子材料科学与工程》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670162A (en) * | 2016-01-20 | 2016-06-15 | 苏州市景荣科技有限公司 | Preparation method of high-toughness antistatic PVC (polyvinyl chloride) composite sole material |
| CN105670162B (en) * | 2016-01-20 | 2018-05-11 | 林家豪 | A kind of preparation method of high tenacity anti-static PVC composite sole material |
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Application publication date: 20130918 |