CN103304917A - Synthetic resin granule material for liner of fire hose and preparation method of synthetic resin granule material - Google Patents

Synthetic resin granule material for liner of fire hose and preparation method of synthetic resin granule material Download PDF

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Publication number
CN103304917A
CN103304917A CN2013101999155A CN201310199915A CN103304917A CN 103304917 A CN103304917 A CN 103304917A CN 2013101999155 A CN2013101999155 A CN 2013101999155A CN 201310199915 A CN201310199915 A CN 201310199915A CN 103304917 A CN103304917 A CN 103304917A
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CN
China
Prior art keywords
fire hose
synthetic resin
granule material
districts
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013101999155A
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Chinese (zh)
Inventor
肖金涛
王圣宏
王小峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAIZHOU DONGFANG HOSE Co Ltd
Original Assignee
TAIZHOU DONGFANG HOSE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAIZHOU DONGFANG HOSE Co Ltd filed Critical TAIZHOU DONGFANG HOSE Co Ltd
Priority to CN2013101999155A priority Critical patent/CN103304917A/en
Publication of CN103304917A publication Critical patent/CN103304917A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04Particle-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/78Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/875Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885Screw or gear
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention discloses a synthetic resin granule material for a liner of a fire hose. The synthetic resin granule material comprises the following components in percentage by mass: PVC (Poly Vinyl Chloride) resin, light calcium carbonate, dioctyl phthalate, dibutyl phthalate, a composite stabilizer and adipic acid pentaerythritol ester. The invention also discloses a preparation method for realizing the synthetic resin for the liner of the fire hose. The synthetic resin granule material disclosed by the invention has the advantages of reasonability in component and appropriateness in proportion and the preparation method is simple and convenient; and the liner, which is manufactured from the synthetic resin granule material, of the fire hose has the advantages of high tensile strength, good flexibility, high corrosion resistant capacity and low production cost. The synthetic resin granule material disclosed by the invention is suitable for manufacturing the liners of the fire hose and an agricultural water delivery hose which are used for various occasions.

Description

Fire hose lining synthetic resins pellet and preparation method
Technical field
The present invention relates to a kind of synthetic resins pellet and preparation method, specifically, the present invention relates to a kind of fire hose lining synthetic resins pellet and preparation method.
Background technology
Fire hose is a kind of flexible duct of pressure-bearing, and it is made up of outer layer fiber braiding pipe racks and inner liner fit.The lining of commodity fire hose all is rubber materials on the market, and current rubber tube-making process is very ripe, easily reaches the supporting requirement of fire hose lining.But usefulness rubber material manufacturing liner thickness is thick relatively, weight is big, adds rubber raw materials price height, causes production cost high.
Summary of the invention
The present invention is primarily aimed at the deficiency of the supporting rubber mass lining of fire hose, proposes a kind of fire hose lining synthetic resins pellet and preparation method, and it is simple to make lining technology with this pellet, and bearing capacity is strong, flexible foot, and production cost is low.
The present invention is achieved through the following technical solutions technical object.
Fire hose lining synthetic resins pellet, its improvements are that the component that it is measured by mass percentage comprises: polyvinyl chloride resin 30%~32%, light calcium carbonate 36%~40%, o-phthalic acid dibutyl ester 14.5%~16%, dibutyl phthalate (DBP) 12.5%~14%, one package stabilizer 1.6%~2.5% and hexanodioic acid pentaerythritol ester 0.5%~0.7%.The present invention also comprises the fire hose lining preparation method of synthetic resins pellet, and its improvements are to follow these steps to carry out:
Mixing will be put in the high mixer in the lump by the raw material of proportioning metering and mix, and mix at least 15 minutes under 50 ℃ ± 2 ℃ conditions;
Spreading for cooling is divided room temperature to be cooled in open container with compound;
Granulation is injected into compound in the screw extrusion press that has heated, and heating takes the subregion to heat in proper order, and the die head through screw extrusion press when compound is heated to 142 ℃ is extruded into bulk goods.
Polyvinyl chloride resin in the said components is suspension pvc resin, and the polymerization degree is 1300.
As further improvement project, it is the heating of axial subregion from the charging opening of screw extrusion press inner chamber to die head that described subregion heats in proper order, concrete regional Heating temperature: 142 ℃ ± 1 ℃ of 125 ℃ in a district, 125 ℃ in two districts, 130 ℃ in three districts, 130 ℃ in four districts, 135 ℃ in five districts, 140 ℃ in six districts and die head.
The present invention compared with prior art has following positively effect:
1, the component wide material sources are with low cost, and manufacturing process is simple;
2, the lining intensity height of plastic material, withstand voltage, anti-corrosion, difficult be full of cracks;
3, the plastic material flexibility is good, and the fire hose of making is convenient to the collection of reeling.
Embodiment
Further specify the present invention below by embodiment.
The present invention is a kind of fire hose lining synthetic resins pellet, and the component that it is measured by mass percentage comprises: polyvinyl chloride resin 30%~32%, light calcium carbonate 36%~40%, o-phthalic acid dibutyl ester 14.5%~16%, dibutyl phthalate (DBP) 12.5%~14%, one package stabilizer 1.6%~2.5% and hexanodioic acid pentaerythritol ester 0.5%~0.7%.The present invention also comprises the realization fire hose lining preparation method of synthetic resins pellet, and concrete operations follow these steps to carry out: mixing will be put in the high mixer in the lump by the raw material of proportioning metering and mix, and mix at least 15 minutes under 50 ℃ ± 2 ℃ conditions; Spreading for cooling is divided room temperature to be cooled in open container with compound; Granulation is injected into compound in the screw rod machine that has heated, heating takes the subregion to heat in proper order, namely axially divide 7 zone heating from the charging opening of screw extrusion press inner chamber to die head, 142 ℃ of 125 ℃ in a district, 125 ℃ in two districts, 130 ℃ in three districts, 130 ℃ in four districts, 135 ℃ in five districts, 140 ℃ in six districts and die heads.Die head through screw extrusion press when compound is heated to 142 ℃ ± 1 ℃ is extruded into bulk goods.
Embodiment 1~3
Embodiment below by three different proportionings further specifies the present invention, and concrete proportioning sees the following form one, and the salient features data see Table two.
Table one, proportioning
Figure 39074DEST_PATH_IMAGE001
Table two, synthetic resins pellet salient features data
Figure 144171DEST_PATH_IMAGE002
The synthetic resins pellet salient features data that state clearly from table two as can be known, the pellet the key technical indexes of above-mentioned three embodiment preparation all is better than the performance of general soft PVC, considerably beyond rubber.Component of the present invention is reasonable, and proportioning is appropriate, and the preparation method is easy, and for the manufacture of fire hose lining tensile strength height, flexible good, corrosion resistance is strong, and production cost is low.The present invention is suitable for making the fire hose of various occasions uses and the lining of agricultural Flexible water pipe.

Claims (4)

1. a fire hose lining synthetic resins pellet is characterized in that the component that it is measured by mass percentage comprises: polyvinyl chloride resin 30%~32%, light calcium carbonate 36%~40%, o-phthalic acid dibutyl ester 14.5%~16%, dibutyl phthalate (DBP) 12.5%~14%, one package stabilizer 1.6%~2.5% and hexanodioic acid pentaerythritol ester 0.5%~0.7%.
2. fire hose lining synthetic resins pellet according to claim 1, it is characterized in that: described polyvinyl chloride resin is suspension pvc resin, the polymerization degree is 1300.
3. realize the described fire hose lining of claim 1 preparation method of synthetic resins pellet for one kind, it is characterized in that: follow these steps to carry out:
Mix 3.1 mix to put in the high mixer in the lump by the raw material of proportioning metering, under 50 ℃ ± 2 ℃ conditions, mixed at least 15 minutes;
3.2 spreading for cooling is divided room temperature to be cooled in open container with compound;
3.3 granulation is injected into compound in the screw extrusion press that has heated, heating takes the subregion to heat in proper order, and the die head through screw extrusion press when compound is heated to 142 ℃ is extruded into bulk goods.
4. fire hose lining according to claim 3 is with the preparation method of synthetic resins pellet, it is characterized in that: it is the heating of axial subregion from the charging opening of screw extrusion press inner chamber to die head that described subregion heats in proper order, concrete regional Heating temperature: 142 ℃ ± 1 ℃ of 125 ℃ in a district, 125 ℃ in two districts, 130 ℃ in three districts, 130 ℃ in four districts, 135 ℃ in five districts, 140 ℃ in six districts and die head.
CN2013101999155A 2013-05-27 2013-05-27 Synthetic resin granule material for liner of fire hose and preparation method of synthetic resin granule material Pending CN103304917A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013101999155A CN103304917A (en) 2013-05-27 2013-05-27 Synthetic resin granule material for liner of fire hose and preparation method of synthetic resin granule material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013101999155A CN103304917A (en) 2013-05-27 2013-05-27 Synthetic resin granule material for liner of fire hose and preparation method of synthetic resin granule material

Publications (1)

Publication Number Publication Date
CN103304917A true CN103304917A (en) 2013-09-18

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101362846A (en) * 2007-08-09 2009-02-11 新疆天业(集团)有限公司 Nano material modified PVC water transfer hosetube
CN101531794A (en) * 2009-04-14 2009-09-16 漯河科莱堡洁具配件有限公司 Composite of nanometer grade calcium carbonate modified spiral winded PVC hose for sanitary ware and preparation method thereof
US20100292379A1 (en) * 2009-05-12 2010-11-18 Nan Ya Plastics Corporation PVC resin composition and products made of the same
CN102558713A (en) * 2011-12-30 2012-07-11 福建思嘉环保材料科技有限公司 Nanometer bi-layer film biogas digester material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101362846A (en) * 2007-08-09 2009-02-11 新疆天业(集团)有限公司 Nano material modified PVC water transfer hosetube
CN101531794A (en) * 2009-04-14 2009-09-16 漯河科莱堡洁具配件有限公司 Composite of nanometer grade calcium carbonate modified spiral winded PVC hose for sanitary ware and preparation method thereof
US20100292379A1 (en) * 2009-05-12 2010-11-18 Nan Ya Plastics Corporation PVC resin composition and products made of the same
CN102558713A (en) * 2011-12-30 2012-07-11 福建思嘉环保材料科技有限公司 Nanometer bi-layer film biogas digester material and preparation method thereof

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Application publication date: 20130918