CN103296106B - Solar module - Google Patents
Solar module Download PDFInfo
- Publication number
- CN103296106B CN103296106B CN201210326349.5A CN201210326349A CN103296106B CN 103296106 B CN103296106 B CN 103296106B CN 201210326349 A CN201210326349 A CN 201210326349A CN 103296106 B CN103296106 B CN 103296106B
- Authority
- CN
- China
- Prior art keywords
- busbar
- region
- electrode
- emitter
- open area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000758 substrate Substances 0.000 claims abstract description 132
- 239000002245 particle Substances 0.000 claims description 96
- 239000002313 adhesive film Substances 0.000 claims description 81
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 56
- 229910052709 silver Inorganic materials 0.000 claims description 49
- 239000004332 silver Substances 0.000 claims description 49
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 46
- 238000007747 plating Methods 0.000 claims description 40
- 239000010949 copper Substances 0.000 claims description 37
- 229910052751 metal Inorganic materials 0.000 claims description 36
- 239000002184 metal Substances 0.000 claims description 36
- 239000011347 resin Substances 0.000 claims description 31
- 229920005989 resin Polymers 0.000 claims description 31
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 19
- 229910052802 copper Inorganic materials 0.000 claims description 19
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- 230000005611 electricity Effects 0.000 claims description 18
- 239000010936 titanium Substances 0.000 claims description 14
- 239000012528 membrane Substances 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 239000010931 gold Substances 0.000 claims description 11
- 239000013528 metallic particle Substances 0.000 claims description 11
- 239000011777 magnesium Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 229910000679 solder Inorganic materials 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 4
- 229910021334 nickel silicide Inorganic materials 0.000 claims description 4
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 claims description 4
- 230000001788 irregular Effects 0.000 claims 1
- 238000000034 method Methods 0.000 description 68
- 239000012535 impurity Substances 0.000 description 52
- 239000000463 material Substances 0.000 description 42
- 239000006071 cream Substances 0.000 description 24
- 230000008569 process Effects 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 21
- 238000009713 electroplating Methods 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 16
- 239000004411 aluminium Substances 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 239000004065 semiconductor Substances 0.000 description 13
- 230000000875 corresponding effect Effects 0.000 description 11
- 230000001678 irradiating effect Effects 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- 230000002093 peripheral effect Effects 0.000 description 7
- 238000000151 deposition Methods 0.000 description 6
- 239000000428 dust Substances 0.000 description 6
- 238000011109 contamination Methods 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 229910004205 SiNX Inorganic materials 0.000 description 2
- 229910020286 SiOxNy Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 238000005036 potential barrier Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000005336 safety glass Substances 0.000 description 2
- 150000003376 silicon Chemical class 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical class N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910016909 AlxOy Inorganic materials 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910007637 SnAg Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 230000002968 anti-fracture Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/05—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
- H01L31/0504—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/05—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/05—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
- H01L31/0504—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
- H01L31/0512—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module made of a particular material or composition of materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
- H01L31/068—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1804—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic Table
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Photovoltaic Devices (AREA)
Abstract
The invention provides a kind of solar module, comprising: multiple solar cells, each solar cell includes: substrate, the emitter region being arranged on substrate, the antireflection region being arranged on emitter region, the first electrode being arranged on substrate, the first busbar being arranged on substrate and being connected to the first electrode, the second electrode being arranged on substrate and be arranged on substrate and be connected to the second busbar of the second electrode.Antireflection region includes one or more the second open areas of a part for the first open area and the exposure emitter region exposing a part for emitter region.First electrode is connected to the emitter region of the exposure of described first open area by metal-plated by described antireflection region, and the first busbar is connected to the emitter region of exposure of one or more the second open areas by metal-plated by institute's reflector space.
Description
Technical field
The present invention relates to solar module.
Background technology
Since it is expected that the such existing energy of such as oil and coal is by depleted, therefore recently to by existing for the replacement energy
The interest of alternative energy source day by day increase, thus the solar cell using solar energy to produce electric energy receives publicity.
Common solar cell includes that semiconductor regions (is formed by the different conduction-types of such as p-type and N-shaped
P-n junction) and it is connected to the electrode with each semiconductor regions of different conduction-types.
When sunlight incidence on the solar cell time, produce electronics and hole from semiconductor.The electronics produced from p-n junction
Move to n-type semiconductor region, and move to p-type semiconductor region from the hole that p-n junction produces.The electricity of movement
Son and hole are connected to the Different electrodes of p-type semiconductor region and n-type semiconductor region and collect, and by using
Electric wire connects electrode and obtains electric power.
Summary of the invention
Solar module according to aspects of the present invention includes: multiple solar cells, each solar cell bag
Include: substrate, the emitter region being arranged on substrate, the antireflection region being arranged on emitter region, be arranged in
The first electrode on substrate, it is arranged on substrate and is connected to the first busbar of the first electrode, be arranged on substrate
The second electrode and be arranged on substrate and be connected to the second busbar of the second electrode, antireflection region includes
One open area and one or more the second open areas, by one of the first open area emitter region
Point, a part for emitter region is exposed by the second open area, wherein, the first electrode utilizes metal-plated to pass through to prevent
Reflector space is connected to the emitter region of the exposure of the first open area, and the first busbar utilizes metal-plated to pass through
Antireflection region is connected to the emitter region of the exposure of one or more the second open areas；And cross tie part,
Cross tie part is by first busbar or second of the adjacent solar battery in the first busbar and multiple solar cell
Busbar is electrically connected.
The resistance value of the emitter region of the exposure of the first open area can be more than one or more the second openings
The resistance value of the emitter region of the exposure in region.
Electroconductive adhesive films can be arranged between at least one in the first busbar and the second busbar and cross tie part, and
And the multiple conductive particles being dispersed in resin can be comprised with by least in the first busbar and the second busbar
Individual and cross tie part is electrically connected.
At least one particle in multiple conductive particles can have the thickness of the thickness more than or equal to electroconductive adhesive films
Degree.In yet another aspect, at least one particle in multiple conductive particles has the thickness of the thickness less than electroconductive adhesive films
Degree.
At least one in multiple conductive particles can be embedded in cross tie part and the first busbar or the second busbar
In at least one.
Conductive particle can be formed by the resin particle being coated with metal, and the resin particle being coated with metal includes from copper
(Cu), silver (Ag), gold (Au), iron (Fe), nickel (Ni), lead (Pb), zinc (Zn), cobalt (Co), titanium
And the one that selects of magnesium (Mg) or more kinds of as composition (Ti).
Conductive particle can be formed by metallic particles, and metallic particles is by from copper (Cu), silver (Ag), gold (Au), iron
(Fe) one that, nickel (Ni), lead (Pb), zinc (Zn), cobalt (Co), titanium (Ti) and magnesium (Mg) select or
More kinds of make.
Metallic particles can have circle, ellipse or radiation shape.In yet another aspect, in conductive particle extremely
A few particle can have irregularities or ledge.
Cross tie part can be made up of conducting metal.
Conducting metal can include 1000ppm or less lead composition.
Cross tie part may further include the solder on the surface being coated in conducting metal.
At least one in first busbar and the second busbar can have uneven surface.
Electroconductive adhesive films can have the width identical with the width of at least one in the first busbar and the second busbar
Degree.
Electroconductive adhesive films can have bigger than the width of at least one in the first busbar and the second busbar wide
Degree.
Antireflection region may further include the multiple grooves separated with multiple second open areas and by multiple
Groove exposes antireflection region or emitter region.
Nickel silicide can be included between at least one in substrate and the first electrode and the first busbar.
At least one in first electrode and the first busbar can be formed by metal-plated thus to form at least one curved
Curved surface shape.
At least one in first electrode and the first busbar may include that and be arranged on substrate and made by nickel (Ni)
The first film become and the second film being arranged on the first film and being made up of silver (Ag) or copper (Cu).
At least one in first electrode and the first busbar may further include: tertiary membrane, and tertiary membrane is arranged in
On two films, and, when the second film can be made up of copper (Cu), tertiary membrane is by silver (Ag) or tin (Sn)
Make.
The first surface contacted with electroconductive adhesive films of at least one in first busbar and the second busbar can have
There is convex curved surface.
The height at the center of electroconductive adhesive films can be less than the height at the edge of electroconductive adhesive films.
Accompanying drawing explanation
Fig. 1 is the partial perspective view of the example of solar cell according to the embodiment of the present invention；
Fig. 2 is the sectional view of the solar cell of the Fig. 1 along line II-II intercepting；
Fig. 3 (a) and Fig. 3 (b) is the figure of the amplifier section illustrating " A " in Fig. 2 respectively；
Fig. 4 (a) and Fig. 4 (b) is the first open area or the plane of the second open area respectively；
Fig. 5 and Fig. 6 is all a part and the layout of the front electrode zone illustrating the solar cell according to present embodiment
The schematic diagram of a part for emitter region below the front electrode zone of solar cell；
Fig. 7 and Fig. 8 is all to illustrate that formed in antireflection region multiple first and second according to present embodiment open
The schematic diagram of port area；
Fig. 9 is to illustrate being plated in the second emitter part by the second open area exposure according to present embodiment
The schematic section of a part of front busbar；
Figure 10 (a) to Figure 10 (c) is to illustrate passing through by the second open area exposure according to present embodiment
The second emitter part on perform plating and form the schematic section of process of front busbar；
Figure 11 is the partial section view of another example of solar cell according to the embodiment of the present invention；
Figure 12 A to Figure 12 G is the figure sequentially illustrating the method manufacturing the solar cell shown in Fig. 1 and Fig. 2；
Figure 13 is the plane of solar module according to the embodiment of the present invention；
Figure 14 is to illustrate that the adjacent solar cell in Figure 13 is by the schematic side of the example of cross tie part coupled in series
Figure；
Figure 15 is the signal exploded perspective view of solar module according to the embodiment of the present invention；
Figure 16 to Figure 19 is that before the electroconductive adhesive films being shown with in Figure 13 couples, busbar and the various of cross tie part are shown
The sectional view of example；
Figure 20 (a) and Figure 20 (b) are that to illustrate that the front busbar according to comparative example and cross tie part are coupled various
The sectional view of state；
Figure 21 is the partial perspective view of the another example of solar cell according to the embodiment of the present invention；
Figure 22 is the sectional view of the solar cell of the Figure 21 along line XXII-XXII intercepting；And
Figure 23 is multiple first open regions formed in the antireflection region in the solar cell of Figure 21 and Figure 22
The schematic plan view in territory.
Detailed description of the invention
Below, will be described in detail with reference to the accompanying drawings some illustrative embodiments of the present invention, in order to people in the art
Member can be easily implemented with the present invention.However, it is possible to revise the present invention in a variety of manners, and it is not limited to following enforcement
Mode.In order to the description making embodiments of the present invention is clear, it is convenient to omit the part unrelated with description, and attached
Figure use same reference numerals represent same or like parts.
In the accompanying drawings, the thickness in each layer and region can amplify to be best understood from and being easy to describe.When describing such as
One parts of layer, region or plate are when another parts " top ", and it does not mean only that these parts are by directly
Be arranged in another parts " on ", and mean between these parts and another parts, be disposed with the 3rd
Part.It addition, when describe such as layer, region or such a parts of plate directly another parts " on " time,
This means not exist between these parts and another parts the 3rd parts.
Solar cell according to the embodiment of the present invention and solar module are described referring to the drawings.
Example referring to figs. 1 through Fig. 8 description solar cell 1 according to the embodiment of the present invention.
Seeing figures.1.and.2, solar cell 1 according to the embodiment of the present invention includes substrate 110, is arranged in
The emitter region 121 of front surface (i.e. first surface) side that the light of substrate 110 is incident, it is arranged in emitter region
Antireflection region 130 on 121, it is arranged on the front surface of substrate 110 and is construed as including multiple front electrode
141 (the most multiple first electrodes) and be connected to the multiple front busbar 142 (the most multiple first of multiple front electrode 141
Busbar) front electrode zone 140, be arranged in rear surface (i.e. second surface) side (the i.e. substrate 110 of substrate 110
The surface contrary with front surface) on back surface field region 172 and be arranged in back surface field region 172 and substrate
On the rear surface of 110 and be construed as including multiple rear electrode 151 (the i.e. second electrode) and be connected to rear electrode 151
The rear electrode region 150 of multiple rear busbar 152 (the most multiple second busbar).
Substrate 110 is formed as having the first conduction type (such as p-type electric-conducting type) and by the half of such as silicon
The semiconductor substrate that conductor is made.Semiconductor is the crystalline semiconductor of such as polysilicon or monocrystalline silicon.
When substrate 110 is p-type electric-conducting type, the III unit of such as boron (B), gallium (Ga) or indium (In)
The impurity of element is doped in substrate 110.But, substrate 110 can be N-shaped conduction type, and can be by removing
Semi-conducting material outside silicon is made.When substrate 110 has N-shaped conduction type, such as phosphorus (P), arsenic (As)
Or the impurity of the V group element of antimony (Sb) is doped in substrate 110.
As shown in Fig. 1 to Fig. 3, the front surface of substrate 110 is textured, thus has with having multiple protuberance
11 and the texturizing surfaces (that is, convex-concave surface) of multiple recess 12.Owing to adding substrate by texturizing surfaces
The surface area of 110, the area that therefore light is incident increases, but reduces from the amount of the light of substrate 110 reflection.Therefore,
The amount inciding the light on substrate 110 increases.
As it has been described above, the front surface of substrate 110 is to have multiple protuberance 11 and the convex-concave surface of multiple recess 12.As
Shown in Fig. 1 to Fig. 3, the emitter region that is arranged on the front surface of substrate 110 121 and be arranged in emitter region
The surface in the antireflection region 130 on territory 121 the most all has the concavo-convex table including multiple protuberance 21 and multiple recess 22
Face.
Emitter region 121 is doped with having second conduction type contrary with the conduction type of substrate 110 (such as
N-shaped conduction type) the impurity doping region of impurity, and be disposed in the front-surface side of substrate 110.Thus,
First conductivity type regions of emitter region 121 and substrate 110 forms p-n junction.
Emitter region 121 includes the first emitter stage portion with different impurities doping thickness and different surfaces resistance value
Divide 1211 (the i.e. first impurity doped portions) and the second emitter part 1212 (the i.e. second impurity doped portion).
In the present embodiment, the impurity doping thickness of the first emitter part 1211 is less than the second emitter part
The impurity doping thickness (i.e. the degree of depth) of 1212, thus the impurity doping concentration of the first emitter part 1211 again smaller than
The impurity doping concentration of the second emitter part 1212.Thus, the sheet resistance value of the first emitter part 1211 is big
Sheet resistance value in the second emitter part 1212.Such as, the sheet resistance value of the first emitter part 1211 can
To be about 80 Ω/sq. to 120 Ω/sq., and the sheet resistance value of the second emitter part 1212 can be about 10 Ω/sq.
To 50 Ω/sq..
Therefore, the emitter region 121 of present embodiment has selective emitting electrode structure, and it includes having different table
Surface resistance value and the first emitter part 1211 and the second emitter part 1212 of different impurities doping content.
The p-n junction of the first emitter part 1211 and substrate 110 (i.e. the first conductivity type regions of substrate 110) is (i.e.
First knot) and the p-n junction (the i.e. second knot) of the second emitter part 1212 and substrate 110 be disposed in Bu Tong height
Degree.Therefore, it is more than from the rear surface of substrate 110 to the second knot from the rear surface of substrate 110 to the thickness of the first knot
Thickness.
As shown in Figures 1 and 2, the first emitter part 1211 of emitter region 121 is disposed in antireflection
The lower section in region 130.Second emitter part 1212 is disposed in multiple front electrode 141 and multiple front busbar 142
Lower section.Second emitter part 1212 includes the second emitter part 12a (that is, the emitter stage for multiple electrodes
The Part I in region) (being i.e. arranged in the second emitter part 1212 below multiple front electrode 141) and for many
Multiple second emitter part 12b (i.e. the Part II of emitter region) of individual busbar (be i.e. arranged in multiple before
The second emitter part 1212 below busbar 142).
For the width W11 of the second emitter part 12a of each electrode and the second transmitting for each busbar
The width W12 of pole part 12b is identical.Such as, for the width W11 of the second emitter part 12a of each electrode
May each be about 5 μm to 15 μm with the width W12 of the second emitter part 12b for each busbar.
As shwon in Figures 5 and 6, for the second emitter part 12a edge below front electrode 141 of each electrode
Before, electrode 141 is extending on front electrode 141 equidirectional.Thus, electrode 141 exists be used in each of front
Second emitter part 12a of one electrode.
For the second emitter part 12b of each busbar below front busbar 142 along front busbar 142
Extending on front busbar 142 equidirectional.The second emitter part 12b for busbar is spaced apart.Cause
This, the first emitter part 1211 is between the second emitter part 12b of adjacent busbar.
As shown in fig. 1, multiple front electrodes 141 extend direction and multiple front busbar 142 extend direction each other
Intersect.Thus, multiple front electrodes 141 and multiple front busbar 142 are at multiple front electrodes 141 and multiple front busbar
Interconnect at 142 parts intersected with each other.Therefore, respectively below multiple front electrodes 141 and multiple front busbar 142
At side upwardly extending second emitter stage for electrode identical with multiple front electrodes 141 and multiple front busbar 142
Part 12a and for the second emitter part 12b of busbar for the second emitter part 12a of electrode and use
Interconnect at the part that the second emitter part 12b of busbar is intersected with each other.
When not including multiple front electrode 141 and multiple front busbar 142 part intersected with each other, conflux in each of front
There are multiple second emitter part 1212 being spaced apart (i.e. for the second emitter stage of busbar below bar 142
Part 12b).In the present embodiment, between the second emitter part 12b of two adjacent busbars
Can be that 15 μm are to 30 μm every D11.
In the solar cell 1 of present embodiment, as shown in Figure 1, Figure 2, shown in Fig. 5 and Fig. 7, it is arranged in every
The second emitter part 1212 (that is, for the second emitter part 12b of busbar) below individual front busbar 142
Between interval D 11 be rule.
But, in another embodiment, as shown in Fig. 6 and Fig. 8, arrange busbar 142 in each of front
Interval between second emitter part 1212 (that is, for the second emitter part 12b of busbar) of lower section
D11 is different.
Such as, as shown in Fig. 6 and Fig. 8, the front busbar being arranged in antireflection region 130 forms region AB's
Width or width W3 (are formed in this place corresponding to for busbar second of each front busbar 142 multiple
Emitter-base bandgap grading part 12b) core AB2 at the second emitter part 12b for busbar between interval
D11 can (formed corresponding to each front busbar 142 in this place be multiple for confluxing more than being arranged in width W3
Second emitter part 12b of bar) marginal portion AB1 and AB3 at the second emitter stage portion for busbar
Divide the interval D 11 between 12b.
In the case, be arranged in width W3 (formed in this place corresponding to each front busbar 142 be used for conflux
Multiple second emitter part 12b of bar) core AB2 at the second emitter part for busbar
Interval D 11 between 12b can be identical.It is arranged in width W3 (to be formed in this place and conflux before each
Multiple second emitter part 12b for busbar of bar 142) marginal portion AB1 and AB3 at be used for
Interval D 11 between second emitter part 12b of busbar can be identical.
Here, (formed corresponding to each front busbar 142 in this place is many for busbar to be arranged in width W3
Individual second emitter part 12b) core AB2 at the second emitter part 12b for busbar it
Between interval D 11 can be arranged on width W3 (formed in this place corresponding to each front busbar 142 for converging
Multiple second emitter part 12b of stream bar) marginal portion AB1 and AB3 at for second of busbar
About 1.5 to 5 times of interval D 11 between emitter-base bandgap grading part 12b.
But, the invention is not restricted to above example.Such as, no matter width W3 (is formed in this place for busbar
Multiple second emitter part 12b) position how, for the second emitter part 12b of two adjacent busbars
Between interval D 11 can be different.
In the present embodiment, second emitter part 1212 of lower section of busbar 142 in each of front is arranged (i.e.
The second emitter part 12b for busbar) quantity can such as be about 30 to 70, this quantity depends on
Width in each second emitter part 1212, the second emitter part 12b for two adjacent busbars
Between interval D 11 and the width of each second emitter part 12b.
Electronics and hole (i.e. utilize in causing due to the p-n junction formed between substrate 110 and emitter region 121
Build the electric charge that electrical potential difference is produced by the light that is incident on substrate 110) in electronics move to N-shaped, and hole is to p
Type moves.Therefore, when substrate 110 is p-type and emitter region 121 is N-shaped, electronics is to emitter region
121 move, and hole is moved to the rear surface of substrate 110.
Emitter region 121 forms p-n junction together with substrate 110.Unlike those described above, when substrate 110 has
During N-shaped conduction type, emitter region 121 has p-type electric-conducting type.In the case, electronics is to substrate 110
Rear surface move, and hole is moved to emitter region 121.
When emitter region 121 has N-shaped conduction type, the impurity of V group element can be doped to emitter stage
In region 121.When emitter region 121 has p-type electric-conducting type, the impurity of group-III element can be adulterated
In emitter region 121.
When the first emitter part 1211 has about 80 Ω/sq. or the surface of the most about 120 Ω/sq. or lower
During resistance value, the first emitter part 1211 amount of the light absorbed reduces further.Thus, it is incident on substrate 110
On the amount of light increase, and the charge loss caused due to impurity reduces further.
If additionally, the second emitter part 1212 has about 10 Ω/sq. or the most about 50 Ω/sq. or lower
Sheet resistance value time, then because specific contact resistivity between the second emitter part 1212 and front electrode zone 140
Rate reduces, and the charge loss therefore caused due to resistance during charge movement reduces.
Due to the first emitter part 1211 of emitter region 121 be disposed in below antireflection region 130 (as
Upper described), therefore antireflection region 130 is disposed in above the first emitter part 1211 of emitter region 121.
Therefore, the first emitter part 1211 be in arrange below busbar 142 in each of front for the second of busbar
Between the second emitter part 12b for two adjacent busbars in emitter part 12b.Thus, counnter attack
Penetrate region 130 and be in the first emitter stage portion being arranged between the second emitter part 12b of adjacent busbar
Divide above in the of 1211.
Antireflection region 130 is by hydrogenated silicon nitride (SiNx:H), hydrogenated silicon oxide (SiOx:H), hydrogenated silicon oxynitride
(SiOxNy:H) or aluminum oxide (AlxOy) composition.
The reflection of the light that antireflection region 130 is incident on solar cell 1 by minimizing and increase specific wavelength district
The selectivity in territory increases the efficiency of solar cell 1.
Additionally, antireflection region 130 is used as passive area, it is by the hydrogen injected when antireflection region 130 is formed
Or the dangling bond in the surface of substrate 110 and peripheral part thereof is changed into stable keys and performed to subtract by oxygen (O) (H)
The deactivation function died out of the electric charge that the surface to substrate 110 caused due to defect less is moved.Thus, because counnter attack
Penetrate region 130 and decrease the amount of the charge loss in the surface of the substrate 110 caused due to defect and peripheral part thereof,
Therefore the efficiency of solar cell 1 can be improved.
As it has been described above, the top surface in antireflection region 130 (that is, the surface contacted with front electrode zone 140) includes
Have multiple owing to being arranged in the texturizing surfaces (i.e. convex-concave surface) of the substrate 110 below antireflection region 130
First protuberance 21 and the convex-concave surface of multiple second recess 22.Therefore, the amount of the light being incident on substrate 110 increases.
Additionally, the top surface in antireflection region 130 partly contacts with front electrode 141 and front busbar 142.
The top surface in the antireflection region 130 contacted with front electrode 141 and front busbar 142 includes multiple groove 180,
As shown in Fig. 3 (a).
Each groove 180 is disposed in each recess 21 that (protuberance 21 is disposed in and contacts with front electrode zone 140
Antireflection region 130 top surface in), and formed by partly removing antireflection region 130.Groove
180 top surfaces from antireflection region 130 (that is, are arranged in and antireflection district to the basal surface in antireflection region 130
The surface contacted on the side that the top surface in territory 130 is contrary and with emitter region 121) depression specific thicknesses or
Degree of depth D1.In Fig. 3 (a), the multiple grooves 180 formed in the top surface in antireflection region 130 are by only
Partly remove antireflection region 130 and formed, and be only arranged in antireflection region 130.
But, in another embodiment, as shown in Fig. 3 (b), contact with front electrode zone 140
The multiple grooves 180 formed in antireflection region 130 are by partly removing antireflection region 130 and being in antireflection
Emitter region (that is, the first emitter part 1211) below region 130 and formed.
Therefore, the first emitter part of antireflection region 130 or emitter region 121 is exposed by groove 180
1211。
In Fig. 3 (b), degree of depth D1 of each groove 180 is more than degree of depth D1 shown in Fig. 3 (a).
Multiple groove 180 can be formed at desired locations by irradiating laser beam.The degree of depth of each groove 180 is permissible
Change according to the intensity of laser beam.
In the present embodiment, degree of depth D1 of each groove 180 can be from when being arranged in groove 180 with straight line connection
Near protuberance time in each groove 180 formed dummy line start deep with what the side of groove 180 was measured abreast
The maximum of degree.
In the present embodiment, when only being exposed antireflection region 130 (as shown in Fig. 3 (a)) by groove 180
Time, degree of depth D1 of each groove 180 and diameter may each be about 300nm to 10 μm.When by groove 180
When exposing emitter region 121 (as shown in Fig. 3 (b)), degree of depth D1 of each groove 180 and diameter
To be about 70nm to 120nm.
Groove 180 can have strips, and its further groove 180 and the second open area 182 are abreast along second
Open area 182 extends in the same direction, or can be circular or oval.
In the present embodiment, antireflection region 130 is shown as having monofilm structure, but can have the most double
The multi-layer film structure of film or can omit in appropriate circumstances.
Front electrode zone 140 including multiple front electrodes 141 and multiple front busbar 142 is disposed in emitter region
121 and antireflection region 130 above, and be connected to the second emitter part 1212 of emitter region 121.
Therefore, antireflection region 130 includes multiple first open area 181 and multiple second open area 182.Many
Individual first open area 181 is formed by partly removing antireflection region 130, in order to connect each front electrode
141 and each second emitter part 12a of electrode for the second emitter part 1212, and multiple first open
Port area 181 is formed as being exposed for below multiple first open areas 181 respectively the second emitter part of electrode
12a.Multiple second open areas 182 are formed by partly removing antireflection region 130, in order to connect every
Individual front busbar 142 and each second emitter part 12b for busbar of the second emitter part 1212,
And multiple second open areas 182 are formed as being exposed for busbar below multiple second open areas 182 respectively
The second emitter part 12b.
Multiple first open areas 181 and the second open area 182 can be by the relevant bits to antireflection region 130
Put irradiation laser beam to be formed.
The second emitter part 12a of being exposed by the first open area 181 and the second open area 182 respectively and
The both sides of each in 12b can have the plane as shown in Fig. 4 (a), or can have such as Fig. 4 (b)
Shown in convex-concave surface (that is, on-plane surface).
When the second emitter part 12a exposed by the first open area 181 and the second open area 182 respectively and
When the both sides of 12b have plane, the laser beam LB of use can have strips, and this strips has and the
The width that one open area 181 is identical with the second open area 182.When respectively by the first open area 181 and the
When second emitter part 12a of two open areas 182 exposures and the both sides of 12b are respectively provided with plane, the laser of use
Bundle LB can be to have a form, and this form has identical with the first open area 181 and the second open area 182
Width.
When the second emitter part 12a exposed by the first open area 181 and the second open area 182 respectively and
When the both sides of 12b are respectively provided with convex-concave surface, front electrode 141 and the contact area of the second emitter part 12a and front
The contact area of busbar 142 and the second emitter part 12b increases, this is because by the first open area 181
The second emitter part 12a exposed with the second open area 182 and the area of 12b all increase.When by making apparatus
When the laser beam LB having strips forms the first open area 181 and the second open area 182, form first and open
The time that port area 181 and the second open area 182 spend reduces.
As shown in Figures 7 and 8, the width W41 of the first open area 181 and the width of the second open area 182
W42 is identical for degree.The width W41 and the width W42 of the second open area 182 of the first open area 181
With about 5 μm to about 15 μm.
Multiple first open areas 181 are that the open area for forming multiple front electrode 141 is (that is, for front electrode
Open area), and multiple second open area 182 is the open area for forming multiple front busbar 142
(that is, for the open area of front busbar).
Each first open area 181 is the open area for each front electrode 141.Thus, antireflection region
Formation region (hereinafter referred to as " front electrode formation region " or " first electrode of a front electrode 141 is formed in 130
Form region ") quantity of the first open area 181 that formed in AA is one.Therefore, the first open area 181
Quantity identical with the quantity of front electrode 141.
Unlike multiple front electrodes 141, in order to form of the width with about 1mm to 1.5mm
Front busbar 142, it is desirable to quantity is about second open area 182 of 30 to about 70.Thus, antireflection region
The formation region of a front busbar 142 is formed (hereinafter referred to as " front busbar formation region " or " first in 130
Busbar forms region ") quantity of the second open area 182 that formed in AB is about 30 to about 70.Therefore,
The quantity of the second open area 182 is more much bigger than the quantity of front busbar 142.
For a front busbar 142 formed as discussed above, when multiple second open areas 182 that formation is spaced apart
Rather than formed when having at least with second open area 182 of front busbar 142 same widths, one
The overall width of multiple second open areas 182 that individual front busbar 142 is formed below and the front remittance in antireflection region 130
Stream bar formed region AB width or formed corresponding to a front busbar 142 for multiple the second of busbar
The ratio of the width W3 of emitter part 12b can be about 1:0.2 to 0.5.
As it has been described above, multiple front electrodes 141 are spaced apart and with extend in parallel in a predetermined direction.Front electrode 141
In each by electrically and be physically connected to the second emitter stage portion of the electrode for the second emitter part 1212
Divide each in 12a.
Each in front electrode 141 is disposed in above each second emitter part 12a of electrode, and
Also it is partially disposed within above adjacent antireflection region 130.Therefore, as shwon in Figures 5 and 6, it is arranged in
The width W21 of each front electrode 141 above each second emitter part 12a of electrode is more than each the
The width W11 of two emitter part 12a.Such as, the width W21 of each front electrode 141 can be that 20 μm arrive
40μm。
Thus, each front electrode 141 electrically and is physically connected to the second emitter part 1212 (that is, for electricity
Second emitter part 12a of pole).
The first emitter part 1211 that multiple front electrodes 141 are collected by emitter region 121 moves to second
The electric charge (such as, electronics) of second emitter part 12a for electrode of emitter-base bandgap grading part 1212.
As it has been described above, be exposed for the second emitter part 12a of electrode to form the first of first electrode 141
The quantity of open area 181 can be one, and is exposed for the second emitter part 12b of busbar to form one
The quantity of the second open area 182 of individual front busbar 142 can be about 30 to 70.
In the present embodiment, at the beam overall of front busbar 142 multiple second open areas 182 formed below
Degree and the width forming multiple second emitter part 12b for busbar corresponding to a front busbar 142
The ratio of W3 can be about 1:0.2 to 0.5.
When multiple second open areas 182 formed below at front busbar 142 overall width with formed corresponding to
The ratio for the width W3 of multiple second emitter part 12b of busbar of one front busbar 142 is about 1:0.2
Or time higher, it is possible to obtain and there is desired width and the front busbar 142 of expectation electric conductivity, this is because more stable
Define and be exposed for above the second emitter part 12a of busbar by multiple second open areas 182
The front busbar 142 formed.
When multiple second open areas 182 formed below at front busbar 142 overall width with formed corresponding to
The ratio for the width W3 of multiple second emitter part 12b of busbar of one front busbar 142 is about 1:0.5
Or time lower, the time forming multiple second open area 182 cost can be further decreased, and for shape
Become multiple second open area 182 and be exposed to the area of the emitter region 121 of heat and can be further decreased.
Multiple front busbars 142 are spaced apart and extend concurrently on the direction intersected with multiple front electrodes 141.
Each front busbar 142 electrically and is physically connected to the second emitter stage exposed by multiple second open areas 182
Second emitter part 12b for busbar of part 1212.
Additionally, due to antireflection region 130 is disposed in the second emitter part for two adjacent busbars
Between 12b, therefore a front busbar 142 is connected not only to the second emitter part 1212 (i.e. for busbar
Second emitter part 12b) and it is connected to antireflection region 130.
As it has been described above, the first emitter part 1211 is in the second emitter part for two adjacent busbars
Below antireflection region 130 between 12b.Therefore, the second emitter part 1212 is (i.e. for the second of busbar
Emitter part 12b) and the first emitter part 1211 all in front busbar 142 below.
With in each front electrode 141 similarly, be arranged in each in 142 of the front busbar above substrate 110
Width W22 more than wherein arrange be in the second emitter stage portion for busbar below a front busbar 142
Divide the overall width W3 (that is, forming the width of multiple second emitter part for busbar) of the substrate 110 of 12b
(i.e., in Figure 5, it is arranged in the second emitter part 12b for busbar below a front busbar 142
In, from be arranged in top (exterior angle i.e.) the second emitter part 12b for busbar cross side to
It is arranged in the distance of the cross side of second emitter part 12b for busbar of bottom (exterior angle i.e.)).
Such as, the width W22 of each front busbar 142 can be 1mm to 1.5mm.
Therefore, each front busbar 142 electrically and be physically connected to the second emitter part 1212 for electrode
The second emitter part 12a and second emitter part 12b for busbar of the second emitter part 1212.
Multiple front busbars 142 are arranged to be in same layer with multiple front electrodes 141.As it has been described above, at Qian Hui
At the point that stream bar 142 and each front electrode 141 intersect, multiple front busbars 142 are electric and are physically connected to be correlated with
Front electrode 141.
Therefore, as shown in Figure 1 and Figure 3, multiple front electrodes 141 have strips, plurality of front electrode
The 141 upper extensions in a direction (that is, first direction) of such as horizontal direction or vertical direction.Additionally, it is multiple
Front busbar 142 has strips, and plurality of front busbar 142 is at such as vertical direction or horizontal direction
Other direction (that is, second direction) is upper to be extended to intersect with multiple front electrodes 141.Therefore, front electrode zone 140
By in the front surface being arranged in substrate 110 in a grid formation.
The electricity that the second emitter part 1212 from emitter region 121 moves not only collected by multiple front busbars 142
Lotus, and collect the electric charge collected by multiple front electrodes 141 and moved and the electricity sending up collection related side
Lotus.
Each front busbar 142 must collect the electric charge collected by the multiple front electrode 141 intersected with front busbar 142
And move these electric charges in the desired direction.Therefore, the width W22 of each front busbar 142 is more than before each
The width W21 of electrode 141.
As it has been described above, emitter region 121 has includes the first emitter part 1211 and the second emitter part 1212
Selective emitting electrode structure.Thus, the first emitter stage portion of the main movement performing electric charge electrode zone 140 forward
1211 are divided to have low impurity doping concentration, and the second emitter part 1212 contacted with front electrode zone 140
There is high impurity concentration.Therefore, owing to due to by the first emitter part 1211 of emitter region 121
The increase of the electric conductivity that the increase of the amount of the electric charge that electrode zone 140 moves causes and the increase of impurity concentration forward,
Increase from the amount of the second emitter part 1212 electric charge that electrode zone 140 moves forward.Consequently, because by launching
The amount of the electric charge that the front electrode zone 140 in territory, polar region 121 is collected increases, therefore, it is possible to significantly increase solar-electricity
The efficiency in pond 1.
Further, since high impurity doping concentration, by main and front electrode zone 140 front electrode 141 and Qian Hui
Stream bar 142 contacts the second emitter part 1212 of output charge and has lead more higher than the first emitter part 1211
Electrical and lower than the first emitter part 1211 sheet resistance value.Accordingly, because the second emitter part 1212
With the ohmic contact resistance between front electrode zone 140 reduces, enabling improve from the second emitter part 1212
The efficiency of transmission of the electric charge that electrode zone 140 moves forward.
Here, because each in second emitter part 12a for electrode of the second emitter part 1212
Width W11 less than the width W21 of each in front electrode 141, therefore reduce the formed for electrode
The area (i.e. high concentration impurities doped region) of two emitter part 12a.It is used for the multiple of busbar additionally, formed
The width W3 of the second emitter part 12b is less than the width W22 of each front busbar 142.It addition, before each
Busbar 142 completely attaches to the second emitter part 1212, but each front busbar 142 is partially attached to
The second emitter part 12b (that is, high concentration impurities doped region) for busbar.Thus, it is possible to reduction shape
Become the high concentration impurities doped region of the lower section of busbar 142 in each of front (that is, for the second emitter stage of busbar
Part 12b) area.Accordingly, because considerably reduce high concentration impurities doped region in emitter region 121
Territory 1212 and therefore considerably reduce the amount of the charge loss caused by impurity, therefore improves solar cell
The efficiency of 1.
In order to manufacture a solar module, many by being connected in series or in parallel multiple solar cell 1
Individual front busbar 142 is arranged the cross tie part of such as rib.In the present embodiment, at multiple front busbars 142 with mutual
Even arrange electroconductive adhesive films between part, thus electrically and physically couple multiple front busbar 142 and cross tie part.Due to
Multiple front busbars 142 are connected to external equipment by cross tie part, the electric charge therefore collected by multiple front busbars 142
(such as, electronics) exports external equipment via cross tie part.
As it has been described above, each front electrode 141 and each front busbar 142 are not arranged only at the second transmitting for electrode
Pole part 12a and above the second emitter part 12b of busbar, and is arranged on antireflection region 130
Side.Thus, the width of each front electrode 141 and each front busbar 142 is more than the width of open area 181 and 182
Degree.Accordingly, because each front electrode 141 and the surface area of each front busbar 142 and cross section increase, therefore can
Enough stably keep each front electrode 141 and the electric conductivity of each front busbar 142, and therefore electric charge can be stablized
Ground is mobile.Additionally, because electroconductive adhesive films and the contact area increase of front busbar 142, therefore further improve
Bonding strength between each front busbar 142 and the electroconductive adhesive films being arranged on front busbar 142.
As it has been described above, the front electrode 141 of antireflection region 130 and the front electrode zone 140 in antireflection region 130
The part contacted with front busbar 142 is formed and exposes antireflection region 130 or first of emitter region 121
Multiple grooves 180 of emitter-base bandgap grading part 1211.Therefore, front electrode 141 He above antireflection region 130 it is arranged in
Front busbar 142 is also formed in multiple groove 180.
Therefore, front electrode 141 and front busbar 142 are anti-be arranged in below front electrode 141 and front busbar 142
The area that reflector space 130 contacts with emitter region 121 increases.Thus, front electrode 141 and at front electrode 141
Bonding strength between antireflection region 130 and the emitter region 121 of lower section and front busbar 142 and at Qian Hui
The bonding strength between antireflection region 130 and emitter region 121 below stream bar 142 increases.Therefore, front electricity
Physical engagement intensity between pole 141 and the antireflection region 130 below front electrode 141 and emitter region 121
Increase, and front busbar 142 and the antireflection region 130 below front busbar 142 and emitter region 121
Between physical engagement intensity increase.
In the present embodiment, electroplating method is used to form front electrode zone 140.To this end, in antireflection region 130
After forming multiple first open areas 181 and second open area 182 of exposure emitter region 121, make electricity consumption
Electroplating method is held on the emitter region 121 exposed by multiple first open areas 181 and the second open area 182
Row plating.
Referring to Fig. 9 and Figure 10, front electrode 141 He when using electroplating method to manufacture front electrode zone 140 is described
The characteristic of front busbar 142.In figure 9 and in figure 10, for simplicity, the surface of substrate 110 is shown as
There is the surface of plane and texture-free.
As shown in Figure 9, when the second opening being respectively provided with preset width Wc by removing antireflection region 130 formation
Region 182 (or multiple first open area 181) and expose the second emitter part 1212 on perform plating
Time, the plating thickness from the height of the top surface in antireflection region 130 is Hf.Be as noted previously, as plating be each to
Same sex growth, therefore in level side from the end of the second open area 182 (or first open area 181)
Upwards being plated in the thickness on antireflection region 130 is also Hf.Therefore, by the second open area 182 (or
One open area 181) top surface of the part of plating has curved surface shape in the second emitter part 1212 of exposing
Shape.
Therefore, when performing plating, as shown in Figure 10 (a), it is being arranged in each second open area 182 and each
The second emitter part 1212 in first open area 181 (not shown in Fig. 9) performs metal-plated, thus
Grow desired metal.Thus include multiple front electrode 141 and the front electrode of multiple front busbar 12 when initially forming
During region 140, little by little grow front electrode 141 in the outside of the first open area 181 and the second open area 182
With front busbar 142.
Here, as it has been described above, for front electrode zone 140 metal plating growth be not only in the vertical direction but also
The isotropic growth performed with identical speed in the horizontal direction.Thus, when as shown in Figure 10 (b) first
In open area 181 and the second open area 182, front electrode 141 and the front busbar 142 of growth grow into adjacent
During the height of the top surface in antireflection region 130, metal the most also grows, thus front electrode 141
With front busbar 142 also in the antireflection region 130 adjacent with the first open area 181 and the second open area 182
Grown above.
Therefore, each in the top surface of each front electrode 141 and the top surface of each front busbar 142 has curved
Curved surface shape.
In the present embodiment, in order to form a front busbar 142, multiple adjacent open regions 182 is formed.Cause
This, adjacent one another are in multiple second open areas 182 formed to form a front busbar 142 two
The metal part of busbar 142 (that is, each) of growth in each in the second open area 182 is in counnter attack
Penetrate and encounter one another, as shown in Figure 10 (c) above region 130.
Therefore, although performing metal-plated growth in each in the second open area 182 being spaced apart, but
Interval D 11 between two the second adjacent open areas 182 is included metal-plated growth in the horizontal direction
In the range of.Thus, the metal at two the second adjacent open area 182 surrounding growth is being arranged in the two respectively
Meet above antireflection region 130 between second open area 182, thus form a front busbar 142.
Therefore, the width of each front busbar 142 ultimately formed (that is, is launched with antireflection region 130 and second
The width of the basal surface of each front busbar 142 of pole part 1212 contact) form region AB more than front busbar
Width D 21.
Owing to metal-plated described above growth is isotropic growth, therefore based on each second open area 182 plating
The top surface of the metal part of busbar 142 (that is, front) is (that is, before being arranged in the side contrary with basal surface
The surface of busbar 142) also there is curved surface shape.Based in two the second adjacent open areas 182
Each performs the antireflection between metal-plated and metal-plated the second open area 182 adjacent with being arranged in two
Region 130 overlaps.Thus, the height of the top surface of the overlapping part of the metal grown by plating becomes ratio by logical
The top surface of the metal part crossing plating in the second emitter part 1212 that the second open area 182 exposes and grow
The highest.
Therefore, on antireflection region 130 and in the second emitter part exposed by the second open area 182
The top surface of each front busbar 142 formed on 1212 (that is, is arranged in the front remittance of the side contrary with basal surface
The surface of stream bar 142) there is curved surface shape, it includes having multiple protuberance and the convex-concave surface of multiple recess.
As it has been described above, the front busbar being arranged in the second emitter part 1212 by the second open area 182 exposure
The height of the top surface of 142 is higher than the height of the front busbar 142 being arranged on antireflection region 130.
Accordingly, because the surface roughness increase of the top surface of each front busbar 142 makes each front busbar 142
The contact area contacted with cross tie part increases.Thus, the amount of the electric charge that busbar 142 moves to cross tie part increases in the past.
As shown in Fig. 6 and Fig. 8, when arranging the second transmitting for busbar below busbar 142 in each of front
When interval D between part 12b of pole 11 is different according to position, by edge part office for adjacent busbar
The second emitter part 12b on plating and the overlapping area ratio of part that grows by busbar 142 in each of front
The overlapping area of the part plated in the second emitter part 12b of adjacent busbar at heart part and grow increases
Obtain more.Therefore, the subtractive of the height between core and the marginal portion of each front busbar 142 is little, and
Thus the top surface (that is, including multiple protuberance and the convex-concave surface of multiple recess) of each front busbar 142 is smooth
Degree increases further.Therefore, be conducive to utilizing the bonding arranging the electroconductive adhesive films above busbar 142 in each of front
Operation, and add bonding strength.
Not there is each in the front electrode 141 of multiple protuberance and multiple recess because being to use first opening
Region 181 formed thus there is the surface configuration of smooth curved.
In fig .9, the overall width Wf of the front busbar 142 of plating is Wc+2Hf.Due to plating metal (such as,
Silver (Ag)) there is the ratio linear resistivity of about 2.2 μ Ω cm, therefore, it is possible to it is seen that, the ratio line electricity of the metal of plating
About the 1/3 of the ratio linear resistivity (i.e., about 6.7 μ Ω cm) of the front busbar that resistance rate is made up of silver (Ag) cream.Plating
Material there is the ohmic contact resistance of about 1m Ω cm.Can also be seen that, the ohmic contact resistance of plating material is
About 1/3 of ohmic contact resistance (i.e., about 3m Ω cm) when using silver (Ag) cream.
As it has been described above, use every than in linear resistivity value and ohmic contact resistance value being coated with the front busbar 142 made
One is each than in linear resistivity value and ohmic contact resistance value of the front busbar that uses silver (Ag) cream to manufacture
Individual about 1/3.If using the front busbar 142 that electroplating method manufactures and the front busbar using silver (Ag) cream to manufacture
142 have identical sectional area, then it can be seen that use and be coated with the operating characteristic of the front busbar made (such as,
Contact performance or electric conductivity) it is about 3 times of operating characteristic of the front busbar using silver (Ag) cream to manufacture.
In fig .9, when Wc is 10 μm and Hf is 10 μm, by second open area 182
In the section A of a part of front busbar 142 of plating growth be about 257 μm2。
The line electricity that the front busbar 142 having and use silver (Ag) cream to manufacture is identical can be calculated based on below equation
Section A 1:R (line resistance)=[ρ (than linear resistivity) x l (length)]/A1 (cross section of one front busbar 142 of resistance
Long-pending).In the equations, the factor for length I is omitted, this is because conflux before using silver (Ag) cream manufacture
Bar has and use is coated with length I that the front busbar 142 made is identical.
Assuming that the line resistance using the front busbar of silver (Ag) cream manufacture is Rpaste, then because that compare line
Resistivity is 6.7 μ Ω cm and sectional area is 37500 μm2, thus Rpaste=6.7/37500=1.786 × 10-4Ω。
Therefore, before using the line resistance Rplating being coated with the front busbar made to manufacture with use silver (Ag) cream
When the line resistance Rpaste of busbar is identical, calculate sectional area A1 according to below equation.Make here, use to be coated with
Front busbar 142 has the ratio linear resistivity of 2.2 μ Ω cm as mentioned above.
In (Rplating=ρ/A1), because 1.786 × 10-4Ω=2.2/A1, therefore sectional area A1 is about
12313μm2。
Therefore, when sectional area A1 is divided by the sectional area in the part grown by the plating in an open area 182
During A, calculate the quantity of the second open area 182 formed in antireflection region 130 so that obtaining sectional area
A1, and thus be respectively provided with the quantity of the second open area 182 of the width of about 10 μm and can be about 48.
In other words, in order to form one of the width with about 1.5mm front busbar 142, in antireflection region
The open area 182 rather than the formation one that form about 48 width being respectively provided with about 10 μm in 130 have about
Second open area of the width of 1.5mm, and busbar before being formed by the plating in the second open area 182
142.In the case, the width of each front busbar 142 formed on multiple second open areas 182 is about
1.5mm, this is because the plating of front busbar 142 is as mentioned above above the second open area 182 and in right and left
The most isotropically grow.
It can be seen that by electroplating method, at the emitter region exposed by multiple second open areas 182
The front busbar 142 forming the width with about 1mm to 1.5mm above in the of 121 needs about 30 to 70 all
There is the second open area 182 of the width of about 5 μm to 15 μm.Here, two adjacent second open areas 182
Between interval can be about 15 μm to 30 μm.The quantity of the second open area 182 is according to the second open area
Interval between the width of 182 and two adjacent second open areas 182 and change.
Interval between two adjacent second open areas 182 be about 15 μm or higher time because reducing shape
Become the area of the second emitter part 12b (that is, high concentration impurities doped portion), therefore due to the second emitter stage portion
The loss of the electric charge that the second emitter part 12b for busbar dividing 1212 causes stably reduces.When two
Interval between adjacent second open area 182 be about 30 μm or higher time because respectively at adjacent second opening
In region 182, the front busbar 142 of growth more stably contacts adjacent second open area 182, therefore multiple the
A front busbar 142 with stable electric conductivity is formed on two open areas 182.
As it has been described above, in order to form each front busbar 142, partly or optionally remove and will arrange one
The antireflection region 130 of the part of front busbar 142 rather than in order to form each front busbar 142 and by making
The whole antireflection region 130 of the part that will arrange a front busbar 142 is removed with laser.It therefore reduces
The area in the antireflection region 130 of illuminated laser beam.
Therefore, decrease the time of manufacture solar cell 1 cost and the change of the characteristic of solar cell 1, this
It is because decreasing the time irradiating laser cost and the thermal conductance applied by laser beam causes emitter region 121 or base
The phenomenon of plate 110 deterioration.
In the present embodiment, when the quantity of the second open area 182 for a front busbar 142 be 30 or
When person is bigger, define the front busbar 142 with more stable electric conductivity and surface area.When converging before one
The quantity of the second open area 182 of stream bar 142 be 70 or less time, reduce unnecessary time waste and swash
The irradiated area of light.
Additionally, the width ratio of each in the first open area 181 and the second open area 182 is when using etching paste
Or width during additional masking reduces further, this is because by using direct irradiation in antireflection region 130
The laser beam of top removes the expectation part in antireflection region 130 rather than use utilizes etching paste or mask to move
Operation except antireflection region 130.
It therefore reduces form the area of multiple front electrode 141, this is because reduce formation the second emitter part
The area of 1212 (that is, high concentration impurities doped portions) and reduce the width of front electrode 141.
In the solar cell 1 according to alternative embodiment, as shown in Figure 11, the second emitter part is exposed
Second emitter part 12b for busbar of 1212 is so that the second opening of the front busbar 142 of new city one
The quantity in region 182 can be one.
In the case, due to each front busbar 142 and the second emitter part 1212 for the of busbar
The contact area of two emitter part 12b contacts increases, busbar 142 and the second emitter part 1212 before institute
Between bonding strength increase.
In the case, as electrode 141 in each of front, a front busbar 142 is by by an opening
Plating in region 182 and the material that grows are made, this is because front busbar 142 only needs the second open area 182.
Therefore, the top surface of the front busbar 142 formed in the second open area 182 has curved surface shape, with
The top surface of each front electrode 141 is the same, and the top surface of front busbar 142 has less than opening by multiple second
The roughness of the top surface of the front busbar 142 that port area 182 is formed.Therefore, the top surface of front busbar 142
Flatness is more than the flatness of the top surface of the front busbar 142 formed by multiple second open areas 182.
In the present embodiment, multiple grooves 180 are not used for front electrode zone 140 and the of emitter region 121
Contact between two emitter part 1212, but be used for strengthening front electrode zone 140 and being arranged in front electrode zone
The bonding strength between element below 140.Therefore, degree of depth D1 of each groove 180 is not more than the first open region
Degree of depth D2 of each in territory 181 and the second open area 182, and degree of depth D1 of groove 180 and opening
Degree of depth D2 in region 181 and 182 changes according to the intensity (that is, the size of wavelength) of laser beam.Therefore, for
Formation multiple first open area 181 and the second open area 182 and the intensity of laser beam irradiated can with in order to
The intensity of the laser beam forming multiple groove 180 and irradiate is different, and in order to form multiple first open area 181
With the second open area 182 and the intensity of laser beam irradiated can be more than irradiating to form multiple groove 180
The intensity of laser beam.
In the present embodiment, it is used for being formed multiple first open area 181 and the second open area 182 and multiple recessed
The wavelength of the laser beam of each in groove 180 can be about 350nm to 1100nm.Such as, it is used for being formed many
The laser beam of individual first open area 181 and the second open area 182 can have the wavelength of 532nm.For shape
The laser beam becoming multiple groove 180 can have the wavelength of about 1100nm.Additionally, for the first open area 181
5W to 20W is can be about with the power of the laser beam of each in the second open area 182.Can be according to anti-
The material of reflector space 130 or thickness determine the power of laser beam, intensity (or wavelength) or irradiation time.
Galvanoplastic or photoinduction plating (LIP) can be used as electroplating method.
Because using identical depositing process to concurrently form front electrode 141 and front busbar 142, the most multiple front electrodes 141
With multiple front busbars 142, there is identical membrane structure and material.Additionally, due to electrode zone before being formed by plating
140, before electrode zone 140 density than use such as silver (Ag) cream silk screen print method manufacture front electrode
The density in region is much higher.Therefore, it can significantly improve the electric conductivity of front electrode zone 140.
Have been illustrated with including that the front electrode zone 140 of multiple front electrode 141 and multiple front busbar 142 has by all
The monofilm structure made such as the material of silver (Ag).In alternative embodiment, front electrode zone 140 can have
The most double films or many membrane structures of three films.
During the monofilm that front electrode region 140 is made up of silver (Ag), front electrode zone 140 can have 1.6 μ Ω cm
Ratio linear resistivity to 2.5 μ Ω cm.In the case, the ratio linear resistivity of front electrode zone 140 is than using silk screen
The ratio linear resistivity (i.e., about 6.7 μ Ω cm) of the front electrode zone 140 that print process is made up of silver (Ag) cream is little
Many.
When front electrode region 140 has two film construction, (that is, the second of substrate 110 is led with emitter region 121
Electricity type area) the lower film (that is, the first film) that contacts can make due to nickel (Ni), and be arranged on lower film
Upper film (that is, the second film) can by silver (Ag) make.When front electrode region 140 has three membrane structures,
The lower film (that is, the first film) contacted with emitter region 121 can be made due to nickel (Ni), is arranged on lower film
Intermediate coat (that is, the second film) can be made up of copper (Cu), and the upper film being arranged on intermediate coat is (i.e.,
Tertiary membrane) can be made up of silver (Ag) or tin (Sn).When front electrode region 140 is double film, lower film can
About 5 μm thickness to about 10 μm can be had with the thickness and upper film with about 0.5 μm to about 1 μm.When
When front electrode zone 140 is three film, each in lower film and upper film can have about 0.5 μm thickness to about 1 μm
Degree and intermediate coat can have about 5 μm thickness to about 10 μm.
Here, the lower film of each front electrode 141 and each front busbar 142 is for by reducing the second emitter part
1212 ohmic contact resistance contacted with lower film to improve contact performance, and as plating Seed Layer.Each
The intermediate coat of front electrode 141 and each front busbar 142 is used for reducing cost and can be by such as copper (Cu)
The material with low cost and excellent electric conductivity is made.When intermediate coat is made up of copper (Cu), it is arranged in centre
Lower film below film is used for preventing have the copper (Cu) of excellent bond strength to be used as to penetrate into by silicon (Si) with silicon (Si)
In the second emitter part 1212 made (or being absorbed) thus hinder the impurity of movement of electric charge.
Additionally, upper film for prevent from being arranged in the film (such as, lower film or intermediate coat) below film oxidized and
The bonding strength of the electroconductive adhesive films improved and be arranged in above film.
Each in electrode 141 and front busbar 142 is formed and lower film by double films or three films before as mentioned above
When being made up of nickel (Ni), owing to nickel (Ni) and emitter region 1212 (i.e. form the second conduction of substrate 110
The silicon (Si) of type area) joint cause there is nickel silicide between lower film and emitter region 1212.
Meanwhile, front electrode 141 and front busbar 142 are by using silk screen print method by the silver (Ag) including glass dust
When cream is made, therefore glass dust through antireflection region 130 and contact with emitter region 1212.Therefore, exist
The part that front electrode 141 contacts with emitter region 1212 with front busbar 142 detects in the composition of glass dust
At least one (such as, the material based on lead (Pb) of such as PbO, such as Bi2O3Based on bismuth (Bi)
Material, such as Al2O3Material based on aluminium (Al), such as B2O3Material based on boron (B), such as
The material based on tin (Sn) of SnO, the material based on zinc (Zn) of such as ZnO, such as TiO based on titanium
(Ti) material, such as P2O5Material based on phosphorus (P) at least one).
But, in the present embodiment, at front electrode 141 and front busbar 142 and substrate 110 (that is, emitter stage
Region 121) between be not detected by the composition of glass dust, this is because front electrode 141 and front busbar 142 are logical
Cross what plating was formed.When front electrode region 140 has multilayer film as above, use electroplating method from lower film to upper film
It is sequentially formed the multilayer film with expectation thickness.
In FIG, the quantity of the front electrode 141 being arranged in substrate 110, the quantity of front busbar 142 and
The quantity of two emitter part 1212 is only to illustrate, and can according to circumstances change.
Back surface field region 172 is wherein to have and substrate with doped in concentrations profiled more higher than the extrinsic region of substrate 110
The extrinsic region of the impurity of 110 identical conduction types, and can be p+ region.
Owing to the official post of the impurity concentration between the first conductivity type regions and the back surface field region 172 of substrate 110 obtains
Form potential barrier, thus potential barrier hinders electronics rearward surface field areas 172 to move, but be advantageous for rearward surface field, hole
The movement in region 172.Accordingly, because electronics and hole being combined in the rear surface and adjacent part thereof of substrate 110
And the amount of the electric charge being lost reduces, and be conducive to expecting the movement in electric charge (such as, hole).Therefore, electric backward
The amount of the electric charge that territory, polar region 150 is moved increases.
Rear electrode region 150 includes multiple rear electrode 151 and is connected to the multiple rear busbar 152 of rear electrode 151.
Rear electrode 151 contacts with the back surface field region 172 in the rear surface being arranged in substrate 110.Rear electrode 151
It is arranged substantially at the edge of the rear surface except substrate 110 of substrate 110 and is disposed with the portion of rear busbar 152
In whole rear surface beyond Fen.
Rear electrode 151 includes such as aluminium (Al) or the conductive material of silver (Ag).
The electric charge (such as, hole) that rearward surface field areas 172 of collecting rear electrode 151 moves.
Because rear electrode 151 contacts with the back surface field region 172 with impurity concentration more higher than substrate 110, because of
Ohmic contact resistance between this substrate 110 (that is, back surface field region 172) and rear electrode 151 reduces.Therefore,
Improve from substrate 110 to the charge transfer efficiency of rear electrode 151.
Multiple rear busbars 152 are disposed in the rear surface of the substrate 110 not arranging rear electrode 151, and even
Receive adjacent rear electrode 151.
Additionally, multiple rear busbars 152 are based on each front busbar 142 faced by substrate 110.
Multiple rear busbars 152 electric charge of collecting from rear electrode 151 transmission the same with multiple front busbars 142.
As multiple front busbars 142, cross tie part is disposed on multiple rear busbar 152, and multiple rear remittance
Stream bar 152 is connected to external equipment by cross tie part.Therefore, multiple rear busbars 152 electric charge collected is (such as,
Hole) it is output to external equipment.In the case, electroconductive adhesive films is disposed in multiple rear busbar 152 with mutual
Even between part, thus electrically and physically couple multiple rear busbar 152 and cross tie part.
Multiple rear busbars 152 can be made up of the material with electric conductivity more more preferable than rear electrode 151, and includes
Such as at least one conductive material of silver (Ag).Therefore, rear electrode 151 and rear busbar 152 can be by differences
Material is made.
The cream including aluminium (Al) or silver (Ag) can be used to form rear electrode 151 by silk screen print method, it is possible to
Include that the cream of silver (Ag) forms rear busbar 152 by silk screen print method to use.
Additionally, as front electrode 141 and front busbar 142, it is also possible to form rear electrode 151 by electroplating method
With rear busbar 152.In the case, as front electrode zone 140, after using identical depositing process to concurrently form
Electrode 151 and rear busbar 152, and thus rear electrode 151 and rear busbar 152 can be manufactured from the same material.
Further, it is possible to use be used for depositing process and front electrode 141 and the front busbar of front electrode 141 and front busbar 142
142 simultaneously form rear electrode 151 and rear busbar 152.In the case, rear electrode region 150 by with front electricity
The identical material in territory, polar region 140 is made.Additionally, rear electrode region 150 can not only have monofilm, it is also possible to tool
There is multimembrane, the most double films or three films.
Formed as described above by electroplating method rear electrode 151 and rear busbar 152 and rear electrode 151 and after conflux
In the case of bar 152 has double film or three moulds, when back surface field region 172 (that is, with substrate 110 with highly concentrated
Degree is doped with the lower film of part contact of the impurity of the first conduction type) when being made up of nickel (Ni), due to nickel (Ni)
With the silicon (Si) synthesis in back surface field region 172 so that there is nickel between lower film and back surface field region 172
Silicide.
Additionally, between rear electrode 151 and back surface field region 172 and after busbar 152 and back surface field region
Detect between 172 in the composition of glass dust at least one (such as, such as PbO material based on lead (Pb),
Such as Bi2O3Material based on bismuth (Bi), such as Al2O3Material based on aluminium (Al), such as B2O3
Material based on boron (B), the material based on tin (Sn) of such as SnO, such as ZnO based on zinc (Zn)
Material, the material based on titanium (Ti) of such as TiO and such as P2O5Material based on phosphorus (P) in extremely
Few one).
Unlike present embodiment, in alternative example, the emitter region 121 of solar cell 1 can not
There is selective emitting electrode structure.
In the case, because not arranging antireflection region 130, antireflection region therefore it is directly arranged at 130 times
The emitter region 121 of side has with to be directly arranged at the emitter region 121 below front electrode zone 140 identical
Impurity doping concentration, impurity doping thickness and sheet resistance value.Therefore, no matter position how, all emitter regions
121 can have identical sheet resistance value (such as, about 50 Ω/sq. to 80 Ω/sq.).
The operation of the solar cell 1 with said structure according to present embodiment is described below.
When light is irradiated to solar cell 1 and then incides substrate 110 via antireflection region 130, by light
Energy produces electronics and hole from semiconductor regions.Now, because being reduced by antireflection region 130 and being incident on base
The reflection loss of the light on plate 110, therefore adds the amount of the light being incident on substrate 110.
Electronics and hole by means of the p-n junction of substrate 110 and emitter region 121 respectively to having N-shaped conduction type
Emitter region 121 and there is the substrate 110 of p-type electric-conducting type move.As it has been described above, to emitter region
121 electronics moved move to the second emitter part 1212 via the first emitter part 1211, by multiple front electricity
Pole 141 and multiple front busbar 142 are collected, and move then along multiple front busbars 142.To substrate 110
The hole of movement is collected by rear electrode 151 adjacent one another are and multiple rear busbar 152, and then along after multiple
Busbar 152 moves.When current busbar 142 and rear busbar 152 are interconnected part coupling, electric current flows, and
Electric current is used as electric power in outside.
In the case, because utilizing the emitter region 121 with selective emitting electrode structure to reduce charge loss
Amount, therefore add the amount of the electric charge that electrode 141 moves forward, thus significantly improve the effect of solar cell 1
Rate.
Additionally, due to front electrode zone 140 is formed by electroplating method, the width ratio of the most each front electrode 141
The width (such as, 80 μm are to 120 μm) of each front electrode of silver (Ag) cream manufacture is used by silk screen print method
Much smaller.Accordingly, because reduce front electrode 141 to hinder the area of light incidence so that the light of solar cell 1 enters
The area penetrated increases.Therefore, the efficiency of solar cell 1 is improved.
Additionally, when defining selective emitting electrode structure, the second emitter region 1212 (that is, high concentration impurities
Doped region) it is not arranged in below whole front busbar 142, but optionally it is arranged in front busbar
Below 142, and the width of each front electrode 141 is less than being arranged in the second emitter region below front busbar 142
The width in territory 1212.It therefore reduces high concentration impurities doped region, thus considerably reduce owing to impurity draws
The amount of the charge loss risen.
Additionally, in including the top surface in antireflection region 130 of the first protuberance 21 and the first recess 22, pass through cloth
The multiple grooves 180 put in the part that groove 180 contacts with front electrode zone 140 increase front electrode 141 and counnter attack
Penetrate the contact area of region 130 contact and the contact area that contacts with emitter region 121 of front electrode 141 and front
Contact area and front busbar 142 that busbar 142 contacts with antireflection region 130 contact with emitter region 121
Contact area.Therefore, front electrode 141 is improved and the antireflection region 130 being arranged in below front electrode 141
Between and front electrode 141 and emitter region 121 between bonding strength and front busbar 142 be arranged in front remittance
Bonding between antireflection region 130 below stream bar 142 and between front busbar 142 and emitter region 121 is strong
Degree.
Manufacture method with reference to Figure 12 A to Figure 12 G description solar cell 1 according to the embodiment of the present invention.
As shown in figure 12a, by using wet etch process or dry etching method to have first being formed as
The front surface of conduction type (such as, p-type) and the substrate 110 be made up of monocrystalline silicon or polysilicon is (that is, flat
Face) in formed and include the texturizing surfaces (that is, convex-concave surface) of multiple protuberance and multiple recess.
As shown in Figure 12B, be formed as having the first conduction type (such as, p-type) and by monocrystalline silicon or
Impurity (such as, the phosphorus including there is the second conduction type is formed in the front-surface side of the substrate 110 that polysilicon is made
(P) emitter region 120).Here, ion implantation or thermal diffusion method can be used to form emitter region
120, and the first conductivity type regions and the p-n junction of substrate 110 can be formed in emitter region 120.Send out
Emitter region 120 can have the sheet resistance value of about 80 Ω/sq. to 120 Ω/sq..Due to as described above by by
The impurity of two conduction types is injected in substrate 110 and forms emitter region 120, therefore emitter region 120 by
The crystalline semiconductor identical with substrate 110 of such as monocrystalline silicon or polysilicon is made.Therefore, substrate 110 and transmitting
Territory, polar region 120 forms homojunction.
In alternative embodiment, before forming emitter region 120 or after forming emitter region 120,
Can pass through to use the wet etch process of such as reactive ion etching or dry etching method before substrate 110
In surface (that is, plane) (or surface of emitter region 120) or the front surface of substrate 110 and rear surface
Formed and there is multiple protuberance and the texturizing surfaces of multiple recess.When the surface of substrate 110 described above has veining
During surface, owing to improving the effect preventing being incident on the reflection of the light on substrate 110, thus add and be incident on base
The amount of the light on plate 110.
Then, as shown in figure 12 c, by using plasma enhanced chemical vapor deposition (PECVD) method
Antireflection region 130 is formed above emitter region 120 in the front-surface side being formed at substrate 110.Here,
Antireflection region 130 can be by hydrogenated silicon nitride (SiNx:H), hydrogenated silicon oxynitride (SiOxNy:H), hydrogenation oxygen
SiClx (SiOx:H) or aluminum oxide (Al2O3) make.
Then, as seen in fig. 12d, by using injection print process, spin-coating method or silk screen print method in counnter attack
Penetrate the contamination film 20 forming the impurity including the second conduction type above region 130.
Then, as shown in fig. 12e, by irradiating laser beam at antireflection at antireflection region 130 upper section
Region 130 is formed multiple first open area 181 and second open areas 182 of emitter region 120.
The width W41 of the first open area 181 and width W42 of the second open area 182 is mutually the same, and
The width W41 of the first open area 181 and width W42 of the second open area 182 may each be about 5 μm and arrives
About 15 μm.Multiple first open areas 181 are (that is, to be used for for forming the open area of multiple front electrode 141
The open area of front electrode), and multiple second open area 182 is for forming opening of multiple front busbar 142
Port area (that is, for the open area of front busbar).
Each first open area 181 is the open area for forming each front electrode 141.At front electrode 141
Will be formed in the formation region AA of the front electrode in antireflection region 130 forms the first open area 181.Multiple
Two open areas 182 are the open areas for forming front busbar 142.In order to be formed above with reference to Fig. 9 and Tu
One front busbar 142 of 10 width with about 1mm to 1.5mm described, in antireflection region 130
Front busbar is formed in the AB of region and forms about 30 to 70 the second open areas 182.
When as described above by contamination film 20 irradiate laser beam formed above antireflection region 130 exposure emitter stage
When multiple first open areas 181 in region 120 and the second open area 182, it is arranged in antireflection region 130
The impurity of the second conduction type that the contamination film 20 of top includes further injects into and is doped to emitter region
In the part by the first open area 181 and the exposure of the second open area 182 of 120.
The purpose irradiating laser beam is in order to the expectation part by removing antireflection region 130 is in antireflection region 130
Desired locations form multiple first open area 181 and the second open area 182 and further by the second conductive-type
The impurity of type is doped in the expectation part of emitter region 120.
Therefore, by the part of the illuminated emitter region 120 having laser beam (that is, multiple first open area
181 and second open area 182) part of emitter region 120 that exposes has than not irradiated by laser beam
The higher impurity doping concentration of remainder of emitter region 120.Therefore, the table of the part of emitter region 120
Surface resistance value is less than the initial surface resistivity value of emitter region 120.
Therefore, being exposed by multiple first open areas 181 and the second open area 182 of emitter region 120
Part has lower for sheet resistance value 80 Ω/sq. to the 120 Ω/sq. sheet resistance value (example than emitter region 120
As, 10 Ω/sq. to 50 Ω/sq.).
After the operation irradiating laser beam completes, emitter region 120 becomes the emitter stage of selective emitting electrode structure
Region 121, this emitter region 121 includes the first emitter part 1211 and the second emitter part 1212, the
One emitter part 1211 is arranged in below antireflection region 130 and is all formed as having about 80 Ω/sq. and arrives
The sheet resistance value (that is, first surface resistance value) of 120 Ω/sq., and the second emitter part 1212 be arranged in send out
In the part exposed by multiple first open areas 181 and the second open area 182 of emitter region 120 and shape
Become the sheet resistance value (that is, second surface resistance value) with about 10 Ω/sq. to 50 Ω/sq..
The width W41 of the first open area 181 and width W42 of the second open area can respectively with by first
Width W11 and W12 of the second emitter part 1212 that open area 181 and the second open area 182 are formed
Identical.In multiple second open areas 182 formed to form a front busbar 142 two adjacent second
Interval D 11 between open area 182 can be adjacent with by two second open area 182 formed two
The adjacent interval between the second emitter part 1212 is identical.
Then, remaining contamination film 20 on antireflection region 130 is removed with hydrogen fluorine (HF) acid and pure water.
By irradiating as mentioned above multiple first open areas 181 that laser beam formed in antireflection region 130 and the
Two open areas 182 when using electroplating method to form multiple front electrodes 141 and multiple front busbar 142 for emitter stage
Between region 121 (that is, the second emitter part 1212) and multiple front electrode 141 and emitter region 121
And the contact between multiple front busbar 142.
As it has been described above, or optionally move by use laser beam portion ground to form each front busbar 142
Except antireflection region 130 the part that will arrange a front busbar 142 rather than in order to formed each before conflux
Bar 142 and by using laser beam to remove the portion that will form a front busbar 142 in antireflection region 130 completely
Point.It therefore reduces the area in the antireflection region 130 irradiated by laser beam.
Accordingly, because irradiate the emitter region that the time that laser spends reduces and the thermal conductance that causes due to laser beam causes
121 or the phenomenon of substrate 110 deterioration reduce, therefore decrease and manufacture time and too that solar cell 1 spends
The change of the characteristic of sun energy battery 1.
Additionally, shine directly into the laser beam in antireflection region 130 by use to remove the expectation in antireflection region 130
Part rather than use etching paste or additional masking remove the operation in antireflection region 130.Therefore, formed
The first open area 181 and the second open area 182 in the width ratio of each when using etching paste or mask
Time formed width much smaller.
Accordingly, because reduce the face forming the second emitter part 1212 (that is, high concentration impurities doped portion)
Amass and the width of front electrode 141, therefore reduce the area forming multiple front electrodes 141.
In the present embodiment, irradiate to form multiple first open area 181 and the second open area 182
Laser beam can have the wavelength of 532nm, and the power of laser beam can be about 5W to 20W.Here, can
Power or the irradiation time of laser beam is determined with the material according to antireflection region 130 or thickness.
As described above by each irradiated in multiple first open areas 181 that laser beam is formed and multiple second
The side of each in open area 182 can have plane or convex-concave surface (that is, on-plane surface).
As the second emitter part 12a exposed by the first open area 181 and the second open area 182 and 12b
Two sides when all there is plane, the laser beam of use can have width and the first open area 181 and second is opened
Each identical strips in port area 182.When by the first open area 181 and the second open area
When two sides of 182 the second emitter part 12a exposed and 12b have convex-concave surface, the laser beam of use can
To have each the identical some form in width and the first open area 181 and the second open area 182.
As the second emitter part 12a exposed by the first open area 181 and the second open area 182 and 12b
Two sides time there is convex-concave surface, second exposed by the first open area 181 and the second open area 182
The area of emitter part 12a and 12b increases.Therefore, front electrode 141 and the second emitter part 12a and 12b
The contact area that the contact area of contact contacts with the second emitter part 12a and 12b with front busbar 142 increases.
When use have the laser beam of strips form the first open area 181 and the second open area 182 time, form the
The time that one open area 181 and the second open area 182 spend reduces.
As mentioned above in order to before using electroplating method to be formed electrode zone 140 and formed multiple in antireflection region 130
After first open area 181 and the second open area 182, by by multiple first open areas 181 and many
In the second emitter part 1212 that individual second open area 182 exposes, execution plating is formed and includes multiple front electrode
141 and the front electrode zone 140 of multiple front busbar 142.Here, electro-plating method or photoinduction plating can be used
(LIP) method is as electroplating method.
Therefore, by solution (such as, the KAg (CN of relevant metal ions (such as, silver (Ag) ion) will be comprised2))
It is deposited to the emitter region 121 exposed by multiple first open areas 181 and multiple second open area 182
The second emitter part 1212 perform plating.
As with reference to Figure 10 (a) to Figure 10 (c) described above, the top surface of each front electrode 141 and
The top surface of each front busbar 142 is respectively provided with the curved surface shape according to plating characteristic, and in order to form one
Front busbar 142 and form multiple open areas 182 adjacent one another are.Therefore, in order to form a front busbar
142 and the gold of growth in two the second open areas 182 adjacent one another are in multiple second open areas 182 of being formed
Belong to (that is, a part for busbar 142) to encounter one another above antireflection region 130, thus converge before forming one
Stream bar 142.
Therefore, the width of each front busbar 142 ultimately formed is (that is, with antireflection region 130 and emitter stage portion
Divide the width of the basal surface of each in the front busbars 142 of 1212 contacts) form region AB more than front busbar
Width D 21.
Being as noted previously, as metal-plated growth is isotropic growth, therefore based on each second open area 182
The top surface of the metal part of busbar 142 (that is, front) of plating (that is, is arranged in the side contrary with basal surface
The surface of front busbar 142) also there is curved surface shape.Based on two the second adjacent open areas 182
Perform the antireflection region 130 between metal-plated and metal-plated the second open area 182 adjacent with being arranged in two
Overlapping.Therefore, the height of the top surface of the overlapping part of the metal grown by plating becomes ratio by opening by second
The plating in the second emitter part 1212 that port area 182 exposes and the height of the top surface of metal part that grows are more
High.
Therefore, on antireflection region 130 and in the second emitter part exposed by the second open area 182
The top surface of each front busbar 142 formed on 1212 (that is, is arranged in the front remittance of the side contrary with basal surface
The surface of stream bar 142) there is curved surface shape, it includes having multiple protuberance and the convex-concave surface of multiple recess.
Therefore, the surface roughness of the top surface of each front busbar 142 increases.
The each front electrode 141 included as described above by the front electrode zone 140 of electroplating method formation and each front remittance
Stream bar 142 is shown as having the monofilm structure being made up of the metal of such as silver (Ag), but, in alternative example
In, it can have many membrane structures of the most double film or three films.
When each front electrode 141 and each front busbar 142 have two film construction, contact with emitter region 121
Lower film can be made up of nickel (Ni), and the upper film being arranged on lower film can by silver (Ag) make.Additionally,
When each front electrode 141 and each front busbar 142 have three membrane structures, contact down with emitter region 121
Film can be made up of nickel (Ni), and being arranged in the intermediate coat on lower film can be made up of copper (Cu), and is arranged in
Upper film on intermediate coat can be made up of silver (Ag) or tin (Sn).
Here, the lower film of each front electrode 141 and each front busbar 142 is for by reducing the second emitter part
1212 ohmic contact resistance contacted with lower film are to improve adhesion characteristic.Each front electrode 141 and each front busbar
The intermediate coat of 142 is used for reducing cost and can be had low cost and excellent electric conductivity by such as copper (Cu)
Material is made.When intermediate coat is made up of copper (Cu), it is arranged in the lower film below intermediate coat for preventing and silicon (Si)
The copper (Cu) having the bond strength of excellence be used as to penetrate in the second emitter part 1212 of being made up of silicon (Si) (or
Person is absorbed) thus hinder the impurity of the movement of electric charge.
Additionally, upper film for prevent from being arranged in the film (such as, lower film or intermediate coat) below film oxidized and
The bonding strength of the conductive strips improved and be arranged in above film.
When front electrode region 140 has multilayer film as above, use electroplating method from lower film to upper film order landform
Become the multilayer film with expectation thickness.
Because using depositing process to concurrently form multiple front electrode 141 and multiple front busbar 142, the most multiple front electrodes
141 is identical with material with the membrane structure of multiple front busbars 142.
As shown in fig. 12g, by using the silk screen print method printing cream that comprises silver (Ag) and then cream being done
Dry in the rear surface of substrate 110 corresponding to front busbar 142 be partly formed after busbar pattern 52.Additionally,
By use silk screen print method remaining rear surface of substrate 110 printing aluminium (Al), aluminium (Al)-silver (Ag) or
The cream that comprises silver (Ag) and then by aluminium (Al), aluminium (Al)-silver (Ag) or the cream comprising silver (Ag)
It is arranged in the rear electrode in the rear surface of the substrate 110 not having cloth to postpone busbar pattern 52 with being dried forming part
Pattern 51.Therefore, complete all to include rear electrode pattern 51 and the rear electrode zone map 50 of rear busbar pattern 52.
Here, rear electrode pattern 51 is partially disposed within adjacent rear busbar pattern 52 and can be with adjacent
Rear busbar pattern 52 partly overlap, but can be formed without in the marginal portion of the rear surface of substrate 110
Rear electrode pattern 51.
When substrate 110 is p-type, rear electrode pattern 51 can be made up of the cream comprising aluminium (Al).When substrate 110
When being N-shaped, rear electrode pattern 51 can be by the cream comprising aluminium (Al)-silver (Ag) or comprise silver (Ag)
Cream is made.
Here, can be at the dried electrode pattern of temperature 51 of about 120 DEG C to about 200 DEG C and rear busbar pattern
52.The order forming rear electrode pattern 51 and rear busbar pattern 52 can change.
Then, which has been formed the temperature warp that rear electrode zone map 50 substrate 110 is at about 750 DEG C to about 800 DEG C
Heat-treated technique.
Therefore, define the rear electrode 151 including being connected electrically to substrate 110 and be connected to substrate 110 and rear electrode
The rear electrode region 150 of the multiple rear busbar 152 of 151 and be arranged in the substrate 110 contacted with rear electrode 151
Rear surface in back surface field region 172 (seeing Fig. 1 and Fig. 2).
In other words, by Technology for Heating Processing by the rear electrode pattern 51 of rear electrode zone map 50 and rear busbar figure
Case 52 chemically combines with substrate 110.Thus, rear electrode pattern 51 and rear busbar pattern 52 are formed independently
For rear electrode 151 and multiple rear busbar 152.Here, rear electrode pattern 51 adjacent one another are and rear busbar figure
Case 52 is chemically combined, thus rear electrode 151 and rear busbar 152 electrically couple.
Additionally, in Technology for Heating Processing, the aluminium (Al) that the rear electrode pattern 51 of rear electrode zone map 50 includes
Or silver (Ag) is diffused in substrate 110, thus is formed in substrate 110 and there is impurity more higher than substrate 110
The back surface field region 172 (that is, impurity doping region) of concentration.Thus, rear electrode 151 with have than substrate 110
The back surface field region 172 of higher electric conductivity contacts and is connected electrically to substrate 110.Therefore, it is easier to collect
Electric charge from substrate 110.
In the present embodiment, owing to only forming emitter region 121 in the front surface of substrate 110, so not
Ask the edge isolation that the emitter region for stoping and be arranged in the rear surface of substrate 110 is electrically connected to process or
Person is for removing the extra process of the emitter region formed in the rear surface of substrate 110.Consequently, because decrease
Manufacturing the time that solar cell 1 spends, therefore the productivity ratio of solar cell 1 improves and manufacturing cost reduces.
In the present embodiment, describe following example, wherein formed include multiple front electrode 141 and multiple before conflux
The front electrode zone 140 of bar 142 and then formed and include rear electrode 151 and the rear electrode of multiple rear busbar 152
Region 150.In alternative example, rear electrode region 150 can be initially formed, and then can form front electrode
Region 140.
It is as noted previously, as and forms multiple front electrodes 141 by plating, so when by using silk screen print method to be formed many
During individual front electrode 141, the width of each front electrode 141 is less than the width of each front electrode 141.Therefore, add
The area of the solar cell 1 that light is incident, and improve the efficiency of solar cell 1.
Unlike present embodiment, (that is, arrange when emitter region 121 does not have selective emitting electrode structure
Emitter region 121 below front electrode zone 140 has and except sending out below electrode zone 140 before being arranged in
The sheet resistance value that emitter region 121 outside emitter region 121 is identical, this is because no matter position how, is sent out
Emitter region 121 all has identical sheet resistance value) time, the place of Figure 12 D in omission process described above
Reason.
In the case, after antireflection region 130 is formed on the emitter region 120 of substrate 110, pass through
Above antireflection region 130, direct irradiation laser beam forms multiple first open area in antireflection region 130
181 and multiple second open area 182.
Further the impurity of the second conduction type can be noted additionally, antireflection region 130 either above or below does not exist
Enter the extra contamination film in emitter region 120, and the purpose irradiating laser beam is not doping second further
The impurity of conduction type, but only remove the expectation part in antireflection region 130.Therefore, at emitter region
Extra impurity doping treatment it is not carried out in the part irradiated by laser beam of 120.
Therefore, the part irradiated by laser beam of emitter region 120 and emitter region 120 not by laser beam
The part irradiated has identical impurity doping concentration and sheet resistance value.
As it has been described above, the purpose irradiating laser beam is different from the purpose described with reference to Figure 12 E.Here, the laser irradiated
Bundle can have the wavelength of 355nm.Additionally, material or thickness according to antireflection region 130 determine laser beam
Power (about 5W to 20W) or irradiate laser beam spend time.
In the case, being formed and the process of removal of impurity film 20 because eliminating, therefore decreasing manufacture solar energy
The time that battery 1 spends and the cost manufactured needed for solar cell 1.
In the present embodiment, rear electrode 151 is by using silk screen print method by comprising aluminium (Al) or silver (Ag)
Cream make, and rear busbar 152 is also by using silk screen print method by comprising aluminium (Al) or silver (Ag)
Cream make.
In alternative embodiment, with front electrode 141 and front busbar 142 equally, after also using electroplating method to be formed
Electrode 151 and rear busbar 152.
In the case, with front electrode zone 140 equally, it is possible to use identical depositing process concurrently forms rear electrode
151 and rear busbar 152, thus rear electrode 151 and rear busbar 152 can be manufactured from the same material.
It addition, by using the depositing process for front electrode 141 and front busbar 142 can be with front electrode 141 and front
Busbar 142 simultaneously forms rear electrode 151 and rear busbar 152.In the case, rear electrode region 150
Material is identical with the material of front electrode zone 140.Additionally, rear electrode region 150 can not only have monofilm, also may be used
To have multimembrane, the most double films or three films.
When by electroplating method formed rear electrode region 150 time, rear electrode 151 and rear busbar 152 have double film or
Three films.Instantly when film is made up of nickel (Ni), in back surface field region 172 (that is, substrate 110 with high concentration
Be doped with between the part of the impurity of the first conduction type and rear electrode 151 and substrate 110 and rear busbar 152 it
Between) there is nickel silicide, and between rear electrode 151 and substrate 110 (or back surface field region 172) and
The composition of glass dust it is not detected by between rear busbar 152 and substrate 110 (or rear portion field areas 172).
Figure 12 A to Figure 12 G shows the method manufacturing solar cell 1 shown in Fig. 1 and Fig. 2.Form figure
The method of the solar cell 1 shown in 11 is identical with the method described with reference to Figure 12 A to Figure 12 G, difference
It is quantity and the width of front busbar 142 of the second open area 182 for forming front busbar 142.
In other words, in solar cell 1 shown in fig. 11, a front busbar 142 needs one second
Open area 182.Thus, it is only necessary to formation the first open area 181 shown in fig. 12e and the second open region
The process in territory 182 changes quantity and the width of each second open area 182 of the second open area 182.Therefore,
Eliminate the method manufacturing the solar cell 1 shown in Figure 11.
Describe by using cross tie part to be electrically connected the solar-electricity that multiple solar cells 1 manufacture referring to Figure 13
Pond module.
Solar module 100 includes the multiple solar cells 1 being electrically connected by multiple cross tie parts 210, by structure
Make as protecting the passivating film 220 of multiple solar cells 1, being arranged in the optical receiving surface side of multiple solar cell 1
On passivating film 220 on transparent component 230 and be arranged in the passivating film 220 of the side contrary with optical receiving surface
The rear panel 240 of lower section.
Solar module 100 be may further include and arrived by the element 210 that lamination treatment is integrated for reception
The framework of 240 and for collecting the terminal box of the electric power produced from multiple solar cells 1.
Rear panel 240 for prevent moist invade from the rear surface of solar module 100 and thus protect multiple too
Sun energy battery 1 is from external environment influence.Rear panel 240 can have sandwich construction, it include for prevent moist and
Layer that oxygen invades, for preventing the layer of chemical attack and there is the layer of insulation characterisitic.Rear panel 240 can be by opaque
Material is made.
Passivating film 220 is arranged on multiple solar cell 1 above and below in the matrix form, and multiple too with encirclement
The mode of sun energy battery 1 is integrally forming with multiple solar cells 1 by lamination treatment.Passivating film 220 is used for preventing
The corrosion that causes due to the intrusion of external humidification and for for the multiple solar cell of surge protection 1.Passivating film
220 can be made up of the material of such as ethane-acetic acid ethyenyl ester (EVA).
It is arranged in the transparent component 230 above passivating film 220 by having high-transmission rate and the steel of excellent anti-fracture function
Change glass to make.Safety glass can be the low iron safety glass with low iron content.The inside of transparent component 230 can
With through embossed with increase light dispersion effect.
The multiple sun included according to the solar module 100 of the present invention are described in detail with reference to Figure 14 and Figure 15
The connecting structure for electrical equipment of energy battery 1.
As shown in figure 13 and figure 14, multiple solar cells 1 that solar module 100 includes are with matrix
Form arranges and is coupled by multiple cross tie parts.
As shown in Figure 15, each cross tie part 210 includes the unleaded material of the lead content comprising 1000ppm or lower
The conducting metal (such as, copper (Cu)) 212 of material and the lead-containing materials being coated on the surface of conducting metal 212
Solder (such as, SnPbAg) 214.According to circumstances, the material of coating conducting metal 212 can be not comprise lead (Pb)
Conducting metal (such as, SnAg) and cross tie part 210 can be only made up of conducting metal 212.
As shown in Figure 15, each in the top surface of cross tie part 210 and basal surface have curved surface rather than
Plane.Therefore, before being connected electrically in the basal surface of the cross tie part 210 of busbar 142, in cross tie part 210
The peripheral part of heart part and cross tie part 210 is not disposed on sustained height, but has height difference H 41 (such as,
Figure 20).
Layout in the multiple solar cells 1 being arranged in matrix two adjacent sun in the same row
In energy battery 1, the front busbar 142 being arranged in in two solar cells 1 is by cross tie part 210
Electrically and be physically connected to be arranged in the two solar cell 1 another in each rear busbar 152.This
Outward, be arranged in same row two adjacent solar energy in the multiple solar cells 1 being arranged in matrix
In battery 1, it is arranged in in two solar cells 1 and is not connected to the two solar cell 1
In another front busbar 142 electrically and be physically connected to be arranged in the two solar energy by cross tie part 210
In another in battery 1 and each rear busbar of one that is not connected in the two solar cell 1
152。
The front busbar 142 of the solar cell 1 of the multiple cross tie part of use as above 210 described in detail below
And the attachment structure between rear busbar 152.
As it has been described above, in the present embodiment, front busbar 142 and rear busbar 152 be not directly connected to each mutually
Even part 210, but physics and be electrically coupled to each cross tie part 210 and be inserted with each electroconductive adhesive films 260 therebetween.
As shown in Figure 15, electroconductive adhesive films 260 and cross tie part 210 are sequentially disposed at front busbar 142 respectively
With on rear busbar 152, and electroconductive adhesive films 260 and cross tie part 210 are at front busbar 142 and rear busbar
152 sides extended upwardly extend.
In fig .15, after a front busbar 142 and one, busbar 152 is arranged in the front table of substrate 110
Face and rear surface, and thus it is arranged in the front surface of substrate 110 and the electroconductive adhesive films 260 of rear surface with mutual
Even the quantity of each in part 210 is one.Electroconductive adhesive films 260 and cross tie part 210 are disposed in substrate 110
In each in multiple front busbar 142 in front surface, and electroconductive adhesive films 260 and cross tie part 210 are by cloth
Put in each in the multiple rear busbar 152 in the rear surface of substrate 110.Therefore, substrate 110 it is arranged in
Front surface in quantity and the electroconductive adhesive films 260 being arranged in above front busbar 142 and mutually of front busbar 142
Even the quantity of each in part 210 is identical.The quantity of the rear busbar 152 being arranged in the rear surface of substrate 110
Be arranged in the electroconductive adhesive films 260 above rear busbar 152 and the quantity of each in cross tie part 210 is identical.
As shown in Figure 16 to Figure 19, electroconductive adhesive films 206 includes resin 262 and is dispersed in resin 262 many
Individual conductive particle 264.Resin 262 can be made by having sticking any materials.Preferably, thermosetting tree is used
Fat is as resin 262, in order to increase adhesion reliability.For the ease of describing, Figure 16 to Figure 19 only illustrates it
In coupled a front busbar 142 and the example of a cross tie part 210 by electroconductive adhesive films 260.But, such as figure
Shown in 16 to Figure 19, electroconductive adhesive films 260 busbar 152 and a cross tie part 210 after coupling one.
From epoxy resin, phenolic resin, acrylic resin, polyimide resin, polycarbonate resin select to
Few one can serve as thermosetting resin.
Resin 262 can include that known curing agent and known hardening accelerator are as in addition to thermosetting resin
Special component.Such as, in order to improve between front busbar 142 and cross tie part 210 and busbar 152 and interconnection afterwards
Viscosity between part 210, resin 262 can include reformed material, such as based on silane couplant, based on metatitanic acid
The couplant of salt and couplant based on aluminate.In order to improve the disperse properties of the first conductive particle 264, resin
262 may further include dispersant, such as calcium phosphate or calcium carbonate.In order to control elastic modelling quantity, resin 262
May further include rubber constituent, such as acrylic rubber, silicon rubber or carbamate.
As shown in Figure 16 to Figure 19, conductive particle 264 includes multiple first conductions being respectively provided with the first thickness T1
Particle 2641 and the second conductive particle 2642 being respectively provided with the second thickness T2 less than the first thickness T1.Multiple first
Conductive particle 2641 and multiple second conductive particle 2642 are dispersed in resin 262.
As shown in Figure 16, the first thickness T1 of each in multiple first conductive particles 2641 can be less than leading
The thickness T3 of electricity bonding film 260.
But, the first thickness of each as shown in Figure 17 to Figure 19, in multiple first conductive particles 2641
T1 can be more than the thickness T3 of electroconductive adhesive films 260.In the case, each first conductive particle 2641 is extremely
A few part highlights on electroconductive adhesive films 260.In the case, the thickness T3 of electroconductive adhesive films 260 and tree
The thickness of fat 260 is identical.
In alternative embodiment, in the case of figure 16, conductive particle 264 can only include multiple first conduction
One in particle 2641 and multiple second conductive particle 2642.In the case of Figure 17 to Figure 19, conductive particle
264 can only include multiple first conductive particle 2641.
When electroconductive adhesive films 260 includes that be respectively provided with the thickness of the thickness T3 more than electroconductive adhesive films 260 first conducts electricity
During particle 2641, front busbar 142 and cross tie part 210 are only by first conductive particle 2641 electrically and physically
Connect, this is because the thickness T1 of the first conductive particle 2641 is more than the thickness T3 of electroconductive adhesive films 260.Therefore,
The electric charge collected by front busbar 142 is by preferably and be stably transmitted to cross tie part 210.
At multiple first conductive particles 2641 be respectively provided with the thickness T1 less than the first conductive particle 2641 or conduction
In multiple second conductive particles 2642 of the thickness of the thickness T3 of bonding film 260, as shown in Figure 16 and Figure 19,
At least two the second conductive particle 2642 is handed between front busbar 142 and cross tie part 210 the most each other
Folded, thus form front physical connection path between busbar 142 and cross tie part 210.Therefore, at least two second
The electric charge collected by front busbar 142 is passed through the company formed by multiple second conductive particles 2642 by conductive particle 2642
The electric charge pump connect between path or the first conductive particle 2641 and the second conductive particle 2642 is transferred to cross tie part
210, and busbar 142 moves to cross tie part 210 in the past.
Therefore, the electric charge being arranged in front busbar 142 moves to the first conductive particle contacted with front busbar 142
2641 and second conductive particle 2642, or jump to the most directly directly to contact with front busbar 142 adjacent the
One conductive particle 2641 and the second conductive particle 2642, and once or repeatedly jump to the first adjacent conductive particle
2641 and second conductive particle 2642, thus electric charge busbar 142 in the past moves to cross tie part 210.
In the present embodiment, the thickness T1 and the thickness T2 of the second conductive particle 2642 of the first conductive particle 2641
In each can be about 2 μm to about 30 μm.
Each in first conductive particle 2641 and the second conductive particle 2642 can be by the resin being coated with metal
Particle shape becomes, and it includes from copper (Cu), silver (Ag), gold (Au), iron (Fe), nickel (Ni), lead (Pb), zinc
(Zn), at least one metal of selecting of cobalt (Co), titanium (Ti) and magnesium (Mg) as main component, or can
Using by including that the above-mentioned metal metallic particles as main component is formed.
First conductive particle 2641 and the second conductive particle 2642 all can have the circle as shown in Figure 16 and Figure 17
Shape or elliptical shape, or can have the radial shape as shown in Figure 18 and Figure 19.
Term " radial shape " refers to the shape of metallic particles, wherein has the metallic particles of approximately spherical shape
Multiple projection it has been irregularly formed on surface.
When the first conductive particle 2641 and the second conductive particle 2642 are respectively provided with circle or elliptical shape, first
Each in the thickness T1 of the conductive particle 2641 and thickness T2 of the second conductive particle 2642 can be first to lead
The diameter of each in electricity particle 2641 and the second conductive particle 2642 (that is, is minimum straight in the case of ellipse
Footpath).
When the first conductive particle 2641 and the second conductive particle 2642 are formed by the metallic particles with radial shape
Time, each in the thickness T1 of the first conductive particle 2641 and thickness T2 of the second conductive particle 2642 is permissible
It it is the almost spherical shape of the dummy line formation of the end of the multiple projections formed from the surface being connected to metallic particles
Measure the shortest diameter arrived.
The first conductive particle 2641 and the second conductive particle 2642 made by the metallic particles with radial shape
There is the first conductive particle 2641 and the second conductive particle 2642 than being respectively provided with circle or elliptical shape lower
Ohmic contact resistance, this is because the first conductive particle 2641 and the second conductive particle 2642 and front busbar 142
Increase with at least one contact area contacted in cross tie part 210.
In order to keep front busbar 142 and the stable bonding strength of cross tie part 210 after hardening at resin 262 and glue
Closing intensity, the combined amount of the conductive particle 264 being dispersed in resin 262 can be the total amount of electroconductive adhesive films 260
0.5wt% to 20wt%.
When the combined amount of conductive particle 264 be 0.5wt% or higher time, more stably perform electric charge in the past busbar
The movement of 142.When the combined amount of conductive particle 264 be 20wt% or lower time, more stably perform and front conflux
The connection of bar 142 and bonding.
When electroconductive adhesive films 260 is previously discussed for the electrical connection between front busbar 142 and cross tie part 210,
Include gluing conduction for being attached the overlap joint process of electroconductive adhesive films 260 and cross tie part 210 above front busbar 142
Close film 260 be joined to solar cell 1 front busbar 142 pre-engagement step (that is, the first engagement step) and
The final engagement step (that is, the second engagement step) that cross tie part 210 and electroconductive adhesive films 260 are engaged.
Perform pre-engagement step electroconductive adhesive films 260 to be more stably arranged on front busbar 142.Perform final
Engagement step to be stably joined to electroconductive adhesive films 260 be arranged in the cross tie part 210 above front busbar 142,
Thus front busbar 142 and electroconductive adhesive films 260 and front busbar 142 and cross tie part 210 are by electrically and physically
Stable coupling.Therefore, the pressure at the top being applied to electroconductive adhesive films 260 in pre-engagement step and treatment temperature
(that is, heating-up temperature) is respectively lower than pressure and the process at the top being applied to cross tie part 210 in final engagement step
Temperature.
Such as, in pre-engagement step, heating-up temperature can be about 100 DEG C or lower, and pressure can be about
1MPa.Additionally, in final engagement step, heating-up temperature can be about 140 DEG C to 180 DEG C, and pressure can
To be about 2MPa to 3MPa.
Therefore, front busbar 142 and cross tie part 210 by the electroconductive adhesive films 260 between being stably closely adhering to,
Thus it is typically connected to electroconductive adhesive films 260.Rear busbar 152 and cross tie part 210 are also stably closely adhering to
Between electroconductive adhesive films 260, thus be typically connected to electroconductive adhesive films 260.
Additionally, within the time of heating in pre-engagement step and pressurization can be about set in 5 seconds.Final joint
Within heating in step and the time of pressurization can be about set in 10 seconds.In the case, front busbar 142,
Electroconductive adhesive films 260 and cross tie part 210 do not damage due to heat or deformation.
When the most front busbar 142 and cross tie part 210 are coupled by electroconductive adhesive films 260, electroconductive adhesive films
Heat and pressure that the resin 262 of 260 can be applied in pre-engagement step and final engagement step soften or molten
Melt.In the case, in resin 262 includes the first conductive particle 2641 and the second conductive particle 2642 extremely
At least one entered in cross tie part 210 and front busbar 142 at least some of of few one.
Therefore, when front busbar 142 is joined to cross tie part 210 by electroconductive adhesive films 260, conduction
The contact surface that the contact surfaces that contact with cross tie part 210 of grain 264 and conductive particle 264 contact with front busbar 142
In each become on-plane surface, i.e. be not plane.
It is to say, as shown in Figure 16 to Figure 19, conductive particle 264 is embedded in cross tie part 210 and front busbar
In 142, thus each that embedded in the cross tie part 210 of conductive particle 142 and front busbar 142 has and leads
The surface configuration that electricity particle 264 is identical.
When cross tie part 210 includes conducting metal 212 and solder 214, at least some in conductive particle 264 is permissible
It is embedded into until the solder 214 of cross tie part 210 or can embed until conducting metal 212 via solder 214.
It is embedded in cross tie part 210 when overlap joint task is carried out and by being executed here, conductive particle 264 can be worked as
The pressure distortion added is oval (as shown in Figure 17), or can be when conductive particle 264 is held round
It is embedded in cross tie part 210 (as shown in Figure 16).The shape of conductive particle 2641 and 2642 can be applied in
Hardness according to conductive particle 2641 and 2642 and intensity at least one and the hardness of cross tie part 210 and strong when having pressure
Difference between at least one in degree and change.
Pressure during being processed by control overlap joint, electroconductive adhesive films 260, cross tie part 210 and front busbar 142
Can terminate to be formed as afterwards in overlap joint process to there is identical line width or be made with identical line width.
In alternative embodiment, by controlling the pressure applied during overlap joint processes, terminate it in overlap joint process
After, electroconductive adhesive films 260 can be formed as having bigger than each in cross tie part 210 and front busbar 142
Line width, or electroconductive adhesive films 260 can be made with the width bigger than front busbar 142.Therefore,
Electroconductive adhesive films 260 covers the both sides of front busbar 142, and electroconductive adhesive films 260 is disposed in front busbar
The end of the both sides of 142 and being according to circumstances also arranged on adjacent antireflection region 130.In the case,
Because adding and the contact area of electroconductive adhesive films 260, thus add and the bonding strength of electroconductive adhesive films 260,
Because busbar 142 and cross tie part 210 are more stably joined together before this.
Although not shown, but in alternative embodiment, cross tie part 210 and front busbar 142 can be formed as tool
There is the line width bigger than electroconductive adhesive films 260.
When electroconductive adhesive films 260 used as discussed above connects front busbar 142 and cross tie part 210, front busbar
142 and cross tie part 210 more stably engaged and do not damage or destroy cross tie part 210.
In the present embodiment, because front electrode 141 and front busbar 142 are formed by plating, front electrode 141
With front busbar 142, there is curved surface shape, i.e. be not plane.Therefore, each front electrode 141 and each
The each front electrode 141 of aspect ratio of the part in the core of front busbar 142 and the limit of each front busbar 142
The height of edge portion is higher.
Therefore, as it has been described above, with in the top surface of the cross tie part 210 of front busbar 142 electrical contact and basal surface
Each also has curved surface, is not the most plane.
Therefore, before cross tie part 210 is directly attached to, the ratio of electroconductive adhesive films 260 is not used on busbar 142
In relatively example, because the top surface of front busbar 142 has curved surface shape, and the top table of cross tie part 260
Face and basal surface have curved surface shape, because busbar 142 and cross tie part 260 are difficult to be joined together before this.
In other words, on the surface (that is, top surface) of the front busbar 142 being joined to cross tie part 210 be joined to
Each in the surface (that is, basal surface) of the cross tie part 210 of front busbar 142 has curved surface shape
In the case of, in the top surface of current busbar 142 and the basal surface of cross tie part 210 there is recessed curved surface and
Another in the top surface of front busbar 142 and the basal surface of cross tie part 210 has convex curved surface (vice versa)
Time, it is possible to it is easily performed joint.
Current busbar 142 be directly joined to cross tie part 210 together with time, but, because front busbar 142
Top surface and the basal surface of cross tie part 210 all there is convex curved surface (as shown in Figure 20 (a)), front conflux
The core of bar 142 and cross tie part 210 contacts with each other, but front busbar 142 and the periphery of cross tie part 210
Divide and be spaced from one another by specific interval H51 and do not contact with each other.
Interval H51 between front busbar 142 and cross tie part 210 can be that the core of cross tie part 210 is with mutual
Even poor H41 between the height of the peripheral part of part 210 and the core of front busbar 142 and front busbar 142
Peripheral part height between the sum of poor H42.
Therefore, busbar before using solder flux to be directly bonded to by cross tie part 210 by welding in comparative example
Time on 142, apply pressure by straight for cross tie part 210 by the temperature at about 220 DEG C to 260 DEG C to cross tie part 210
It is connected on front busbar 142.
Owing to front busbar 142 and cross tie part 210 are spaced from one another by interval H51 and cross tie part 210 by than resin
The conducting metal that heat is more insensitive is made, owing to the pressure applied cracks in a part for cross tie part 210
2611 or produce the defect 2612 (Figure 20 (b)) that the part of such as cross tie part 210 is broken.Additionally, at figure
In 20 (a), bonding area and electric conductivity between front busbar 142 and cross tie part 210 reduce, this is because by
Interval H51 between front busbar 142 and cross tie part 210 causes cross tie part 210 and front busbar 142 occur
The part being the most stably joined together.
It addition, when in order to by be spaced from one another by interval H51 and cross tie part 210 facing with each other peripheral part and
When the peripheral part of front busbar 142 engages and increases pressure or the heating-up temperature of applying, there is problems in that
The part that is joined together (such as, the core of front busbar 142 and the core of cross tie part 210) is produced
Raw crackle, or the damage of these parts is caused due to excess pressure, excess temperature etc..In some cases, front
At least one in busbar 142, cross tie part 210 and emitter region 121 can deteriorate due to heat.
But, in the present embodiment, as it has been described above, comprise the resin more more sensitive to heat than conducting metal by use
Electroconductive adhesive films 260 front busbar 142 and cross tie part 210 are joined together.
In the case, the resin 262 of electroconductive adhesive films 260 is applied in pre-engagement step and final engagement step
Thermal softening, and the resin 262 softened has the flexibility bigger than conducting metal and mouldability.
Therefore, it is closely adhering to the top surface of front busbar 142 when electroconductive adhesive films 260 by pressure applied
During with the basal surface of cross tie part 210, the resin 262 of softening is along the front busbar 142 being respectively provided with convex curved surface
Top surface and the surface configuration of basal surface of cross tie part 210 be smoothly molded.Thus, it is respectively provided with curved surface shape
The top surface of the front busbar 142 of shape and the basal surface of cross tie part 210 and electroconductive adhesive films 260 are stably engaged
To together.
Accordingly, because increase flexibility and the mouldability of resin 262 as described above by the ruckbildung of resin 262,
Therefore bonding strength between electroconductive adhesive films 260 and front busbar 142 and electroconductive adhesive films 260 and front busbar
Bonding strength between contact area and electroconductive adhesive films 260 and the cross tie part 210 of 142 contacts and conductive adhesion
The contact area that film 260 contacts with cross tie part 210 increases.Resin is compared having additionally, be substantially reduced or prevent
The cross tie part 210 of less flexibility and mouldability occurs crackle, or destroying or damage cross tie part 210
Dangerous.
Additionally, when using the electroconductive adhesive films 260 comprising resin 262 front busbar 142 and cross tie part 210 to be engaged
To time together, the temperature at about 100 DEG C to 180 DEG C performs to use the lap-joint of electroconductive adhesive films 260 as mentioned above
Reason, this is because resin 262 has the fusing point more much lower than conducting metal 212 or solder 214.But, when such as
In comparative example such cross tie part 210 be directly joined to front busbar 142 together with time, arrive at about 220 DEG C
The temperature of 260 DEG C performs overlap joint and processes.
Accordingly, because much lower than in comparative example of the treatment temperature of present embodiment, therefore prevent front busbar
142, cross tie part 210 and the phenomenon of emitter region 121 deterioration.
When as mentioned above employing multiple second open area 182 to form a front busbar 142, and lead
The top surface of the front busbar 142 of the basal surface contact of electricity bonding film 260 also has curved surface shape.But,
Compared with another embodiment that second open area 182 used as discussed above forms a front busbar 142,
The roughness of the top surface of front busbar 142 and flatness increase.Therefore, electroconductive adhesive films 260 and Qian Hui is improved
Bonding strength between stream bar 142, this is because form a front busbar with using second open area 182
Another embodiment of 142 is compared, and the contact area that front busbar 142 contacts with electroconductive adhesive films 260 increases.This
Outward, because the increase of flatness, therefore electroconductive adhesive films 260 and front busbar 142 are by more stable and easily engage
To together.
Although the attachment structure the foregoing described between front busbar 142, electroconductive adhesive films 260 and cross tie part 210,
But above description can also be applied similarly between rear busbar 152, electroconductive adhesive films 260 and cross tie part 210
Attachment structure.
In the above description, by the multiple protuberances 11 formed in substrate 110 and formed in antireflection region 130
Multiple protuberances 21 between the numerical value (such as, thickness and the degree of depth) that causes of difference in height between difference can be left in the basket,
And the different numerical value in difference in height is assumed identical.
In embodiments of the present invention, the example below, plurality of front electrode 141 and multiple front busbar are described
142 are formed through multiple first open area 181 and multiple second open area 182 through antireflection region 130
And it is connected to emitter region 121.Alternative embodiment party at the solar cell 1a shown in Figure 21 to Figure 23
In formula, multiple front electrodes 141 are connected to emitter region 121 by antireflection region 130, and multiple before conflux
Bar 142a is disposed on antireflection region 130.Here, a part of each front busbar 142a be arranged to
It is connected to the part intersection of each front electrode 141 of emitter region 121.
In the solar cell 1a shown in Figure 21 to Figure 23, have and the solar energy shown in Fig. 1 and Fig. 2
The part of the structure that battery 1 is identical is assigned identical reference, and omits its detailed description.
To this end, unlike the solar cell 1 shown in Fig. 1 and Fig. 2, as shown in Figure 21 to Figure 23,
The each open area 181 of the part exposing emitter region 121 is only arranged to each front electrode 141 times
Side, and there is not multiple open area 182 in the lower section of busbar 142a in each of front.
Therefore, as shown in Figure 23, open area 181 is spaced apart and is formed in the same direction.Here,
Form each position corresponding to the multiple front electrodes 141 of formation, position of multiple open area 181, and multiple opening
The direction that region 181 extends is identical with the direction that multiple front electrodes 141 extend.
In the solar cell 1a according to alternative embodiment, have higher more miscellaneous than the first emitter part 1211
Second emitter part 1212 of matter concentration is only arranged to the lower section of each front electrode 141, and is not arranged in
The lower section of each front busbar 142a.Thus, the most multiple front electrodes 141 are connected to the second emitter part 1212,
And multiple front busbar 142a are connected to antireflection region 130.Additionally, due to arrange each front electrode 141
Each first open area 181 be also formed in the part intersected with each front busbar 142a, so before each
Busbar 142a is connected to emitter region 121 (that is, second in this part intersected with each front electrode 141
Emitter part 1212).
But, in fig 23, the first open area 181 can be not arranged in front electrode 141 and front busbar
In the part that 142a intersects.In the case, it not even for an open area 181 of a front electrode 141
Continue, but cut-off in the part of busbar 142 before arranging.In the case, each front busbar 142a
In the part that front busbar 142 does not intersect with each front electrode 141 and front busbar 142 with each before electric
The part that pole 141 intersects is not connected to emitter region 121, but is disposed on antireflection region 130 also
And directly contact with antireflection region 130.
Because that carry out electrode plating on front electrode 141, the most each front electrode 141 has and Fig. 1 and Tu
The structure that structure shown in 2 is identical.Therefore, each front electrode 141 can have the monofilm being made up of silver (Ag),
Or can have multilayer film, such as, include the lower film being made up of nickel (Ni) and by silver (Ag) the upper film made
Double films or include the lower film being made up of nickel (Ni), the intermediate coat being made of copper and by silver (Ag) or tin (Sn)
Three moulds of the upper film made.
The conductive paste comprising metal material that can use such as silver (Ag) forms front busbar by silk screen print method
142。
Each front electrode 141 and each front busbar 142 can have identical height or differing heights.Using plating
After method defines the multiple front electrode 141 all including at least one film, it is possible to use silk screen print method is formed multiple
Front busbar 142.In alternative embodiment, being formed after multiple front busbars 142, can be formed multiple before
Electrode 141.
In the first open area 181 is also formed in the part that each front electrode 141 and each front busbar 142 intersect
(as shown in Figure 23), time, front electrode 141 can be only existed.But, in alternative embodiment, when first
When open area 181 is also formed in the part that each front electrode 141 and each front busbar 142 intersect, by plating
The film for front electrode 141 formed and the film for front busbar 142a formed by silk screen print method can be together
Time exist.Here, the film formed by plating and the order of film formed by silk screen print method can be according to electricity before being formed
The order of pole 141 and front busbar 142 changes.
In the case, because the height of the part of front busbar 142a that intersects of front busbar 142a and front electrode 141
Degree is higher than the height of the part that front busbar 142a does not intersect with front electrode 141, the most each front busbar 142
Surface there is convex-concave surface.Additionally, because the surface area of front busbar 142a increases, because of busbar 142a before this
The contact area contacted with cross tie part increases.Further, since before front busbar 142a is connected to the portion of electrode 141
Ohmic contact resistance is reduced, so electric charge is easier to electrode 141 in the past and moves to front busbar 142a in Fen.
Although show and describing the present invention according to preferred embodiment, but it will be understood by those skilled in the art that be
Variations and modifications can be carried out in the case of without departing substantially from the scope of the present invention the most defined in the appended claims.
This application claims the korean patent application submitted on February 23rd, 2012 in Korean Intellectual Property Office
The priority of No.10-2012-0018330, its complete content is incorporated herein by reference.
Claims (24)
1. a solar module, described solar module includes:
Multiple solar cells, each solar cell includes: substrate, arrange emitter region on the substrate,
The antireflection region that is arranged on described emitter region, arrange the first electrode on the substrate, be arranged in described
On substrate and be connected to the first busbar of described first electrode, arrange the second electrode on the substrate and cloth
Put on the substrate and be connected to the second busbar of described second electrode；
Cross tie part, described cross tie part by first busbar of in the plurality of solar cell and the plurality of too
First busbar of the adjacent solar battery in sun energy battery or the electrical connection of the second busbar；And
Electroconductive adhesive films, described electroconductive adhesive films is disposed in described first busbar and described second busbar extremely
Few between one and described cross tie part, and comprise the multiple conductive particles being dispersed in resin with by described cross tie part electricity
Gas is connected at least one in described first busbar and described second busbar,
Wherein, described antireflection region includes the first open area and the exposure exposing a part for described emitter region
Multiple second open areas of a part for described emitter region,
Wherein, described first electrode is connected to described first by metal-plated by described antireflection region and opens
The emitter region of the exposure of port area, and described first busbar by metal-plated by described counnter attack
Penetrate the emitter region that region is connected to the exposure of the plurality of second open area；And
Wherein, each first busbar of described first busbar overlaps with the plurality of second open area.
Solar module the most according to claim 1, wherein, the exposure of described first open area
The resistance value of emitter region is more than the emitter region of the exposure of one or more second open area
Resistance value.
Solar module the most according to claim 1, wherein, in the plurality of conductive particle at least
The thickness of one thickness having more than or equal to described electroconductive adhesive films.
Solar module the most according to claim 1, wherein,
At least one in the plurality of conductive particle is embedded in described cross tie part and described first busbar or described
In at least one in second busbar.
Solar module the most according to claim 1, wherein, in the plurality of conductive particle at least
One conductive particle has the thickness of the thickness less than described electroconductive adhesive films.
Solar module the most according to claim 5, wherein, two in the plurality of conductive particle
Or more conductive particles be in direct contact with one another with described cross tie part and described first busbar or described second
At least one in busbar directly contacts.
Solar module the most according to claim 5, wherein, two in the plurality of conductive particle
Or the mediate contact each other of more conductive particles is to conflux with described cross tie part and described first busbar or second
At least one mediate contact in bar.
Solar module the most according to claim 1, wherein, described conductive particle by include from copper (Cu),
Silver (Ag), gold (Au), iron (Fe), nickel (Ni), lead (Pb), zinc (Zn), cobalt (Co), titanium (Ti)
Formed with a kind of or more kinds of resin particle being coated with metal as composition selected in magnesium (Mg).
Solar module the most according to claim 1, wherein, described conductive particle is by metallic particles shape
Become, described metallic particles by from copper (Cu), silver (Ag), gold (Au), iron (Fe), nickel (Ni), lead (Pb),
The one that selects in zinc (Zn), cobalt (Co), titanium (Ti) and magnesium (Mg) or more kinds of make.
Solar module the most according to claim 1, wherein, in the plurality of conductive particle at least
One conductive particle has circle, oval or radial shape.
11. solar modules according to claim 1, wherein, in the plurality of conductive particle at least
One conductive particle has irregular part.
12. solar modules according to claim 1, wherein, described cross tie part is made up of conducting metal.
13. solar modules according to claim 12, wherein, described conducting metal includes 1000ppm
Or less lead content.
14. solar modules according to claim 12, wherein, described cross tie part farther includes to be coated with
Overlay on the solder on the surface of described conducting metal.
15. solar modules according to claim 1, wherein, described first busbar and described second
At least one in busbar includes uneven surface.
16. solar modules according to claim 1, wherein, described electroconductive adhesive films has with described
The width that first busbar is identical with the width of at least one in described second busbar.
17. solar modules according to claim 1, wherein, it is described that described electroconductive adhesive films has ratio
The width that the width of at least one in first busbar and described second busbar is bigger.
18. solar modules according to claim 1, wherein, described antireflection region farther includes
The multiple grooves separated with multiple first open areas, and expose described antireflection region or described emitter region
Territory.
19. solar modules according to claim 1, wherein, described substrate and described first electrode and
Nickel silicide is included between at least one in described first busbar.
20. solar modules according to claim 1, wherein, described first electrode and described first converges
At least one in stream bar is formed by metal-plated, thus defines at least one curved surface shape.
21. solar modules according to claim 1, wherein, described first electrode and described first converges
At least one in stream bar includes:
The first film that plating on the substrate and is made up of nickel (Ni), and
The second film being plated on described first film and be made up of silver (Ag) or copper (Cu).
22. solar modules according to claim 21, described solar module farther includes
Tertiary membrane, described tertiary membrane is plated on described second film, and when described second film is made up of copper (Cu), institute
State tertiary membrane to be made up of silver (Ag) or tin (Sn).
23. solar modules according to claim 1, wherein,
Described first busbar and contact with described electroconductive adhesive films of at least one in described second busbar
One surface has convex curved surface.
24. solar modules according to claim 1, wherein, the height at the center of described electroconductive adhesive films
Degree is less than the height at the edge of described electroconductive adhesive films.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120018330A KR20130096823A (en) | 2012-02-23 | 2012-02-23 | Solar cell module |
| KR10-2012-0018330 | 2012-02-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103296106A CN103296106A (en) | 2013-09-11 |
| CN103296106B true CN103296106B (en) | 2016-08-17 |
Family
ID=46514061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210326349.5A Expired - Fee Related CN103296106B (en) | 2012-02-23 | 2012-09-05 | Solar module |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US9040813B2 (en) |
| EP (1) | EP2631953A3 (en) |
| JP (2) | JP5651651B2 (en) |
| KR (1) | KR20130096823A (en) |
| CN (1) | CN103296106B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130096823A (en) | 2012-02-23 | 2013-09-02 | 엘지전자 주식회사 | Solar cell module |
| KR20130096822A (en) * | 2012-02-23 | 2013-09-02 | 엘지전자 주식회사 | Solar cell and method for manufacturing the same |
| CN106463570B (en) * | 2013-12-19 | 2019-04-30 | 深圳市泽智知识产权有限公司 | Solar battery and preparation method thereof |
| DE102015104236B4 (en) * | 2015-03-20 | 2021-11-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Photovoltaic solar cell |
| JP7064823B2 (en) | 2016-08-31 | 2022-05-11 | 株式会社マテリアル・コンセプト | Solar cells and their manufacturing methods |
| US10325842B2 (en) * | 2017-09-08 | 2019-06-18 | Advanced Semiconductor Engineering, Inc. | Substrate for packaging a semiconductor device package and a method of manufacturing the same |
| WO2019188133A1 (en) * | 2018-03-30 | 2019-10-03 | 株式会社カネカ | Solar cell, solar cell module, and method for manufacturing solar cell |
| CN109494281B (en) * | 2018-12-03 | 2024-01-26 | 乐山新天源太阳能科技有限公司 | PID-resistant device for solar cell |
| US11558010B2 (en) * | 2021-02-22 | 2023-01-17 | Merlin Solar Technologies, Inc. | Method for blackening an electrical conduit |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002373996A (en) * | 2001-04-11 | 2002-12-26 | Daido Steel Co Ltd | Solar battery cell and manufacturing method therefor |
| WO2006005116A1 (en) * | 2004-07-08 | 2006-01-19 | Newsouth Innovations Pty Limited | Laser-formed electrodes for solar cells |
| EP2020688A2 (en) * | 2007-08-02 | 2009-02-04 | Sanyo Electric Co., Ltd. | Solar cell interconnection using thermo-compression bonding and correspondingly fabricated module |
| CN101512781A (en) * | 2006-08-29 | 2009-08-19 | 日立化成工业株式会社 | Conductive adhesive film and solar cell module |
| CN102017163A (en) * | 2008-03-10 | 2011-04-13 | 卡里太阳能公司 | A solar cell and fabrication method using crystalline silicon based on lower grade feedstock materials |
| WO2011046176A1 (en) * | 2009-10-15 | 2011-04-21 | 日立化成工業株式会社 | Conductive adhesive, solar cell, method for manufacturing solar cell, and solar cell module |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004266023A (en) | 2003-02-28 | 2004-09-24 | Sharp Corp | Solar battery and method of manufacturing the same |
| EP1687852A2 (en) * | 2003-11-27 | 2006-08-09 | Kyocera Corporation | Solar cell module |
| JP2005347628A (en) * | 2004-06-04 | 2005-12-15 | Sharp Corp | Electrode forming method, electrode, and solar cell |
| TWI334649B (en) | 2005-09-27 | 2010-12-11 | Lg Chemical Ltd | Method for forming buried contact electrode of semiconductor device having pn junction and optoelectronic semiconductor device using the same |
| US20070144578A1 (en) * | 2005-12-02 | 2007-06-28 | Bp Corporation North America Inc. | Means and Method for Electrically Connecting Photovoltaic Cells in a Solar Module |
| US7638708B2 (en) * | 2006-05-05 | 2009-12-29 | Palo Alto Research Center Incorporated | Laminated solar concentrating photovoltaic device |
| JP5528653B2 (en) * | 2006-08-09 | 2014-06-25 | 信越半導体株式会社 | Semiconductor substrate, electrode forming method and solar cell manufacturing method |
| EP1936698A1 (en) | 2006-12-18 | 2008-06-25 | BP Solar Espana, S.A. Unipersonal | Process for manufacturing photovoltaic cells |
| KR100974221B1 (en) | 2008-04-17 | 2010-08-06 | 엘지전자 주식회사 | Method for forming selective emitter of solar cell using laser annealing and Method for manufacturing solar cell using the same |
| TWI368999B (en) * | 2008-07-15 | 2012-07-21 | Mosel Vitelic Inc | Method for manufacturing solar cell |
| US8633374B2 (en) | 2008-12-18 | 2014-01-21 | Gtat Corporation | Photovoltaic cell comprising contact regions doped through a lamina |
| US20100218821A1 (en) * | 2009-03-02 | 2010-09-02 | Sunyoung Kim | Solar cell and method for manufacturing the same |
| US20100224228A1 (en) * | 2009-03-03 | 2010-09-09 | Jinah Kim | Solar cell and method for manufacturing the same, and solar cell module |
| KR101199822B1 (en) | 2009-04-27 | 2012-11-09 | 쿄세라 코포레이션 | Solar cell element, segmented solar cell element, solar cell module, and electronic appliance |
| WO2010143285A1 (en) | 2009-06-10 | 2010-12-16 | 日東精工株式会社 | Torque sensor |
| KR20100135618A (en) * | 2009-06-17 | 2010-12-27 | 삼성전자주식회사 | Solar cell and method for manufacturing the same |
| KR101057124B1 (en) * | 2009-11-03 | 2011-08-16 | 엘지전자 주식회사 | Solar cell and manufacturing method thereof |
| KR101038967B1 (en) | 2009-12-21 | 2011-06-07 | 엘지전자 주식회사 | Solar cell and method for manufacturing the same |
| WO2011152319A1 (en) | 2010-05-31 | 2011-12-08 | 三洋電機株式会社 | Solar cell module and solar cell module manufacturing method |
| KR101203623B1 (en) * | 2010-06-18 | 2012-11-21 | 엘지전자 주식회사 | Solar cell and method for manufacturing the same |
| CN102893411B (en) | 2010-06-25 | 2015-10-21 | 京瓷株式会社 | The manufacture method of solar cell device and this solar cell device and solar module |
| KR101077504B1 (en) * | 2010-08-17 | 2011-10-28 | 엘지전자 주식회사 | Solar cell module |
| KR101642152B1 (en) | 2010-08-20 | 2016-07-22 | 엘지전자 주식회사 | Solar cell module |
| TWI460871B (en) * | 2011-05-23 | 2014-11-11 | Au Optronics Corp | Solar cell |
| KR101732633B1 (en) * | 2011-05-26 | 2017-05-04 | 엘지전자 주식회사 | Solar cell module |
| TWI601157B (en) | 2011-12-13 | 2017-10-01 | 道康寧公司 | Composition and conductor formed therefrom |
| KR20130096823A (en) * | 2012-02-23 | 2013-09-02 | 엘지전자 주식회사 | Solar cell module |
-
2012
- 2012-02-23 KR KR1020120018330A patent/KR20130096823A/en not_active Application Discontinuation
- 2012-05-15 US US13/472,038 patent/US9040813B2/en not_active Expired - Fee Related
- 2012-06-26 EP EP12004785.7A patent/EP2631953A3/en not_active Ceased
- 2012-08-10 JP JP2012177820A patent/JP5651651B2/en not_active Expired - Fee Related
- 2012-09-05 CN CN201210326349.5A patent/CN103296106B/en not_active Expired - Fee Related
-
2014
- 2014-11-14 JP JP2014231800A patent/JP6006279B2/en not_active Expired - Fee Related
-
2015
- 2015-04-30 US US14/701,197 patent/US9496440B2/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002373996A (en) * | 2001-04-11 | 2002-12-26 | Daido Steel Co Ltd | Solar battery cell and manufacturing method therefor |
| WO2006005116A1 (en) * | 2004-07-08 | 2006-01-19 | Newsouth Innovations Pty Limited | Laser-formed electrodes for solar cells |
| CN101512781A (en) * | 2006-08-29 | 2009-08-19 | 日立化成工业株式会社 | Conductive adhesive film and solar cell module |
| EP2020688A2 (en) * | 2007-08-02 | 2009-02-04 | Sanyo Electric Co., Ltd. | Solar cell interconnection using thermo-compression bonding and correspondingly fabricated module |
| CN102017163A (en) * | 2008-03-10 | 2011-04-13 | 卡里太阳能公司 | A solar cell and fabrication method using crystalline silicon based on lower grade feedstock materials |
| WO2011046176A1 (en) * | 2009-10-15 | 2011-04-21 | 日立化成工業株式会社 | Conductive adhesive, solar cell, method for manufacturing solar cell, and solar cell module |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2631953A2 (en) | 2013-08-28 |
| KR20130096823A (en) | 2013-09-02 |
| US20150249176A1 (en) | 2015-09-03 |
| CN103296106A (en) | 2013-09-11 |
| US9040813B2 (en) | 2015-05-26 |
| US9496440B2 (en) | 2016-11-15 |
| US20130220400A1 (en) | 2013-08-29 |
| JP5651651B2 (en) | 2015-01-14 |
| JP2015053515A (en) | 2015-03-19 |
| JP6006279B2 (en) | 2016-10-12 |
| EP2631953A3 (en) | 2013-12-25 |
| JP2013175703A (en) | 2013-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103296106B (en) | Solar module | |
| US10164127B2 (en) | Module fabrication of solar cells with low resistivity electrodes | |
| CN105874609B (en) | The modular manufacture of solar energy battery core with low resistance electrode | |
| WO2016045227A1 (en) | Main-gate-free and high-efficiency back contact solar cell module, assembly and preparation process | |
| US20160163903A1 (en) | High-efficiency pv panel with conductive backsheet | |
| CN105027301B (en) | Independent metal part for semiconductor | |
| JP2018500775A (en) | Non-main grid high-efficiency back contact solar cell, assembly and manufacturing process thereof | |
| KR20140110231A (en) | Solar cell and method for manufacturing the same | |
| CN110335912B (en) | Photovoltaic conductive glass, solar cell double-glass assembly and preparation method thereof | |
| CN104269454B (en) | High-efficiency back contact solar cell back sheet without main grids, high-efficiency back contact solar cell assembly without main grids and manufacturing technology | |
| CN204204885U (en) | Without main grid high efficiency back contact solar cell backboard | |
| US11189738B2 (en) | Solar cell side surface interconnects | |
| CN104319301A (en) | Main gate-free, high-efficiency and back-contact solar battery backplane, assembly and preparation process | |
| JP2024084109A (en) | Photovoltaic Module | |
| CN102820357A (en) | Solar cell module | |
| US20220293809A1 (en) | A method of forming a device structure | |
| CN204088340U (en) | Without main grid high efficiency back contact solar cell backboard | |
| CN109449236A (en) | A kind of interconnection mode between heterojunction solar battery | |
| CN209471983U (en) | A kind of interconnection architecture between heterojunction solar battery | |
| CN204088342U (en) | Without main grid high efficiency back contact solar cell assembly | |
| CN110085692B (en) | Photovoltaic conductive backboard, solar cell module and preparation method of photovoltaic conductive backboard | |
| WO2021106417A1 (en) | Photovoltaic cell, photovoltaic cell module, and method for manufacturing photovoltaic cell | |
| US10749061B1 (en) | Solar cell edge interconnects |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160817 Termination date: 20180905 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |