CN1032898C - Method for preparing artificial sea cucumbers - Google Patents
Method for preparing artificial sea cucumbers Download PDFInfo
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- CN1032898C CN1032898C CN92109818A CN92109818A CN1032898C CN 1032898 C CN1032898 C CN 1032898C CN 92109818 A CN92109818 A CN 92109818A CN 92109818 A CN92109818 A CN 92109818A CN 1032898 C CN1032898 C CN 1032898C
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Abstract
The present invention relates to a technology method for preparing artificial sea cucumbers, which is characterized in that seatangle is directly used as the main raw material, the seatangle becomes slurry through chemical treatment, and egg white and soybean protein are added to the slurry; then, the slurry is poured into an improved sea cucumber mould with a wooden core of which one end is provided with a lace hole, and the mould is dipped in the mixed liquid of calcium gluconate and calcium lactate, so that the slurry is solidified; after being shaped, the solidified slurry is softened so as to obtain the artificial sea cucumbers. The sea cucumbers which are prepared by the technology method have the advantage of low cost, and the nutrient components of the original seatangle are reserved, so the sea cucumbers have high nutritive values and are good slimming food and curative food.
Description
The method for production of a kind of bionical sea cucumber, the manufacture technology technology of the manufacture technology, particularly artificial sea cucumber of genus bionic foods.
Bionic foods is an emerging technology, in the existing technology, the production technology patent No. 87105149 of artificial sea cucumber is arranged, and is the preparation method of bionical sea cucumber in addition, the patent No. 87103581.2.
The manufacture method of above-mentioned disclosed two bionical sea cucumbers also exists shortcoming and defect, as: the technology primary raw material of the bionical sea cucumber of this binomial all is to be primary raw material with the sodium alginate, and sodium alginate is Sodium Alginate, (C again
8H
7O
6Na) n can be used as thickener, does the cost of material height with it in food additives, and main is that various nutritional labelings in the sea-tangle do not exist; And raw material is done with starch in these bionical sea cucumber middle parts, starch is a kind of polysaccharose substance, food can change into glucose behind enteral digestion, after being absorbed by the body, in human body cell, change into energy and heat, sharp have more than is needed sugar just will change into fat, be stored in subcutaneous and the abdominal cavity omentum majus, and this has just increased the factor of getting fat of human body.The food of advocating in the world is high protein, low sugar, low-fat food at present, and therefore adding starch is that raw material is unfavorable, in addition, return product and bring bad mouthfeel, and as not tasty and refreshing, no tenacious and persistent will etc.
Also added agar and gelatin in the bionical sea cucumber, these two kinds of materials are the cost height not only, the more important thing is after these two kinds of materials are heated to dissolve again, if during with this bionical sea cucumber cooking, and the dish of making, its color shape is influenced by it all can.
What have makes coagulating agent with calcium chloride, and the bionical sea cucumber of making like this can have a large amount of bitter tastes, can bring bad mouthfeel to product.
The pigment of above-mentioned two bionical sea cucumbers is to be imitative source of joining pigment with laver or black soya bean pigment, and this also can bring many disadvantageous aspects to bionic foods, as has increased cost, makes process complications, brings harmful effect or the like to product.
The mould that bionical sea cucumber is used also has many disadvantages, if any mould in mould do not have the reel body, in process of setting, need to join abdomen halfway and cut open, take out the virgin pulp liquid that does not have curing, then continue again to solidify, do like this and cause waste on the one hand, the virgin pulp liquid that takes out can not continue to use, because mixed solidification liquid in these slurries, forms many cakings in wherein, so lost the value that continues application, this just causes unnecessary waste.It is even to make the sea cucumber became uneven on the other hand, even has plenty of solid.The mould of another kind of bionical sea cucumber has core body, and this core body is a round log rod, and the sea cucumber stomach wall of making like this is too thick, ginseng body gage distortion.
Ginseng body after last two kinds of bionical sea cucumbers are solidified lacks softening the processing, causes bionical sea cucumber sclerosis, and sense organ is not beautiful, and mouthfeel is also bad.
Above-mentioned bionical sea cucumber has adds natural broken sea cucumber milk in slurry, this has not only increased cost, and the source of raw material is restricted, and the tenacious and persistent will of the sea cucumber that solidifies out can weaken greatly, and mouthfeel is also poor.
In view of the deficiency of above-mentioned technology, purpose of the present invention provides that a kind of mouthfeel that is of high nutritive value is good, cost is low, image good, and has the method for production of the bionical food of sea cucumber of certain curative effect.
The objective of the invention is to realize by following technical scheme: present technique is to be primary raw material with the sea-tangle, treatedly make it be dissolved into slurries, allocate egg white and soybean protein again into, injection is through improved mould, solidify in the mixed liquor of immersion calcium gluconae and calcium lactate, get product through softening the processing again after the moulding.
Prescription of the present invention and technical process:
One, prescription by weight
Major ingredient: the clear 40g soybean protein of bright sea-tangle dish 100g egg 20g
Material delivering: soda ash (Na
2CO
310H
2O) 5g
Inorganic acid (HCl) 1% 50g
Organic acid (citric acid) is an amount of
Thickener (sodium alginate) 10g
Water 400g
Two, operation
At first join slurry
1, with bright sea-tangle 100 grams, add 1% watery hydrochloric acid 50 grams, (purpose that adds usefulness watery hydrochloric acid is except the mucus of removing the sea-tangle surface to add water 200～250 gram bubble flush away silts and mucus, can also tentatively destroy the crude fibre on sea-tangle surface, make next step alkali dissolving accelerate speed, pull sea-tangle out, clean several times with water purification again, remove surperficial acid solution.Pull out and spill solid carbon dioxide, with cutter slitting piece, (or pulverize with pulverizer) put into container and added water 400 grams, adds soda ash 5 grams, and heating is boiled, and changes that little fire is stewing to boil 15 fens kinds, leaves standstill two hours from fire, and this process is the process that sea-tangle is dissolved in alkali lye.
2. take by weighing soybean protein 20g, add water 50 gram and stir the molten 40 gram eggs (clearly) that add again and stir molten stand-by with soya-bean milk water.
3. taking by weighing sodium alginate 10 gram adds water 200 grams and stirs molten.
4. above three kinds of glues that prepare are added together, it is even with the colloid mill mill again to stir well the even an amount of preservative sodium benzoate (pressing food law regulation addition) that adds, survey its acid-base value with litmus paper, with citric acid allotment pH value is between 6.9～7.1, so far join the slurry process and all finish, next step will be an injection molding.
Three, injection molding and curing:
1. the preparation of consolidation liquid: calcium gluconae 100 gram, calcium lactate 100 grams, the deficiency that overcomes prior art adds water 2000 grams, and is solvent, leave standstill 10 minutes stand-by.
2. injection molding: the sea cucumber mould is put into soaked 5 fens kinds in the consolidation liquid for preparing earlier, taking-up is anhydrated, backform and bed die and reel body are covered, use lanyard, the confected materials slurries are injected in the mould from mould lace hole, enter in the consolidation liquid immediately after filling with, solidify to take out in four hours and remove stationary rope, take off bed die, cut the ginseng abdomen open with blade and take out the reel body, put into consolidation liquid again and solidify for the second time, it is capable of bionical sea cucumber to remove backform after two hours, send consolidation liquid again to and solidify for the third time, take out after one hour and wash with bubble.
3. finishing
After the ginseng body and function clear water that is cured bubble washed, remove the corner, used bubble again 1～2 hour with the scissors finishing.
4. quality-improving is softening with the ginseng body:
Ginseng body after curing and the shaping is soaked with potassium chloride and sodium chloride again, potassium chloride is 1: 4 with the ratio of sodium chloride, add water and be mixed with 3% solution, to join body and put immersion into, take out after two hours, at this moment join body and just become bright, soft cunning is translucent, do not have great difference with natural waterishlogged Stichopus japonicus, at this moment whole technical process finish.
5. used mould is by backform and bed die in the technology, and two compositions up and down for space of the imitative sea cucumber bodily form, also have real core body in the middle of it in its space, and an end of real core body has the plug in lace hole, supports stable between backform and bed die of core body really.
Effect compared with prior art of the present invention and advantage:
1. bionical sea cucumber virgin pulp liquid of the present invention has changed to be cooked major ingredient with sodium alginate but is primary raw material with sea-tangle, the cost of bionical sea cucumber is reduced, various nutritional labelings in the sea-tangle all do not have destroyed untouched remaining simultaneously, with sea-tangle is the sea cucumber that raw material is made, and its nutritive value is than high many of the bionical sea cucumber made from sodium alginate.Contain protein 8.2 grams, 1177 milligrams of calcium, 150 milligrams of iron, 216 milligrams in phosphorus, 24 milligrams of iodine, 1503 milligrams in potassium, 460 milligrams in magnesium, 140 milligrams in fluorine, 0.57 milligram of carrotene, Cobastab in per 100 gram sea-tangles
1(thiamine) 0.09 milligram, Cobastab
2(riboflavin) 0.36 milligram, 1.6 milligrams of niacins.Especially the amount that contains water-soluble cellulose is very big, belongs to alginic acid and its esters, this cellulose can not by human body change into can with heat.Has satiety, but can not make body fat, opposite sea-tangle is a kind of good diet food, can promote gastral function again, make defecation smooth, it is a kind of good anticancer food, can reduce brown fat matter and peroxide in cholesterol and blood fat, the removing blood again, therefore be a kind of good anti-senility, promote longevity and the food of body-building and face-beautifying, world many countries is attached great importance to kelp food at present, China people like very also that to sea-tangle especially those are away from the outlying district in sea, and it is common endemic disease that human body lacks iodine.Most of people are to the peculiar smell of sea-tangle, and be difficult to digestion, and feel bad, know perfectly well nutritious, but be reluctant mostly to make inquiries, especially can not enter refined taste, if, be dissolved into slurries with the chemical treatment of sea-tangle process, make bionic foods again, not only eliminated peculiar smell, the food back is digestion easily also, can make various delicious foods.Enumerate a table below, contrast the comparison of contained mineral matter of natural sea cucumber and sea-tangle and vitamin.The per 100 gram units of table 1: milligram
| Ca | P | Fe | I | K | Mg | F | VB 1 | VB 2 | Niacin | |
| Sea-tangle | 1172 | 216 | 150 | 24 | 1503 | 460 | 140 | 0.09 | 0.36 | 1.6 |
| Sea cucumber | 357 | 12 | 2.4 | X | Trace | Trace | Trace | 0.01 | 0.02 | 0.1 |
By last table as can be seen sea-tangle nutrition except protein less than the natural sea cucumber, remaining minerals and vitamins all is higher than sea cucumber far away.
2. the present invention has added the so deficiency of not only enriching and improved protein in the sea-tangle slurries of the cleer and peaceful soybean protein of egg in the sea-tangle slurries, what is more important has been replenished the deficiency of animal protein, complete eight kinds of essential amino acids of needed by human body in the bionical sea cucumber, raw egg clearly can sex change during cooking in bionical sea cucumber on the other hand.This is the intrinsic characteristic of animal protein, and it can strengthen coagulation force when heated denaturalization matter, makes bionical sea cucumber have more elasticity and toughness.The variation of bionical sea cucumber when cooking so just in time with existing bionical sea cucumber in gelatin and the variation of agar be opposite reaction, egg white is heated more, solidify more, gelatin and agar then are the dissolvings more of being heated more just, have more the principle of elasticity, toughness after the bionical sea cucumber that Here it is adds egg white is heated.
The present invention has also added the soybean protein of solubility except adding egg white, soybean protein is best protein in value thing protein, and it almost can be compared with animal protein.Except methionine, other essential amino acid portion can with its than U.S., the deficiency of this point is remedied by egg white again, egg white is animal protein, wherein the content of methionine is particularly high.In addition, the coagulation force that soybean protein is met calcium is very strong, and it is exactly with calcium salt (bittern or gypsum CaCl that our the daily beans of eating are paid
2Or CaSO
4) soya-bean milk of ordering becomes.This soybean protein is joined in the slurries of bionical sea cucumber, still do not improve its nutritive value, also strengthened coagulability at solidification liquid.
3. the present invention does not add other pigment, but with the pigment source of the pigment of sea-tangle as bionical sea cucumber own, this has not only reduced technical process, shortened the time of production technology, also reduced cost, this pigment is nontoxic, has improved the safe and sanitary sense of bionic foods.
4. the present invention improves aspect coagulating agent, with calcium gluconae and each equivalent of calcium lactate, does coagulating agent, and these two kinds of calcium salt portions are soluble-salts, and both form reversible reaction in a kind of solvent.
Excited the activity of calcium ion in this reaction, this has just quickened the solidification process of bionical sea cucumber.Shortened the time of solidifying.
5. improve on mould, moduli is made two, top flat is a main body, and egative film is for paying body, and also dying into the reel body in the centre, has so not only made things convenient for injection molding curing, also makes sea cucumber sense more true to nature.
6. the bionical sea cucumber of moulding is softened and quality-improving, existing bionical sea cucumber does not have this road technical process, the present invention puts the ginseng body of moulding in the solution of potassium chloride and sodium chloride softening again, the calcium ion of ginseng body surface layer is reduced, perhaps make the calcium ion that has solidified form active ion, not only soft true to nature through the ginseng body of handling like this, the same with waterishlogged Stichopus japonicus, but also making the intensely dark ginseng body transparent hypertrophy that becomes, gloss is satiny.Potassium chloride is 1: 4 with the ratio of sodium chloride, and the reaction in same solvent is reversible,
The K ion in the solution and the activity of Na ion strengthen, and make the calcium activation of its surperficial calcium alginate.Make the calcium alginate recovery on top layer be potassium alginate, so impel bionical sea cucumber to be the soft satiny and translucent sense of tool.
7. the present invention has added an amount of Sodium Benzoate in order to allow the shelf-life of sea cucumber prolong when joining slurry, in case slurries and putrid and deteriorated in moulding have also added Sodium Benzoate in consolidation liquid, the ginseng body shelf-life through handling like this prolongs.
8. reinforcement sea cucumber of the present invention, added multivitamin and phosphate, to growing of human body, disease-resistant health care plays very important effect, VB
1Add the metabolism of carbohydrate at the body confidential reference items, to keeping normal nerve conduction, the normal activity of heart digestive system is had important function.VB
2Be the vitamin that promotes that body growth is grown, change lactofiavine phosphate and yellow adenine two nucleic acid etc. into through phosphorylation in vivo and become a kind of enzyme unit that regulates oxidizing process with combined with protein, this kind of enzyme participates in the metabolic process of protein and fat, if multiple disease will take place in the above-mentioned two kinds of vitamin deficiencies of human body, as polyneuritis, beriberi heart disease, stomatitis and various dermatitis.The metabolic process of vitamin C and body complexity can promote the formation of antibody in the human body, increases the resistance to various diseases, also has detoxication.Countries in the world are very paid attention to VC at present, and electricity is an additive main in the present condensed food.Add phosphatic effect have following some, the one, increase the P elements in the bionic foods because the calcium salt content in the sea-tangle is very high, human body has certain ratio to the absorption and the phosphorus of calcium, if phosphorus content deficiency then can influence human calcium's utilization.So increase the phosphorus amount in right amount for better absorption and utilization to calcium, phosphate can also improve the moisture holding capacity of product in the higher food of edible protein on the other hand, when solidification process, bionical sea cucumber just can not lose too much moisture like this, has kept the tender and pliable and tough of product.
9. disinfection by ultraviolet light: virgin pulp liquid of the present invention will be used the vitalight lamp sterilizing before injection molding.The disinfection method is than good many of steam and heating disinfection, because can guarantee the concentration of slurries so like this.
Fig. 1 is a mold top holder schematic diagram of the present invention.
Fig. 2 is a mold bottom die schematic diagram of the present invention.
Fig. 3 is a mould reel schematic diagram of the present invention.
1-backform, 2-bed die, 3-reel, 4-lace hole.
The present invention improves on the basis of existing technology to mould, is characterized in that solid (3) is oval-shaped reel (3), is that lace is poroid at the one end, for supporting backform and bed die, is the reperfusion serosity entrance in addition on the one hand.
The following specifically describes one embodiment of the invention.
Get bright sea-tangle 250g and clean, after water cleans again, sea-tangle is drained the water, go into aluminum pot, soda ash (Na after the chopping (0.5cm striped blocks) through 1% dilute hydrochloric acid solution
2CO
310H
2O) 12 grams add water 1000 grams, after very hot oven boils, change low baking temperature stewing 15 minutes, leave standstill two hours to 4 hours from fire, make the sea-tangle dissolving.
In another container, add soybean protein 50 grams and add water 130 grams and stir moltenly, add freshly-slaughtered poultry egg white 100 grams and soya-bean milk liquid again and stir well even together.
Take by weighing mosanom 20～25 grams (increasing and decreasing in right amount) and add water 400～500 grams, stir molten according to concentration.
Sea-tangle liquid, soybean egg white solution, mosanom liquid added together stir well, add Sodium Benzoate 2 grams again, test acid-base value with litmus paper, regulate with citric acid, make it pH value and reach 6.9～7, utilization colloid mill mill is even, left standstill 10～20 minutes, injection molding solidifies, and consolidation liquid is that (use the disinfection by ultraviolet light sterilization before solidifying, method is that virgin pulp liquid is slowly flowed to another container for 5～8% calcium gluconae and the mixed liquor of calcium lactate, a ultraviolet lamp is pressed on top at flow path) in consolidation liquid, before and after solidify three times, through wash bubble, prunings, warp softens again, is finished product.
The course of dissolution of sea-tangle is that the composition of sea-tangle is the algal polysaccharides based on algin, and it is that many alginic acid combination of monomers form with the similar long-chain corpus fibrosum of cellulose.
These marine alga saccharic acids are organic acids, all belong to weak acid, and their bonding forces in long-chain are strong, if under the influence of inorganic acid (as at H
2SO
4HNO
3HCl) between strong acid and the weak acid displacement reaction has taken place.
In reaction, H has produced exchange, has so just impacted the bonding force between the alginic acid fibre, and its stability is weakened, and adds alkali (salt of actual usefulness, basic salt Na subsequently
2CO
3) make alginic acid and sodium carbonate salt play displacement reaction, generating sodium alginate and carbonic acid, carbonic acid is decomposed into carbon dioxide and water under normal pressure.In this reaction, disintegrated by the alginic acid fibre of long-chain, or be the monomer sodium alginate, and generated new acid, promptly carbonic acid is decomposed into carbon dioxide and water immediately.Sodium alginate is a kind of soluble-salt, becomes hydrophilic ionic group after its hydrophilic group suction, forms colloid.This is the overall process of sea-tangle dissolving.After the somebody eats sea-tangle, feel that belly feels bad, this is because the nondigestible symptom that occurs of sea-tangle, if add some points food alkali (sodium carbonate Na less when boiling sea-tangle
2CO
310H
2O).Just do not have this sensation after eating, this is because run under one's belt after the acid (HCl) again and sodium ion (Na
+) reaction, generate sodium alginate and dissolved.
Though sea-tangle can be dissolved under the effect of acid and alkali, but still can not be digested and assimilated, can not be utilized by human body, the material that belongs to hemicellulose and pectic substance and so on character, in human body, can not produce monomer glucose, thereby the tricarboxylic acid cycle that can not enter human body, can not carry out biological oxidation process, so do not belong to heat production nutrients, the sea-tangle fiber can also stimulate the wriggling ability of intestinal tube, strengthens the function of defecation, be regarded as abroad at present and prevent and treat the optimal food of intestinal cancer, it can remove the deposit on the intestinal mucosa cells again, removes cholesterol and glyceride in the blood vessel, so sea-tangle is again desirable diet food.
People are reluctant that edible sea-tangle is not its bad digestion, and also have a kind of special disagreeable taste, if according to said method handle, above-mentioned contradiction all can be eliminated.To be a kind of rising food from now on.
Claims (1)
1. the method for production of a bionical sea cucumber, comprise the mould of forming by backform bed die, solid, it is characterized in that: the bionical sea cucumber of this kind is to be primary raw material with the sea-tangle, and is treated, makes it be dissolved into slurries, allocate the cleer and peaceful soybean protein of egg again into, inject then through improved mould, solid is that an oval end has lacy hole, immerses in the calcium gluconae calcium lactate mixed liquor to be cured again, promptly obtain bionical sea cucumber finished product through softening processing again after the moulding
A, its prescription: (by weight)
Major ingredient: bright sea-tangle dish 100g
The clear 40g of egg
Soybean protein 20g
Material delivering: soda ash (Na
2CO
310H
2O) 5g
HCl 1% 50g in the inorganic acid
Citric acid in the organic acid is an amount of
Sodium alginate 10g in the thickener
Water 400g
B, processing step
(1) at first be to join slurry, fresh sea-tangle 100g is added 1% watery hydrochloric acid 50 grams, add water 200～250 gram bubbles and wash, remove silt and mucus, pull out and spill solid carbon dioxide, be cut into striped blocks or pulverizing by knife, put into container and add water 400 grams, add soda ash 5 grams, heat to boil afterwards and boiled 15 minutes so that little fire is stewing, leave thermal source, left standstill two hours
(2). get soybean protein 20g, add water 50 gram, stir molten add again 40 gram eggs stir with soya-bean milk water clearly molten stand-by,
(3). get sodium alginate 10 grams and add water 200 grams,
(4). above-mentioned three kinds of glues that prepare are added together, and stirring adds an amount of preservative sodium benzoate again, even with the colloid mill mill again, surveys its acid-base value with litmus paper, is between 6.9～7.1 with citric acid allotment pH value, and so far join the slurry process and all finish,
The C injection molding solidifies
The preparation of consolidation liquid:
(1) calcium gluconae 100 gram, calcium lactate 100 grams, add water 2000 grams solvent leave standstill 10 minutes stand-by,
(2) injection molding: the sea cucumber mould is put in the consolidation liquid for preparing, soaked 5 minutes, taking-up is spilt and is anhydrated, backform and bed die and reel body are covered, be fastened with rope, the former raw slurry for preparing lace hole from the mould is poured in the mould, putting into consolidation liquid after filling with immediately carries out solidifying the first time, wait to solidify after four hours and take out mould, open and take off bed die, cut the ginseng abdomen open with cutter and take out the reel body, putting into consolidation liquid again solidifies for the second time, remove backform after two hours and obtain bionical sea cucumber, solidify for the third time again to take out after one hour and wash with the clear water bubble
(3) finishing
After the bionical cleaning sea cucumber, with the scissors finishing, remove the corner, the water purification bubble is 1～2 hour again,
(4) quality-improving is softening with the ginseng body
With solidify and shaping after the ginseng body soak with potassium chloride and sodium chloride again, the ratio of potassium chloride and sodium chloride is to add water at 1: 4 to be mixed with 3% solution, bionical sea cucumber is put into immersion, taking-up after two hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92109818A CN1032898C (en) | 1992-08-05 | 1992-08-05 | Method for preparing artificial sea cucumbers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92109818A CN1032898C (en) | 1992-08-05 | 1992-08-05 | Method for preparing artificial sea cucumbers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1074814A CN1074814A (en) | 1993-08-04 |
| CN1032898C true CN1032898C (en) | 1996-10-02 |
Family
ID=4944371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92109818A Expired - Fee Related CN1032898C (en) | 1992-08-05 | 1992-08-05 | Method for preparing artificial sea cucumbers |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1032898C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1388297A1 (en) * | 2002-08-06 | 2004-02-11 | Nestec S.A. | Calcium absorption enhancer |
| CN1305411C (en) * | 2004-04-20 | 2007-03-21 | 大连轻工业学院 | River crab bionic food and its preparing method |
| CN101869233B (en) * | 2010-06-04 | 2012-11-07 | 上海师范大学 | Application of sodium alginate composite food heat-resistant adhesive in preparing Taiwan baked sausage |
| CN102106549A (en) * | 2011-02-18 | 2011-06-29 | 福州素天下食品有限公司 | Method for preparing simulated sea cucumber |
| CN102626228A (en) * | 2012-03-20 | 2012-08-08 | 天津科技大学 | Bionic abalone and preparation method thereof |
| CN103549516B (en) * | 2013-11-01 | 2015-03-11 | 青岛明月海洋科技有限公司 | Preparation method for instant seaweed fresh vermicelli |
| CN114343139A (en) * | 2021-12-29 | 2022-04-15 | 好当家集团有限公司 | Preparation method of artificial sea cucumber |
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1992
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Also Published As
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|---|---|
| CN1074814A (en) | 1993-08-04 |
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