CN103289801A - Special transmission extreme-pressure anti-wear lubricating oil combination for rotary drilling rig - Google Patents

Special transmission extreme-pressure anti-wear lubricating oil combination for rotary drilling rig Download PDF

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Publication number
CN103289801A
CN103289801A CN2013101904013A CN201310190401A CN103289801A CN 103289801 A CN103289801 A CN 103289801A CN 2013101904013 A CN2013101904013 A CN 2013101904013A CN 201310190401 A CN201310190401 A CN 201310190401A CN 103289801 A CN103289801 A CN 103289801A
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China
Prior art keywords
pressure anti
extreme
drilling rig
rotary drilling
wear
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CN2013101904013A
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CN103289801B (en
Inventor
陆希峰
王士平
袁俊洲
何茂伟
刘珊珊
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Shandong Xiaosong Oil Products Co., Ltd.
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Shandong Source Root Petrochemical Co Ltd
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Abstract

The invention discloses a special transmission extreme-pressure anti-wear lubricating oil combination for a rotary drilling rig, and belongs to the field of production of lubricants. The combination is formed by mixing lubricant base oil, a pour point depressant, an S extreme-pressure anti-wear additive, a P extreme-pressure anti-wear additive and a system deformation resisting agent. Compared with the prior art, the special transmission extreme-pressure anti-wear lubricating oil combination for the rotary drilling rig has the characteristics of being high in extreme-pressure anti-wear performance and bearing capacity and high in popularization and application value.

Description

The special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig oil compositions
Technical field
The present invention relates to the lubricant production field, specifically the special-purpose transmission extreme-pressure anti-wear lubricating of a kind of rotary drilling rig oil compositions.
Background technology
Quick increase along with the engineering mechanical device kind, rotary drilling rig arises at the historic moment, and digs power resources partly in the oil motor of the hydraulic efficiency system of rotary drilling rig revolving of rotary drilling rig, the rotation of oil motor driven gear step-down gear, gear reduction unit drives the drilling rod rotation, thereby realizes rotary operation.In the prior art, the lubricating oil of rotary drilling rig is antiwear hydraulic oil.
The use of rotary drilling rig has improved working efficiency greatly, but the work-ing life of gear reduction unit is extremely short.Lost efficacy through the dissection of gear reduction unit being discovered gear heavy wear, even the broken teeth phenomenon arranged, its major cause is: one, the heterogeneity of the inner hardness in stratum, impact load takes place at any time, the over-all properties of antiwear hydraulic oil does not satisfy this gear train lubricated needs, particularly extreme pressure and antiwear behavior far away; Therefore two, rotary drilling rig is that hydraulic efficiency system and gear train are combined togather, and just requires this lubricating oil can satisfy the need of work of hydraulic efficiency system, satisfies the needs of gear train again.Particularly the lubricated oil viscosity of oil motor is the smaller the better to hydraulic efficiency system, but the lubricated oil viscosity to gear is to be the bigger the better, the gear lubrication oil viscosity is more big, the ability that relaxes impact load is just more big, the ability of anti-load is also more high, and antiwear hydraulic oil of the prior art can't satisfy the requirement of hydraulic efficiency system and gear train simultaneously.
Though, say in theory, can reduce the tooth of gear and the load between the tooth by the size that adds master wheel, will cause gear train very big like this, be unfavorable for the lightweight of engineering mechanical device and the movement of equipment.
Therefore how solve by lubricated, have very important significance the work-ing life of lubricating, prolong this system that the performance of several aspects is combined to satisfy this system.
Summary of the invention
Technical assignment of the present invention is at above-mentioned the deficiencies in the prior art, and the special-purpose transmission extreme-pressure anti-wear lubricating of a kind of rotary drilling rig oil compositions is provided.
Technical assignment of the present invention is realized in the following manner: the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig oil compositions is mixed by following materials of weight proportions:
88~95 parts of lubricant bases;
0.2~1 part of pour point depressant;
1~5 part of S extreme pressure anti-wear additives;
1~3 part of P extreme pressure anti-wear additives;
0.5~2 part of system's antimutagen;
Defoamer 15ppm.
40 ℃ of viscositys of described lubricant base are 42~50mm 2/ s, 100 ℃ of viscositys are 6.4~9.5 mm 2/ s.
Described pour point depressant is poly-a alkene and/or methyl polyacrylic ester.
Described S extreme pressure anti-wear additives is sulfide isobutene and/or benzyl disulfide thing.
Described P extreme pressure anti-wear additives is any one material in tritolyl phosphate, thio-ammonium phosphate, the triphenyl-thiophosphate or the mixture of more than one materials.
Described system antimutagen is the mixture of material a and material b, and the mass ratio of material a and material b is 1: 2;
Described material a is 2,6 ditertiary butyl p cresol, 2, any one material in 6-di-t-butyl mixed phenol, 2,6 di t butyl phenol, N-phenyl-αNai An or the nonyl diphenylamine or the mixture of more than one materials;
Described material b is any one material in barium mahogany sulfonate, synthetic barium sulfonate, benzotriazole, the alkenyl succinic acid or the mixture of more than one materials.
Described defoamer is the mixture of dimethyl silicone oil and aviation kerosene, and the volume ratio of dimethyl silicone oil and aviation kerosene is 1:5.
The molecular weight of described dimethyl silicone oil is 500~1000.
The preparation method of the special-purpose transmission extreme-pressure anti-wear lubricating of above-mentioned rotary drilling rig oil compositions is:
The preparation of defoamer: dimethyl silicone oil and the aviation kerosene ratio in 1:5 is mixed;
Moderate lubrication oil base oil is added in the reactor, after being warming up to 40~60 ℃, under the continuously stirring state, pour point depressant, system's antimutagen, P extreme pressure anti-wear additives, the S extreme pressure anti-wear additives even velocity of flow in 15~20 minutes with formula ratio adds in the lubricant base successively;
Under 40~50 ℃, stirred 30 minutes, spray into defoamer with spraying plant, restir 30 minutes filters packing and gets product.
The special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig of the present invention oil compositions compared with prior art has following outstanding beneficial effect:
(1) its viscosity had both been taken into account the powerdriven lubricated needs of rotary drilling rig hydraulic efficiency system, had satisfied rotary drilling rig again and had revolved the lubrication needs of digging gear, for rotary drilling rig provides special-purpose transmission lubrication agent;
(2) S extreme pressure anti-wear additives, P extreme pressure anti-wear additives, system's antimutagen of proper ratio have been added, make said composition have splendid extreme pressure and antiwear behavior and supporting capacity, make revolving of rotary drilling rig dig service life of gear and prolonged more than 4 times.
Embodiment
Explain below with specific embodiment the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig of the present invention oil compositions being done.
Embodiment one:
Prescription
Lubricant base 94.07g;
Poly-a alkene 0.5g;
Benzyl disulfide thing 3.5g;
Tritolyl phosphate 1.1g;
The antimutagen 0.8g of system;
Defoamer 15ppm.
40 ℃ of viscositys of lubricant base are 45mm 2/ s, 100 ℃ of viscositys are 8.2mm 2/ s.
Described defoamer is the mixture of dimethyl silicone oil and aviation kerosene, and the volume ratio of dimethyl silicone oil and aviation kerosene is 1:5, the molecular weight 500~1000 of dimethyl silicone oil.
Described system antimutagen is the mixture of 2,6 ditertiary butyl p cresol and benzotriazole, and the mass ratio of 2,6 ditertiary butyl p cresol and benzotriazole is 1: 2.
The preparation method is:
The lubricant base of formula ratio is added in the reactor, after being warming up to 50 ℃, under the continuously stirring state, poly-a alkene, benzyl disulfide thing, tritolyl phosphate, the system's antimutagen even velocity of flow in 20 minutes with formula ratio adds in the lubricant base successively;
Under 45 ℃, stirred 30 minutes, spray into defoamer with spraying plant, restir 30 minutes filters packing and gets product.
Embodiment two:
Prescription:
Lubricant base 93.48g;
Methyl polyacrylic ester 0.6g;
Sulfide isobutene 3.8g;
Triphenyl-thiophosphate 1.2g;
The antimutagen 0.9g of system;
Defoamer 15ppm.
40 ℃ of viscositys of lubricant base are 45mm 2/ s, 100 ℃ of viscositys are 8.2mm 2/ s.
Described defoamer is the mixture of dimethyl silicone oil and aviation kerosene, and the volume ratio of dimethyl silicone oil and aviation kerosene is 1:5, the molecular weight 500~1000 of dimethyl silicone oil.
Described system antimutagen is the mixture of N-phenyl-αNai An and barium mahogany sulfonate, and the mass ratio of N-phenyl-αNai An and barium mahogany sulfonate is 1: 2.
The preparation method is:
The lubricant base of formula ratio is added in the reactor, after being warming up to 50 ℃, under the continuously stirring state, methyl polyacrylic ester, sulfide isobutene, triphenyl-thiophosphate, the system's antimutagen even velocity of flow in 20 minutes with formula ratio adds in the lubricant base successively;
Under 45 ℃, stirred 30 minutes, spray into defoamer with spraying plant, restir 30 minutes filters packing and gets product.
Embodiment three:
Prescription:
Lubricant base 93g;
Poly-a alkene 0.6g;
Sulfide isobutene 4.0g;
Thio-ammonium phosphate 1.26g;
The antimutagen 1.1g of system;
Defoamer 15ppm.
40 ℃ of viscositys of lubricant base are 45mm 2/ s, 100 ℃ of viscositys are 8.2mm 2/ s.
Described defoamer is the mixture of dimethyl silicone oil and aviation kerosene, and the volume ratio of dimethyl silicone oil and aviation kerosene is 1:5, the molecular weight 500~1000 of dimethyl silicone oil.
Described system antimutagen is the mixture of 2,6 di t butyl phenol and alkenyl succinic acid, and the mass ratio of 2,6 di t butyl phenol and alkenyl succinic acid is 1: 2.
The preparation method is:
The lubricant base of formula ratio is added in the reactor, after being warming up to 50 ℃, under the continuously stirring state, poly-a alkene, sulfide isobutene, thio-ammonium phosphate, the system's antimutagen even velocity of flow in 20 minutes with formula ratio adds in the lubricant base successively;
Under 45 ℃, stirred 30 minutes, spray into defoamer with spraying plant, restir 30 minutes filters packing and gets product.
Experimental example one:
Embodiment one resulting composition is carried out performance test, and test result as shown in Table 1.Table one:
Project Test result
Outward appearance Transparent fluid
40 ℃ of kinematic viscosity, mm 2/S 42∽50
100 ℃ of kinematic viscosity, mm 2/S 6.4∽50
Four ball-joint loading capabilities loads (N) 1700
The anti-sintering loads of four balls (N) 5000
100 ℃ of oxygen times (min) 960
Experimental example two:
Embodiment one resulting composition and antiwear hydraulic oil and industrial extreme pressure gear oil are carried out the supporting capacity contrast test, and test result as shown in Table 2.
Table two:
The oil product kind Four ball-joint loading capabilities loads (N) The anti-sintering loads of four balls (N)
Antiwear hydraulic oil 930N 2000N
Embodiment one composition 1700N 5000N
The industry extreme pressure gear oil 940N 2450N
Experimental example three:
Embodiment one resulting composition and antiwear hydraulic oil and industrial extreme pressure gear oil are carried out the oxygen time test comparison, and test result as shown in Table 3.
Table three:
The oil product kind 70 ℃ of oxygen times (min) 100 ℃ of oxygen times (min) 150 ℃ of oxygen times (min)
Antiwear hydraulic oil 980 530 360
Embodiment one composition 1750 960 520
The industry extreme pressure gear oil 1100 550 365

Claims (8)

1. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig oil compositions is characterized in that: mixed by following materials of weight proportions:
88~95 parts of lubricant bases;
0.2~1 part of pour point depressant;
1~5 part of S extreme pressure anti-wear additives;
1~3 part of P extreme pressure anti-wear additives;
0.5~2 part of system's antimutagen;
Defoamer 15ppm.
2. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 1 oil compositions, it is characterized in that: 40 ℃ of viscositys of described lubricant base are 42~50mm 2/ s, 100 ℃ of viscositys are 6.4~9.5 mm 2/ s.
3. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 1 oil compositions, it is characterized in that: described pour point depressant is poly-a alkene and/or methyl polyacrylic ester.
4. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 1 oil compositions, it is characterized in that: described S extreme pressure anti-wear additives is sulfide isobutene and/or benzyl disulfide thing.
5. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 1 oil compositions is characterized in that: described P extreme pressure anti-wear additives is any one material in tritolyl phosphate, thio-ammonium phosphate, the triphenyl-thiophosphate or the mixture of more than one materials.
6. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 1 oil compositions, it is characterized in that: described system antimutagen is the mixture of material a and material b, the mass ratio of material a and material b is 1: 2;
Described material a is 2,6 ditertiary butyl p cresol, 2, any one material in 6-di-t-butyl mixed phenol, 2,6 di t butyl phenol, N-phenyl-αNai An or the nonyl diphenylamine or the mixture of more than one materials;
Described material b is any one material in barium mahogany sulfonate, synthetic barium sulfonate, benzotriazole, the alkenyl succinic acid or the mixture of more than one materials.
7. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 1 oil compositions, it is characterized in that: described defoamer is the mixture of dimethyl silicone oil and aviation kerosene, the volume ratio of dimethyl silicone oil and aviation kerosene is 1:5.
8. the special-purpose transmission extreme-pressure anti-wear lubricating of rotary drilling rig according to claim 7 oil compositions, it is characterized in that: the molecular weight of described dimethyl silicone oil is 500~1000.
CN201310190401.3A 2013-05-21 2013-05-21 Special transmission extreme-pressure anti-wear lubricating oil combination for rotary drilling rig Active CN103289801B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724580A (en) * 2018-07-16 2020-01-24 中国石油化工股份有限公司 Gear oil extreme pressure antiwear additive composition and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1288047A (en) * 2000-09-23 2001-03-21 中国科学院兰州化学物理研究所 Composite additive of lubricating oil for industrial gear turbine
CN1673321A (en) * 2004-03-24 2005-09-28 中国石油天然气股份有限公司 Prepn of automatic automobile driving liquid with hydrogenated oil
US20070293408A1 (en) * 2005-03-11 2007-12-20 Chevron Corporation Hydraulic Fluid Compositions and Preparation Thereof
US7902132B2 (en) * 2005-04-08 2011-03-08 The Lubrizol Corporation Additive system for lubricants

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1288047A (en) * 2000-09-23 2001-03-21 中国科学院兰州化学物理研究所 Composite additive of lubricating oil for industrial gear turbine
CN1673321A (en) * 2004-03-24 2005-09-28 中国石油天然气股份有限公司 Prepn of automatic automobile driving liquid with hydrogenated oil
US20070293408A1 (en) * 2005-03-11 2007-12-20 Chevron Corporation Hydraulic Fluid Compositions and Preparation Thereof
US7902132B2 (en) * 2005-04-08 2011-03-08 The Lubrizol Corporation Additive system for lubricants

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724580A (en) * 2018-07-16 2020-01-24 中国石油化工股份有限公司 Gear oil extreme pressure antiwear additive composition and application thereof
CN110724580B (en) * 2018-07-16 2022-04-05 中国石油化工股份有限公司 Gear oil extreme pressure antiwear additive composition and application thereof

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Effective date of registration: 20190410

Address after: 272000 Kaiyuan Road, Jining High-tech Zone, Jining City, Shandong Province

Patentee after: Shandong Xiaosong Oil Products Co., Ltd.

Address before: 272071 No. 12 Kaiyuan Road, Rencheng Economic and Technological Development Zone, Jining City, Shandong Province

Patentee before: Shandong source root Petrochemical Co., Ltd.

TR01 Transfer of patent right