CN103289488A - Oxidative polymerization type adhesive - Google Patents

Oxidative polymerization type adhesive Download PDF

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Publication number
CN103289488A
CN103289488A CN2012105179095A CN201210517909A CN103289488A CN 103289488 A CN103289488 A CN 103289488A CN 2012105179095 A CN2012105179095 A CN 2012105179095A CN 201210517909 A CN201210517909 A CN 201210517909A CN 103289488 A CN103289488 A CN 103289488A
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CN
China
Prior art keywords
coating
polymerization type
oxidative polymerization
type adhesive
sizing agent
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CN2012105179095A
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Chinese (zh)
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CN103289488B (en
Inventor
侯保荣
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Nitto Denko China Investment Co Ltd
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侯保荣
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Publication of CN103289488B publication Critical patent/CN103289488B/en
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Abstract

The invention relates to an adhesive, and in particular relates to an oxidative polymerization type adhesive for the corrosion protection of steel facilities, building construction, mechanical equipment and the like. The oxidative polymerization type adhesive comprises the following components in percentage by weight: 30-34% of acrylic polymers, 34-38% of water, 0.1-1% of titanium dioxide, 0.5-2% of silicon dioxide, 8-10% of silica powder, 12-16% of micaceous iron oxide and 4-8% of butyl carbamic acid iodo-allylene ester. The oxidative polymerization type adhesive is conveniently applied on protected objects, has strong adherence and good permeability, forms a high-strength attractive coating after solidification, can form a dense sealing coating with a basic coating so as to have excellent resistance to water vapor permeation, resists wind, sunshine, rain, frost and dew, melting snow and ionizing radiation, and have function of effectively preventing ultraviolet lights from degradating the coating and a special function of resisting chalking.

Description

A kind of oxypolymerization type sizing agent
Technical field
The present invention relates to sizing agent, specifically be used for power plant's iron and steel structures, the oxypolymerization type sizing agent of the rust resistance and corrosion resistances such as mechanical means of stay cables of bridge, various storage tank margin plate, gas pipeline, valve, flange, joist steel, spherical contact, screw, nut and various complicated shapes.
Background technology
Power plant's iron and steel structures, the mechanical means of stay cables of bridge, various storage tank margin plate, gas pipeline, valve, flange, joist steel, spherical contact, screw, nut and various complicated shapes etc. exposes to the open air at outdoor steel construction, the invasion and attack that continue to be subjected to wind, Exposure to Sunlight, drench with rain, the corrosion situation is very serious.Especially the power plant of bridge, trestle, shore protection, strand etc. is subjected to the influence of moist marine atmosphere, and the corrosion situation is even more serious.In order to ensure its safe operation, production, economize on resources, need formulate the protection against corrosion countermeasure targetedly.A lot of anti-corrosion methods of Cai Yonging in the past; such as: methods such as coating protective system, metal spraying, epoxy blanket, covering cement layer; the protection effect is not really desirable and attractive in appearance inadequately, and especially ultraviolet ray is quite rapid to degraded and the efflorescence of coating, causes the rust resistance and corrosion resistance life-span short.
Summary of the invention
At the problems referred to above, the invention provides a kind of oxypolymerization type sizing agent.
For achieving the above object, the technical solution used in the present invention is:
A kind of oxypolymerization type sizing agent, by weight percentage, acrylate copolymer 30-34%, water 34-38%, titanium dioxide 0.1-1%, silicon-dioxide 0.5-2%, silicon powder 8-10%, iron mica 12-16% and butyl carboxylamine iodo propynyl ester 4-8%.Described acrylate copolymer is to be main component with vinylformic acid emulsion, comprises the water-based rustproof lacquer of Red copper oxide and organic biological active material, mixed solvent.Described silicon powder i.e. " ball-type " silicon powder
The present invention has the following advantages: oxypolymerization type sizing agent of the present invention has good rust resistance and corrosion resistance effect, use this oxypolymerization type sizing agent, protected object is smeared conveniently, strong adhesion, seepage force are good, can form fine and close sealer coat with basic coating has excellent resistibility to the infiltration of steam, solidify the back and form high-intensity epithelium attractive in appearance, anti-wind, Exposure to Sunlight, drench with rain, snow melt, anti-ionizing radiation prevents that effectively ultraviolet ray is to the degraded of coating and the special role of anti-efflorescence; Corrosion Protection is good, and anti-impact force is strong, and ageing resistance is good, and the rust resistance and corrosion resistance life-span is long.
Oxypolymerization type sizing agent of the present invention is widely used in power plant's iron and steel structures, the mechanical means of stay cables of bridge, various storage tank margin plate, gas pipeline, valve, flange, joist steel, spherical contact, screw, nut and various complicated shapes etc.Especially coat protection against corrosion band top layer add be coated with more apparent superior.
Embodiment
Embodiment 1
Oxypolymerization type sizing agent by weight percentage, acrylate copolymer 30%, water 35%, titanium dioxide 1%, silicon-dioxide 2%, silicon powder 10%, iron mica 15% and butyl carboxylamine iodo propynyl ester 7%.
Wherein acrylate copolymer is to be main component with vinylformic acid emulsion, adds Red copper oxide and organic biological active material, mixed solvent etc., and it is big to have viscosity, and strong adhesion, seepage force are good.
Described silicon powder i.e. " ball-type " silicon powder, and outward appearance is white powder, the spherulitic texture that it is unique, compare with other angular silica powders (silicon powder), powder fluidity is good, and it is little that powder is piled up the slope of repose that forms, thereby mix with organic polymer material very closely knit, body intensity height; Described iron mica can form fine and close sealer coat with coating has excellent resistibility to the infiltration of steam, anti-wind, Exposure to Sunlight, drench with rain, frost and dew, snow melt, anti-ionizing radiation prevents that effectively ultraviolet ray is to the degraded of coating and the special role of anti-efflorescence.
Measure the general characteristic of embodiment gained material, see table.
Project Unit Observed value Testing method
Outward appearance - Silver gray -
Viscosity Pa·s 1.10 Brookfield viscometer
Proportion - 1.10 JIS?K?5600
Heat residual branch % 59.1 JIS?K?5601
Time of drying In 3 JIS?K?5600
Embodiment 2
Oxypolymerization type sizing agent by weight percentage, acrylate copolymer 31%, water 36%, titanium dioxide 1%, silicon-dioxide 2%, silicon powder 10%, iron mica 16% and butyl carboxylamine iodo propynyl ester 4%.
Wherein acrylate copolymer is to be main component with vinylformic acid emulsion, adds Red copper oxide and organic biological active material, mixed solvent etc., and it is big to have viscosity, and strong adhesion, seepage force are good.
Described silicon powder i.e. " ball-type " silicon powder, and outward appearance is white powder, the spherulitic texture that it is unique, compare with other angular silica powders (silicon powder), powder fluidity is good, and it is little that powder is piled up the slope of repose that forms, thereby mix with organic polymer material very closely knit, body intensity height; Described iron mica can form fine and close sealer coat with coating has excellent resistibility to the infiltration of steam, anti-wind, Exposure to Sunlight, drench with rain, frost and dew, snow melt, anti-ionizing radiation prevents that effectively ultraviolet ray is to the degraded of coating and the special role of anti-efflorescence.
Effect is identical with embodiment 1 with characteristic.
Use the oxypolymerization type sizing agent of above-mentioned composition, solidify the back and form high-intensity epithelium attractive in appearance, Corrosion Protection is good, life-span is long, be widely used in the iron and steel structures of bridge, power plant, the mechanical means of stay cables of bridge, various storage tank margin plate, gas pipeline, valve, flange, joist steel, spherical contact, screw, nut and various complicated shapes etc.Especially coat protection against corrosion band top layer add be coated with more apparent superior.

Claims (3)

1. oxypolymerization type sizing agent, it is characterized in that: by weight percentage, acrylate copolymer 30-34%, water 34-38%, titanium dioxide 0.1-1%, silicon-dioxide 0.5-2%, silicon powder 8-10%, iron mica 12-16% and butyl carboxylamine iodo propynyl ester 4-8%.
2. by the described oxypolymerization type of claim 1 sizing agent, it is characterized in that: described acrylate copolymer is to be main component with vinylformic acid emulsion, comprises the water-based rustproof lacquer of Red copper oxide and organic biological active material, mixed solvent.
3. by the described oxypolymerization type of claim 1 sizing agent, it is characterized in that: described silicon powder i.e. " ball-type " silicon powder.
CN201210517909.5A 2012-12-06 2012-12-06 A kind of Oxidative polymerization type adhesive Active CN103289488B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210517909.5A CN103289488B (en) 2012-12-06 2012-12-06 A kind of Oxidative polymerization type adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210517909.5A CN103289488B (en) 2012-12-06 2012-12-06 A kind of Oxidative polymerization type adhesive

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CN103289488A true CN103289488A (en) 2013-09-11
CN103289488B CN103289488B (en) 2015-11-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114763454A (en) * 2021-01-11 2022-07-19 昆明路迈土工合成材料制造有限公司 EVA composite waterproof board and processing technology thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1702130A (en) * 2004-05-24 2005-11-30 上海涂料有限公司上海长风化工厂 Aqueous rust proof coating and preparation method thereof
CN101045843A (en) * 2007-04-18 2007-10-03 邹磊 Water industrial antirust paint and preparation method thereof
CN101967316A (en) * 2010-09-08 2011-02-09 中国乐凯胶片集团公司 Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1702130A (en) * 2004-05-24 2005-11-30 上海涂料有限公司上海长风化工厂 Aqueous rust proof coating and preparation method thereof
CN101045843A (en) * 2007-04-18 2007-10-03 邹磊 Water industrial antirust paint and preparation method thereof
CN101967316A (en) * 2010-09-08 2011-02-09 中国乐凯胶片集团公司 Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114763454A (en) * 2021-01-11 2022-07-19 昆明路迈土工合成材料制造有限公司 EVA composite waterproof board and processing technology thereof

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Owner name: QINGDAO HAILAN RIDONG MATERIALS TECHNOLOGY CO., LT

Effective date: 20140429

C41 Transfer of patent application or patent right or utility model
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Inventor after: Hou Baorong

Inventor after: Kosuga Masahiko

Inventor before: Hou Baorong

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Address after: 201, room 15, 266071 Qixia Road, Shandong, Qingdao

Applicant after: Hou Baorong

Applicant after: QINGDAO HAILANRIDONG MATERIAL TECHNOLOGY CO., LTD.

Address before: 201, room 15, 266071 Qixia Road, Shandong, Qingdao

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Address after: 201, room 15, 266071 Qixia Road, Shandong, Qingdao

Patentee after: Hou Baorong

Patentee after: Nitto denko (China) Investment Company Limited

Address before: 201, room 15, 266071 Qixia Road, Shandong, Qingdao

Patentee before: Hou Baorong

Patentee before: QINGDAO HAILANRIDONG MATERIAL TECHNOLOGY CO., LTD.