CN103289481B - A kind of celluloid paint for lacquer painting - Google Patents
A kind of celluloid paint for lacquer painting Download PDFInfo
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- CN103289481B CN103289481B CN201310276815.8A CN201310276815A CN103289481B CN 103289481 B CN103289481 B CN 103289481B CN 201310276815 A CN201310276815 A CN 201310276815A CN 103289481 B CN103289481 B CN 103289481B
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- phthalic acid
- celluloid paint
- nitrocellulose
- acid dibutyl
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Abstract
The invention provides a kind of novel transparent for lacquer painting to paint, described celluloid paint comprises nitrocellulose, resin, softening agent, strong solvent and thinner; Wherein resin and part softening agent composition and be 1.5:1 with the ratio of nitrocellulose composition, with this understanding, this celluloid paint can solve the shortcoming that with the passing of time white background paint film turns yellow, and makes the dress look of works effect and the traditional lacquer painting made completely different, bright in luster, texture is true to nature.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of celluloid paint for lacquer painting.
Background technology
General PASS is not strong, and acid resistance and alkali resistance are not strong, and be not pure colourless water-white clean oil, existing defects to a certain extent, does not reach the basic demand of polished lacquer, ink traditional Chinese Painting effect.
Along with epoch and now scientific and technological development, contemporary people is made also constantly to change the cognition of lacquer painting and upgrade.The development of lacquer painting be unable to do without cognition to material technology, deciphering, research and exploration, and this is the inexorable law of lacquer painting development, and contemporary lacquer painting is all the more so, more payes attention to exploration and the utilization of novel material.
In traditional Chinese Painting creation in the past, can only use on the material of rice paper or similar rice paper, the uniqueness of zapon varnish and the unlimited abundant of technique, make lacquer painting create other and draw kind of an irreplaceable artistic charm; This product breaches limitation in the past, is embodied in by ink traditional Chinese Painting and buffed lacquer represents its art, and picture background color and quick-drying, never fades again, a great problem that with the passing of time white background paint film of solving over turns yellow.
Summary of the invention
The present invention, in order to overcome the deficiency of lacquer painting of the prior art, develops a kind of novel nitro celluloid paint, the problem that with the passing of time white background paint film of can solving over turns yellow.
The invention provides a kind of novel transparent for lacquer painting to paint, described celluloid paint comprises nitrocellulose, resin, softening agent, strong solvent and thinner;
Further, described celluloid paint is made up of following raw material: nitrocellulose 18-24 part, Synolac 5-10 part, acrylic resin 3-8 part, maleic-modified rosin resin 2-6 part, phthalic acid dibutyl ester or dimethyl ester 2-5 part, phthalic acid dibutyl ester 3-7 part; fourth Bian fat 3-6 part, barium sulfate, pottery scholar powder, chlorodiphenyl and/or each 5-6 part of Basic Bismuth Chloride, talcum powder 2-4 part; clorafin and/or butyl stearate 8-11 part; Oleum Cocois or synthetic fatty acid 2-4 part, propyl alcohol or butanols 2-8 part, toluene 7-10 part;
Further, the ratio of described Synolac, acrylic resin, maleic-modified rosin resin, phthalic acid dibutyl ester or dimethyl ester, phthalic acid dibutyl ester composition summation and nitrocellulose composition is 1.5:1.
The invention has the beneficial effects as follows: traditional lacquer painting painted, mainly adopt the gimmick of Chinese realistic painting " dress look ", color is more dull, stiff.Use this product, by the rational allocation of the raw materials such as various oil colour box water white transparency paint, thinner, with the gimmick substantive dyeing of traditional Chinese Painting freehand brushwork, picture color is enriched, and bright-coloured operation, is rich in texture.This product has broken the gimmick of traditional Chinese realistic painting lacquer painting simple " dress look ", and the gimmick adopting Chinese realistic painting traditional Chinese Painting " to play up ", according to the content of different works, organically combines use by various craft and techniques; Make the dress look of works effect and the traditional lacquer painting made completely different, bright in luster, texture is true to nature.
Embodiment
Following content will the present invention is described in detail in conjunction with embodiment:
For in the celluloid paint of lacquer painting, non-volatile content and filmogen, mainly comprise nitrocellulose, resin, softening agent and pigment extender.Nitrocellulose is main component, and the non-volatile content of paint is mainly nitrocellulose, so first its volatilization formula will consider the solvency power to nitrocellulose; Use full-bodied nitrocellulose can improve temp. variation resistant performance. but require that having higher nonvolatile component content contradicts, so majority all uses nitrocellulose and balances with soft resin or softening agent with woodenware lacquer; With solvent-borne type plasticity agent Be very effective in softening agent.Plasticizer volatility be must be noted that, when the shorter ester class (as phthalic acid dibutyl ester, dimethyl ester etc.) of alkyl carbon chain is used alone, plasticising performance is lasting not, preferably mixes the softening agent such as nonvolatile dioctyl phthalate, fourth Bian ester, tritolyl phosphate, sebate simultaneously; It is not the Synolac of short oil that Synolac is held, and very large to the viscosity influence of paint, consumption is larger, and viscosity is higher; Maleic-modified rosin resin is slightly large to viscosity influence, uses acrylic resin, also easily causes painting increasing of viscosity.In addition, the gloss of nitrocellulose paint film is poor, needs dependence to add resin and softening agent to improve gloss; The paint film not adding the celluloid lacquer of resin can whole stripping, adds appropriate barium sulfate, talcum powder, potter's clay powder etc., also can improve sticking power.Consider that protection against the tide and the water tolerance of nitrocellulose are not strong, and silicone alkyd is owing to having strong hydrophobic group, so can improve water repelling property widely; The hydrophobic plasticizer such as clorafin, butyl stearate is helpful to water repelling property, but consumption is unsuitable many, in order to avoid affect other performance.The evaporation rate of butanols can obtain comparatively ideal paint film; Alcohols is often the non-solvent of Composite, and it as the solubility promoter of nitrocellulose (strong solvent), can use butanols; It is all more satisfactory, the most conventional in many-sides such as evaporation rate, dilution ratio, prices that thinner made by toluene, and Basic Bismuth Chloride is used as hyperchromic pigment, and Oleum Cocois, pine-seed oil or synthetic fatty acid are used for Bao Se and protect light.Composition by weight percentage in the present invention.
[embodiment one]: a kind of novel transparent for lacquer painting paints, and described celluloid paint is made up of following raw material: 18 parts, T nitrocellulose, Synolac 9 parts, acrylic resin 3 parts, maleic-modified rosin resin 4 parts, phthalic acid dibutyl ester 5 parts, phthalic acid dibutyl ester 3 parts, 3 parts, fourth Bian fat, barium sulfate, pottery scholar powder, chlorodiphenyl, each 6 parts of Basic Bismuth Chloride, talcum powder 3 parts, clorafin 2 parts, butyl stearate 7 parts, synthetic fatty acid 3 parts, 6 parts, butanols, toluene 10 parts.Mentioned component mixes.
[embodiment two]:
A kind of novel transparent for lacquer painting paints, and is made up of following raw material: 18 parts, nitrocellulose, Synolac 5 parts, acrylic resin 5 parts, maleic-modified rosin resin 6 parts, phthalic acid dibutyl ester 3 parts, phthalic acid dibutyl ester 4 parts, 4 parts, fourth Bian fat, barium sulfate, pottery scholar powder, chlorodiphenyl, each 5 parts of Basic Bismuth Chloride, talcum powder 4 parts, clorafin 3 parts, butyl stearate 8 parts, Oleum Cocois 4 parts, ethanol 8 parts, toluene 8 parts.Mentioned component mixes.
[embodiment three]:
A kind of novel transparent for lacquer painting paints, and is made up of following raw material: 24 parts, nitrocellulose, Synolac 8 parts, acrylic resin 7 parts, maleic-modified rosin resin 5 parts, dimethyl ester 5 parts, phthalic acid dibutyl ester 6 parts; 5 parts, fourth Bian fat, barium sulfate, pottery scholar powder, each 6 parts of Basic Bismuth Chloride, talcum powder 2 parts; clorafin 9 parts; pine-seed oil 2 parts, ethanol 2 parts, toluene 7 parts.Mentioned component mixes.
[embodiment four]:
A kind of novel transparent for lacquer painting paints, and is made up of following raw material: 24 parts, nitrocellulose, Synolac 10 parts, acrylic resin 8 parts, maleic-modified rosin resin 2 parts, dimethyl ester 3 parts, phthalic acid dibutyl ester 7 parts; 6 parts, fourth Bian fat, barium sulfate, pottery scholar powder, each 5 parts of chlorodiphenyl, talcum powder 4 parts; butyl stearate 8 parts; pine-seed oil 2 parts, 3 parts, butanols, toluene 8 parts.Mentioned component mixes.
[embodiment five]:
A kind of novel transparent for lacquer painting paints, and is made up of following raw material: 20 parts, nitrocellulose, Synolac 10 parts, acrylic resin 8 parts, maleic-modified rosin resin 2 parts, dimethyl ester 2 parts, phthalic acid dibutyl ester 5 parts, 3 parts, fourth Bian fat, barium sulfate, pottery scholar powder, each 6 parts of Basic Bismuth Chloride, talcum powder 3 parts, clorafin 2 parts, butyl stearate 8 parts, synthetic fatty acid 3 parts, ethanol 6 parts, toluene 10 parts.Mentioned component mixes.
In the present invention, obtain through a large amount of tests, in mentioned component, resin (Synolac, acrylic resin, maleic-modified rosin resin) and softening agent (dimethyl ester, phthalic acid dibutyl ester and fourth Bian fat) composition and be 1.5:1 with the ratio of nitrocellulose composition, with this understanding, the performance of this celluloid paint: viscosity, glossiness, sticking power and weathering resistance reach best, because the now making of the most applicable lacquer painting of ratio of volatile matter and involatile substance, color and luster tint retention is obvious, the shortcoming that with the passing of time white background paint film turns yellow can be solved, make the dress look of works effect and the traditional lacquer painting made completely different, bright in luster, texture is true to nature.
Above content is in conjunction with embodiment further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (7)
1. the celluloid paint for lacquer painting, it is characterized in that, described celluloid paint is made up of following raw material: nitrocellulose 18-24 part, Synolac 5-10 part, acrylic resin 3-8 part, maleic-modified rosin resin 2-6 part, phthalic acid dibutyl ester or dimethyl ester 2-5 part, phthalic acid dibutyl ester 3-7 part, fourth Bian fat 3-6 part, barium sulfate, pottery scholar powder, chlorodiphenyl and/or each 5-6 part of Basic Bismuth Chloride, talcum powder 2-4 part, clorafin and/or butyl stearate 8-11 part, Oleum Cocois, pine-seed oil or synthetic fatty acid 2-4 part, propyl alcohol or butanols 2-8 part, toluene 7-10 part, each component sum is 100 weight parts,
The ratio of described Synolac, acrylic resin, maleic-modified rosin resin, phthalic acid dibutyl ester or dimethyl ester, phthalic acid dibutyl ester composition summation and nitrocellulose composition is 1.5:1.
2. celluloid paint according to claim 1, is characterized in that, described celluloid paint is made up of following raw material: 18 parts, nitrocellulose, Synolac 9 parts, acrylic resin 3 parts, maleic-modified rosin resin 4 parts, phthalic acid dibutyl ester 5 parts, phthalic acid dibutyl ester 3 parts, 3 parts, fourth Bian fat, barium sulfate, pottery scholar powder, chlorodiphenyl, each 6 parts of Basic Bismuth Chloride, talcum powder 3 parts, clorafin 2 parts, butyl stearate 7 parts, synthetic fatty acid 3 parts, 6 parts, butanols, toluene 10 parts.
3. celluloid paint according to claim 1, is characterized in that, described celluloid paint is made up of following raw material: 18 parts, nitrocellulose, Synolac 5 parts, acrylic resin 5 parts, maleic-modified rosin resin 6 parts, phthalic acid dibutyl ester 3 parts, phthalic acid dibutyl ester 4 parts, 4 parts, fourth Bian fat, barium sulfate, pottery scholar powder, chlorodiphenyl, each 5 parts of Basic Bismuth Chloride, talcum powder 4 parts, clorafin 3 parts, butyl stearate 8 parts, Oleum Cocois 4 parts, ethanol 8 parts, toluene 8 parts.
4. celluloid paint according to claim 1, is characterized in that, described celluloid paint is made up of following raw material: 24 parts, nitrocellulose, Synolac 8 parts, acrylic resin 7 parts, maleic-modified rosin resin 5 parts, dimethyl ester 5 parts, phthalic acid dibutyl ester 6 parts, 5 parts, fourth Bian fat, barium sulfate, pottery scholar powder, each 6 parts of Basic Bismuth Chloride, talcum powder 2 parts, clorafin 9 parts, pine-seed oil 2 parts, ethanol 2 parts, toluene 7 parts.
5. celluloid paint according to claim 1, is characterized in that, described celluloid paint is made up of following raw material: 24 parts, nitrocellulose, Synolac 10 parts, acrylic resin 8 parts, maleic-modified rosin resin 2 parts, dimethyl ester 3 parts, phthalic acid dibutyl ester 7 parts, 6 parts, fourth Bian fat, barium sulfate, pottery scholar powder, each 5 parts of chlorodiphenyl, talcum powder 4 parts, butyl stearate 8 parts, pine-seed oil 2 parts, 3 parts, butanols, toluene 8 parts.
6. celluloid paint according to claim 1, is characterized in that, described celluloid paint is made up of following raw material: 20 parts, nitrocellulose, Synolac 10 parts, acrylic resin 8 parts, maleic-modified rosin resin 2 parts, dimethyl ester 2 parts, phthalic acid dibutyl ester 5 parts, 3 parts, fourth Bian fat, barium sulfate, pottery scholar powder, each 6 parts of Basic Bismuth Chloride, talcum powder 3 parts, clorafin 2 parts, butyl stearate 8 parts, synthetic fatty acid 3 parts, ethanol 6 parts, toluene 10 parts.
7. according to the celluloid paint one of claim 2-6 Suo Shu, it is characterized in that, each moiety forming described celluloid paint mixes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310276815.8A CN103289481B (en) | 2013-07-03 | 2013-07-03 | A kind of celluloid paint for lacquer painting |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310276815.8A CN103289481B (en) | 2013-07-03 | 2013-07-03 | A kind of celluloid paint for lacquer painting |
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| Publication Number | Publication Date |
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| CN103289481A CN103289481A (en) | 2013-09-11 |
| CN103289481B true CN103289481B (en) | 2015-10-28 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312300A (en) * | 2014-10-29 | 2015-01-28 | 曾文江 | Anti-dulling paint and preparation process thereof |
| CN104312299A (en) * | 2014-10-29 | 2015-01-28 | 曾文江 | Cracking-resistant nitrocellulose paint and preparation method thereof |
| CN104327605A (en) * | 2014-10-30 | 2015-02-04 | 曾文江 | Paint with chlorinated paraffin improver and preparation method thereof |
| CN104356770A (en) * | 2014-10-30 | 2015-02-18 | 曾文江 | Preparation process of paint with phthalic acid diethyl ester |
| CN104371476B (en) * | 2014-11-14 | 2017-02-08 | 国家电网公司 | Flame-retardant and moisture-proof coating for solar cells and preparation method of coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1590133A (en) * | 2003-09-03 | 2005-03-09 | 刘占海 | Method of making coloured lacquer picture on bottle gourd |
| CN101250358A (en) * | 2008-03-12 | 2008-08-27 | 刘春雨 | Flame-proof nitrocellulose lacquer prepared by halogen-free flame retardant and preparation method thereof |
| CN101781495A (en) * | 2010-01-26 | 2010-07-21 | 中华制漆（深圳）有限公司 | Environmental-friendly nitryl wood lacquer and preparation method thereof |
-
2013
- 2013-07-03 CN CN201310276815.8A patent/CN103289481B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1590133A (en) * | 2003-09-03 | 2005-03-09 | 刘占海 | Method of making coloured lacquer picture on bottle gourd |
| CN101250358A (en) * | 2008-03-12 | 2008-08-27 | 刘春雨 | Flame-proof nitrocellulose lacquer prepared by halogen-free flame retardant and preparation method thereof |
| CN101781495A (en) * | 2010-01-26 | 2010-07-21 | 中华制漆（深圳）有限公司 | Environmental-friendly nitryl wood lacquer and preparation method thereof |
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