CN103289403A - Antistatic flame-retardant glass-fiber plastic - Google Patents
Antistatic flame-retardant glass-fiber plastic Download PDFInfo
- Publication number
- CN103289403A CN103289403A CN2013102516157A CN201310251615A CN103289403A CN 103289403 A CN103289403 A CN 103289403A CN 2013102516157 A CN2013102516157 A CN 2013102516157A CN 201310251615 A CN201310251615 A CN 201310251615A CN 103289403 A CN103289403 A CN 103289403A
- Authority
- CN
- China
- Prior art keywords
- parts
- fiber plastic
- retardant
- halogen
- antistatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an antistatic flame-retardant glass-fiber plastic. The antistatic flame-retardant glass-fiber plastic comprises the following raw materials: by weight, 30-35 parts of the polyimide resin, 10-15 parts of phenolic resin, 2-6 parts of a curing agent, 50-65 parts of a nanofiller, 5-10 parts of a halogen-free flame retardant, 1-2 parts of barium stearate, 1-1.5 parts of a lubricant, 15-20 parts of pigment carbon black and 10-15 parts of glass fiber. The halogen-free flame retardant is adopted in the antistatic flame-retardant glass-fiber plastic, so that the antistatic flame-retardant glass-fiber plastic has the advantages of no secondary pollution, good heat stability, no toxicity and no corrosivity, low price. The pigment carbon black is adopted to serve as a conductive agent, so that the antistatic flame-retardant glass-fiber plastic has a good antistatic effect, and can keep higher tensile properties.
Description
Technical field
The present invention relates to a kind of plastics, relate in particular to a kind of anti-electrostatic fire retardant fiberglass plastic.
Background technology
Present plastics require to have antistatic and fire-retardant performance, and common fiberglass plastic is to improve its flame retardant resistance by add the halogen fire retardant in raw material mostly, by adding graphitized carbon black, to reach anlistatig requirement.But halogen-containing flame retardant can produce toxic and harmful in combustion processes, to human body, all unfavorable to environment.The graphitized carbon black complex manufacturing yields poorly, and the cost height can not satisfy growing plastic prod demand.
Summary of the invention
The technical problem that solves:At the above-mentioned deficiency of prior art, the invention provides a kind of anti-electrostatic fire retardant fiberglass plastic, use the halogen-free flame retardants of environmental protection and the colour carbon black conductive agent that cost is low, output is high, improve the performance of plastics.
Technical scheme:The invention provides a kind of anti-electrostatic fire retardant fiberglass plastic, raw material by following parts by weight is formed: polyimide resin 30-35 part, resol 10-15 part, solidifying agent 2-6 part, Nano filling 50-65 part, halogen-free flame retardants 5-10 part, barium stearate 1-2 part, lubricant 1-1.5 part, colour carbon black 15-20 part, glass fibre 10-15 part.
Described solidifying agent is epoxy curing agent, and described Nano filling is nanoclay; Described halogen-free flame retardants is magnesium hydroxide or aluminium hydroxide; Described lubricant is paraffin.
Beneficial effect:Because the present invention has adopted technique scheme, has adopted halogen-free flame retardants, does not produce secondary pollution, Heat stability is good, nontoxic nothing corrosion, price is low; Adopt the colour carbon black conductive agent, antistatic effect is good, and can keep higher tensile property.
Embodiment
Mode below by embodiment further specifies the present invention, but therefore the present invention is not confined to following embodiment.
Embodiment 1
30 parts of polyimide resins
10 parts in resol
2 parts in solidifying agent
50 parts of Nano fillings
5 parts of halogen-free flame retardantss
1 part of barium stearate
1 part of lubricant
15 parts of colour carbon blacks
10 parts in glass fibre
Add raw material by above-mentioned parts by weight in high-speed mixer, stirred 2-7 minute, the control built-in temperature is not higher than 105 ℃, the blowing cooling; With the double-screw extruding pelletizing machine granulation of gained cooling material, extrusion temperature 140-180 ℃.
Embodiment 2
32 parts of polyimide resins
12 parts in resol
3 parts in solidifying agent
52 parts of Nano fillings
6 parts of halogen-free flame retardantss
1 part of barium stearate
1 part of lubricant
16 parts of colour carbon blacks
12 parts in glass fibre
Add raw material by above-mentioned parts by weight in high-speed mixer, stirred 2-7 minute, the control built-in temperature is not higher than 105 ℃, the blowing cooling; With the double-screw extruding pelletizing machine granulation of gained cooling material, extrusion temperature 140-180 ℃.
Embodiment 3
33 parts of polyimide resins
13 parts in resol
5 parts in solidifying agent
60 parts of Nano fillings
8 parts of halogen-free flame retardantss
1 part of barium stearate
1 part of lubricant
18 parts of colour carbon blacks
13 parts in glass fibre
Add raw material by above-mentioned parts by weight in high-speed mixer, stirred 2-7 minute, the control built-in temperature is not higher than 105 ℃, the blowing cooling; With the double-screw extruding pelletizing machine granulation of gained cooling material, extrusion temperature 140-180 ℃.
Embodiment 4
35 parts of polyimide resins
15 parts in resol
6 parts in solidifying agent
65 parts of Nano fillings
10 parts of halogen-free flame retardantss
2 parts of barium stearates
1.5 parts of lubricants
20 parts of colour carbon blacks
15 parts in glass fibre
Add raw material by above-mentioned parts by weight in high-speed mixer, stirred 2-7 minute, the control built-in temperature is not higher than 105 ℃, the blowing cooling; With the double-screw extruding pelletizing machine granulation of gained cooling material, extrusion temperature 140-180 ℃.
Above-described embodiment gained anti-electrostatic fire retardant fiberglass plastic is carried out performance test, test result such as following table:
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Tensile strength (Mpa) | 100 | 105 | 90 | 102 |
| Extension at break strain (%) | 10 | 12 | 11 | 9 |
| Flexural strength (Mpa) | 70 | 78 | 73 | 64 |
Claims (5)
1. anti-electrostatic fire retardant fiberglass plastic, it is characterized in that being formed by the raw material of following parts by weight: polyimide resin 30-35 part, resol 10-15 part, solidifying agent 2-6 part, Nano filling 50-65 part, halogen-free flame retardants 5-10 part, barium stearate 1-2 part, lubricant 1-1.5 part, colour carbon black 15-20 part, glass fibre 10-15 part.
2. a kind of anti-electrostatic fire retardant fiberglass plastic according to claim 1 is characterized in that described solidifying agent is epoxy curing agent.
3. a kind of anti-electrostatic fire retardant fiberglass plastic according to claim 1 is characterized in that described Nano filling is nanoclay.
4. a kind of anti-electrostatic fire retardant fiberglass plastic according to claim 1 is characterized in that described halogen-free flame retardants is magnesium hydroxide or aluminium hydroxide.
5. a kind of anti-electrostatic fire retardant fiberglass plastic according to claim 1 is characterized in that described lubricant is paraffin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102516157A CN103289403A (en) | 2013-06-24 | 2013-06-24 | Antistatic flame-retardant glass-fiber plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102516157A CN103289403A (en) | 2013-06-24 | 2013-06-24 | Antistatic flame-retardant glass-fiber plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103289403A true CN103289403A (en) | 2013-09-11 |
Family
ID=49090965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102516157A Withdrawn CN103289403A (en) | 2013-06-24 | 2013-06-24 | Antistatic flame-retardant glass-fiber plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103289403A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262962A (en) * | 2014-09-09 | 2015-01-07 | 丹阳丹金汽车部件有限公司 | Carbon nanotube grafted glass fiber multi-scale reinforced composite material and preparation method thereof |
| CN104610699A (en) * | 2014-12-26 | 2015-05-13 | 神盾防火科技有限公司 | Phenolic resin fire hydrant and preparation method thereof |
| CN105255178A (en) * | 2015-10-12 | 2016-01-20 | 苏州亿馨源光电科技有限公司 | Impact-resistant composite insulating material and preparing method thereof |
| CN105885412A (en) * | 2016-05-06 | 2016-08-24 | 金宝丽科技（苏州）有限公司 | Heat conduction type antistatic composite material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070066737A1 (en) * | 2005-09-16 | 2007-03-22 | Gallucci Robert R | Flame retardant polymer blends |
| CN102199350A (en) * | 2011-03-17 | 2011-09-28 | 上海同明材料科技有限公司 | Production method of high-temperature-resistant workable polyimide plastic alloy |
| CN102850726A (en) * | 2012-09-07 | 2013-01-02 | 广东生益科技股份有限公司 | Composite material, high frequency circuit substrate produced by using composite material, and production method of high frequency circuit substrate |
-
2013
- 2013-06-24 CN CN2013102516157A patent/CN103289403A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070066737A1 (en) * | 2005-09-16 | 2007-03-22 | Gallucci Robert R | Flame retardant polymer blends |
| CN102199350A (en) * | 2011-03-17 | 2011-09-28 | 上海同明材料科技有限公司 | Production method of high-temperature-resistant workable polyimide plastic alloy |
| CN102850726A (en) * | 2012-09-07 | 2013-01-02 | 广东生益科技股份有限公司 | Composite material, high frequency circuit substrate produced by using composite material, and production method of high frequency circuit substrate |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262962A (en) * | 2014-09-09 | 2015-01-07 | 丹阳丹金汽车部件有限公司 | Carbon nanotube grafted glass fiber multi-scale reinforced composite material and preparation method thereof |
| CN104610699A (en) * | 2014-12-26 | 2015-05-13 | 神盾防火科技有限公司 | Phenolic resin fire hydrant and preparation method thereof |
| CN104610699B (en) * | 2014-12-26 | 2017-03-29 | 神盾防火科技有限公司 | Phenolic resin fire hydrant and preparation method thereof |
| CN105255178A (en) * | 2015-10-12 | 2016-01-20 | 苏州亿馨源光电科技有限公司 | Impact-resistant composite insulating material and preparing method thereof |
| CN105885412A (en) * | 2016-05-06 | 2016-08-24 | 金宝丽科技（苏州）有限公司 | Heat conduction type antistatic composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103450668B (en) | High-strength carbon fiber strengthens halogen-free flameproof PA6 composite and preparation method thereof | |
| CN103289403A (en) | Antistatic flame-retardant glass-fiber plastic | |
| CN103289164A (en) | Flame-retardant polymer antistatic plastic | |
| CN101550249A (en) | Halogen-free expandable fire retardant fiber glass reinforced polypropylene material and preparation method thereof | |
| CN104098897A (en) | Corrosion-resistant anti-fatigue cable sheath material | |
| CN102020827A (en) | Phenolic moulding plastic for low-voltage apparatus | |
| CN112592566B (en) | Low-smoke-density halogen-containing flame-retardant reinforced PBT/PET compound and preparation method and application thereof | |
| CN103980700A (en) | Antistatic halogen-free flame-retardant nylon engineering plastic and preparation method thereof | |
| CN112625405A (en) | Low-smoke density halogen-free flame-retardant reinforced PBT/PET compound and preparation method and application thereof | |
| CN104098886A (en) | Water-proof heat-proof inflaming retarding cable sheath material | |
| CN104479218A (en) | Low-luster high-hardness polypropylene composite material | |
| CN103289368B (en) | A kind of continuous carbon fibre strengthens halogen-free reinforced nylon composite and preparation method thereof | |
| CN103756268A (en) | Polyimide fiber enhanced PBT (Polybutylece Terephthalate) composite material and preparation method thereof | |
| CN103613913B (en) | A kind of Halogen-free flame-retardant thermoplastic polyester elastomer material and preparation method thereof | |
| CN108148239A (en) | A kind of polyethylene sheath material for communication cable | |
| CN104387743A (en) | Abrasion-resistant PC composite material | |
| CN104072906A (en) | Polyvinyl chloride-polyethylene composite plastic | |
| CN103254610A (en) | Flame-retardant glass fiber-reinforced polyphenylene ether composite material | |
| CN103374212A (en) | High-impact-resistance low-shrinkage polybutylene terephthalate composite material and preparation method thereof | |
| CN103214817A (en) | White halogen-free flame-retardant polycarbonate composite material | |
| CN105602244A (en) | Preparation method of glass fiber reinforced nylon | |
| CN104387742A (en) | High-temperature-resistant PC composite material | |
| CN103254577A (en) | Flame-retardant polyethylene glycol terephthalate moulded plastic | |
| CN103254641A (en) | Polyethylene glycol terephthalate modified fire-retardant polyamide composite material | |
| CN109206740A (en) | Low warpage flame-proof reinforced polypropylene material of a kind of uvioresistant and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20130911 |