CN103289241A - Antistatic HPVC foaming sole material - Google Patents
Antistatic HPVC foaming sole material Download PDFInfo
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- CN103289241A CN103289241A CN2013102499005A CN201310249900A CN103289241A CN 103289241 A CN103289241 A CN 103289241A CN 2013102499005 A CN2013102499005 A CN 2013102499005A CN 201310249900 A CN201310249900 A CN 201310249900A CN 103289241 A CN103289241 A CN 103289241A
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- hpvc
- antistatic
- sole material
- foaming sole
- foaming
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
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Abstract
The present invention relates to an antistatic HPVC foaming sole material, which comprises the following components, by mass: 60-75% of HPVC, 5-10% of powder nitrile butadiene rubber, 10-20% of a plasticizer, 0.05-3% of a foaming agent, 1-5% of CaCO3, 0.05-2% of a metal salt stabilizer, 2-10% of an antistatic agent, and 0.5-3% of titanium dioxide. According to the present invention, the used antistatic agent provides good compatibility with the HPVC resin, has characteristics of low toxicity, good heat resistance and good processability, and does not cause adverse affects on physical properties of the product; an electric conduction performance of the material can be increased with addition of the titanium dioxide; and the HPVC foaming sole material prepared through the formula has a good antistatic performance.
Description
Technical field:
The present invention relates to a kind of technical field of HPVC material for sole of shoe, more specifically to a kind of antistatic HPVC foaming sole material.
Background technology:
HPVC is often referred to mean polymerisation degree in (mean polymerisation degree commonly used is 2500) or intermolecular polyvinyl chloride (PVC) RESINS with crosslinking structure more than 1700.The HPVC material also has characteristics such as compression set and thermal distortion are little, intensity is high, rebound resilience is excellent, delustring except the general property with PVC material.In recent years, along with the high speed development of HPVC research and development, and the rubber and plastic theory and technology reaches its maturity, this material with rubber, the dual performance of plastics of HPVC, and its application more and more comes into one's own.HPVC is used for material for sole of shoe also more and more widely, particularly is fit to manufacture wear resistance, winter hardiness and chemical proofing senior footwear material preferably.Material for sole of shoe requires the quality softness, and proportion is less, so need the processing of inflating and foam of HPVC material to improve its pliability, is reduced its density at shoe-making process, makes the cheaper material for sole of shoe of the better price of performance.
The HPVC material generally has than higher surface resistivity and volume specific resistance, easily produces accumulation of static electricity, and the harm that accumulation of static electricity causes is serious, by accumulation of static electricity cause dust absorption, be detrimental to health, fire even blast etc.Therefore under the occasion of some particular job, need carry out modification to it and handle, take certain measure to eliminate static and be subjected to extensive concern.
Summary of the invention:
The objective of the invention is to easily produce at the HPVC material for sole of shoe defective of accumulation of static electricity, the HPVC foaming sole material of the effective antistatic lotus of a kind of energy is provided.
The present invention is achieved by the following technical solutions.
A kind of antistatic HPVC foaming sole material comprises following component by weight percentage:
Preferred as technique scheme, described softening agent is o-phthalic acid dibutyl ester (DOP), dibutyl phthalate (DBP), one or more in the clorafin.
Preferred as technique scheme, described whipping agent is Cellmic C 121 (AC).
Preferred as technique scheme, described metallic salt stablizer is barium stearate, Zinic stearas, one or more in the calcium stearate.
The consistency of non-ionic antistatic agent and HPVC resin is good, and toxicity is low has good thermotolerance and processability, and physical properties of articles is had no adverse effects.Titanium dioxide adds in the material, plays the effect of nucleator on the one hand, can increase the conductivity of material on the other hand.
The present invention has following beneficial effect: non-ionic antistatic agent and titanium dioxide resistance toheat are good, are difficult for pyrolytic decomposition in PVC foaming sole material building-up process.The present invention makes the HPVC foaming sole material by interpolation non-ionic antistatic agent and titanium dioxide and has good antistatic property.
Embodiment:
In order to deepen the understanding of the present invention, the invention will be further described below in conjunction with embodiment, and this embodiment only is used for explaining the present invention, does not constitute the restriction to protection domain of the present invention.
Embodiment 1:
A kind of antistatic HPVC foaming sole material, the quality of its each component is as follows:
Its production method step is as follows:
(1) by the accurate weighing of prescription, HPVC, DOP, barium stearate, titanium dioxide fully mixed put into 120～130 ℃ of kneaders and carry out preplasticizing 20min, make the compound of preplasticizing.
(2) compound with preplasticizing adds in the twin-roll plastic mixing mill (the roller temperature is 150～160 ℃), and the 3min that plasticates adds Powdered acrylonitrile-butadiene rubber, and mixing 7min slice treats that material wraps other auxiliary agent of roller plasticizing back adding fully and mixes mixing slice.
(3) get the heating mould that tablet places 165 ℃, compacting makes its foaming under the 10MPa condition, and the depanning cooling makes the HPVC foaming sole material of antistatic lotus.
According to the examination criteria of GB GB21148-2007, the volume resistance that records sole is 4.1 * 10
7Ω cm has tangible antistatic effect.
Embodiment 2:
A kind of antistatic HPVC foaming sole material, the quality of its each component is as follows:
Its production method step is as follows:
(1) by the accurate weighing of prescription, HPVC, clorafin, calcium stearate, titanium dioxide fully mixed put into 120～130 ℃ of kneaders and carry out preplasticizing 20min, make the compound of preplasticizing.
(2) compound with preplasticizing adds in the twin-roll plastic mixing mill (the roller temperature is 150～160 ℃), and the 3min that plasticates adds Powdered acrylonitrile-butadiene rubber, and mixing 7min slice treats that material wraps other auxiliary agent of roller plasticizing back adding fully and mixes mixing slice.
(3) get the heating mould that tablet places 165 ℃, compacting makes its foaming under the 10MPa condition, and the depanning cooling makes the HPVC foaming sole material of antistatic lotus.
According to the examination criteria of GB GB21148-2007, the volume resistance that records sole is 3.4 * 10
7Ω cm has tangible antistatic effect.
Claims (5)
1. antistatic HPVC foaming sole material, it is characterized in that: each constituent mass per-cent is as follows:
2. according to the described a kind of antistatic HPVC foaming sole material of claim 1, it is characterized in that: described softening agent is o-phthalic acid dibutyl ester, dibutyl phthalate, one or more in the clorafin.
3. according to the prescription of the described a kind of antistatic HPVC foaming sole material of claim 1, it is characterized in that: described whipping agent is Cellmic C 121.
4. according to the described a kind of antistatic HPVC foaming sole material of claim 1, it is characterized in that: described metallic salt stablizer is barium stearate, Zinic stearas, one or more in the calcium stearate.
5. according to the described a kind of antistatic HPVC foaming sole material of claim 1, it is characterized in that: described static inhibitor is non-ionic antistatic agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102499005A CN103289241A (en) | 2013-06-21 | 2013-06-21 | Antistatic HPVC foaming sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102499005A CN103289241A (en) | 2013-06-21 | 2013-06-21 | Antistatic HPVC foaming sole material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103289241A true CN103289241A (en) | 2013-09-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102499005A Pending CN103289241A (en) | 2013-06-21 | 2013-06-21 | Antistatic HPVC foaming sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103289241A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558967A (en) * | 2015-01-16 | 2015-04-29 | 江苏美誉虹新材料科技有限公司 | Novel functional food shoes |
| CN104672718A (en) * | 2015-03-09 | 2015-06-03 | 苏州市景荣科技有限公司 | Heat-resistant PVC shoe material and preparation method thereof |
| CN105542342A (en) * | 2016-01-20 | 2016-05-04 | 苏州市景荣科技有限公司 | Novel antistatic PVC sole material |
| CN106432982A (en) * | 2016-11-17 | 2017-02-22 | 无锡市长安曙光手套厂 | High-polymerization-degree polyvinyl chloride wear-resistant sole material |
| CN106519506A (en) * | 2016-11-17 | 2017-03-22 | 无锡市长安曙光手套厂 | HPVC (PVC with high degree of polymerization) sole material |
| CN107501806A (en) * | 2017-10-08 | 2017-12-22 | 界首市旭升塑胶制品有限公司 | A kind of hard plastic sole product of wear-resisting height |
| CN115558220A (en) * | 2022-10-14 | 2023-01-03 | 深圳市好亚通防护用品有限公司 | Antistatic SPU sole material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61143456A (en) * | 1984-12-17 | 1986-07-01 | Nippon Rubber Co Ltd | Antistatic rubber composition |
| CN1408755A (en) * | 2001-09-28 | 2003-04-09 | 朱国侯 | Flame-retardant anti-static boots material formulation and its prepducing method |
| CN102634131A (en) * | 2012-04-11 | 2012-08-15 | 深圳市新纶科技股份有限公司 | Low-density PVC (Poly Vinyl Chloride) injection-molded shoe material and preparation method thereof |
-
2013
- 2013-06-21 CN CN2013102499005A patent/CN103289241A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61143456A (en) * | 1984-12-17 | 1986-07-01 | Nippon Rubber Co Ltd | Antistatic rubber composition |
| CN1408755A (en) * | 2001-09-28 | 2003-04-09 | 朱国侯 | Flame-retardant anti-static boots material formulation and its prepducing method |
| CN102634131A (en) * | 2012-04-11 | 2012-08-15 | 深圳市新纶科技股份有限公司 | Low-density PVC (Poly Vinyl Chloride) injection-molded shoe material and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 张玉龙等: "《塑料注射制品配方设计与加工实例》", 31 January 2006, 国防工业出版社 * |
| 辛忠: "《合成材料添加剂化学》", 31 August 2005, 化学工业出版社教材出版中心 * |
| 连荣炳等: ""成核剂对软质PVC鞋底发泡材料的影响"", 《塑料科技》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558967A (en) * | 2015-01-16 | 2015-04-29 | 江苏美誉虹新材料科技有限公司 | Novel functional food shoes |
| CN104672718A (en) * | 2015-03-09 | 2015-06-03 | 苏州市景荣科技有限公司 | Heat-resistant PVC shoe material and preparation method thereof |
| CN105542342A (en) * | 2016-01-20 | 2016-05-04 | 苏州市景荣科技有限公司 | Novel antistatic PVC sole material |
| CN106432982A (en) * | 2016-11-17 | 2017-02-22 | 无锡市长安曙光手套厂 | High-polymerization-degree polyvinyl chloride wear-resistant sole material |
| CN106519506A (en) * | 2016-11-17 | 2017-03-22 | 无锡市长安曙光手套厂 | HPVC (PVC with high degree of polymerization) sole material |
| CN107501806A (en) * | 2017-10-08 | 2017-12-22 | 界首市旭升塑胶制品有限公司 | A kind of hard plastic sole product of wear-resisting height |
| CN115558220A (en) * | 2022-10-14 | 2023-01-03 | 深圳市好亚通防护用品有限公司 | Antistatic SPU sole material and preparation method thereof |
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Application publication date: 20130911 |