CN103275592A - Anticorrosion acrylic ester paint and preparation method thereof - Google Patents
Anticorrosion acrylic ester paint and preparation method thereof Download PDFInfo
- Publication number
- CN103275592A CN103275592A CN2013101973598A CN201310197359A CN103275592A CN 103275592 A CN103275592 A CN 103275592A CN 2013101973598 A CN2013101973598 A CN 2013101973598A CN 201310197359 A CN201310197359 A CN 201310197359A CN 103275592 A CN103275592 A CN 103275592A
- Authority
- CN
- China
- Prior art keywords
- parts
- protection against
- against corrosion
- acrylate paint
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides anticorrosion acrylic ester paint having good adhesive force, excellent weather resistance and excellent corrosion resistance and applied to the outer surface of a steel pipe. The anticorrosion acrylic ester paint is prepared from the following components in parts by mass: 30 to 40 parts of epoxy acrylic acid resin, 4 to 6 parts of hydroxyethyl acrylate, 4 to 6 parts of benzoic acid dibutyl phthalate, 2 to 3 parts of dimethylbenzene, 4 to 6 parts of hydroxyethyl methylacrylate, 6 to 8 parts of acrylic acid, 8 to 10 parts of terpene resin and 2 to 3 parts of polymerization inhibitor. The anticorrosion acrylic ester paint has good corrosion resistance and good adhesive force, can be dried quickly and can provide excellent anticorrosive protection for the steel pipe under different severe natural conditions.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of protection against corrosion acrylate paint and preparation method thereof.
Background technology
Steel pipe is after Steel Plant's streamline rolls off the production line, and its surface corrosion resistance performance is poor, is easy to be corroded in storage and transport process, has a strong impact on its performance and work-ing life.In case its surface is corroded, its subsequent processes is loaded down with trivial details, and workload is big.Adopt steel tube surface plating alloy in producing at present, technologies such as alramenting are handled light pipe, improve its antiseptic property.Compare with other surface preservative treatment techniques, painting anticorrosion erosion coating forms coating protection technology and has simple to operation, excellent performance and the incomparable advantage of more high other material of economic benefit.Therefore, for guaranteeing the surperficial intact of steel pipe in the storage and transport process, the present invention has developed a kind of have good sticking power and good weather-proof, the outer surface of steel tube protection against corrosion acrylate paint of corrosion resistance nature.
Summary of the invention
The invention provides a kind of good sticking power and good weather-proof that has, the outer surface of steel tube protection against corrosion acrylate paint of corrosion resistance nature, for this reason, the present invention also provides its preparation method.
The invention provides a kind of protection against corrosion acrylate paint, described protection against corrosion acrylate paint is prepared from by each component of following mass fraction: epoxy acrylic resin 30-40 part, Hydroxyethyl acrylate 4-6 part, phenylformic acid dibutylester 4-6 part, dimethylbenzene 2-3 part, hydroxyethyl methylacrylate 4-6 part, vinylformic acid 6-8 part, terpine resin 8-10 part, stopper 2-3 part.
Further, described protection against corrosion acrylate paint is prepared from by each component of following mass fraction: 35 parts of epoxy acrylic resins, 5 parts of Hydroxyethyl acrylates, 5 parts of phenylformic acid dibutylesters, 2.5 parts of dimethylbenzene, 5 parts of hydroxyethyl methylacrylates, 7 parts in vinylformic acid, 9 parts of terpine resins, 2.5 parts of stoppers.
Further, described terpine resin is the macromolecular compound that turps α-firpene and β-firpene are polymerized under the Louis acid catalysis effect, and its softening temperature is 80～130 ℃, acid number≤2mgKOH/g, saponification value≤2mgKOH/g.
Further, described stopper is p methoxy phenol or 2-Tert. Butyl Hydroquinone.
Second purpose of the present invention provides the preparation method of above-mentioned protection against corrosion acrylate paint, and step is as follows: each component is mixed, be warming up to 40-45 ℃ and stirred 4-5 hour, be cooled to room temperature, obtain the protection against corrosion acrylate paint.
Protection against corrosion acrylate paint of the present invention has good Corrosion Protection, and is rapidly dry, has good sticking power, can provide excellent anti-corrosion protection for steel pipe under various abominable natural condition.
Embodiment
Embodiment 1
The prescription of protection against corrosion acrylate paint of the present invention is as follows:
Epoxy acrylic resin 35kg, Hydroxyethyl acrylate 5kg, phenylformic acid dibutylester 5kg, dimethylbenzene 2.5kg, hydroxyethyl methylacrylate 5kg, vinylformic acid 7kg, terpine resin 9kg, stopper 2.5kg.
Wherein, terpine resin is the macromolecular compound that turps α-firpene and β-firpene are polymerized under the Louis acid catalysis effect, and its softening temperature is 80～130 ℃, acid number≤2mgKOH/g, saponification value≤2mgKOH/g.
Stopper is p methoxy phenol.
The preparation method of protection against corrosion acrylate paint of the present invention is:
Each component of formula ratio is mixed, be warming up to 40-45 ℃ and stirred 4-5 hour, be cooled to room temperature, obtain the protection against corrosion acrylate paint.
Embodiment 2
The prescription of protection against corrosion acrylate paint of the present invention is as follows:
Epoxy acrylic resin 30kg, Hydroxyethyl acrylate 4kg, phenylformic acid dibutylester 4kg, dimethylbenzene 2kg, hydroxyethyl methylacrylate 4kg, vinylformic acid 6kg, terpine resin 8kg, stopper 2kg.
Wherein, terpine resin is the macromolecular compound that turps α-firpene and β-firpene are polymerized under the Louis acid catalysis effect, and its softening temperature is 80～130 ℃, acid number≤2mgKOH/g, saponification value≤2mgKOH/g.
Stopper is p methoxy phenol.
The preparation method of protection against corrosion acrylate paint of the present invention is:
Each component of formula ratio is mixed, be warming up to 40-45 ℃ and stirred 4-5 hour, be cooled to room temperature, obtain the protection against corrosion acrylate paint.
Embodiment 3
The prescription of protection against corrosion acrylate paint of the present invention is as follows:
Epoxy acrylic resin 40kg, Hydroxyethyl acrylate 6kg, phenylformic acid dibutylester 6kg, dimethylbenzene 3kg, hydroxyethyl methylacrylate 6kg, vinylformic acid 8kg, terpine resin 10kg, stopper 3kg.
Wherein, terpine resin is the macromolecular compound that turps α-firpene and β-firpene are polymerized under the Louis acid catalysis effect, and its softening temperature is 80～130 ℃, acid number≤2mgKOH/g, saponification value≤2mgKOH/g.
Stopper is the 2-Tert. Butyl Hydroquinone.
The preparation method of protection against corrosion acrylate paint of the present invention is:
Each component of formula ratio is mixed, be warming up to 40-45 ℃ and stirred 4-5 hour, be cooled to room temperature, obtain the protection against corrosion acrylate paint.
Embodiment 4
The prescription of protection against corrosion acrylate paint of the present invention is as follows:
Epoxy acrylic resin 38kg, Hydroxyethyl acrylate 5kg, phenylformic acid dibutylester 5kg, dimethylbenzene 2kg, hydroxyethyl methylacrylate 4kg, vinylformic acid 5kg, terpine resin 9kg, stopper 2kg.
Wherein, terpine resin is the macromolecular compound that turps α-firpene and β-firpene are polymerized under the Louis acid catalysis effect, and its softening temperature is 80～130 ℃, acid number≤2mgKOH/g, saponification value≤2mgKOH/g.
Stopper is the 2-Tert. Butyl Hydroquinone.
The preparation method of protection against corrosion acrylate paint of the present invention is:
Each component of formula ratio is mixed, be warming up to 40-45 ℃ and stirred 4-5 hour, be cooled to room temperature, obtain the protection against corrosion acrylate paint.
Table 1 is conventional protection against corrosion acrylate paint and protection against corrosion acrylate paint performance comparison test of the present invention.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment the present invention is had been described in detail, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. protection against corrosion acrylate paint, it is characterized in that: described protection against corrosion acrylate paint is prepared from by each component of following mass fraction: epoxy acrylic resin 30-40 part, Hydroxyethyl acrylate 4-6 part, phenylformic acid dibutylester 4-6 part, dimethylbenzene 2-3 part, hydroxyethyl methylacrylate 4-6 part, vinylformic acid 6-8 part, terpine resin 8-10 part, stopper 2-3 part.
2. protection against corrosion acrylate paint according to claim 1, it is characterized in that: described protection against corrosion acrylate paint is prepared from by each component of following mass fraction: 35 parts of epoxy acrylic resins, 5 parts of Hydroxyethyl acrylates, 5 parts of phenylformic acid dibutylesters, 2.5 parts of dimethylbenzene, 5 parts of hydroxyethyl methylacrylates, 7 parts in vinylformic acid, 9 parts of terpine resins, 2.5 parts of stoppers.
3. protection against corrosion acrylate paint according to claim 1 and 2, it is characterized in that: described terpine resin is the macromolecular compound that turps α-firpene and β-firpene are polymerized under the Louis acid catalysis effect, its softening temperature is 80～130 ℃, acid number≤2mgKOH/g, saponification value≤2mgKOH/g.
4. protection against corrosion acrylate paint according to claim 1 and 2, it is characterized in that: described stopper is p methoxy phenol or 2-Tert. Butyl Hydroquinone.
5. the preparation method of the described protection against corrosion acrylate paint of claim 1-4, step is as follows: each component is mixed, be warming up to 40-45 ℃ and stirred 4-5 hour, be cooled to room temperature, obtain the protection against corrosion acrylate paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101973598A CN103275592A (en) | 2013-05-24 | 2013-05-24 | Anticorrosion acrylic ester paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101973598A CN103275592A (en) | 2013-05-24 | 2013-05-24 | Anticorrosion acrylic ester paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103275592A true CN103275592A (en) | 2013-09-04 |
Family
ID=49058224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013101973598A Pending CN103275592A (en) | 2013-05-24 | 2013-05-24 | Anticorrosion acrylic ester paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103275592A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592849A (en) * | 2015-02-03 | 2015-05-06 | 安徽工业大学 | Multifunctional composite coating for lithium aluminate nanosheets |
| CN106349842A (en) * | 2016-08-26 | 2017-01-25 | 山东北方现代化学工业有限公司 | Quick-drying terpene resin modified thermoplastic acrylic resin paint and parathion method thereof |
| CN108912884A (en) * | 2018-06-19 | 2018-11-30 | 界首市创新门窗有限公司 | A kind of alum gate column anticorrosive paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006118532A1 (en) * | 2005-05-04 | 2006-11-09 | Perstorp Specialty Chemicals Ab | Hybrid radiation curable composition and use thereof |
| CN101037564A (en) * | 2006-03-17 | 2007-09-19 | 浙江安邦新材料发展有限公司 | Self-emulsification crylic acid epoxy emulsification agent and its aqueous crylic acid epoxy resin latex |
| CN102120909A (en) * | 2010-12-23 | 2011-07-13 | 天津科瑞达涂料化工有限公司 | Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall |
| CN102964970A (en) * | 2012-12-24 | 2013-03-13 | 青岛宣威涂层材料有限公司 | Epoxy acrylic anticorrosive paint |
-
2013
- 2013-05-24 CN CN2013101973598A patent/CN103275592A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006118532A1 (en) * | 2005-05-04 | 2006-11-09 | Perstorp Specialty Chemicals Ab | Hybrid radiation curable composition and use thereof |
| CN101037564A (en) * | 2006-03-17 | 2007-09-19 | 浙江安邦新材料发展有限公司 | Self-emulsification crylic acid epoxy emulsification agent and its aqueous crylic acid epoxy resin latex |
| CN102120909A (en) * | 2010-12-23 | 2011-07-13 | 天津科瑞达涂料化工有限公司 | Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall |
| CN102964970A (en) * | 2012-12-24 | 2013-03-13 | 青岛宣威涂层材料有限公司 | Epoxy acrylic anticorrosive paint |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592849A (en) * | 2015-02-03 | 2015-05-06 | 安徽工业大学 | Multifunctional composite coating for lithium aluminate nanosheets |
| CN104592849B (en) * | 2015-02-03 | 2017-01-18 | 安徽工业大学 | Multifunctional composite coating for lithium aluminate nanosheets |
| CN106349842A (en) * | 2016-08-26 | 2017-01-25 | 山东北方现代化学工业有限公司 | Quick-drying terpene resin modified thermoplastic acrylic resin paint and parathion method thereof |
| CN106349842B (en) * | 2016-08-26 | 2019-04-23 | 山东北方现代化学工业有限公司 | A kind of terpene resin modification thermoplastic acrylic acid resin quick-drying paint and preparation method thereof |
| CN108912884A (en) * | 2018-06-19 | 2018-11-30 | 界首市创新门窗有限公司 | A kind of alum gate column anticorrosive paint |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103305092A (en) | Anticorrosive coating and preparation method thereof | |
| CN103421416A (en) | Anticorrosive coating and preparation method thereof | |
| CN102477245A (en) | Ultraviolet light curing anticorrosion paint and its preparation method | |
| CN103012634A (en) | Organic phosphate modified acrylate oligomer cured by ultraviolet light and preparation method of organic phosphate modified acrylate oligomer | |
| CN103275592A (en) | Anticorrosion acrylic ester paint and preparation method thereof | |
| CN102702936A (en) | High-performance UV (Ultraviolet) paint | |
| CN102875741A (en) | Anticorrosive paint used for aluminum evaporator of refrigerator | |
| CN104804621A (en) | Anticorrosive coating | |
| CN105440894A (en) | Light-cured coating composition for metal surface corrosion resistance | |
| CN105034487B (en) | Corrosion-resistant PVDF film coated plates | |
| CN106700824A (en) | Preparation method of modified epoxy resin anticorrosive paint with epoxy acrylic resin | |
| CN111471337A (en) | Composition, preparation method and application in field of anticorrosive coating | |
| CN105238231A (en) | Special-purposed anticorrosion paint for metal | |
| CN105244455A (en) | Anti-corrosion protective film for soft package lithium battery and preparation method and application thereof | |
| CN104830125A (en) | Water-based acrylate anticorrosive coating | |
| CN105219228A (en) | A kind of anticorrosive metal paint | |
| CN104250460A (en) | Wear-resistant paint used for metal components, and preparation method of wear-resistant paint | |
| CN101003605A (en) | Technique for synthesizing air-dry type oxirene ester resin | |
| CN113150243A (en) | Dynamic self-healing antirust epoxy resin and preparation method thereof | |
| CN107715811B (en) | Self-repairing microcapsule for aqueous coating on surface of wood material and preparation method thereof | |
| CN104312475A (en) | Emergency adhesive tape with acrylic composite | |
| CN104974571A (en) | Shock resistant high-abrasion-proof paint for hydraulic parts | |
| CN103739772B (en) | Resin for plurality of types of base materials as well as preparation method and application thereof | |
| CN105219229A (en) | A kind of anticorrosive metal paint and preparation method thereof | |
| CN103602255A (en) | Anti-sinking roller coating primer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130904 |