CN103275425A - Novel polyvinyl chloride (PVC) sole material - Google Patents
Novel polyvinyl chloride (PVC) sole material Download PDFInfo
- Publication number
- CN103275425A CN103275425A CN2013102130490A CN201310213049A CN103275425A CN 103275425 A CN103275425 A CN 103275425A CN 2013102130490 A CN2013102130490 A CN 2013102130490A CN 201310213049 A CN201310213049 A CN 201310213049A CN 103275425 A CN103275425 A CN 103275425A
- Authority
- CN
- China
- Prior art keywords
- sole
- shoe
- pvc material
- novel pvc
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 23
- 239000004800 polyvinyl chloride Substances 0.000 title abstract 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004593 Epoxy Substances 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- LHWIBZQIEODOQQ-UHFFFAOYSA-H S(=O)(=O)([O-])[O-].C(CCC)[Sn+3].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-].C(CCC)[Sn+3] Chemical compound S(=O)(=O)([O-])[O-].C(CCC)[Sn+3].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-].C(CCC)[Sn+3] LHWIBZQIEODOQQ-UHFFFAOYSA-H 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- -1 Zinic stearas Chemical compound 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 159000000007 calcium salts Chemical class 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- WNVQCJNZEDLILP-UHFFFAOYSA-N dimethyl(oxo)tin Chemical compound C[Sn](C)=O WNVQCJNZEDLILP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 2
- 229960003656 ricinoleic acid Drugs 0.000 claims description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 238000005452 bending Methods 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 239000006084 composite stabilizer Substances 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a novel polyvinyl chloride (PVC) sole material, comprising the following components in percentage by weight: 50 to 70 percent of PVC, 5 to 10 percent of CaCO3, 2 to 3 percent of an organic tin stabilizer, 0.5 to 1 percent of a calcium zinc composite stabilizer, 20 to 30 percent of dibutyl phthalate (DBP) and 3 to 6 percent of a curing agent E51. The novel PVC sole material is scientific in formula, low in production cost and simple in preparation process, and has the capability of enhancing the bonding strength, the tensile strength and the bending strength of a sole, thereby improving the mechanical properties.
Description
Technical field:
The present invention relates to footwear material technical field, relate in particular to a kind of PVC material for sole of shoe.
Background technology:
That the PVC material for sole of shoe has is fire-retardant, corrosion-resistant, insulation, good performance such as wear-resistant, and it is cheap, raw material sources are wide, but there is obvious defects when being to use, poor as shock resistance, thermotolerance is bad, and 100 ℃ just begin to decompose, the thing that is hit is broken etc. easily, and the range of application of PVC is restricted.
Resins, epoxy is the thermosetting polymer synthetic materials that a class has performances such as good bonding, corrosion-resistant, insulation, high strength, intrinsic polarity hydroxyl and the existence of ether in its molecular chain, make it have higher adhesive power to various materials, shrinkability during curing is low, the internal stress that produces is little, help the raising adhesion strength, be widely used in the aspect such as bonding, corrosion-resistant, insulating material of multiple metal and non-metallic material.
Resins, epoxy adds in the PVC material for sole of shoe as solidifying agent, can improve stretching and the flexural strength of material.
Summary of the invention:
The purpose of this invention is to provide a kind of novel PVC material for sole of shoe, this material has higher bonding strength, tensile strength and flexural strength.
Purpose of the present invention is achieved through the following technical solutions:
A kind of novel PVC material for sole of shoe comprises following component by weight percentage:
Preferred as technique scheme, described organotin stabilizer is one or more mixtures in dimethyl tin oxide, the butyl tin sulphate.
Preferred as technique scheme, described calcium zinc stabilizer is less fatty calcium salt and the zinc salt of carbon number that is soluble in organic solvent, and main component has calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil, UV light absorber.
Preferred as technique scheme, described DBP is dibutyl phthalate, by the compound that carbon, hydrogen, oxygen element are formed, its chemical formula is C
16H
22O
4
Preferred as technique scheme, described solidifying agent E51 is a kind of epoxy curing agent, exactly Resins, epoxy and solidifying agent is made into glue, soaks numb felt, then curing molding.
Beneficial effect of the present invention is: its scientific formulation, cost is low, preparation technology is simple, can increase bonding strength, tensile strength and the flexural strength of sole, thereby improves its mechanical property.
Embodiment:
In order to deepen the understanding of the present invention, the invention will be further described below in conjunction with embodiment, and this embodiment only is used for explaining the present invention, does not constitute the restriction to protection domain of the present invention.
Embodiment 1:
Take by weighing PVC material 60g, CaCO
38g, organotin stabilizer 2.5g, calcium-zinc composite stabilizing agent 0.5g, DBP 25g, solidifying agent E51 4g mixes 10min in 95 ℃ of heat, cold mixing to room temperature again, extruding pelletization in conical double screw extruder then, rotating speed 15r/min is with pellet injection moulding in injection moulding machine.
Embodiment 2:
Take by weighing PVC material 60g, CaCO
36g, organotin stabilizer 2.5g, calcium-zinc composite stabilizing agent 0.5g, DBP 26g, solidifying agent E51 5g mixes 10min in 95 ℃ of heat, cold mixing to room temperature again, extruding pelletization in conical double screw extruder then, rotating speed 15r/min is with pellet injection moulding in injection moulding machine.
Embodiment 3:
Take by weighing PVC material 60g, CaCO
36g, organotin stabilizer 2.5g, calcium-zinc composite stabilizing agent 0.5g, DBP 25g, solidifying agent E51 6g mixes 10min in 95 ℃ of heat, cold mixing to room temperature again, extruding pelletization in conical double screw extruder then, rotating speed 15r/min is with pellet injection moulding in injection moulding machine.
Claims (7)
1. novel PVC material for sole of shoe is characterized in that: comprise following component by weight percentage:
2. according to the described a kind of novel PVC material for sole of shoe of claim 1, it is characterized in that: the content of described PVC is 60%.
3. according to the described a kind of novel PVC material for sole of shoe of claim 1, it is characterized in that: described CaCO
3Content be 8-10%.
4. according to the described a kind of novel PVC material for sole of shoe of claim 1, it is characterized in that: described organotin stabilizer is one or more mixtures in dimethyl tin oxide, the butyl tin sulphate.
5. according to the described a kind of novel PVC material for sole of shoe of claim 1, it is characterized in that: described calcium zinc stabilizer is less fatty calcium salt and the zinc salt of carbon number that is soluble in organic solvent, and main component has calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil, UV light absorber.
6. according to the described a kind of novel PVC material for sole of shoe of claim 1, it is characterized in that:
Described DBP is dibutyl phthalate, and by the compound that carbon, hydrogen, oxygen element are formed, its chemical formula is C
16H
22O
4
7. according to the described a kind of novel PVC material for sole of shoe of claim 1, it is characterized in that: described solidifying agent E51 is a kind of epoxy curing agent, exactly Resins, epoxy and solidifying agent is made into glue, soaks numb felt, then curing molding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310213049.0A CN103275425B (en) | 2013-05-31 | 2013-05-31 | A kind of PVC sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310213049.0A CN103275425B (en) | 2013-05-31 | 2013-05-31 | A kind of PVC sole material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103275425A true CN103275425A (en) | 2013-09-04 |
| CN103275425B CN103275425B (en) | 2016-01-20 |
Family
ID=49058060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310213049.0A Expired - Fee Related CN103275425B (en) | 2013-05-31 | 2013-05-31 | A kind of PVC sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103275425B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571090A (en) * | 2013-10-15 | 2014-02-12 | 苏州市景荣科技有限公司 | Radiation-proof PVC (polyvinyl chloride) sole material |
| CN113214575A (en) * | 2021-04-24 | 2021-08-06 | 温州市剑利鞋业有限公司 | PVC sole and preparation process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101817962A (en) * | 2010-02-11 | 2010-09-01 | 国家复合改性聚合物材料工程技术研究中心 | Polyvinyl chloride/epoxy resin blend and preparation method thereof |
| CN101935428A (en) * | 2010-09-14 | 2011-01-05 | 国家复合改性聚合物材料工程技术研究中心 | Method for preparing epoxy resin cross-linked high-elasticity flexible polyvinyl chloride material |
-
2013
- 2013-05-31 CN CN201310213049.0A patent/CN103275425B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101817962A (en) * | 2010-02-11 | 2010-09-01 | 国家复合改性聚合物材料工程技术研究中心 | Polyvinyl chloride/epoxy resin blend and preparation method thereof |
| CN101935428A (en) * | 2010-09-14 | 2011-01-05 | 国家复合改性聚合物材料工程技术研究中心 | Method for preparing epoxy resin cross-linked high-elasticity flexible polyvinyl chloride material |
Non-Patent Citations (1)
| Title |
|---|
| 罗万湘: ""聚氯乙烯透明注塑底"", 《四川皮革》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571090A (en) * | 2013-10-15 | 2014-02-12 | 苏州市景荣科技有限公司 | Radiation-proof PVC (polyvinyl chloride) sole material |
| CN113214575A (en) * | 2021-04-24 | 2021-08-06 | 温州市剑利鞋业有限公司 | PVC sole and preparation process thereof |
| CN113214575B (en) * | 2021-04-24 | 2022-03-25 | 温州市剑利鞋业有限公司 | PVC sole and preparation process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103275425B (en) | 2016-01-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Feng Biying Inventor before: Huang Chao |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151216 Address after: Anxi County of Quanzhou City, Fujian province 362417 Tao Zhou Xiang Nan Keng Cun Nan Kang No. 14 Applicant after: Feng Biying Address before: 215000 Suzhou high tech Zone, Jiangsu, the British road, No. 88 Applicant before: Suzhou Jingro Technology Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Cai Xiaolin Inventor after: Cai Xiaodong Inventor after: Li Dequan Inventor after: Wang Dawei Inventor after: Zhang Longjian Inventor before: Feng Biying |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160918 Address after: 325000 5 Willow Road, Ouhai Economic Development Zone, Wenzhou, Zhejiang Patentee after: Wenzhou Xiaolin Shoes Materials Co., Ltd. Address before: Anxi County of Quanzhou City, Fujian province 362417 Tao Zhou Xiang Nan Keng Cun Nan Kang No. 14 Patentee before: Feng Biying |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20210414 Address after: 226100 No. 38 Zhonghua East Road, three Factory Street, Haimen City, Nantong, Jiangsu Patentee after: Nantong an art design Co.,Ltd. Address before: No.5, Lvliu Road, Ouhai Economic Development Zone, Wenzhou, Zhejiang 325000 Patentee before: WENZHOU XIAOLIN SHOES MATERIALS Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160120 Termination date: 20210531 |
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| CF01 | Termination of patent right due to non-payment of annual fee |