CN103273755A - Transfer membrane for curved surface transfer printing - Google Patents
Transfer membrane for curved surface transfer printing Download PDFInfo
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- CN103273755A CN103273755A CN2013102574858A CN201310257485A CN103273755A CN 103273755 A CN103273755 A CN 103273755A CN 2013102574858 A CN2013102574858 A CN 2013102574858A CN 201310257485 A CN201310257485 A CN 201310257485A CN 103273755 A CN103273755 A CN 103273755A
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- curved surface
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- dry coating
- ink jet
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Abstract
The invention relates to a transfer membrane for curved surface transfer printing, which is characterized by comprising a substrate layer, an isolation coating, a drying coating and an ink jet coating from the bottom up. The transfer membrane has the advantages that the transfer membrane can allow a printing process of a curved surface product to be simple, is high in yield, and can be applied to transfer printing of a complicated three-dimensional curved surface.
Description
Technical field
The present invention relates to a kind of transfer membrane, relate in particular to a kind of transfer membrane for the curved surface transfer printing.
Background technology
Curved article typography more complicated adopts corresponding printing process at difform implements at present, also need make many anchor clamps, mould simultaneously, so complex manufacturing process, and yield rate is low; The tradition transfer printing need be through complicated net processed and the color matching operation of sizing mixing, use has the dyestuff of distillation characteristic, floral designs are printed on the transfer printing paper, the transfer printing paper that will be printed on floral designs then contacts closely with printing item, makes dye sublimation to the printing item surface by hot pressing; Because paper can not be out of shape or fold, so can not be applied to the transfer printing of complex three-dimensional curved surface.
Summary of the invention
At above-mentioned shortcoming, the object of the present invention is to provide a kind of transfer membrane for the curved surface transfer printing, it can make curved article stamp manufacturing process simple, the yield rate height; Can be applied to simultaneously the transfer printing of complex three-dimensional curved surface.
Technology contents of the present invention is, a kind of transfer membrane for the curved surface transfer printing, it have down and on comprise substrate layer, barrier coat, dry coating and ink jet coatings; Substrate layer is amorphous membrance, crystalline form film or polymeric membrane are arranged; The thickness of barrier coat is 5～100 microns, and barrier coat comprises following components in weight percent:
Water 60～80
Crosslinking agent 5～15
Organosilicon 10～15
Polymer Solution 5～15;
Wherein crosslinking agent is divinylbenzene, vulcabond, acrylamide, aziridine crosslinker or peroxide cross-linking agent; Organosilicon is silane or siloxanes; Macromolecule emulsion is polyacrylate or polyurethane;
The thickness of dry coating is 5～100 microns, and dry coating comprises following components in weight percent:
Adhesive 50～80
Inorganic matter 5～20
Water-absorbing resin 10～20
Nano particle 5～15;
Adhesive wherein: polyvinyl alcohol, polyurethane, acrylic resin or epoxy resin; Inorganic matter is CaCO
3Or kaolin, its fineness is 100～200 orders; Water-absorbing resin is acrylic acid salt or Sodium Polyacrylate; Nano particle is nanometer SiO
2Or nanometer Al
2O
3
The thickness of ink jet coatings is 5～100 microns, and ink jet coatings comprises following components in weight percent:
Resin cation 40～60
Coalescents 40～60;
Wherein resin cation pH value is 2～6; Coalescents is TMPTA(trihydroxy acrylate), trimethylolpropane or triacrylate.
The present invention earlier prints to back oven dry on the ink jet coatings with pattern with ink jet coatings in use, by Packing Machine pattern plane is pasted the transfer membrane plastic uptake after to curved article then and is the stamp of finishing curved article on the curved article.
At above-mentioned transfer membrane for the curved surface transfer printing, substrate layer is can deformation more than 150 ℃, but the plastic film material that can not break, and under the heating jump condition, can make pattern on the film according to deformation of surface, and keep pattern continuity and fineness; Barrier coat can prevent the heat sublimation dyestuff on the polymeric membrane of transferring to substrate layer after the heating, improves the rate of transform of dyestuff, bright-colored degree; Dry coating is not under absorbing the situation of disperseing dye component in the ink, and the moisture in can the rapid draing ink improves print speed and pattern fineness; Ink jet coatings can make pigment pass through printer directly with the pattern spray printing to ink jet coatings, pattern precision height, dyestuff is stayed the transfer membrane surface, has improved the rate of transform.
At the barrier coat of above-mentioned transfer membrane for the curved surface transfer printing, crosslinking agent can improve hear resistance, resistance to chemical corrosion, dimensional stability, weatherability and the mechanical performance etc. of barrier coat; Organosilicon has the excellent electric insulating energy, weatherability, heat endurance height; Macromolecule emulsion can strengthen the wearability of barrier coat, anti-solvent and lower temperature resistance.
At the dry coating of above-mentioned transfer membrane for the curved surface transfer printing, adhesive can make dry coating that good adsorptivity is arranged, and can regulate flowability and the viscosity of dry coating simultaneously; Inorganic matter can strengthen deposition and the permeability of ink in dry coating, makes ink rapid draing; Water-absorbing resin has extremely strong water absorbing properties; Nano particle forms network structure when dry coating is dry, increased intensity and the fineness of dry coating simultaneously, and improved the suspension of pigment, improves dry coating fracture toughness, creep-resistant property.
At the ink jet coatings of above-mentioned transfer membrane for the curved surface transfer printing, resin cation is ink-jet ink-droplet fixedly, and ink droplet can not spread, thereby improves the pattern fineness.Coalescents can make the ink jet coatings uniformity, makes the digital ink-jet image can be attached to the transfer membrane surface uniformly, reduces aberration.
The advantage that the present invention compared with prior art has is: simplified the printing technology of curved article, improved yield rate; Also can be applied to simultaneously the transfer printing of complex three-dimensional curved surface.
Description of drawings
Fig. 1 is structural representation of the present invention.
Specific embodiment
As shown in Figure 1, a kind of transfer membrane for the curved surface transfer printing, it have down and on comprise substrate layer 1, barrier coat 2, dry coating 3 and ink jet coatings 4.
The invention is further illustrated by the following examples, but be not limited to for embodiment.
Example 1: a kind of transfer membrane for the curved surface transfer printing, it have down and on comprise substrate layer, barrier coat and dry coating; Substrate layer is the Supreme Being people of Du Pont white translucent polyester film Melinex238; The thickness of barrier coat is 20 microns, and barrier coat is made up of following components in weight percent:
Water 70
Crosslinking agent 10
Organosilicon 15
Polymer Solution 5;
Wherein crosslinking agent is the Bayhydur BL116 crosslinking agent of Bayer company; Organosilicon is the Sxloff7362 organosilicon of Dow Corning Corporation; Polymer Solution is the Airflex540 emulsion of aerochemistry company;
The thickness of dry coating is 15 microns, and dry coating is made up of following components in weight percent:
Adhesive 50
Inorganic matter 20
Water-absorbing resin 15
Nano particle 15;
Wherein adhesive is the Prime4990 adhesive of U.S. Michen company; Inorganic matter kaolin, its fineness are 150 orders; Water-absorbing resin is the pvp-90 resin of American I SP company; The nanometer SiO of nano particle: Tai Sexin letter company
2
The thickness of ink jet coatings is 15 microns, and ink jet coatings is by following components in weight percent:
Resin cation 50
Coalescents 50;
Wherein resin cation is the Alcostat567 resin cation of U.S. Allied Colloid company, and the pH value is 4; Coalescents is trimethylolpropane.
Example 2: a kind of transfer membrane for the curved surface transfer printing, it have down and on comprise substrate layer, barrier coat and dry coating; Substrate layer is the XMB7930F BK507 PBT of Du Pont; The thickness of barrier coat is 20 microns, and barrier coat is made up of following components in weight percent:
Water 80
Crosslinking agent 5
Organosilicon 10
Polymer Solution 5;
Wherein crosslinking agent is the Bayhydur BL116 crosslinking agent of Bayer company; Organosilicon is the Sxloff7362 organosilicon of Dow Corning Corporation; Polymer Solution is the Airflex540 emulsion of aerochemistry company;
The thickness of dry coating is 15 microns, and dry coating is made up of following components in weight percent:
Adhesive 60
Inorganic matter 10
Water-absorbing resin 20
Nano particle 10;
Wherein adhesive is the Prime4990 adhesive of U.S. Michen company; Inorganic matter kaolin, its fineness are 150 orders; Water-absorbing resin is the pvp-90 resin of American I SP company; The nanometer SiO of nano particle: Tai Sexin letter company
2
The thickness of ink jet coatings is 15 microns, and ink jet coatings is by following components in weight percent:
Resin cation 40
Coalescents 60;
Wherein resin cation is the Alcostat567 resin cation of U.S. Allied Colloid company, and the pH value is 4; Coalescents is triacrylate.
Example 3: a kind of transfer membrane for the curved surface transfer printing, it have down and on comprise substrate layer, barrier coat and dry coating; Substrate layer is the PA6 nylon film; The thickness of barrier coat is 20 microns, and barrier coat is made up of following components in weight percent:
Water 60
Crosslinking agent 15
Organosilicon 10
Polymer Solution 15;
Wherein crosslinking agent is the Bayhydur BL116 crosslinking agent of Bayer company; Organosilicon is the Sxloff7362 organosilicon of Dow Corning Corporation; Polymer Solution is the Airflex540 emulsion of aerochemistry company;
The thickness of dry coating is 15 microns, and dry coating is made up of following components in weight percent:
Adhesive 70
Inorganic matter 10
Water-absorbing resin 15
Nano particle 5;
Wherein adhesive is the Prime4990 adhesive of U.S. Michen company; Inorganic matter kaolin, its fineness are 150 orders; Water-absorbing resin is the pvp-90 resin of American I SP company; The nanometer SiO of nano particle: Tai Sexin letter company
2The thickness of ink jet coatings is 15 microns, and ink jet coatings is by following components in weight percent:
Resin cation 60
Coalescents 40;
Wherein resin cation is the Alcostat567 resin cation of U.S. Allied Colloid company, and the pH value is 4; Coalescents is TMPTA.
Claims (2)
1. transfer membrane that is used for the curved surface transfer printing, it is characterized in that it have down and on comprise substrate layer, barrier coat, dry coating and ink jet coatings.
2. a kind of transfer membrane for the curved surface transfer printing according to claim 2 is characterized in that substrate layer is amorphous membrance, crystalline form film or polymeric membrane arranged; The thickness of barrier coat is 5～100 microns, and barrier coat comprises following components in weight percent:
Water 60～80
Crosslinking agent 5～15
Organosilicon 10～15
Polymer Solution 5～15;
Wherein crosslinking agent is divinylbenzene, vulcabond, acrylamide, aziridine crosslinker or peroxide cross-linking agent; Organosilicon is silane or siloxanes; Macromolecule emulsion is polyacrylate or polyurethane;
The thickness of dry coating is 5～100 microns, and dry coating comprises following components in weight percent:
Adhesive 50～80
Inorganic matter 5～20
Water-absorbing resin 10～20
Nano particle 5～15;
Adhesive wherein: polyvinyl alcohol, polyurethane, acrylic resin or epoxy resin; Inorganic matter is CaCO
3Or kaolin, its fineness is 100～200 orders; Water-absorbing resin is acrylic acid salt or Sodium Polyacrylate; Nano particle is nanometer SiO
2Or nanometer Al
2O
3
The thickness of ink jet coatings is 5～100 microns, and ink jet coatings comprises following components in weight percent:
Resin cation 40～60
Coalescents 40～60;
Wherein resin cation pH value is 2～6; Coalescents is TMPTA, trimethylolpropane or triacrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310257485.8A CN103273755B (en) | 2013-06-26 | 2013-06-26 | Transfer membrane for curved surface transfer printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310257485.8A CN103273755B (en) | 2013-06-26 | 2013-06-26 | Transfer membrane for curved surface transfer printing |
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| Publication Number | Publication Date |
|---|---|
| CN103273755A true CN103273755A (en) | 2013-09-04 |
| CN103273755B CN103273755B (en) | 2014-11-26 |
Family
ID=49056423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310257485.8A Active CN103273755B (en) | 2013-06-26 | 2013-06-26 | Transfer membrane for curved surface transfer printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103273755B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276891A (en) * | 2018-02-05 | 2018-07-13 | 佛山市龙源镭射科技有限公司 | A kind of coloring coating and preparation method thereof that can be used for cold wave and the boiling hot rear print laser stamping systems of blanching high speed |
| CN108749385A (en) * | 2018-06-13 | 2018-11-06 | 和峻（广州）胶管有限公司 | A kind of method of outer textured fiber line hose transfer lettering |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1552579A (en) * | 2003-05-29 | 2004-12-08 | 中国乐凯胶片集团公司 | Ink-jet printing accepting medium and use thereof |
| CN100471688C (en) * | 2006-11-30 | 2009-03-25 | 中国乐凯胶片集团公司 | Front-spraying film for water-proof ink jetting |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| JP2013039791A (en) * | 2011-08-19 | 2013-02-28 | Fujifilm Corp | Transfer film and transfer method |
| CN202952675U (en) * | 2012-10-22 | 2013-05-29 | 佛山市天元汇邦装饰材料有限公司 | Polypropylene (PP) plastic uptake transfer film |
-
2013
- 2013-06-26 CN CN201310257485.8A patent/CN103273755B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1552579A (en) * | 2003-05-29 | 2004-12-08 | 中国乐凯胶片集团公司 | Ink-jet printing accepting medium and use thereof |
| CN100471688C (en) * | 2006-11-30 | 2009-03-25 | 中国乐凯胶片集团公司 | Front-spraying film for water-proof ink jetting |
| JP2013039791A (en) * | 2011-08-19 | 2013-02-28 | Fujifilm Corp | Transfer film and transfer method |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN202952675U (en) * | 2012-10-22 | 2013-05-29 | 佛山市天元汇邦装饰材料有限公司 | Polypropylene (PP) plastic uptake transfer film |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276891A (en) * | 2018-02-05 | 2018-07-13 | 佛山市龙源镭射科技有限公司 | A kind of coloring coating and preparation method thereof that can be used for cold wave and the boiling hot rear print laser stamping systems of blanching high speed |
| CN108749385A (en) * | 2018-06-13 | 2018-11-06 | 和峻（广州）胶管有限公司 | A kind of method of outer textured fiber line hose transfer lettering |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103273755B (en) | 2014-11-26 |
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Inventor after: Guo Zhenrong Inventor after: Wu Xianguo Inventor before: Guo Zhenrong |
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Owner name: ZHEJIANG LANYU DIGITAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: GUO ZHENRONG Effective date: 20150601 |
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Effective date of registration: 20150601 Address after: The temple town of Yiwu city 322002 Zhejiang city of Jinhua Province Du Qing Road No. 180 Patentee after: ZHEJIANG LANYU DIGITAL TECHNOLOGY CO., LTD. Address before: 214434, room 211, block D, hi tech Pioneer Park, No. Chengjiang Middle Road, Jiangyin, Jiangsu,, Wuxi Patentee before: Guo Zhenrong |
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Address after: The temple town of Yiwu city 322002 Zhejiang city of Jinhua Province Du Qing Road No. 180 Patentee after: Zhejiang Lanyu digital Polytron Technologies Inc Address before: The temple town of Yiwu city 322002 Zhejiang city of Jinhua Province Du Qing Road No. 180 Patentee before: ZHEJIANG LANYU DIGITAL TECHNOLOGY CO., LTD. |