Gradual Sulphitation and Neutralization reaction unit and method
Technical field
The invention belongs to sulfurous method cane sugar manufacture field neutralization reaction device, be specifically related to a kind of gradual Sulphitation and Neutralization reaction unit and method.
Background technology
In sulfurous method sugar refining technology, neutralization reaction is the peace and quiet key link of sugarcane juice, and its principle is in sugarcane juice, add sulfurous gas and milk of lime, and reaction forms calcium sulfite to adsorb non-sugar impurities, reaches the object of peace and quiet sugarcane juice.
The effect of neutralization reaction has material impact to sulfurous method white sugar quality and sugar yield.Current sulfitation sugar mill normally by sugarcane juice after stove drying, milk of lime is added in the tail pipe of pipeline sulfitator, then enter a loose gas bucket and carry out loose gas and simple mixing, because a large amount of sulfurous gas and milk of lime almost add in sugarcane juice simultaneously, chemical reaction is very violent.And due to the Main Function of loose gas bucket be the air dissipated in sugarcane juice and the sulfurous gas cannot absorbed completely, do not consider chemical reaction function, therefore loose gas bucket design volume is less, there is no agitator, this causes the mixing of sulfurous gas, milk of lime, sugarcane juice uneven, the purification effect of sugarcane juice is low, affects quality product and sugar total recovery.In addition, failing the lime of fully reaction and sulfurous gas enters into subsequent production link along with sugarcane juice, produces after reaction, follow-up evaporating pot incrustation is increased, reduces evaporation performance.
In recent years sugar refinery is in order to improve neutralization reaction efficiency, also use some utility appliance as: rotary hopper-type adds grey device, overflow type adds grey device, duct type adds grey device, shock flow type reactor, defeco-sulfitated juice enhanced reactor etc.
It is that master adds grey device and prelimer can be installed on a shaft simultaneously, adds ash from contrary two aspects simultaneously by regulating rotating bucket rotating speed and milk of lime overflow plate height to carry out a kind of equipment adjusted that rotary hopper-type adds grey device.Structure is simple, convenient and practical, but ignore sugarcane juice and milk of lime, sulfurous gas reaction needed room and time, rotary hopper-type add grey device add ash complete rear sugarcane juice directly enter mixed juice case then pump to subsequent processing, milk of lime, sulfurous gas, sugarcane juice have little time abundant hybrid reaction, cause the problems such as follow-up workshop section incrustation is many, poor product quality.
Overflow type adds grey device, and by moving left and right, (moving with suspension pulley) is main adds ash and preliming chute, regulates and accesses milk of lime amount, reach the object regulating main, pre-ash quantity.It is not high to the control accuracy of ash quantity fed that overflow type adds grey device, there is control hysteresis to a certain degree, and overflow is entered ash and caused sugarcane juice and milk of lime cannot abundant hybrid reaction, and defeco-sulfitated juice pH is locally too high or too low.
Duct type adds grey device and is mainly used in adding ash; When ash load is large, sugarcane juice flow is large, irregular for avoiding adding ash, ash can be added at several overflow port (trumpet type funnel) simultaneously.Duct type adds grey device and mixes with sugarcane juice with certain flow rate, is obviously better than first two equipment, and enters ash and have multiple overflow port, and it is more uniform for relatively adding ash.But thisly add grey device and do not have reaction time, namely add and namely walk to cause neutralization reaction not exclusively to enter settling vessel, the impact particularly for accelerated clarifier is large especially, and that easily causes settling vessel turns over the end.
Shock flow type reactor and defeco-sulfitated juice enhanced reactor all above, several shortcoming adding grey device are improved, and also paying special attention to, especially strengthening the mixture strength of sugarcane juice and milk of lime to adding the reaction required time after ash, promote neutralization reaction.But these two kinds of reactors easily deposit slag incrustation, there is blocking situation.
Summary of the invention
The present invention aims to provide a kind of gradual Sulphitation and Neutralization reaction unit, this gradual Sulphitation and Neutralization reaction unit overcomes the defect of current common Sulphitation and Neutralization reaction unit, solves that current sugarcane juice neutralization reaction is insufficient, the reaction times is too short, purification effect is low, incrustation blocks up the problems such as slag is serious.
Technical solution of the present invention is as follows: a kind of gradual Sulphitation and Neutralization reaction unit, comprises casing, row's juice mouth, diffuser, sulfitator tail pipe, milk of lime adding tube, adds grey performer, dividing plate, pH control device;
Be plural responding layer by baffle for separating in the horizontal direction in described casing; Connect in the mode of series connection between each responding layer, the dividing plate at each responding layer serial connection place is provided with through hole;
At least be provided with two milk of lime adding tubes, the described grey performer that adds is connected with milk of lime adding tube;
Described pH control device detects the pH of casing (1) interior sugarcane juice, according to the pH information detected, sends steering order to adding grey performer (6), controls the milk of lime addition added in grey performer (6);
Described pH control device detects by pH the pH that mouth detects casing, it is corresponding with milk of lime adding tube that described pH detects mouth, a pH detects the corresponding milk of lime adding tube of mouth, on sugarcane juice flow direction, after pH detection mouth is arranged at the milk of lime adding tube of its correspondence in casing.
When the dividing plate set in described casing is as more than two pieces, the through hole on the dividing plate at adjacent reaction layer serial connection place distributes in mode staggered up and down;
If the number of milk of lime adding tube is in a reactive layer less than or equal to the number that through hole is positioned at the dividing plate on responding layer top, the milk of lime adding tube mouth of pipe of these milk of lime adding tubes is located at the through hole being positioned at responding layer top;
Described pH control device detects by pH the pH that mouth detects casing, it is corresponding with milk of lime adding tube that described pH detects mouth, a pH detects the corresponding milk of lime adding tube of mouth, on sugarcane juice flow direction, after pH detection mouth is arranged at the milk of lime adding tube of its correspondence in casing;
Described pH detection mouth is positioned at the through hole of responding layer bottom after being located at the milk of lime adding tube of its correspondence.
Described pH control device comprises pH control module, pH detector;
Described pH detector is used for detecting mouth by pH and detects the pH mixing sugarcane juice in casing, and pH is transferred to pH control module;
The pH information that described pH control module transmits according to pH detector, calculating the increase and decrease amount of milk of lime, sending steering order to adding grey performer;
Described adds the steering order of grey performer according to pH control module, arranges valve opening, controls the milk of lime addition in milk of lime adding tube.
Described pH detector detects by pH the pH that mouth detects casing, it is corresponding with milk of lime adding tube that described pH detects mouth, a pH detects the corresponding milk of lime adding tube of mouth, on sugarcane juice flow direction, after pH detection mouth is arranged at the milk of lime adding tube of its correspondence in casing.
Preferably a milk of lime adding tube is located on stove drying tail pipe, and remaining milk of lime adding tube is established in a reactive layer.
The described reaction number of plies is preferably 2 ~ 8.
Whipping appts is equipped with in each responding layer.
At least one responding layer is provided with diffuser.
The shape of described casing is the one in the linker of rectangular parallelepiped, square, tri-prismoid, right cylinder, multiple cylindrical reaction layer, also can be the shape that other are applicable to.。
The present invention also provides a kind of Sulphitation and Neutralization reaction method, comprises the following steps:
Sugarcane juice in a, sulfitator tail pipe is before inflow casing, and the milk of lime adding tube controlling that it is arranged by adding grey performer passes into the milk of lime of predetermined amount;
B, stove drying add the first responding layer that the mixing sugarcane juice after ash flows into casing, and each responding layer after being flowed into by the through hole on dividing plate;
C, pH control device is preset and is limited pH, in the process of sugarcane juice flowing, detect the pH in casing, and according to this pH and the difference limiting pH, calculating the increase and decrease amount of milk of lime, sending steering order to adding grey performer, by adding the milk of lime addition in grey performer control milk of lime adding tube, sugarcane juice in final control casing remains on suitable pH scope, can react completely when making sugarcane juice flow to relief outlet;
D, react completely after sugarcane juice send into subsequent processing by relief outlet.
A kind of Sulphitation and Neutralization reaction method of the present invention, its preferred version comprises the following steps:
After sugarcane juice in a, sulfitator tail pipe flows into casing, add by n group the milk of lime that milk of lime adding tube that grey performer controls setting it on passes into predetermined amount, described n >=2;
B, stove drying add the first responding layer that the mixing sugarcane juice after ash flows into casing, and each responding layer after being flowed into by the through hole on dividing plate;
C, after each milk of lime adding tube, correspondence arranges pH and detects mouth one by one, and in the process of sugarcane juice flowing, pH control device is according to sugarcane juice sequence of flow in a reactive layer, and each pH corresponding detects mouth and presets pH limit value respectively, total n pH limit value;
D, pH control device detects mouth by each pH and detects each pH, and according to the difference of this pH restriction pH corresponding with it, calculate the increase and decrease amount of milk of lime, send steering order to adding grey performer, by adding the milk of lime addition that grey performer controls in the milk of lime adding tube of each correspondence, suitable pH scope can be remained on when finally making sugarcane juice flow to relief outlet, and fully react;
E, react completely after sugarcane juice send into subsequent processing by relief outlet.
PH control device described in above-mentioned Sulphitation and Neutralization reaction method preferred version arranges n, and to detect mouth corresponding one by one with pH.
The grey performer that adds described in above-mentioned Sulphitation and Neutralization reaction method preferred version arranges n, corresponding one by one with milk of lime adding tube.
Gradual Sulphitation and Neutralization reaction unit of the present invention is by arranging dividing plate, casing is divided in the horizontal direction the responding layer of 3 ~ 8 series connection, add the flowing stroke of sugarcane juice, make sulfurous gas and milk of lime in sugarcane juice that the sufficient time can be had to mix, increase the homogeneity of sugarcane juice, Sulphitation and Neutralization is made to react more even, remarkable effect is had to raising purity of syrup, reduction White Sugar Color, turbidity, minimizing sulfur dioxide residue, with defeco-sulfitated juice accelerated clarifier with the use of, especially can produce the effect of giving prominence to.
Gradual Sulphitation and Neutralization reaction unit of the present invention adopts control automatically at each ash point that adds, pH gradient of going forward one by one accurately is controlled, pH is stabilized near default pH set(ting)value, thus realizes fully carrying out of the controlled guarantee reaction of whole neutralization reaction pH.
The increase and decrease amount that pH control device of the present invention calculates milk of lime can measure pH by timing, contrasted with restriction pH by the pH determined, if below or above set(ting)value, explanation will adjust the amount adding milk of lime, just send increase, reduce to add the signal of grey performer, the acquisition of this signal is by measuring pH and the difference limiting pH, to be multiplied with the performer coefficient of correspondence adding grey performer and to obtain, described performer coefficient of correspondence is presetting by acid-base neutralisation formula, and then pH Control experiment is determined after measuring and correcting.
In gradual Sulphitation and Neutralization reaction unit of the present invention, the milk of lime adding tube mouth of pipe is preferably disposed on the through hole of the dividing plate at corresponding responding layer rear portion, this is because through hole sugarcane juice velocity of flow is maximum, is conducive to mixing of milk of lime and sugarcane juice most.
Gradual Sulphitation and Neutralization reaction unit of the present invention, also in each responding layer, all agitator can be set, compared to than the technical scheme not arranging agitator, sulfurous gas in sugarcane juice and milk of lime are further fully mixed, to raising purity of syrup, reduce White Sugar Color, turbidity, minimizing sulfur dioxide residue have and act on more significantly.
Box shape of the present invention can select rectangular parallelepiped, square, tri-prismoid, right cylinder, the linker of multiple cylindrical reaction layer or other shapes that can be suitable for, its distinctive layered structure can be connected in series in many ways, arranges demand with what adapt to different box shape.
Mixing sugarcane juice is obtained by reacting sufficient reaction through gradual Sulphitation and Neutralization, and color value of clear juice reduces about 20%; Purity of clear juice improves 0.5AP; Intensity of sulfitation fluctuating range obviously reduces and improves the absorption of sulfurous gas, saves sulphur; Reactor and evaporation device significantly reduce; For back segment operation reduces molasses loss, improve the boiling-off rate of recovery.
To sum up, the invention solves the dissatisfactory problem of prior art Sulphitation and Neutralization reaction uniformity coefficient, by carrying out segmentation regulation and control to pH, improve the reaction efficiency of milk of lime, sulfurous gas, stablize sugarcane juice pH, improve purification effect, extend the reaction times, raising sugar refinery quality product and sugar yield are played an important role.
Accompanying drawing explanation
Fig. 1 is the sectional view of the gradual Sulphitation and Neutralization reaction unit that the embodiment of the present invention 1 provides
Fig. 2 is the vertical view of the gradual Sulphitation and Neutralization reaction unit of the embodiment of the present invention 1
Fig. 3 is the vertical view of the gradual Sulphitation and Neutralization reaction unit of the embodiment of the present invention 2
Fig. 4 is the A-A sectional view of the gradual Sulphitation and Neutralization reaction unit of the embodiment of the present invention 2
Fig. 5 is the B-B sectional view of the gradual Sulphitation and Neutralization reaction unit of the embodiment of the present invention 2
1 is casing, and 2 is row's juice mouth, and 3 is diffuser, and 4 is sulfitator tail pipe, and 5 is lime adding tube, and 6 for adding grey performer, and 7 is dividing plate, and 8 is through hole, and 9 is the milk of lime adding tube mouth of pipe, and 10 is pH detection mouth, and 11 is pH detector.
Embodiment
The present invention is illustrated below in conjunction with embodiment.
Embodiment 1
As shown in Figures 1 and 2, the present embodiment comprises casing 1, row's juice mouth 2, diffuser 3, sulfitator tail pipe 4, milk of lime adding tube 5, adds grey performer 6, dividing plate 7, pH control device;
Described casing 1 is the linker of multiple cylindrical reaction layer, is divided into 4 responding layers in the horizontal direction in described casing 1 by dividing plate 7; Connect in the mode of straight line series connection between each responding layer, the dividing plate 7 at each responding layer serial connection place is provided with through hole 8, and the through hole 8 on the dividing plate 7 at adjacent reaction layer serial connection place distributes in mode staggered up and down; Be provided with a milk of lime adding tube 5 in responding layer, the milk of lime adding tube mouth of pipe 9 of milk of lime adding tube 5 is located at through hole 8 place being positioned at responding layer top, and the described grey performer 6 that adds is connected with milk of lime adding tube 5; Sulfitator tail pipe 4 is provided with a milk of lime adding tube 5;
Described pH control device comprises pH control module, pH detector 11;
Described pH detector 11 detects by pH the pH that mouth 10 detects sugarcane juice in casing 1, and pH is transferred to pH control module; It is corresponding with milk of lime adding tube 5 that described pH detects mouth 10, and a pH detects the corresponding milk of lime adding tube 5 of mouth 10, on sugarcane juice flow direction, after pH detection mouth 10 is arranged at the milk of lime adding tube 5 of its correspondence in casing 1;
Described pH control module, according to this pH information, calculating the increase and decrease amount of milk of lime, sending steering order to adding grey performer 6; Described adds grey performer 6 according to the steering order of pH control device, arranges valve opening, controls the milk of lime addition in milk of lime adding tube 5;
Whipping appts is equipped with in each responding layer.
Last responding layer is provided with diffuser 3.
The reaction method of the present embodiment Sulphitation and Neutralization reaction comprises step:
Sugarcane juice in a, sulfitator tail pipe 4 is before inflow casing 1, and the milk of lime adding tube 5 controlling that it is arranged by adding grey performer 6 passes into the milk of lime of predetermined amount;
B, stove drying add the first responding layer that the mixing sugarcane juice after ash flows into casing 1, and each responding layer after being flowed into by the through hole 8 on dividing plate 7;
C, pH control device is preset and is limited pH, in the process of sugarcane juice flowing, detect the pH in casing 1, and according to this pH and the difference limiting pH, calculating the increase and decrease amount of milk of lime, sending steering order to adding grey performer 6, by adding the milk of lime addition that grey performer 6 controls in milk of lime adding tube 5, sugarcane juice in final control casing 1 remains on suitable pH scope, can react completely when making sugarcane juice flow to relief outlet 2;
D, react completely after sugarcane juice send in neutralize juice tank by relief outlet 2, enter subsequent processing.
Embodiment 2
As shown in Fig. 3 ~ Fig. 5, the present embodiment comprises casing 1, row's juice mouth 2, diffuser 3, sulfitator tail pipe 4, milk of lime adding tube 5, adds grey performer 6, dividing plate 7, pH control device;
Described casing 1 is the linker of multiple cylindrical reaction layer, is divided into 4 responding layers in the horizontal direction in described casing 1 by dividing plate 7; Connect in the mode of broken line series connection between each responding layer, except the dividing plate 7 between first responding layer and last responding layer, the dividing plate 7 at each responding layer serial connection place is provided with through hole 8, and the through hole 8 on the dividing plate 7 at adjacent reaction layer serial connection place distributes in mode staggered up and down; Be provided with a milk of lime adding tube 5 in responding layer, the milk of lime adding tube mouth of pipe 9 of milk of lime adding tube 5 is located at through hole 8 place being positioned at responding layer top, and the described grey performer 6 that adds is connected with milk of lime adding tube 5; Sulfitator tail pipe 4 is provided with a milk of lime adding tube 5;
Described pH control device comprises pH control module, pH detector 11;
Described pH detector 11 detects by pH the pH that mouth 10 detects sugarcane juice in casing 1, and pH is transferred to pH control module; It is corresponding with milk of lime adding tube 5 that described pH detects mouth 10, and a pH detects the corresponding milk of lime adding tube 5 of mouth 10, on sugarcane juice flow direction, after pH detection mouth 10 is arranged at the milk of lime adding tube 5 of its correspondence in casing 1;
Described pH control module, according to this pH information, calculating the increase and decrease amount of milk of lime, sending steering order to adding grey performer 6; Described adds grey performer 6 according to the steering order of pH control device, arranges valve opening, controls the milk of lime addition in milk of lime adding tube 5;
Whipping appts is equipped with in each responding layer.
Last responding layer is provided with diffuser 3.
Due to similar with embodiment 1 situation, therefore milk of lime adding tube 5, add grey performer 6 and do not represent in the accompanying drawings with pH control device.
The reaction method of the present embodiment Sulphitation and Neutralization reaction comprises step:
Sugarcane juice in a, sulfitator tail pipe 4 is before inflow casing 1, and the milk of lime adding tube 5 controlling that it is arranged by adding grey performer 6 passes into the milk of lime of predetermined amount;
B, stove drying add the first responding layer that the mixing sugarcane juice after ash flows into casing 1, and each responding layer after being flowed into by the through hole 8 on dividing plate 7;
C, pH control device is preset and is limited pH, in the process of sugarcane juice flowing, detect the pH in casing 1, and according to this pH and the difference limiting pH, calculating the increase and decrease amount of milk of lime, sending steering order to adding grey performer 6, by adding the milk of lime addition that grey performer 6 controls in milk of lime adding tube 5, sugarcane juice in final control casing 1 remains on suitable pH scope, can react completely when making sugarcane juice flow to relief outlet 2.
D, react completely after sugarcane juice send in neutralize juice tank by relief outlet 2, enter subsequent processing.