CN103266005B - High salt mist resistant industrial gear oil - Google Patents
High salt mist resistant industrial gear oil Download PDFInfo
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- CN103266005B CN103266005B CN201310184409.9A CN201310184409A CN103266005B CN 103266005 B CN103266005 B CN 103266005B CN 201310184409 A CN201310184409 A CN 201310184409A CN 103266005 B CN103266005 B CN 103266005B
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- gear
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- 150000003839 salts Chemical class 0.000 title claims abstract description 22
- 239000010722 industrial gear oil Substances 0.000 title claims abstract description 18
- 239000003595 mist Substances 0.000 title abstract 5
- 235000004443 Ricinus communis Nutrition 0.000 claims abstract description 8
- 240000000528 Ricinus communis Species 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 230000003647 oxidation Effects 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 18
- -1 dioctyl sebacate compound Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 239000007866 anti-wear additive Substances 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000003852 triazoles Chemical class 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- XPYOEDHOQKQPQE-UHFFFAOYSA-N 3-oxa-1-azabicyclo[3.2.0]heptane-2,4-dione Chemical compound O=C1OC(=O)N2CCC12 XPYOEDHOQKQPQE-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004166 Lanolin Substances 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- OSPSWZSRKYCQPF-UHFFFAOYSA-N dibutoxy(oxo)phosphanium Chemical compound CCCCO[P+](=O)OCCCC OSPSWZSRKYCQPF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229940039717 lanolin Drugs 0.000 claims description 2
- 235000019388 lanolin Nutrition 0.000 claims description 2
- 229920002521 macromolecule Polymers 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 150000004867 thiadiazoles Chemical class 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 7
- KXCHFAULOYOHGH-UHFFFAOYSA-N decanedioic acid dioctyl benzene-1,2-dicarboxylate Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C(CCCCCCCCC(=O)O)(=O)O KXCHFAULOYOHGH-UHFFFAOYSA-N 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 description 5
- 239000012208 gear oil Substances 0.000 description 4
- 230000033001 locomotion Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000013528 artificial neural network Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000028161 membrane depolarization Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to high salt mist resistant industrial gear oil which comprises the following components in percentage by mass: 85%-90% of base oil, and 15%-10% of other additives. Polyinternalolefins (PIO) and castor-oil plant-based sebacic acid dioctyl phthalate are compounded as the base oil. The high salt mist resistant industrial gear oil has good comprehensive properties, good oxidation stability, high temperature stability, demulsibility, spumescence resistance, anti-attrition, extreme pressure, biodegradability, corrosion protection, and prominent salt mist resistance; all the property indexes reach the usage requirement; safe and reliable operation of a gear in severe rugged environments of high temperature difference and thick salt mist is ensured, and the service life and the oil draining period of the gear are effectively prolonged.
Description
Technical field
The present invention relates to lubricating oil for industrial gears, especially high resistance salt fog type industrial gear oil field.
Background technology
Industrial gear oil is the important lubricant of guaranteeing geartransmission working efficiency and extending service life of gear.In gear mechanism, gear oil mainly plays and prevents tooth surface abrasion, take away and contact and avoid the effects such as gear gets rusty, burn into scratch because of the heat that gear tooth friction produces, the isolated flank of tooth and air, moisture, dust.Facts have proved: correctly will extend its work-ing life if lubricated, and make the actual motion life-span exceed life; Otherwise, just there will be early failure.Through constantly practice and research, people have grasped the Lubrication regularity of gear substantially.Its mechanism is to make lubricant enter work place of gear engagement, forms lubricant film and makes mating surface separately, the friction of motion of mesh tooth face is become to the internal friction of lubricant film, produces kinetic pressure balancing contact force by lubricant film.In various forms of geartransmissions, the gear teeth have multi-form friction to exist from starting to enter all processes that is engaged to throw out of gear, have sliding friction and rolling resistance simultaneously.Sliding friction is inconsistent generation of speed of relative movement due to mating surface, and rolling resistance is to exist in the time that mesh tooth face speed of relative movement equates.
Along with expanding economy, oceanographic engineering is Offshore Oil Industry and transportation rapid growth particularly, and marine base oil recovery platform and collection rail engineering are subject to the impact of open ocean.First open ocean characteristic exists its saltiness large, and evaporation is large, and salt fog is large, high-temperature, and the composition of water and total salinity are constant.Except main component, in seawater, also have poor other materials, as: ozone and free iodine are also strong cathodic depolarization agent and corrosion promotor; In addition, seawater also contain trace other be there is not to the element of material impact in corrosion.In a word, in seawater, almost contain all elements of the periodic table of elements.Gear drive moves under such open ocean condition, and wheel casing inevitably infiltrates moisture and salt fog.After gear oil and moisture, salt fog mix, be easy to make gear oil generation emulsification, the corrosion of the existence meeting accelerating gear mechanism of salt fog; Therefore, in the urgent need to thering is the industrial gear oil of good anticorrosive, high bearing capacity and outstanding salt fog resistance performance.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high resistance salt fog type industrial gear oil with good oxidation stability, high-temperature stability, resistance to emulsion, anti-spumescence, anti-attrition, extreme pressure property, biodegradable, corrosion protection and outstanding resistance to salt(spray)fog.
The present invention solves the problems of the technologies described above using following technical scheme: adopt poly-internal olefin PIO and castor-oil plant base dioctyl sebacate compound as base oil, coordinate multiple composite additive, each component and mass percent thereof are:
| Component | Content (mass percent) |
| Composite foundation oil | 85%～90% |
| Extreme pressure anti-wear additives | 5.0%～8.0% |
| Oxidation inhibitor | 1.2%～2.5% |
| Friction improver | 0.8%～1.2% |
| Metal passivator | 0.5%～1.5% |
| Rust-preventive agent | 0.2%～0.6% |
| Foam reducing composition | 0.08%～0.2% |
| Non-emulsifying agent | 0.3%～1.2% |
Base oil is that poly-internal olefin PIO and 20%～30% the castor-oil plant base dioctyl sebacate of mass ratio 80%～70% is compound.
Extreme pressure anti-wear additives is that di-n-butyl phosphite, 50%～40% amino monothioester and 20%～40% the dialkyl phosphate of mass ratio 30%～20% is compound.
Oxidation inhibitor is that phosphoric acid primary-secondary alcohol zinc salt and 30%～20% the 124 Triazole derivative of mass ratio 70%～80% is compound.
Friction improver is that 124 Triazole fatty amine salt and 60%～50% the oleic acid glycol ester of mass ratio 40%～50% is compound.
Metal passivator is that thiadiazoles derivative and 30%～20% the azetidin dicarboxylic anhydride of mass ratio 70%～80% is compound.
Rust-preventive agent is that benzotriazole, 40%～50% dodecenylsuccinic acid ester and 30%～25% the lanolin magnesium soap of mass ratio 30%～25% is compound.
Foam reducing composition is that polysiloxane and 70%～60% the polyacrylic ester of mass ratio 30%～40% is compound.
Non-emulsifying agent is that the polyethers macromolecular compound of glycol ester, 30%～20% amine and ethylene oxide condensate and 30%～20% of mass ratio 40%～60% is compound.
The remarkable advantage of high resistance salt fog type of the present invention industrial gear oil has:
1. good combination property, property indices all reaches service requirements.There is good oxidation stability, high-temperature stability, resistance to emulsion, anti-spumescence, anti-attrition, extreme pressure property, biodegradability, corrosion protection and outstanding resistance to salt(spray)fog; Guarantee that gear, at high temperature difference, severe rugged environment energy safe and reliable operation that salt fog is large, has effectively extended work-ing life and the oil draining period of gear.
2. adopt castor-oil plant base dioctyl sebacate and PIO compound, can improve PIO and exist the problem of additive solvability deficiency, PIO also can improve castor-oil plant base dioctyl sebacate makes the swell deficiency of hardening of nitrile rubber.
3. adopting polyisobutene to concoct out meets GB5903-2011 heavy duty industrial gear oil viscosity grade and is: the performance requriements of N220, N320.
Embodiment
The present invention be directed to the day by day harsh service requirements of industrial gear oil and the gear oil of environment friendly and come into one's own more and more and use, adopt poly-internal olefin (PIO) and the compound base oil as high resistance salt fog type industrial gear oil of castor-oil plant base dioctyl sebacate.By adopting artificial neural network algorithm, targetedly several functions additive is screened and predicted; And adopt genetic algorithm to carry out choosing of Optimization design, seek to obtain the high resistance salt fog type industrial gear oil ingredient of different size, cost performance.There is good oxidation stability, high-temperature stability, resistance to emulsion, anti-spumescence, anti-attrition, extreme pressure property, biodegradability, corrosion protection and outstanding resistance to salt(spray)fog with industrial gear oil prepared by technology of the present invention; Its property indices all meets service requirements, can meet GB5903-2011 heavy duty industrial gear oil viscosity grade to be: the performance requriements of N220, N320.
Embodiment 1
The component of following mass percent is in harmonious proportion and is made:
Each component sum is 100% above.
Embodiment 2
The component of following mass percent is in harmonious proportion and is made:
Each component sum is 100% above.
Embodiment 3
The component of following mass percent is in harmonious proportion and is made:
Each component sum is 100% above.
Measure through provincial technical supervision department, the every physical and chemical index of oil product of the present invention all reaches service requirements, adopts polyisobutene to concoct out to meet GB5903-2011 heavy duty industrial gear oil viscosity grade to be: the performance requriements of N220, N320.The every typical physical and chemical index of embodiment 2 is in table 1.
The typical physical and chemical index of table 1 high resistance salt fog type industrial gear oil
Claims (1)
1. a high resistance salt fog type industrial gear oil, is characterized in that adopting poly-internal olefin PIO and castor-oil plant base dioctyl sebacate compound as base oil, coordinates multiple composite additive, and each component and mass percent thereof are:
Above component summation is 100%;
Wherein:
Base oil is that poly-internal olefin PIO and 20% ~ 30% the castor-oil plant base dioctyl sebacate of mass ratio 80% ~ 70% is compound;
Extreme pressure anti-wear additives is that di-n-butyl phosphite, 50% ~ 40% amino monothioester and 20% ~ 40% the dialkyl phosphate of mass ratio 30% ~ 20% is compound, and each component summation is 100%;
Oxidation inhibitor is that phosphoric acid primary-secondary alcohol zinc salt and 30% ~ 20% the 124 Triazole derivative of mass ratio 70% ~ 80% is compound;
Friction improver is that 124 Triazole fatty amine salt and 60% ~ 50% the oleic acid glycol ester of mass ratio 40% ~ 50% is compound;
Metal passivator is that thiadiazoles derivative and 30% ~ 20% the azetidin dicarboxylic anhydride of mass ratio 70% ~ 80% is compound;
Rust-preventive agent is that benzotriazole, 40% ~ 50% dodecenylsuccinic acid ester and 30% ~ 25% the lanolin magnesium soap of mass ratio 30% ~ 25% is compound, and each component summation is 100%;
Foam reducing composition is that polysiloxane and 70% ~ 60% the polyacrylic ester of mass ratio 30% ~ 40% is compound;
Non-emulsifying agent is that the polyethers macromolecular compound of glycol ester, 30% ~ 20% amine and ethylene oxide condensate and 30% ~ 20% of mass ratio 40% ~ 60% is compound, and each component summation is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310184409.9A CN103266005B (en) | 2013-05-19 | 2013-05-19 | High salt mist resistant industrial gear oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310184409.9A CN103266005B (en) | 2013-05-19 | 2013-05-19 | High salt mist resistant industrial gear oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103266005A CN103266005A (en) | 2013-08-28 |
| CN103266005B true CN103266005B (en) | 2014-05-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310184409.9A Expired - Fee Related CN103266005B (en) | 2013-05-19 | 2013-05-19 | High salt mist resistant industrial gear oil |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525519B (en) * | 2013-10-15 | 2015-03-11 | 广西大学 | Closed-cycle turbine lubricant |
| CN104194896A (en) * | 2014-08-30 | 2014-12-10 | 广西大学 | Caster bean-based composition for oil for high-speed gear pump |
| CN104194897A (en) * | 2014-08-30 | 2014-12-10 | 广西大学 | Composition of castor-based depth drilling and cutting fluid |
| CN104479818A (en) * | 2014-11-17 | 2015-04-01 | 广西大学 | Castor-based pitting corrosion-resistant closed heavy load industrial gear oil composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102618365B (en) * | 2012-03-09 | 2013-10-30 | 广西大学 | Lubricating-oil composition of speed reducing machine in gas turbine for ship |
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| CN103266005A (en) | 2013-08-28 |
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