CN103265998A - Heat-resistant grease - Google Patents
Heat-resistant grease Download PDFInfo
- Publication number
- CN103265998A CN103265998A CN2013101843734A CN201310184373A CN103265998A CN 103265998 A CN103265998 A CN 103265998A CN 2013101843734 A CN2013101843734 A CN 2013101843734A CN 201310184373 A CN201310184373 A CN 201310184373A CN 103265998 A CN103265998 A CN 103265998A
- Authority
- CN
- China
- Prior art keywords
- heat resistant
- lubricating grease
- resistant type
- type lubricating
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004519 grease Substances 0.000 title claims abstract description 31
- 230000001050 lubricating effect Effects 0.000 claims abstract description 24
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims abstract description 6
- 229920000570 polyether Polymers 0.000 claims abstract description 6
- WNVQBUHCOYRLPA-UHFFFAOYSA-N triuret Chemical compound NC(=O)NC(=O)NC(N)=O WNVQBUHCOYRLPA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 10
- -1 alkyl diphenylamine Chemical compound 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 239000007866 anti-wear additive Substances 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 claims description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- 241000158728 Meliaceae Species 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical group S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 6
- 230000003647 oxidation Effects 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 238000007789 sealing Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002562 thickening agent Substances 0.000 abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000013538 functional additive Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 230000000655 anti-hydrolysis Effects 0.000 description 1
- 238000013528 artificial neural network Methods 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses heat-resistant grease. The heat-resistant grease is characterized by comprising the following ingredients by mass percent: 70-80% of base oil, 20-12% of thickening agent, and 10-8% of other additives, wherein polyinternalolefin (PIO) is compounded with polyether to serve as the base oil of the heat-resistant grease, and a triuret thickener is utilized. The heat-resistant grease composition disclosed by the invention is good in overall performance, has good high-and-low temperature performance and lubricating property, excellent high temperature and oxidation stability, long high-temperature service life, excellent extreme pressure property and wear resistance, low frictional coefficient, strong carrying capacity, excellent mechanical stability and water resistance, high oil film strength, and excellent anti-rust and anti-corrosion performances and biodegradability, is suitable for lubricating and sealing of a bearing, a valve and a friction component which run under bad work conditions such as extreme high temperature, heavy load, and humid and polluted conditions, and can provide the maximal anti-wear, anti-rust and anti-corrosion protection.
Description
Technical field
The present invention relates to a kind of heat resistant type lubricating grease.
Background technology
Lubricating grease is to be scattered in a kind of stable solid or the semi-fluid colloidal dispersion system that forms in the liquid lubricant by viscosifying agent, and polarity abrim in disperse phase particulate and dispersion medium more can form firm lubricant film on friction surface.Simultaneously, because the viscosity ratio of lubricating grease basis oil viscosity is much bigger, oil film is also enough thick; Thereby lubricating grease has advantages such as good lubricity, is widely used in fields such as industry, agricultural, communications and transportation, national defense industry.
Along with China's constant development of economy, industrialized level improves constantly, a large amount of introductions of a large amount of uses of advanced equipment technology and external sophisticated equipment, many lubricant housings working temperature is more and more higher, and mechanical means requires lubricating grease to play good lubrication under worst hot case; For this reason, the requirement to the lubricating grease resistance to elevated temperatures also improves constantly.The high temperature grease of China starting evening, develop slowlyer, kind is ideal not enough.The most frequently used lubricating grease of China is to be the metal soap grease of base oil with mineral oil at present, and its maximum operating temperature is no more than 150 ℃; When using, be easy to softening and shedding and volatilization under hot environment, lose lubrication, cause equipment wearing serious, noise increases, and stuck phenomenon often takes place, and has shortened the work-ing life of mechanical means greatly.The heat resistant type lubricating grease that therefore, must development can address the above problem.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of lubricated and sealing that is applicable to the bearing, valve and the friction means that move under the bad working environments conditions such as very high temperature, heavy loading and humidity, pollution, and can provide the wear-resistant heat resistant type lubricating grease that undermines the rust resistance and corrosion resistance protection to greatest extent.
The present invention solves the problems of the technologies described above with following technical scheme:
Heat resistant type lubricating grease of the present invention adopts poly-internal olefin (PIO) compound as base oil with polyethers, uses the triuret viscosifying agent, cooperates multiple composite additive; Its each component and phase mass percent are:
Component | Content (mass percent) |
Base oil | 70%~80% |
Viscosifying agent | 20%~12% |
High-temperature antioxidant | 4%~6% |
Extreme pressure anti-wear additives | 1%~2% |
Rust-preventive agent | 0.2%~0.5% |
Weighting agent | 0.8%~1.5% |
Base oil is that the poly-internal olefin (PIO) of mass ratio 40%~50% is compound with 60%~50% polyethers.
Viscosifying agent is the triuret viscosifying agent.
High-temperature antioxidant is that alkyl diphenylamine and 40%~30% the phenolic ester compounds of mass ratio 60%~70% is compound.
Extreme pressure anti-wear additives is that disulfo-dithiazole ketone and 40%~50% the dialkyl dithiophosphoric acid copper of mass ratio 60%~50% is compound.
Rust-preventive agent is that low alkali value calcium mahogany sulfonate and 30%~40% the high base number calcium alkylbenzenesulfonate of mass ratio 70%~60% is compound.
Weighting agent is tungsten disulfide.
The remarkable advantage of heat resistant type lubricating grease of the present invention has:
1. good combination property, every performance index all reach service requirements.Have good high temperature performance and lubricity, excellent high warm nature and oxidation stability, Chang high temperature life extremely, good extreme pressure property and wear resistance, frictional coefficient is extremely low, and supporting capacity is strong, excellent mechanical stability and water repelling property, the oil film strength height, outstanding anti-rust and anti-corrosion and biological degradability; Be applicable to the lubricated and sealing of the bearing, valve and the friction means that move under the bad working environments conditions such as very high temperature, heavy loading and humidity, pollution, and can provide wear-resistant to greatest extent and undermine the rust resistance and corrosion resistance protection.
2. the dialkyl dithiophosphoric acid copper that adopts of extreme pressure anti-wear additives belongs to the multiple-effect functional additive, not only itself have excellent wear-resistant, supporting capacity, rustless property can also produce good synergistic function with oxidation inhibitor, improves high-temperature oxidation resistance and the anti-hydrolysis ability of lubricating grease.
Embodiment
The present invention is directed to the harsh day by day applying working condition characteristics of bearing, gear and other friction means, adopt poly-internal olefin (PIO) compound as heat resistant type grease base plinth oil, triuret viscosifying agent with polyethers.By adopting artificial neural network algorithm, targetedly to multiple functional additive screening and prediction, and adopt genetic algorithm to carry out choosing of optimization prescription, seek the higher heat resistant type lubricating grease component of acquired price ratio.This component has good high temperature performance, high-temperature thermal oxidation stability, mechanical stability, water resisting property, corrosion-resisting resisting resistance and biological degradability; Its every physical and chemical index all reaches service requirements; can satisfy the lubricated and sealing of bearing, gear, chain and other friction part positions under high temperature, heavy loading or shock load, humidity, the contaminate environment, and provide wear-resistant to greatest extent and undermine the rust resistance and corrosion resistance protection.
Embodiment 1:
Form by following component by mass percent mediation:
Embodiment 2:
Form by following component by mass percent mediation:
Embodiment 3:
Form by following component by mass percent mediation:
Measure through provincial technical supervision department, the every physical and chemical index of product of the present invention all reaches service requirements, and the every typical physical and chemical index of the product of embodiment 1 sees Table 1.
The typical physical and chemical index of table 1 heat resistant type lubricating grease
Claims (7)
1. heat resistant type lubricating grease, it is characterized in that adopting poly-internal olefin PIO and polyethers, compound the triuret viscosifying agent cooperates multiple composite additive as heat resistant type grease base plinth oil, and its each component and mass percent thereof are:
2. heat resistant type lubricating grease as claimed in claim 1 is characterized in that base oil is that poly-internal olefin PIO and 60%~50% the polyethers of mass ratio 40%~50% is compound.
3. heat resistant type lubricating grease as claimed in claim 1 is characterized in that viscosifying agent is the triuret viscosifying agent.
4. heat resistant type lubricating grease as claimed in claim 1 is characterized in that high-temperature antioxidant is that alkyl diphenylamine and 40%~30% the phenolic ester compounds of mass ratio 60%~70% is compound.
5. heat resistant type lubricating grease as claimed in claim 1 is characterized in that extreme pressure anti-wear additives is that disulfo-dithiazole ketone and 40%~50% the dialkyl dithiophosphoric acid copper of mass ratio 60%~50% is compound.
6. heat resistant type lubricating grease as claimed in claim 1 is characterized in that rust-preventive agent is that the low alkali value calcium mahogany sulfonate of mass ratio 70%~60% and 30%~40% high base number calcium alkylbenzenesulfonate are answered.
7. heat resistant type lubricating grease as claimed in claim 1 is characterized in that weighting agent is tungsten disulfide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310184373.4A CN103265998B (en) | 2013-05-19 | 2013-05-19 | Heat-resistant grease |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310184373.4A CN103265998B (en) | 2013-05-19 | 2013-05-19 | Heat-resistant grease |
Publications (2)
Publication Number | Publication Date |
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CN103265998A true CN103265998A (en) | 2013-08-28 |
CN103265998B CN103265998B (en) | 2014-08-27 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201310184373.4A Expired - Fee Related CN103265998B (en) | 2013-05-19 | 2013-05-19 | Heat-resistant grease |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104974845A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Environment-friendly high-temperature long-service-life low-noise bearing lubricating grease composition |
CN105112135A (en) * | 2015-08-25 | 2015-12-02 | 俞凤鸣 | Heat resistant lubricating grease |
CN106479608A (en) * | 2015-08-25 | 2017-03-08 | 石海旺 | A kind of heat resistant type lubricant grease |
CN116082842A (en) * | 2022-12-27 | 2023-05-09 | 东莞市欧迪斯润滑剂科技有限公司 | High-low temperature resistant silicone grease and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101111591A (en) * | 2004-12-16 | 2008-01-23 | 国际壳牌研究有限公司 | Lubricating grease composition |
-
2013
- 2013-05-19 CN CN201310184373.4A patent/CN103265998B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101111591A (en) * | 2004-12-16 | 2008-01-23 | 国际壳牌研究有限公司 | Lubricating grease composition |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104974845A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Environment-friendly high-temperature long-service-life low-noise bearing lubricating grease composition |
CN104974845B (en) * | 2015-07-20 | 2018-04-24 | 广西大学 | A kind of environmental-friendly high-temperature long life noise-free bearing lubricant composition |
CN105112135A (en) * | 2015-08-25 | 2015-12-02 | 俞凤鸣 | Heat resistant lubricating grease |
CN106479608A (en) * | 2015-08-25 | 2017-03-08 | 石海旺 | A kind of heat resistant type lubricant grease |
CN116082842A (en) * | 2022-12-27 | 2023-05-09 | 东莞市欧迪斯润滑剂科技有限公司 | High-low temperature resistant silicone grease and preparation method thereof |
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Publication number | Publication date |
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CN103265998B (en) | 2014-08-27 |
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PB01 | Publication | ||
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SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20130828 Assignee: SHENZHEN HECHENG LUBRICATING MATERIAL Co.,Ltd. Assignor: Guangxi University Contract record no.: 2014440020433 Denomination of invention: Heat-resistant grease Granted publication date: 20140827 License type: Exclusive License Record date: 20141222 |
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LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140827 |
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CF01 | Termination of patent right due to non-payment of annual fee |