CN103265904A - Luminescence gel and preparation method thereof - Google Patents
Luminescence gel and preparation method thereof Download PDFInfo
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- CN103265904A CN103265904A CN2013101633721A CN201310163372A CN103265904A CN 103265904 A CN103265904 A CN 103265904A CN 2013101633721 A CN2013101633721 A CN 2013101633721A CN 201310163372 A CN201310163372 A CN 201310163372A CN 103265904 A CN103265904 A CN 103265904A
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- powder
- luminous
- excipient
- luminescent material
- water
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Abstract
The invention discloses a luminescence gel, which is characterized by comprising the following raw materials, by weight: 5-20% of a polymer resin, 0.1-15% of flash powder, 1-15% of an excipient, 3-40% of luminescence powder, and 20-85% of water. The preparation method comprises the following steps: (1) adding a polymer resin and water to a reaction kettle, heating to a temperature of 60-95 DEG C, and stirring for 30-90 min; (2) adding an excipient to the reaction kettle, carrying out thermal insulation stirring for 10-40 min at a temperature of 60-95 DEG C, and stopping heating, such that the material is naturally cooled along with stirring; (3) adding luminescence powder and flash powder to the reaction kettle, and stirring for 10-40 min to obtain a mixture; and (4) carrying out filling packaging on the obtained mixture to obtain the finished product. According to the present invention, the long time luminescence function under a dark state of the luminescence gel can be achieved through absorbing natural light or artificial light.
Description
Technical field
The present invention relates to a kind of stationery, specifically is a kind of luminous glue and preparation method thereof.
Background technology
The sizing agent that prior art is produced is various, there is a kind of luminous glue to use flashlight powder in the prior art, but lack the luminous luminescent powder of energy self, be difficult to reach the luminous purpose of energy storage, and common sizing agent does not have too big color difference from a different perspective yet.Existing sizing agent for road sign warning sign and various security warning boards all is to lean on light-illuminating and the reflective passerby of prompting or use safety light photograph at night, and is very inconvenient.
Summary of the invention
The technical problem to be solved in the present invention is to overcome the deficiencies in the prior art, provides a kind of energy to realize long-time self luminous luminous glue under the dark state by absorbing natural light or artificial light.
A technical solution of the present invention is: a kind of luminous glue, it is made up of following raw materials by weight percent: macromolecular material 5-20%, flashlight powder 0.1%-15%, excipient 1-15%, luminescent material 3-40%, water 20 ~ 85%.
Described macromolecular material is the mixture of one or more arbitrary proportions in polyvinylpyrrolidone, polyvinyl alcohol, polyvinyl alcohol modification thing, acrylic resin and the modifier thereof.
Described flashlight powder is the mixture of one or more arbitrary proportions in glitter powder, metal powder, the pearlescence.
Described excipient is the mixture of one or more arbitrary proportions in wilkinite, Natvosol, Walocel MT 20.000PV, hydroxypropylcellulose, neusilin, the lithium magnesium silicate.
Described luminous glue, preferred materials in percentage by mass consists of: macromolecular material 5-15%, flashlight powder 4%-10%, excipient 1-15%, luminescent material 3-40%, water 40-60%.
Luminescent material of the present invention is that in sulfide, oxysulfide, silicate, silico-aluminate, the phosphoric acid salt one or more are matrix, with the luminescent material of rare earth element as activator.
Compared with prior art, the invention has the advantages that:
1, this luminous glue is coated in and is glittering and translucent cylindric when not dried on the basal plane, and that stays basal plane after colloid is done is the 3 D stereo shape, does not subside, and can prepare multicolour, is used for advertisement drawing and warning sign etc., and flashlight powder is identification easily under illumination;
2, the contained luminescent material of this luminous glue can be by absorbing and storage light and luminous in the unglazed or low light environment at night;
3, this luminous glue also can be used as common stationery glue usefulness.
The preparation method that another technical solution of the present invention provides a kind of luminous glue, made by following steps:
(1) macromolecular material and water are joined in the reactor, intensification 60-95 ℃ was stirred 30-90 minute;
(2) in the described reactor of step (1), add vehicle, stirred 10-40 minute, stop heating simultaneously, make material with stirring naturally cooling;
(3) in the described reactor of step (2), add luminescent material and flashlight powder, and stirring obtained mixture in 10-40 minute;
(4) the mixture filling and package that step (3) is obtained namely obtains product.
The luminous glue of the present invention adopts the environmental protection macromolecule material as sizing agent, obtains the drawing color by the flashlight powder that adds various colors, by the interpolation luminescent material particularly rare earth luminescent material obtain noctilucent ability.
The invention has the advantages that making method is simple, be suitable for promoting the use of.
Embodiment
The invention will be further described below by embodiment, but the present invention is not limited only to these embodiment.
Macromolecular material of the present invention, flashlight powder, excipient, luminescent material are commercially available, and luminescent material is with the luminescent material of rare earth element as activator.
Embodiment 1
A kind of luminous glue, it is made up of following raw materials by weight percent:
Polyvinylpyrrolidone 8%
Glitter powder 3%
Walocel MT 20.000PV 2%
CaAl
2O
4: Eu
2+, Nd
3+Type calcium aluminate luminescent material 8%
All the other are water.
Be prepared from by following step:
(1) macromolecular material polyvinylpyrrolidone and water are joined in the reactor, heat up 75 ℃ and stirred 50 minutes;
(2) in the described reactor of step (1), add the vehicle Walocel MT 20.000PV, stop heating after 30 minutes 75 ℃ of following insulated and stirred, make material with stirring naturally cooling;
(3) in the described reactor of step (2), add CaAl
2O
4: Eu
2+, Nd
3+Type calcium aluminate luminescent material and flashlight powder glitter powder, and stir and obtained mixture in 30 minutes;
(4) the mixture filling and package that step (3) is obtained namely obtains product.
Embodiment 2:
A kind of luminous glue, it is made up of following raw materials by weight percent:
Water-borne acrylic resin 12%
Glitter powder 2%
Metal powder 3%
Natvosol 4%
Sr
4Al
14O
25: Eu
2+, Dy
3+Type strontium aluminate luminous material 15%
All the other are water.
Be prepared from by following step:
(1) macromolecular material polyvinylpyrrolidone and water are joined in the reactor, heat up 85 ℃ and stirred 40 minutes;
(2) in the described reactor of step (1), add the vehicle Walocel MT 20.000PV, stop heating after 20 minutes 85 ℃ of following insulated and stirred, make material with stirring naturally cooling;
(3) in the described reactor of step (2), add Sr
4Al
14O
25: Eu
2+, Dy
3+Type strontium aluminate luminous material and flashlight powder glitter powder, and stir and obtained mixture in 20 minutes;
(4) the mixture filling and package that step (3) is obtained namely obtains product.
Embodiment 3:
A kind of luminous glue, it is made up of following raw materials by weight percent:
Polyvinyl alcohol 12%
Glitter powder 6%
Pearlescence 4%
Wilkinite 4%
ZnS:Eu
2+Type zinc sulphide luminescent material 19%
All the other are water.
Preparation process is with embodiment 1.
Embodiment 4:
A kind of luminous glue, it is made up of following raw materials by weight percent:
Polyvinyl formal 15%
Glitter powder 3%
Metal powder 4%
Pearlescence 4%
Walocel MT 20.000PV 1%
Wilkinite 2%
Ca
1-XSr
XS:Eu
2+Type sulfide luminescent material 5%
ZnS:Eu
2+Type zinc sulphide luminescent material 5%
All the other are water.
Preparation process is with embodiment 1.
Embodiment 5:
A kind of luminous glue, it is made up of following raw materials by weight percent:
Polyvinyl formal 9%
Polyvinylpyrrolidone 11%
Glitter powder 3%
Metal powder 4%
Pearlescence 4%
Walocel MT 20.000PV 3%
Wilkinite 2%
SrAl
2O
4: Eu
2+Type strontium aluminate luminous material 12%
ZnS:Eu
2+Type zinc sulphide luminescent material 13%
All the other are water.
Preparation process is with embodiment 1.
Claims (7)
1. a luminous glue is characterized in that: be prepared from by following raw materials by weight percent: macromolecular material 5 ~ 20%, flashlight powder 0.1% ~ 15%, excipient 1 ~ 15%, luminescent material 3 ~ 40%, water 20 ~ 85%.
2. luminous glue according to claim 1 is characterized in that: described macromolecular material is polyvinylpyrrolidone, polyvinyl alcohol, modified polyvinyl alcohol, acrylic resin, one or more arbitrary proportion mixtures in acrylic resin modified.
3. luminous glue according to claim 1, it is characterized in that: described flashlight powder is one or more arbitrary proportion mixtures in glitter powder, metal powder, the pearlescence.
4. luminous glue according to claim 1, it is characterized in that: described excipient is one or more arbitrary proportion mixtures in wilkinite, Natvosol, Walocel MT 20.000PV, hydroxypropylcellulose, neusilin, the lithium magnesium silicate.
5. luminous glue according to claim 1 is characterized in that: described luminescent material is that in sulfide, oxysulfide, silicate, silico-aluminate, the phosphoric acid salt one or more are matrix, with the luminescent material of rare earth element as activator.
6. luminous glue according to claim 1 is characterized in that: be prepared from by following materials in percentage by mass: macromolecular material 5 ~ 15%, flashlight powder 4% ~ 10%, excipient 1 ~ 15%, luminescent material 3 ~ 40%, water 40-60%.
7. the preparation method of the described luminous glue of claim 1 is characterized in that: made by following steps:
(1) macromolecular material and water are joined in the reactor, heat up 60 ~ 95 ℃ and stirred 30 ~ 90 minutes;
(2) in the described reactor of step (1), add excipient, stop heating after 10 ~ 40 minutes 60 ~ 95 ℃ of following insulated and stirred, make material with stirring naturally cooling;
(3) in the described reactor of step (2), add luminescent material and flashlight powder, and stir and obtained mixture in 10 ~ 40 minutes;
The mixture filling and package that step (3) is obtained gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310163372.1A CN103265904B (en) | 2013-05-07 | 2013-05-07 | A kind of Luminescence gel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310163372.1A CN103265904B (en) | 2013-05-07 | 2013-05-07 | A kind of Luminescence gel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103265904A true CN103265904A (en) | 2013-08-28 |
| CN103265904B CN103265904B (en) | 2015-10-28 |
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ID=49009571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310163372.1A Expired - Fee Related CN103265904B (en) | 2013-05-07 | 2013-05-07 | A kind of Luminescence gel and preparation method thereof |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104694031A (en) * | 2015-03-17 | 2015-06-10 | 烟台德邦科技有限公司 | Light-storing self-luminous UV curing adhesive film and preparation method thereof |
| CN108314908A (en) * | 2018-01-19 | 2018-07-24 | 义乌市梓绮新材料科技有限公司 | Luminous pigment and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101633806A (en) * | 2009-09-03 | 2010-01-27 | 王建军 | Luminous slurry and preparation method thereof |
| CN102321437A (en) * | 2011-07-25 | 2012-01-18 | 珠海保税区天然宝杰数码科技材料有限公司 | Novel UV (ultraviolet)-curable decoration adhesive |
-
2013
- 2013-05-07 CN CN201310163372.1A patent/CN103265904B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101633806A (en) * | 2009-09-03 | 2010-01-27 | 王建军 | Luminous slurry and preparation method thereof |
| CN102321437A (en) * | 2011-07-25 | 2012-01-18 | 珠海保税区天然宝杰数码科技材料有限公司 | Novel UV (ultraviolet)-curable decoration adhesive |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104694031A (en) * | 2015-03-17 | 2015-06-10 | 烟台德邦科技有限公司 | Light-storing self-luminous UV curing adhesive film and preparation method thereof |
| CN108314908A (en) * | 2018-01-19 | 2018-07-24 | 义乌市梓绮新材料科技有限公司 | Luminous pigment and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103265904B (en) | 2015-10-28 |
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Granted publication date: 20151028 Termination date: 20170507 |
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