CN103265771A - Ecological PVC (polyvinyl chloride) foaming floor filled with waste alkali residue and albarium - Google Patents
Ecological PVC (polyvinyl chloride) foaming floor filled with waste alkali residue and albarium Download PDFInfo
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- CN103265771A CN103265771A CN2013101965055A CN201310196505A CN103265771A CN 103265771 A CN103265771 A CN 103265771A CN 2013101965055 A CN2013101965055 A CN 2013101965055A CN 201310196505 A CN201310196505 A CN 201310196505A CN 103265771 A CN103265771 A CN 103265771A
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Abstract
The invention discloses an ecological PVC (polyvinyl chloride) foaming floor filled with waste alkali residue and albarium. The ecological PVC foaming floor filled with waste alkali residue and albarium comprises the following raw materials in parts by mass: 10-30 parts of waste casting sand, 10-30 parts of alkali residue, 80-110 parts of PVC resin powder, 2-8 parts of tourmaline tailing powder, 1.5-3 parts of a plasticizer, 1-2 parts of a lubricant, 0.5-1 part of a foamer, 2-4 parts of a stabilizer, and 0.5-1 part of a forming regulator. Compared with the prior art, the ecological PVC foaming floor filled with waste alkali residue and albarium disclosed by the invention is excellent in waterproof, fireproof, wear-resistant and pressure-resistant performances, and capable of effectively solving the environmental problems caused by the accumulation of the two wastes by recycling the waste casting sand and alkali residue. The ecological PVC foaming floor filled with waste alkali residue and albarium disclosed by the invention is widely suitable for the fields of building materials such as household floors and guardrails.
Description
Technical field
The invention belongs to PVC foam material field, particularly a kind of discarded alkali slag and albarium filled PVC
The foaming ecological floor.
Background technology
The filler on the floor of the PVC of circulation foaming in the market mostly is calcium carbonate greatly, and along with market is more and more big to the demand on PVC foaming floor, required amount of filler also increases thereupon, and existing filler all comes self filler supplier, and its expense should not be underestimated.
Approximately contain 40% calcium carbonate in the alkaline residue, alkaline residue is extracted and is got by the waste liquid that discharges in the alkali producing process of chemical plant, and any accumulation meeting of alkaline residue causes serious pollution to environment; Calcium carbonate is the main component of albarium, stone quarry and cutting marble factory can produce a large amount of albariums, these albariums are scrap stock, a large amount of stackings not only cause the resources idle waste but also can cause environmental pollution, and discarded alkali slag and albarium all have alternative calcium carbonate as the potentiality of pvc foaming floor filler, it are studied have very big economic worth and social value.
In sum, how to take full advantage of existing waste resource and it is put in the production application on foaming floor become the technical barrier that pvc foam material field needs to be resolved hurrily.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art and propose a kind of discarded alkali slag and albarium and fill pvc foaming ecological floor, discarded alkali slag of the present invention and albarium filling pvc foaming ecological floor have stablizes performance wear-resisting, the raw material environmental protection, but wide popularization and application.
Technical scheme of the present invention is as follows:
Discarded alkali slag and albarium filled PVC foaming ecological floor, comprise the following raw material according to the mass fraction meter: discarded alkali slag 10-30 part, albarium 10-30 part, polyvinyl chloride resin powder 80-110 part, tourmaline tailing powder 2-8 part, softening agent 1.5-3 part, lubricant 1-2 part, whipping agent 0.5-1 part, stablizer 2-4 part, foaming control agent 0.5-1 part.
Described softening agent is Vanay or hexanodioic acid propylene glycol polyester.
Described lubricant is paraffin or stearate.
Described whipping agent is compound ADc whipping agent.
Described stablizer is ricinolic acid calcium and zinc ricinate.
Described foaming control agent is acrylic polymer.
Preparation method of the present invention is: with the discarded casting sand powder after the drying treatment, the alkaline residue powder, the polyvinyl chloride resin powder, tourmaline tailing powder adds mixer according to composition of raw materials batching back, and adding runs up behind the stablizer again mixes it, is warming up to 70 ℃ and adds softening agent, lubricant, whipping agent, foaming control agent successively, behind the 30min, continue to be warming up to 120 ℃, discharging is cooled to 40 ℃ of dischargings behind the 20min to cold mixer, namely gets finished product of the present invention by cutting after granulation, typing, the traction.
Beneficial effect: the first, the discarded casting sand that adds among the present invention and alkaline residue make the present invention have good wear-resisting withstand voltage properties; The second, main stuffing of the present invention, turns waste into wealth to the waste cycling and reutilization for discarded casting sand and alkaline residue; The 3rd, the tourmaline tailing powder among the present invention can discharge negative oxygen ion continuously, for people provide healthy life living environment, can strengthen people's pulmonary function; The 4th, to the cycling and reutilization of discarded casting sand and alkaline residue, can effectively solve the environmental problem that causes because of two kinds of wastes accumulations among the present invention.
Embodiment
Compound ADc whipping agent of the present invention is plastic cement company limited available from Yangzhong City China, and foaming control agent is available from the positive chemical industry of Dongying City perseverance company limited, and model is HP-5.
The present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
Discarded alkali slag and albarium filled PVC foaming ecological floor, comprise the following raw material according to the mass fraction meter: 10 parts of discarded alkali slags, 10 parts of albariums, 80 parts of pvc resin-oatmeals, 2 parts of tourmaline tailing powder, 1.5 parts of Vanays, 1 part in paraffin, 0.5 part of compound ADc whipping agent, 2 parts of ricinolic acid calcium, 0.5 part of acrylic polymer.
With the discarded casting sand powder after the drying treatment, the alkaline residue powder, the polyvinyl chloride resin powder, tourmaline tailing powder adds mixer according to composition of raw materials batching back, adding runs up behind the stablizer again mixes it, be warming up to 70 ℃ and add softening agent, lubricant, whipping agent, foaming control agent successively, behind the 30min, continue to be warming up to 120 ℃, discharging is cooled to 40 ℃ of dischargings behind the 20min to cold mixer, namely get finished product of the present invention by cutting after granulation, typing, the traction, this finished product is carried out performance test, see Table 1.
Embodiment 2
Discarded alkali slag and albarium filled PVC foaming ecological floor, comprise the following raw material according to the mass fraction meter: 25 parts of discarded alkali slags, 25 parts of albariums, 100 parts in polyvinyl chloride resin powder, 6 parts of tourmaline tailing powder, 2.5 parts of Vanays, 1.8 parts of calcium stearates, 0.9 part of compound ADc whipping agent, 3.5 parts of zinc ricinates, 0.8 part of acrylic polymer.
The preparation method carries out performance test with embodiment 1 to this embodiment finished product, sees Table 1.
Embodiment 3
Discarded alkali slag and albarium filled PVC foaming ecological floor, comprise the following raw material according to the mass fraction meter: 30 parts of discarded alkali slags, 30 parts of albariums, 110 parts in polyvinyl chloride resin powder, 8 parts of tourmaline tailing powder, 3 parts of hexanodioic acid propylene glycol polyester, 2.0 parts of Zinic stearass, 1.0 parts of compound ADc whipping agents, 4.0 parts of ricinolic acid calcium, 1.0 parts of acrylic polymers.
The preparation method carries out performance test with embodiment 1 to this embodiment finished product, sees Table 1.
Finished product to embodiment 1-3 carries out following performance test, and by table 1 as seen, the rate of expansion after the present invention's suction is less, and water tolerance is stronger, and the surface of good wear resistance is arranged.
Table 1 is respectively executed the example test data
| Performance | Example 1 | Example 2 | Example 3 |
| Thickness swelling rate, % | 0.033 | 0.036 | 0.030 |
| Hardness, HRR | 82.0 | 81.7 | 81.9 |
| Surface abrasion resistance, g/100r | 0.0793 | 0.0794 | 0.0792 |
| Heating back size changing rate, % | 1.85 | 1.89 | 1.84 |
Above-described embodiment only is the explanation to product of the present invention; be not that the present invention is made any pro forma restriction; do not breaking away within the technical scheme scope of the present invention, any technology contents that utilizes above-mentioned announcement is made the equivalent of simple transformation, all belongs to protection scope of the present invention.
Claims (6)
- Discarded alkali slag and albarium filled PVC the foaming ecological floor, it is characterized in that, comprise the following raw material according to the mass fraction meter: discarded alkali slag 10-30 part, albarium 10-30 part, polyvinyl chloride resin powder 80-110 part, tourmaline tailing powder 2-8 part, softening agent 1.5-3 part, lubricant 1-2 part, whipping agent 0.5-1 part, stablizer 2-4 part, foaming control agent 0.5-1 part.
- 2. discarded alkali slag according to claim 1 and albarium filled PVC foaming ecological floor is characterized in that described softening agent is Vanay or hexanodioic acid propylene glycol polyester.
- 3. discarded alkali slag according to claim 1 and albarium filled PVC foaming ecological floor is characterized in that described lubricant is paraffin or stearate.
- 4. discarded alkali slag according to claim 1 and albarium filled PVC foaming ecological floor is characterized in that described whipping agent is compound ADc whipping agent.
- 5. discarded alkali slag according to claim 1 and albarium filled PVC foaming ecological floor is characterized in that described stablizer is ricinolic acid calcium and zinc ricinate.
- 6. discarded alkali slag according to claim 1 and albarium filled PVC foaming ecological floor is characterized in that described foaming control agent is acrylic polymer.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013101965055A CN103265771A (en) | 2013-05-24 | 2013-05-24 | Ecological PVC (polyvinyl chloride) foaming floor filled with waste alkali residue and albarium |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013101965055A CN103265771A (en) | 2013-05-24 | 2013-05-24 | Ecological PVC (polyvinyl chloride) foaming floor filled with waste alkali residue and albarium |
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| CN103265771A true CN103265771A (en) | 2013-08-28 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130518A (en) * | 2014-07-18 | 2014-11-05 | 西乡县林森建材有限责任公司 | High-temperature-resistant and flame-retardant stone floor |
| CN105086262A (en) * | 2015-08-26 | 2015-11-25 | 安徽北马科技有限公司 | Light wood-plastic composite material for outdoor use |
| CN107312266A (en) * | 2017-07-27 | 2017-11-03 | 绍兴宏润消防器材有限公司 | A kind of PVC heat stabilizer and preparation method thereof |
| CN112708227A (en) * | 2021-01-12 | 2021-04-27 | 中国地质大学（北京） | Basalt fiber reinforced PVC marble tailing composite material and preparation method thereof |
| CN114940597A (en) * | 2022-05-23 | 2022-08-26 | 安徽工业大学 | Industrial solid waste based stone crystal floor base material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039038A (en) * | 1989-08-25 | 1990-01-24 | 轻工业部塑料加工应用科学研究所 | Belozem as plastics filler |
| CN101550756A (en) * | 2009-05-08 | 2009-10-07 | 王树升 | Microcellular foamed anion ecological floor and process for producing same |
| CN101787146A (en) * | 2009-05-31 | 2010-07-28 | 青岛科技大学 | Recycling processing method for preparing rubber ingredient from caustic sludge |
-
2013
- 2013-05-24 CN CN2013101965055A patent/CN103265771A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039038A (en) * | 1989-08-25 | 1990-01-24 | 轻工业部塑料加工应用科学研究所 | Belozem as plastics filler |
| CN101550756A (en) * | 2009-05-08 | 2009-10-07 | 王树升 | Microcellular foamed anion ecological floor and process for producing same |
| CN101787146A (en) * | 2009-05-31 | 2010-07-28 | 青岛科技大学 | Recycling processing method for preparing rubber ingredient from caustic sludge |
Non-Patent Citations (2)
| Title |
|---|
| 柯亮，江海东: "制碱白泥及造纸白泥的综合利用现状", 《纯碱工业》 * |
| 陈长明: "《化学建筑材料手册》", 31 January 1997, 江西科学技术出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130518A (en) * | 2014-07-18 | 2014-11-05 | 西乡县林森建材有限责任公司 | High-temperature-resistant and flame-retardant stone floor |
| CN105086262A (en) * | 2015-08-26 | 2015-11-25 | 安徽北马科技有限公司 | Light wood-plastic composite material for outdoor use |
| CN107312266A (en) * | 2017-07-27 | 2017-11-03 | 绍兴宏润消防器材有限公司 | A kind of PVC heat stabilizer and preparation method thereof |
| CN112708227A (en) * | 2021-01-12 | 2021-04-27 | 中国地质大学（北京） | Basalt fiber reinforced PVC marble tailing composite material and preparation method thereof |
| CN112708227B (en) * | 2021-01-12 | 2021-09-24 | 中国地质大学（北京） | Basalt fiber reinforced PVC marble tailing composite material and preparation method thereof |
| WO2022151961A1 (en) * | 2021-01-12 | 2022-07-21 | 中国地质大学（北京） | Basalt fiber-reinforced pvc marble tailings composite material and preparation method therefor |
| CN114940597A (en) * | 2022-05-23 | 2022-08-26 | 安徽工业大学 | Industrial solid waste based stone crystal floor base material and preparation method thereof |
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Application publication date: 20130828 |