CN103265209B - Calcium carbonate antiflaming foaming agent - Google Patents
Calcium carbonate antiflaming foaming agent Download PDFInfo
- Publication number
- CN103265209B CN103265209B CN201310223181.XA CN201310223181A CN103265209B CN 103265209 B CN103265209 B CN 103265209B CN 201310223181 A CN201310223181 A CN 201310223181A CN 103265209 B CN103265209 B CN 103265209B
- Authority
- CN
- China
- Prior art keywords
- calcium carbonate
- attapulgite clay
- flame
- antiflaming
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 78
- 229910000019 calcium carbonate Inorganic materials 0.000 title claims abstract description 39
- 239000004088 foaming agent Substances 0.000 title abstract description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 48
- 229960000892 attapulgite Drugs 0.000 claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- -1 sodium bicarbonate, sodium alkyl benzene Chemical class 0.000 claims abstract description 9
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 7
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 7
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000009775 high-speed stirring Methods 0.000 claims abstract description 4
- 239000004927 clay Substances 0.000 claims description 42
- 239000003063 flame retardant Substances 0.000 claims description 30
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 28
- 229940010698 activated attapulgite Drugs 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 5
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 230000032683 aging Effects 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 238000000855 fermentation Methods 0.000 claims description 2
- 230000004151 fermentation Effects 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- 238000005065 mining Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 238000003672 processing method Methods 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000006260 foam Substances 0.000 abstract description 16
- 239000000463 material Substances 0.000 abstract description 8
- 239000002002 slurry Substances 0.000 abstract 5
- 239000012528 membrane Substances 0.000 abstract 2
- 230000000979 retarding effect Effects 0.000 abstract 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 229940048086 sodium pyrophosphate Drugs 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000005187 foaming Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000020477 pH reduction Effects 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 210000002808 connective tissue Anatomy 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Abstract
The invention discloses a calcium carbonate antiflaming foaming agent. According to technical scheme, the calcium carbonate antiflaming foaming agent is characterized by consisting of light calcium carbonate, high viscosity attapulgite powder, active attapulgite, sodium bicarbonate, sodium alkyl benzene sulfonate, sodium polyacrylate, sodium pyrophosphate, ammonium polyphosphate and zinc borate. The finished product of the calcium carbonate antiflaming foaming agent is prepared through steps of stirring the components, grinding and packaging. Water is added into the calcium carbonate antiflaming foaming agent, and after high speed stirring, plenty of gas is released rapidly so as to form porous foam slurry, the foam slurry is sprayed by a high pressure water gun and is directly used for putting out a fire, and the foam slurry stably covers the surface of a combustible material to form a foam slurry membrane which can rapidly insulate the combustible material from being in contact with the air, so that the combustible material is prevented from burning, and the foam slurry membrane plays roles in inflaming retarding and extinguishing. The calcium carbonate antiflaming foaming agent is suitable for production of inflaming retarding and lightweight plate materials, lightweight wall bodies and noise reduction products.
Description
Technical field
The present invention relates to whipping agent, be specifically related to flame-retardant expanded dose of a kind of calcium carbonate.
Background technology
City noise is having a strong impact on city resident's orthobiosis and health of human body, city noise mainly refers to traffic noise, factory noise, construction noise pollution and noise of social activities, the range of influence of its noise and influence degree are day by day serious, on the impact of civic living environment greatly, become one of noticeable city environmental pollution problem.
Control noise and conventionally take the measures such as damping, sound insulation, sound absorption, sourdine, personal protection and architectural composition, weaken as far as possible or reduce the vibration of sound source, acoustic energy absorption in propagating is fallen, place obstacles and make that sound is all or part of to be reflected away, weaken the effect of noise, to reach the object of controlling noise.
Conventionally adopt quieter material to produce the products such as some acoustical panels, sound insulation Wall, sound-absorbing net and sound damper and control sound pollution, also having some materials is after processing by foaming, to improve the performance of the said products.
The kind of whipping agent is more, made larger contribution, but the said products can only be used for controlling sound pollution, does not have fire-retardant effect and the function purifying air for controlling sound pollution.
Summary of the invention
The object of the invention is to overcome weak point in prior art, flame-retardant expanded dose of a kind of calcium carbonate is provided.
Flame-retardant expanded dose of calcium carbonate is made up of light calcium carbonate, high sticky attapulgite clay powder, activated attapulgite, sodium bicarbonate, sodium alkyl benzene sulfonate, sodium polyacrylate, trisodium phosphate, ammonium polyphosphate and zinc borate.
The production method that calcium carbonate is flame-retardant expanded dose: by stirring in flame-retardant expanded calcium carbonate dose of batching input stirrer, input after stirring in grinding machine and carry out abrasive dust, be packaged as the finished product of flame-retardant expanded dose of calcium carbonate.
Light calcium carbonate is with a kind of white powder or colourless crystallization, have nontoxic, odorlessness, nonirritant, whiteness higher, easily disperse and the characteristic such as good luster.
Attapulgite has another name called polygorskite or Palygorskite, be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite has unique layer chain-like structure feature, in its structure, there is crystal lattice, therefore contain Na+, Ca2+, Fe3+, the Al3+ of non-quantitative in crystal, crystal is needle-like, fibrous or fiber collection shape.Attapulgite has unique dispersion, high temperature resistant, the anti-good colloidal property such as saline and alkaline and higher adsorptive power, and has certain plasticity-and cohesive force.
High sticky attapulgite clay is the attapulgite clay that adopts the complete processing that improves viscosity of attapulgite clay to produce, attapulgite clay soil property exquisiteness, there is oily soapy, light weight, property are crisp, fracture is conchoidal or irregular shape, and water-absorbent is strong, tool viscosity and plasticity-when wet, more than its viscosity can reach 3000mPas, be conducive to the bonding between raw material.
High sticky attapulgite clay powder refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250ml through high-speed stirring sample suspension again the viscosity that uses NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value>=2200 into
mPasattapulgite clay powder.
The pH value of attapulgite clay raw ore is 8～9, need in the present invention to carry out acidification, acidified attapulgite clay after treatment is activated attapulgite, the various performances of activated attapulgite all will be greatly improved, particularly strengthen the adsorption cleaning ability of Attapulgite, it is 5.5～7.5 that activated attapulgite pH value is controlled, water content≤2%.
Sodium bicarbonate white powder or oblique crystal crystalline powder, odorless, taste are salty and soluble in water, and its aqueous solution starts to split the carbon dioxide off and sodium carbonate in the time of 20 DEG C.
Sodium alkyl benzene sulfonate white or pale yellow powder, water-soluble, oxidizable, foaming power is strong, and detersive power is high, and easily, with various additive compounds, cost is lower, synthesis technique maturation, Application Areas is extensive, is very outstanding anion surfactant.
Sodium polyacrylate is a kind of new functional macromolecule material, for white or buff powder, be dissolved in cold water, stable to temperature variation, be a kind of tensio-active agent with multiple property, be conducive in the present invention improve the effect of the thickening, foaming of flame-retardant expanded dose of calcium carbonate, stable, emulsification, dispersion, bonding, film forming and water conservation.
Trisodium phosphate is a kind of water white transparency crystallization or white crystalline powder, soluble in water, in the present invention as dispersion agent and emulsifying agent.
Ammonium polyphosphate is white crystals or amorphous fine powder, nonpoisonous and tasteless, does not produce etchant gas, thermostability and chemical stability are high, relative density is little, and good dispersity has non-volatility in application process, do not produce corrosive gases, the advantages such as effect is lasting, and safety performance is good are a kind of non-halogen fire retardants of excellent property, ammonium polyphosphate also has expandable flame retardant function, is more conducive to eliminate smoke, fall cigarette and anti-drippage.
Zinc borate white or pale yellow powder, water insoluble, Heat stability is good, easily disperses, and toxicity is low, can effectively improve flame retardant properties, the generation of smog while reducing burning.
The present invention is achieved by following technical proposals:
1, flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: light calcium carbonate 15～45%, high sticky attapulgite clay powder 5～15%, activated attapulgite 5～25%, sodium bicarbonate 1～30%, sodium alkyl benzene sulfonate 1～20%, sodium polyacrylate 0.01～5%, trisodium phosphate 0.01～5%, ammonium polyphosphate 0.01～5% and zinc borate 0.01～5%.
The production method that described calcium carbonate is flame-retardant expanded dose: by stirring in flame-retardant expanded calcium carbonate dose of batching input stirrer, input in grinding machine and carry out abrasive dust after stirring, particle fineness≤0.074 millimeter, is packaged as the finished product of flame-retardant expanded dose of calcium carbonate.
The sticky attapulgite clay of described height is the attapulgite clay that adopts the complete processing that improves viscosity of attapulgite clay to produce, it is characterized in that, and from the attapulgite clay of mining area exploitation, need to be through the weathering of 30～120 days; Modification processing method is: calculate by weight percentage, get the attapulgite clay 94～98% after weathering, evenly add 2～6% sodium carbonate, jointly input in fermentation vat, add clear water to soak ageing, soak time is 72～120 hours; Get the attapulgite clay after immersion, in input stirrer, stir, and by the attapulgite clay after stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5～2 millimeter, by attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after airing, its water content≤15%; Batching is calculated by weight percentage: attapulgite clay 94～98%, High hydrophilous resin 0.5～5% and Mierocrystalline cellulose 0.5～3% after airing, above-mentioned batching is stirred, and after stirring, input and in grinding machine, carry out abrasive dust, particle fineness≤0.074 millimeter.
Above-mentioned production technique is to adopt " the improving the complete processing of viscosity of attapulgite clay " of being applied on June 20th, 2005 by the inventor, and Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
The production method of described activated attapulgite is: the 1. preparation of dilute sulphuric acid, is made up of following component by weight percentage: the sulfuric acid 3～5% of concentration 98 ﹪, water 95～97%; 2. the batching of acidification, comprises following component by weight percentage: attapulgite clay raw ore 55～65%, and dilute sulphuric acid 35～45%, slowly adds dilute sulphuric acid and in attapulgite clay raw ore, carries out acidification; 3. extruding: by Concavo-convex excellent stone clay after the acidify, push as flap thickness≤3 millimeter of flap by extrusion machine; 4. roasting: the flap of attapulgite clay is transported in stoving oven and carries out roasting, and roasting time is 1.5～3 hours, and maturing temperature is controlled at 320～450 DEG C, and the attapulgite clay flap after roasting is activated attapulgite.
This production method is the production method that adopts the activated attapulgite in " embossed rod medicinal health-care bathing-mud powder " of application on March 7th, 2006 by the inventor, the China Patent Publication No. of embossed rod medicinal health-care bathing-mud powder is: CN1850026, open day: on October 25th, 2006.
Described water content is weight percentage.
Flame-retardant expanded calcium carbonate dose is added water after high-speed stirring, discharge fast a large amount of gas, form cavernous foam mud, foam mud sprays by water blast gun, be directly used in fire extinguishing, the stable top layer that covers combustible matl of foam mud forms a kind of foam mud film, and foam mud film can completely cut off rapidly contacting of combustible matl and air, stop combustible matl to burn away, reach object fire-retardant and fire extinguishing.
Also flame-retardant expanded calcium carbonate dose can be added in medium; after water mixing and stirring; can discharge a large amount of gas; in medium, produce a large amount of even and stable foams; be used for pouring into a mould multiple foam materials product, there will not be layering in casting process, the product stripping time is shorter; gas contains a certain amount of oxygen, is conducive to protect the air ambient of working-yard.
Flame-retardant expanded dose of applicable medium of calcium carbonate has the materials such as various cement, flyash and nonmetalliferous ore composition.
When simple use sodium alkyl benzene sulfonate, foam generated is very fast, but what break and disappear is also fast, cause the less stable of foam, in the present invention, after light calcium carbonate and other batching and sodium alkyl benzene sulfonate compatibility, form a kind of compound foaming agent, have that foaming power is strong, foam expansion is high, unit volume bubble production volume is large, foam adventitia good toughness is difficult for brokenly, froth stability is good, can be for a long time not froth breaking, foam exquisiteness, the advantage such as the hole size that generates in medium is even, bleeding quantity is low and the consistency of working medium is good.
Use the product of flame-retardant expanded dose of production of calcium carbonate, not only effective flame-retarding fire-extinguishing, the function of controlling in addition sound pollution, be incubated and purify air, these products are for facilities such as motorway, viaduct, urban light rail, subway, factory, warehouse, public places.
Flame-retardant expanded dose of calcium carbonate is applicable to produce flame-retarding fire-extinguishing, light weight board, Light Wall and sound-deadening and noise-reducing product.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: light calcium carbonate 22%, high sticky attapulgite clay powder 16%, activated attapulgite 18%, sodium bicarbonate 28%, sodium alkyl benzene sulfonate 13.8%, sodium polyacrylate 0.8%, trisodium phosphate 0.6%, ammonium polyphosphate 0.4% and zinc borate 0.4%.
The production method that described calcium carbonate is flame-retardant expanded dose: by stirring in flame-retardant expanded calcium carbonate dose of batching input stirrer, input in grinding machine and carry out abrasive dust after stirring, particle fineness≤0.044 millimeter, is packaged as the finished product of flame-retardant expanded dose of calcium carbonate.
Claims (1)
1. flame-retardant expanded dose an of calcium carbonate, it is characterized in that, flame-retardant expanded dose of batching of calcium carbonate is made up of following component by weight percentage: light calcium carbonate 15～45%, high sticky attapulgite clay powder 5～15%, activated attapulgite 5～25%, sodium bicarbonate 1～30%, sodium alkyl benzene sulfonate 1～20%, sodium polyacrylate 0.01～5%, trisodium phosphate 0.01～5%, ammonium polyphosphate 0.01～5% and zinc borate 0.01～5%;
The production method that described calcium carbonate is flame-retardant expanded dose: by stirring in flame-retardant expanded calcium carbonate dose of batching input stirrer, input in grinding machine and carry out abrasive dust after stirring, particle fineness≤0.074 millimeter, is packaged as the finished product of flame-retardant expanded dose of calcium carbonate;
The sticky attapulgite clay of described height is the attapulgite clay that adopts the complete processing that improves viscosity of attapulgite clay to produce, it is characterized in that, and from the attapulgite clay of mining area exploitation, need to be through the weathering of 30～120 days; Modification processing method is: calculate by weight percentage, get the attapulgite clay 94～98% after weathering, evenly add 2～6% sodium carbonate, jointly input in fermentation vat, add clear water to soak ageing, soak time is 72～120 hours; Get the attapulgite clay after immersion, in input stirrer, stir, and by the attapulgite clay after stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5～2 millimeter, by attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after airing, its water content≤15%; Batching is calculated by weight percentage: attapulgite clay 94～98%, High hydrophilous resin 0.5～5% and Mierocrystalline cellulose 0.5～3% after airing, above-mentioned batching is stirred, and after stirring, input and in grinding machine, carry out abrasive dust, particle fineness≤0.074 millimeter;
The sticky attapulgite clay powder of described height refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250mL through high-speed stirring sample suspension again the viscosity that uses NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value>=2200 into
mPasattapulgite clay powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310223181.XA CN103265209B (en) | 2013-06-07 | 2013-06-07 | Calcium carbonate antiflaming foaming agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310223181.XA CN103265209B (en) | 2013-06-07 | 2013-06-07 | Calcium carbonate antiflaming foaming agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103265209A CN103265209A (en) | 2013-08-28 |
| CN103265209B true CN103265209B (en) | 2014-11-05 |
Family
ID=49008888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310223181.XA Expired - Fee Related CN103265209B (en) | 2013-06-07 | 2013-06-07 | Calcium carbonate antiflaming foaming agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103265209B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105645828A (en) * | 2015-12-23 | 2016-06-08 | 佛山华清智业环保科技有限公司 | Flame retardant foaming agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040028956A1 (en) * | 2002-08-07 | 2004-02-12 | Arpad Savoly | Dispersant and foaming agent combination |
| CN101037312A (en) * | 2006-03-16 | 2007-09-19 | 上海华联建筑外加剂厂有限公司 | Middle-effective pumping aid |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2933994B2 (en) * | 1990-07-10 | 1999-08-16 | 花王株式会社 | Admixture for cement |
-
2013
- 2013-06-07 CN CN201310223181.XA patent/CN103265209B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040028956A1 (en) * | 2002-08-07 | 2004-02-12 | Arpad Savoly | Dispersant and foaming agent combination |
| CN101037312A (en) * | 2006-03-16 | 2007-09-19 | 上海华联建筑外加剂厂有限公司 | Middle-effective pumping aid |
Non-Patent Citations (1)
| Title |
|---|
| JP平4-74748A 1992.03.10 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103265209A (en) | 2013-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103265217B (en) | Phosphogypsum flame retardant foaming agent | |
| CN103274624B (en) | Diatomite flame-retardant foaming agent | |
| CN103265205B (en) | Flame-retardant foaming agent of attapulgite | |
| CN103253954B (en) | Bentonite flame retardant foaming agent | |
| CN103265206B (en) | Zeolite flame-retardant foaming agent | |
| CN103265200B (en) | Kaolin flame-retardant foaming agent | |
| CN103274626B (en) | Red mud flame retardant foaming agent | |
| CN103274627B (en) | Rectorite flame-retardant foaming agent | |
| CN103253962B (en) | Cement flame-retardant foaming agent | |
| CN103265209B (en) | Calcium carbonate antiflaming foaming agent | |
| CN103265321B (en) | Talcum flame-retardant foaming agent | |
| CN103265319B (en) | Gypsum inflaming retarding foaming agent | |
| CN103265210B (en) | Mica flame retardant foaming agent | |
| CN103265322B (en) | Basalt flame-retardant foaming agent | |
| CN103265314A (en) | Serpentine flame retardant foaming agent | |
| CN103265208B (en) | Pumice flame-retardant foaming agent | |
| CN103254458B (en) | Carbide slag flame-retardant foaming agent | |
| CN103253970B (en) | Water quenching slag flame-retardant foaming agent | |
| CN103253964B (en) | Flame-retardant magnesium oxide foaming agent | |
| CN103265313B (en) | Shale flame-retardant foaming agent | |
| CN103265211B (en) | Flame-retardant foaming agent of pyroclastic rocks | |
| CN103265316B (en) | Flint clay anti-flaming foaming agent | |
| CN103265212B (en) | Tailings antiflaming foaming agent | |
| CN103253967B (en) | Lime flame-retardant foaming agent | |
| CN103253969B (en) | Volcanic ash flame-retardant foaming agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170322 Address after: 510640 unit 371-1, public education building, 2414-2416, No. five, Tianhe District, Guangzhou, Guangdong Patentee after: Guangdong Gaohang Intellectual Property Operation Co., Ltd. Address before: 211700 Huaian, Xuyi province Timor King international residential area, building 2, unit 202 room 18 Patentee before: Xu Shengying |
|
| CB03 | Change of inventor or designer information |
Inventor after: Yang Qin Inventor after: Peng Changgen Inventor before: Xu Qinghua Inventor before: Jiang Wenlan Inventor before: Xu Shengying Inventor before: Yuan Changbing |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170419 Address after: 414009 Yueyang green chemical industry park, Yunxi District, Hunan, Hunan, China Patentee after: Yueyang Jin Han new and high technology limited-liability company Address before: 510640 unit 371-1, public education building, 2414-2416, No. five, Tianhe District, Guangzhou, Guangdong Patentee before: Guangdong Gaohang Intellectual Property Operation Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141105 Termination date: 20170607 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |