CN103262931A - Water-soluble lutein ester, preparation method thereof and hard candy containing same - Google Patents
Water-soluble lutein ester, preparation method thereof and hard candy containing same Download PDFInfo
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Abstract
The invention discloses a preparation method of water-soluble lutein ester. The preparation method comprises the steps of sufficiently and uniformly mixing oil-soluble lutein ester with an emulsifying agent and an antioxidant so as to obtain a mixture, and carrying out vacuum drying on the mixture, wherein the emulsifying agent consists of one to three of molecular distillation monoglyceride, polyglycerol fatty ester, tripolyglycerol monostearate, polyglycerol polyricinoleate, diacetyl tartaric acid mono/di-glyceride, polyethylene glycol 300, polyethylene glycol 400 and polyethylene glycol 600. According to the preparation method, the molecular distillation monoglyceride, the polyglycerol fatty ester and the like serve as the emulsifying agent, so that good emulsifying effect can be achieved, and the water-soluble lutein ester with high quality is obtained finally. The invention further provides the water-soluble lutein ester obtained through the preparation method and hard candy containing the water-soluble lutein ester.
Description
Technical field
The present invention relates to food processing field, the hard candy that relates in particular to a kind of method of oil-soluble lutein ester emulsification modification and contain the water-soluble lutein ester that method according to this makes.
Background technology
Hard candy is the most ancient product item in the Chinese candy industry, accounts for 22% of candy market capacity, and it is well received by consumers as daily leisure food.Along with the raising gradually of people's health care consciousness, health and the health of food are also had higher requirement.
Lutein ester is a kind of important carotenoid fatty acid ester, extensively is present in the plants such as marigold flower, pumpkin, wild cabbage, clover.Studies show that at present lutein ester has extensively and the useful physiological function.1, lutein ester can protect eyes not to be subjected to phototoxis, delays the aging of eyes and prevents pathology, especially can effectively prevent the senile macula retinae of AMD(to degenerate).2, lutein ester has and strengthens the exempt from service effect of function of body, and its regulating action to cellular immunity mainly shows with the pass of Apoptosis and Gene regulation to be fastened.3, antioxidation.Studies have shown that it can pass through physics or chemical cancellation effect deactivation singlet oxygen, thereby suppress the activity of active oxygen radical, stop active oxygen radical to Normocellular destruction.4, anticancer.Lutein and Ester thereof all have inhibitory action to multiple cancers such as breast cancer, prostate cancer, the carcinoma of the rectum, cutaneum carcinomas, take the photograph people's lutein Ester and can not only suppress cancer even can play the tumorigenic effect of prevention in meals.In addition, lutein ester also has the blood fat of adjusting, delays effects such as artery sclerosis, cosmetology.
But because the oil-soluble of lutein ester and be insoluble in the character of water has limited its application in fields such as food.If the oil-soluble of lutein ester is modified as water-soluble, not only can directly apply to water-based food, enlarged its range of application, also help absorption by human body, improve the bioavailability of lutein ester.
Summary of the invention
For this reason, the present invention proposes and a kind of the oil-soluble lutein ester is carried out the method that modification prepares water-soluble lutein ester, water-soluble better by the water-soluble lutein ester of this method preparation; The present invention also provides a kind of hard candy that contains the water-soluble lutein ester that above-mentioned preparation method obtains, and this hard candy is sour-sweet suitable, has the health care effect.
According to an aspect of the present invention, provide a kind of water-soluble lutein ester preparation method, oil-soluble lutein ester and emulsifying agent, the abundant mixing of antioxidant have been obtained mixture, with described mixture vacuum drying; Wherein, described emulsifying agent is the 1-3 kind in molecular clock monoglyceride, polyglyceryl fatty acid ester, Tripolyglycerol monostearates, polyglycereol castor-oil plant alcohol ester, diacetyl tartarate list double glyceride, Liquid Macrogol, PEG400, the Macrogol 600.
Alternatively, according to water-soluble lutein ester preparation method of the present invention, described antioxidant is at least a in ditert-butylhydro quinone, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate and the vitamin E.
Alternatively, according to water-soluble lutein ester preparation method of the present invention, be benchmark with oil-soluble lutein ester weight, the consumption of described emulsifying agent is 2-10%, the consumption of described antioxidant is 0.1-0.8%.
Alternatively, according to water-soluble lutein ester preparation method of the present invention, with the oil-soluble lutein ester with before emulsifying agent, antioxidant mix, described oil-soluble lutein ester is heated to 45-65 ℃.
Alternatively, according to water-soluble lutein ester preparation method of the present invention, before vacuum drying, described mixture is carried out homogeneous handle.
According to another aspect of the present invention, provide a kind of water-soluble lutein ester for preparing according to above-mentioned preparation method.
According to a further aspect of the invention, provide a kind of hard candy that contains the water-soluble lutein ester that obtains by described preparation method.
Alternatively, according to hard candy of the present invention, described hard candy prepares according to following steps: (1) prepares raw material: prepare following raw material by percentage to the quality: glucide 75%-90%, water-soluble lutein ester powder 0.05%-5%, inspissated juice 1%-10%, gelling agent 0.5%-10%, acidic flavouring agent 0.01%-3%, flavoring essence 0.01%-0.5%, water 5%-30%; (2) stir off: boil after described glucide is soluble in water, endure to solid content be 85Brix-90Brix, obtain liquid glucose; (3) change glue: place water to heat described gelling agent, make its abundant swelling; (4) mix: with described inspissated juice, acidic flavouring agent and the flavoring essence acidic aqueous solution that gets soluble in water, described water-soluble lutein ester powder is dissolved in the described acidic aqueous solution obtains mixed solution, add described liquid glucose and the abundant gelling agent of swelling then in the described mixed solution, stir, obtain massecuite; (5) moulding: described massecuite is poured in the model, obtained hard candy behind the cooling forming.
Alternatively, according to hard candy of the present invention, the pH value of described massecuite is 3-4.
Alternatively, according to hard candy of the present invention, described glucide is sugar cube or liquid sugar sirup low in calories.
Among the preparation method of water-soluble lutein ester of the present invention, as emulsifying agent, the emulsifying effectiveness of obtaining is better, finally obtains high-quality water-soluble lutein ester with molecular clock monoglyceride, polyglyceryl fatty acid ester etc.The water-soluble lutein ester that makes by this method is water-soluble better, and does not have the sharp aroma after conventional emulsifier (tween) emulsification.The hard candy that contains above-mentioned water-soluble lutein ester of the present invention not only taste is suitable but also have the health care effect, is applicable to the crowd of each age level, the crowd who especially needs to replenish the elderly of lutein class material and symptoms such as eye-blurred are arranged.
Description of drawings
By reading hereinafter detailed description of the preferred embodiment, various other advantage and benefits will become cheer and bright for those of ordinary skills.Accompanying drawing only is used for the purpose of preferred embodiment is shown, and does not think limitation of the present invention.In the accompanying drawings:
Fig. 1 is water-soluble lutein ester preparation method's of the present invention flow chart; And
Fig. 2 is hard candy preparation method's of the present invention flow chart.
The specific embodiment
The invention will be further described below in conjunction with accompanying drawing and concrete embodiment.
The invention provides a kind of water-soluble lutein ester preparation method, oil-soluble lutein ester and emulsifying agent, the abundant mixing of antioxidant are obtained mixture, with described mixture vacuum drying; Wherein, described emulsifying agent is the 1-3 kind in molecular clock monoglyceride, polyglyceryl fatty acid ester, Tripolyglycerol monostearates, polyglycereol castor-oil plant alcohol ester, diacetyl tartarate list double glyceride, Liquid Macrogol, PEG400, the Macrogol 600.
Fig. 1 shows water-soluble lutein ester preparation method's of the present invention flow chart.As shown in Figure 1, at first in the oil-soluble lutein ester, add emulsifying agent and antioxidant, fully stirred 1-3 hour with 200-500 rev/min rotating speed, make the abundant mixing of mixture, then described mixture is carried out vacuum drying.Be benchmark with oil-soluble lutein ester weight, the consumption of described emulsifying agent is 2-10%, and the consumption of described antioxidant is 0.1-0.8%.Among the present invention, employed emulsifying agent is the 1-3 kind in molecular clock monoglyceride, polyglyceryl fatty acid ester, Tripolyglycerol monostearates, polyglycereol castor-oil plant alcohol ester, diacetyl tartarate list double glyceride, Liquid Macrogol, PEG400, the Macrogol 600, and employed antioxidant is at least a in ditert-butylhydro quinone, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate and the vitamin E.Normally used emulsifying agent is tween in the prior art, but tween has special smell, mildly bitter flavor, adopt molecular clock monoglyceride, polyglyceryl fatty acid ester, Tripolyglycerol monostearates etc. as emulsifying agent among the present invention, the emulsifying effectiveness of not only obtaining is better, and does not have the sharp aroma after the tween emulsification.Water-soluble better by the water-soluble lutein ester that this method makes, lutein ester content 〉=55.8% wherein.
Among the water-soluble lutein ester preparation method of the present invention, with the oil-soluble lutein ester with before emulsifying agent, antioxidant mix, described oil-soluble lutein ester can also be heated to 45-65 ℃, to improve the mixed effect of lutein ester and antioxidant and emulsifying agent.Described oil-soluble lutein ester raw material is to be material with the marigold, comes by the preparation of methods such as fermentation, solvent extraction, different concentration ethanol purifying and vacuum concentrate drying.
Before carrying out vacuum drying, can also carry out homogeneous to the mixture of lutein ester, emulsifying agent and antioxidant and handle, among the present invention, mixture is carried out the high speed shear homogeneous, the homogenizer rotating speed is 2500-4000 rev/min, all time matter 15-35 minute.After homogeneous is finished, obtain the water-soluble lutein ester emulsion.Described water-soluble emulsion is carried out vacuum drying at 55 ℃, namely obtain water-soluble lutein ester.
The present invention also provides a kind of hard candy that contains the water-soluble lutein ester that obtains by above-mentioned preparation method.Described hard candy utilizes the distinctive biologically active of lutein ester, plays effects such as protection retina, anti-cancer, has promoted the healthy nutritive value of hard candy greatly.
Among the present invention, described hard candy prepares according to following steps: (1) prepares raw material: prepare following raw material by percentage to the quality: glucide 75%-90%, water-soluble lutein ester powder 0.05%-5%, inspissated juice 1%-10%, gelling agent 0.5%-10%, acidic flavouring agent 0.01%-3%, flavoring essence 0.01%-0.5%, water 5%-30%; (2) stir off: boil after described glucide is soluble in water, endure to solid content be 85Brix-90Brix, obtain liquid glucose; (3) change glue: place water to heat described gelling agent, make its abundant swelling; (4) mix: with described inspissated juice, acidic flavouring agent and the flavoring essence acidic aqueous solution that gets soluble in water, described water-soluble lutein ester powder is dissolved in the described acidic aqueous solution obtains mixed solution, add described liquid glucose and the abundant gelling agent of swelling then in the described mixed solution, stir, obtain massecuite; (5) moulding: described massecuite is poured in the model, obtained hard candy behind the cooling forming.In the technology of above-mentioned preparation hard candy, in described blend step, at first water-soluble lutein ester is dissolved in the acidic aqueous solution of inspissated juice, acidic flavouring agent and flavoring essence, by using the pH value of acidic flavouring agent mediation mixed solution, make the acidic mixed solution that contains lutein ester, and then the oxytropism mixed solution adds described other raw materials of preparation hard candy.This method is gentle simple, workable, has overcome the difficult problem of lutein ester poor stability in the highly acid chemical reagent simultaneously, and the lutein ester content is stable in the feasible hard candy that finally prepares.
Prepare in the material of hard candy of the present invention, the preferential selection of employed glucide sugar cube or liquid sugar sirup low in calories, the preferred glycitols product of sugar cube low in calories wherein, as: at least a in xylitol, low polyxylose alcohol, maltitol, hydroxyl isomaltulose, oligoisomaltose alcohol, antierythrite, lactitol, sorbic alcohol, sweet mellow wine, the sharp voxel etc.In addition, in hard candy manufacturing process, can also use other sugar cube, at least a in white granulated sugar, sucrose, glucose, fructose, FOS, wood sugar, rhamnose, maltose, oligoisomaltose, stachyose, galactolipin, galactooligosaccharide, arabinose, ribose, mannose, the dextrin etc. arranged.Liquid sugar sirup comprise can be in starch syrup, glucose syrup, HFCS, oligoisomaltose slurry, sorbic alcohol syrup, maltitol pulp, the oligoisomaltose alcohol slurry etc. at least a.
Prepare in the material of hard candy of the present invention, employed inspissated juice, adopt the vacuum and low temperature rotary evaporation to concentrate and get, preferentially selecting working concentration is at least a in the grape juice, cider, peach juice, star fruit juice, fresh orange-juice, Cantaloupe juice, blueberry juice, strawberry juice, corn juice, pear juice, watermelon juice etc. more than 90%.
Prepare in the material of hard candy of the present invention, employed gelling agent preferentially selects to use natural polymer and derivative thereof, as: soluble starch, algal polysaccharides, pulullan polysaccharide, gum arabic, gelatin, pectin, sodium alginate, guar gum, crust glue, xanthans, soybean protein glue, lanolin, agar, carragheen, konjac glucomannan etc., or the use cellulose ethers, at least a as in methylcellulose, hydroxypropyl methylcellulose, sodium carboxymethylcellulose, the hydroxyethylcellulose etc.
Prepare in the material of hard candy of the present invention, employed acidic flavouring agent is preferentially selected at least a in VC, hydrochloric acid, phosphoric acid, lactic acid, sodium lactate, malic acid, tartaric acid, sodium potassium tartrate tetrahydrate, citric acid, the natrium citricum etc.
Prepare in the material of hard candy of the present invention, employed flavoring essence is preferentially selected the soluble perfume of floral type and Fruity type, and addition is strict controlled in the scope that national standard allows.
In the sugar cook step of described preparation hard candy, after described carbohydrate and water taken by weighing by a certain percentage, be placed in the proper container, heat slowly with electric furnace, stir, content is all melted open and boil, heating and temperature control is at 100 ℃-105 ℃, to avoid the sugary soln coking.The consumption of described water can filter the sugary soln that obtains for the 10-20% of preparation hard candy raw material gross mass with 300-500 purpose filter membrane, to remove insoluble impurities wherein.After filtration is finished, sugary soln is poured in the container, boiled with moderate heat on electric furnace and constantly stir, temperature is controlled at 110 ℃-130 ℃.Follow earlier at a slow speed again after the middling speed principle fast during stirring, so as to make that sugared body reaches that color and luster is bright, inflation and the moderate requirement of hardness.
In the forming step of described preparation hard candy, when being 75 ℃, the massecuite temperature in model, pours into a mould fast, and temperature is low excessively, and the mobile variation of massecuite can have a strong impact on profile and the transparency of boiled goods.Before cast massecuite in model, can also carry out preliminary treatment to prevent adhesion to model.Method commonly used has: a spot of salad oil of wiping or model is handled with a spot of dextrine powder, flour, starch etc. in model.Before moulding, the pH value of described massecuite is 3-4.
After the hard candy moulding, can also will wherein be the defective sugar of head and gross distortion.Hard candy after the screening is put into and carried out low-temperature vacuum drying in the vacuum drying chamber, and baking temperature is controlled at 45 ℃-55 ℃, dry 15-36h, to the boiled goods water content be 1.5%-5%.Under cryogenic conditions, reach the purpose that reduces moisture by prolonging drying time, guaranteed that simultaneously the content of lutein ester remains unchanged in the boiled goods.After drying is finished, candy carried out packing behind the routine inspection get final product.
The water-soluble lutein ester preparation method who proposes according to the present invention and hard candy preparation technology's optional factor are more, can design various embodiments, therefore specific embodiment is only as the exemplary illustration of specific implementation of the present invention, and do not constitute limitation of the scope of the invention.For concrete description the present invention, select following examples to carry out exemplary illustration.
Embodiment 1
The preparation technology of water-soluble lutein ester:
The oil-soluble lutein ester is heated to 65 ℃, then to wherein adding polyglyceryl fatty acid ester and ditert-butylhydro quinone, places mixer fully to stir 2 hours with 200 rev/mins rotating speed in mixture, make the abundant mixing of mixture.Be benchmark with oil-soluble lutein ester weight, the consumption of described polyglyceryl fatty acid ester is 2%, and the consumption of described ditert-butylhydro quinone is 0.5%.With the speed of high speed shear homogenizer with 2500 rev/mins, homogeneous 35 minutes obtains the lutein ester emulsion, and described emulsion is pulverized after 55 ℃ of following vacuum drying, crosses 100 mesh sieves, obtains the water-soluble lutein ester powder with the mixture of mixing.
Utilize the above-mentioned water-soluble lutein ester that obtains to prepare the technology of hard candy:
Prepare following raw material by percentage to the quality: glucide 75%, water-soluble lutein ester powder 0.1%, AJC 2%, gelling agent 1%, citric acid 0.1%, flavoring apple essence 0.1%, water 10%; Wherein glucide is the combination of white granulated sugar and HFCS, and gelling agent is the combination of gum arabic and agar.
Described white granulated sugar is soluble in water, under 100 ℃ condition, heat, white granulated sugar is all melted open and boils, behind 500 order membrane filtrations, to wherein adding HFCS, under 115 ℃, boil while stirring, to solid content be 87Brix, obtain liquid glucose.Described gum arabic and agar is soluble in water and be heated to 95 ℃, make its abundant swelling.Described flavoring apple essence, citric acid, AJC is soluble in water, again the water-soluble lutein ester powder is dissolved in wherein, place behind the 1h with 320 order membrane filtrations, remove insoluble impurities, obtain the water-soluble lutein ester acid solution; When liquid temp during 85 ℃ of left and right sides, can join gum arabic and agar mixture in the liquid glucose and mix, when liquid temp to be mixed is down to 80 ℃ of left and right sides, described water-soluble lutein ester acid solution is joined, stir at a slow speed and can be injected in the candy model, room temperature is cooled to the candy hardening, candy is taken out again.Pick out qualified confectionary products and carry out determination of moisture and other some indexs detections, qualified lutein ester boiled goods is packed in the packaging bag.
Embodiment 2
The preparation technology of water-soluble lutein ester:
The oil-soluble lutein ester is heated to 45 ℃, then to wherein adding Tripolyglycerol monostearates, polyglycereol castor-oil plant alcohol ester, butylated hydroxy anisole and dibutyl hydroxy toluene, place mixer fully to stir 3 hours with 300 rev/mins rotating speed in mixture, make the abundant mixing of mixture.Be benchmark with oil-soluble lutein ester weight, described Tripolyglycerol monostearates, both total consumptions of polyglycereol castor-oil plant alcohol ester are 5%, and total consumption of described butylated hydroxy anisole and dibutyl hydroxy toluene is 0.3%.With the speed of high speed shear homogenizer with 3500 rev/mins, homogeneous 20 minutes obtains the lutein ester emulsion, and described emulsion is pulverized after 55 ℃ of following vacuum drying, crosses 100 mesh sieves, obtains the water-soluble lutein ester powder with the mixture of mixing.
Utilize the above-mentioned water-soluble lutein ester that obtains to prepare the technology of hard candy:
Prepare following raw material by percentage to the quality: glucide 85%, water-soluble lutein ester powder 0.2%, grape inspissated juice 6%, carragheen 3%, malic acid and tartaric mixture 1%, grape essence 0.2%, water 15%; Wherein glucide is the combination of xylitol and maltitol.
Described xylitol and maltitol is soluble in water, under 102 ℃ condition, heat, xylitol and maltitol are all melted open and boil, behind 300 order membrane filtrations, under 120 ℃, boil while stirring, to solid content be 85Brix, obtain liquid glucose.Described carragheen is soluble in water and be heated to 70 ℃, make its abundant swelling.Described grape essence, malic acid and tartaric acid, grape inspissated juice is soluble in water, again the water-soluble lutein ester powder is dissolved in wherein, place behind the 2h with 400 order membrane filtrations, remove insoluble impurities, obtain the water-soluble lutein ester acid solution; When liquid glucose temperature during 85 ℃ of left and right sides, can join carragheen in the liquid glucose and mix, when liquid temp to be mixed is down to 80 ℃ of left and right sides, described water-soluble lutein ester acid solution is joined, stir at a slow speed and can be injected in the candy model, room temperature is cooled to the candy hardening, candy is taken out again.Pick out qualified confectionary products and carry out determination of moisture and other some indexs detections, qualified lutein ester boiled goods is packed in the packaging bag.
Embodiment 3
The preparation technology of water-soluble lutein ester:
The oil-soluble lutein ester is heated to 50 ℃, then to wherein adding diacetyl tartarate list double glyceride, Liquid Macrogol, PEG400, n-propyl gallate and vitamin E, place mixer fully to stir 1.5 hours with 400 rev/mins rotating speed in mixture, make the abundant mixing of mixture.Be benchmark with oil-soluble lutein ester weight, total consumption of described diacetyl tartarate list double glyceride, Liquid Macrogol and PEG400 three is 8%, and total consumption of described n-propyl gallate and vitamin E is 0.8%.With the speed of high speed shear homogenizer with 3000 rev/mins, homogeneous 25 minutes obtains the lutein ester emulsion, and described emulsion is pulverized after 55 ℃ of following vacuum drying, crosses 100 mesh sieves, obtains the water-soluble lutein ester powder with the mixture of mixing.
Utilize the above-mentioned water-soluble lutein ester that obtains to prepare the technology of hard candy:
Prepare following raw material by percentage to the quality: glucide 80%, water-soluble lutein ester powder 0.05%, orange inspissated juice 1%, gelling agent 0.5%, lactic acid 0.01%, orange flavor 0.01%, water 5%; Wherein glucide is the combination of sweet mellow wine and maltose, and gelling agent is the combination of algal polysaccharides and gelatin.
Described sweet mellow wine and maltose is soluble in water, under 103 ℃ condition, heat, sweet mellow wine and maltose are all melted open and boil, behind 400 order membrane filtrations, under 110 ℃, boil while stirring, to solid content be 88Brix, obtain liquid glucose.Described algal polysaccharides and gelatin is soluble in water and be heated to 100 ℃, make its abundant swelling.Described orange flavor, lactic acid, orange inspissated juice is soluble in water, again the water-soluble lutein ester powder is dissolved in wherein, place behind the 2h with 400 order membrane filtrations, remove insoluble impurities, obtain the water-soluble lutein ester acid solution; When liquid glucose temperature during 85 ℃ of left and right sides, can join algal polysaccharides and gelatin mixture in the liquid glucose and mix, when liquid temp to be mixed is down to 80 ℃ of left and right sides, described water-soluble lutein ester acid solution is joined, stir at a slow speed and can be injected in the candy model, room temperature is cooled to the candy hardening, candy is taken out again.Pick out qualified confectionary products and carry out determination of moisture and other some indexs detections, qualified lutein ester boiled goods is packed in the packaging bag.
Embodiment 4
The preparation technology of water-soluble lutein ester:
The oil-soluble lutein ester is heated to 55 ℃, then to wherein adding polyglyceryl fatty acid ester, Macrogol 600 and butylated hydroxy anisole, places mixer fully to stir 1 hour with 500 rev/mins rotating speed in mixture, make the abundant mixing of mixture.Be benchmark with oil-soluble lutein ester weight, described polyglyceryl fatty acid ester, both total consumptions of Macrogol 600 are 10%, and the consumption of described butylated hydroxy anisole is 0.1%.With the speed of high speed shear homogenizer with 4000 rev/mins, homogeneous 15 minutes obtains the lutein ester emulsion, and described emulsion is pulverized after 55 ℃ of following vacuum drying, crosses 100 mesh sieves, obtains the water-soluble lutein ester powder with the mixture of mixing.
Utilize the above-mentioned water-soluble lutein ester that obtains to prepare the technology of hard candy:
Prepare following raw material by percentage to the quality: glucide 90%, water-soluble lutein ester powder 5%, honey peach inspissated juice and watermelon inspissated juice mixture 10%, gelling agent 10%, the mixture 3% of phosphoric acid and hydrochloric acid, honey peach essence and watermelon essence mixture 0.5%, water 30%; Wherein glucide is the combination of lactitol and starch syrup, and gelling agent is the combination of xanthans and soybean protein glue.
Described lactitol is soluble in water, under 105 ℃ condition, heat, lactitol is all melted open and boils, behind 400 order membrane filtrations, to wherein adding starch syrup, under 130 ℃, boil while stirring, to solid content be 90Brix, obtain liquid glucose.Described xanthans and soybean protein glue is soluble in water and be heated to 110 ℃, make its abundant swelling.Described honey peach essence and watermelon essence mixture, phosphoric acid and hydrochloric acid mixture, honey peach inspissated juice and watermelon inspissated juice mixture is soluble in water, again the water-soluble lutein ester powder is dissolved in wherein, place behind the 2h with 400 order membrane filtrations, remove insoluble impurities, obtain the water-soluble lutein ester acid solution; When liquid glucose temperature during 85 ℃ of left and right sides, can join xanthans and soybean protein glue mixture in the liquid glucose and mix, when liquid temp to be mixed is down to 80 ℃ of left and right sides, described water-soluble lutein ester acid solution is joined, stir at a slow speed and can be injected in the candy model, room temperature is cooled to the candy hardening, candy is taken out again.Pick out qualified confectionary products and carry out determination of moisture and other some indexs detections, qualified lutein ester boiled goods is packed in the packaging bag.
It should be noted that the present invention will be described rather than limit the invention for above-described embodiment, and those skilled in the art can design alternative embodiment under the situation of the scope that does not break away from claims.In the claims, any reference symbol between bracket should be configured to limitations on claims.Word " comprises " not to be got rid of existence and is not listed in element or operation in the claim.Any order is not represented in the use of word first, second and C grade.Can be title with these word explanations.
Claims (10)
1. a water-soluble lutein ester preparation method is characterized in that: oil-soluble lutein ester and emulsifying agent, the abundant mixing of antioxidant are obtained mixture, with described mixture vacuum drying;
Wherein, described emulsifying agent is the 1-3 kind in molecular clock monoglyceride, polyglyceryl fatty acid ester, Tripolyglycerol monostearates, polyglycereol castor-oil plant alcohol ester, diacetyl tartarate list double glyceride, Liquid Macrogol, PEG400, the Macrogol 600.
2. water-soluble lutein ester preparation method according to claim 1 is characterized in that: described antioxidant is at least a in ditert-butylhydro quinone, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate and the vitamin E.
3. water-soluble lutein ester preparation method according to claim 1 is characterized in that: be benchmark with oil-soluble lutein ester weight, the consumption of described emulsifying agent is 2-10%, and the consumption of described antioxidant is 0.1-0.8%.
4. water-soluble lutein ester preparation method according to claim 1 is characterized in that: with the oil-soluble lutein ester with before emulsifying agent, antioxidant mix, described oil-soluble lutein ester is heated to 45-65 ℃.
5. water-soluble lutein ester preparation method according to claim 1 is characterized in that: before vacuum drying, described mixture is carried out homogeneous handle.
6. water-soluble lutein ester for preparing according to each described preparation method among the claim 1-5.
7. hard candy that contains the described water-soluble lutein ester of claim 6.
8. hard candy according to claim 7, it is characterized in that: described hard candy prepares according to following steps:
(1) prepares raw material: prepare following raw material by percentage to the quality: glucide 75%-90%, water-soluble lutein ester powder 0.05%-5%, inspissated juice 1%-10%, gelling agent 0.5%-10%, acidic flavouring agent 0.01%-3%, flavoring essence 0.01%-0.5%, water 5%-30%;
(2) stir off: boil after described glucide is soluble in water, endure to solid content be 85Brix-90Brix, obtain liquid glucose;
(3) change glue: place water to heat described gelling agent, make its abundant swelling;
(4) mix: with described inspissated juice, acidic flavouring agent and the flavoring essence acidic aqueous solution that gets soluble in water, described water-soluble lutein ester powder is dissolved in the described acidic aqueous solution obtains mixed solution, add described liquid glucose and the abundant gelling agent of swelling then in the described mixed solution, stir, obtain massecuite;
(5) moulding: described massecuite is poured in the model, obtained hard candy behind the cooling forming.
9. hard candy according to claim 8 is characterized in that: the pH value of described massecuite is 3-4.
10. hard candy according to claim 8, it is characterized in that: described glucide is sugar cube or liquid sugar sirup low in calories.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103876012A (en) * | 2014-04-19 | 2014-06-25 | 普宁市梅塘桂金红食品厂 | Selenium-enriched health-care purple sweet potato jelly and production process thereof |
| CN104172136A (en) * | 2014-07-22 | 2014-12-03 | 河北中进生物科技有限公司 | Preparation method of cold water dispersible liquid lutein ester |
| CN105076651A (en) * | 2015-09-22 | 2015-11-25 | 哈尔滨宝德生物技术股份有限公司 | Xanthophyll-containing sugar tablet capable of relieving eye fatigue and preparing method of xanthophyll-containing sugar tablet |
| CN106889435A (en) * | 2017-02-17 | 2017-06-27 | 云南瑞宝生物科技股份有限公司 | A kind of lutein ester vermicelli and preparation method thereof |
| CN108402269A (en) * | 2018-02-09 | 2018-08-17 | 云南瑞宝生物科技股份有限公司 | Cranberry taste lutein ester sugar-free soft sweet and preparation method thereof |
| CN109497247A (en) * | 2018-12-11 | 2019-03-22 | 李天� | A kind of trollflower hard candy and preparation method thereof |
| CN110313564A (en) * | 2019-08-15 | 2019-10-11 | 辽宁眼宝生物科技股份有限公司 | Lutein ester Hippophae Rhamnoides L. juice and preparation method thereof |
| CN111387499A (en) * | 2020-04-17 | 2020-07-10 | 山东天音生物科技有限公司 | Lutein ester water-soluble particle and preparation method thereof |
| CN117964534A (en) * | 2024-03-28 | 2024-05-03 | 中国农业大学 | Amorphous lutein with improved solubility and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1193465A (en) * | 1997-03-17 | 1998-09-23 | 霍夫曼-拉罗奇有限公司 | Microemulsion |
| US20050182280A1 (en) * | 2004-01-16 | 2005-08-18 | Indus Biotech Pvt. Ltd. | Process for isolating, purifying and formulating a stable, commercial grade Lutein paste from oleoresin |
| CN101292965A (en) * | 2007-04-24 | 2008-10-29 | 沈阳皓天万嘉医药科技有限公司 | Beta-carotene microcapsule and preparation method thereof |
| CN101507704A (en) * | 2009-03-13 | 2009-08-19 | 沈阳药科大学 | Lutein solid dispersoid and preparation method thereof |
| CN102475696A (en) * | 2010-11-25 | 2012-05-30 | 沈阳药科大学 | Water-soluble lutein and preparation process thereof |
| CN102578346A (en) * | 2012-03-09 | 2012-07-18 | 华北制药集团新药研究开发有限责任公司 | Lutein ester soft sweet and preparation method thereof |
| CN102584662A (en) * | 2011-12-19 | 2012-07-18 | 青岛赛特香料有限公司 | Method for preparing water-soluble lutein |
-
2013
- 2013-05-23 CN CN201310194981.3A patent/CN103262931B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1193465A (en) * | 1997-03-17 | 1998-09-23 | 霍夫曼-拉罗奇有限公司 | Microemulsion |
| US20050182280A1 (en) * | 2004-01-16 | 2005-08-18 | Indus Biotech Pvt. Ltd. | Process for isolating, purifying and formulating a stable, commercial grade Lutein paste from oleoresin |
| CN101292965A (en) * | 2007-04-24 | 2008-10-29 | 沈阳皓天万嘉医药科技有限公司 | Beta-carotene microcapsule and preparation method thereof |
| CN101507704A (en) * | 2009-03-13 | 2009-08-19 | 沈阳药科大学 | Lutein solid dispersoid and preparation method thereof |
| CN102475696A (en) * | 2010-11-25 | 2012-05-30 | 沈阳药科大学 | Water-soluble lutein and preparation process thereof |
| CN102584662A (en) * | 2011-12-19 | 2012-07-18 | 青岛赛特香料有限公司 | Method for preparing water-soluble lutein |
| CN102578346A (en) * | 2012-03-09 | 2012-07-18 | 华北制药集团新药研究开发有限责任公司 | Lutein ester soft sweet and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 任红，等: "叶黄素在功能性食品中的应用进展", 《食品研究与开发》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103876012A (en) * | 2014-04-19 | 2014-06-25 | 普宁市梅塘桂金红食品厂 | Selenium-enriched health-care purple sweet potato jelly and production process thereof |
| CN104172136A (en) * | 2014-07-22 | 2014-12-03 | 河北中进生物科技有限公司 | Preparation method of cold water dispersible liquid lutein ester |
| CN105076651A (en) * | 2015-09-22 | 2015-11-25 | 哈尔滨宝德生物技术股份有限公司 | Xanthophyll-containing sugar tablet capable of relieving eye fatigue and preparing method of xanthophyll-containing sugar tablet |
| CN106889435A (en) * | 2017-02-17 | 2017-06-27 | 云南瑞宝生物科技股份有限公司 | A kind of lutein ester vermicelli and preparation method thereof |
| CN108402269A (en) * | 2018-02-09 | 2018-08-17 | 云南瑞宝生物科技股份有限公司 | Cranberry taste lutein ester sugar-free soft sweet and preparation method thereof |
| CN109497247A (en) * | 2018-12-11 | 2019-03-22 | 李天� | A kind of trollflower hard candy and preparation method thereof |
| CN109497247B (en) * | 2018-12-11 | 2022-03-18 | 李天� | Trollflower hard candy and preparation method thereof |
| CN110313564A (en) * | 2019-08-15 | 2019-10-11 | 辽宁眼宝生物科技股份有限公司 | Lutein ester Hippophae Rhamnoides L. juice and preparation method thereof |
| CN111387499A (en) * | 2020-04-17 | 2020-07-10 | 山东天音生物科技有限公司 | Lutein ester water-soluble particle and preparation method thereof |
| CN117964534A (en) * | 2024-03-28 | 2024-05-03 | 中国农业大学 | Amorphous lutein with improved solubility and preparation method thereof |
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