CN103252862B - A kind of manufacture method of polyurethane foam hollow ball - Google Patents
A kind of manufacture method of polyurethane foam hollow ball Download PDFInfo
- Publication number
- CN103252862B CN103252862B CN201310136525.3A CN201310136525A CN103252862B CN 103252862 B CN103252862 B CN 103252862B CN 201310136525 A CN201310136525 A CN 201310136525A CN 103252862 B CN103252862 B CN 103252862B
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- China
- Prior art keywords
- polyurethane foam
- manufacture method
- hollow ball
- mould
- mould inner
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Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 36
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 26
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 26
- 238000005187 foaming Methods 0.000 claims abstract description 29
- 238000000465 moulding Methods 0.000 claims abstract description 19
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 238000005507 spraying Methods 0.000 claims abstract description 6
- 239000007921 spray Substances 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 7
- 239000003973 paint Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 239000012974 tin catalyst Substances 0.000 claims description 4
- 238000010586 diagram Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention relates to a kind of manufacture method of polyurethane foam hollow ball, it is characterized in that, comprise following step: (1) opens foaming molding mold, at mould inner surface spraying releasing agent; (2) place several movable blocks at mould inner surface, an inflatable bladder is put into the position that mould is limited by several movable blocks described; (3) urethane raw is injected in foaming molding mold; (4) matched moulds and polymerisation; (5) die sinking obtains product; (6) take out described inflatable bladder and described movable block, get product.Adopt the manufacture method of polyurethane foam hollow ball of the present invention, manufacture process is simple, is easy to operate and control, foaming urethane raw consumption greatly reduces, and greatly can reduce production cost, and obtained hollow ball, lighter in weight, product hollowness size is adjustable.
Description
Technical field
The present invention relates to polyurethane foam plastics technical field, be specifically related to a kind of manufacture method of polyurethane foam hollow ball.
Background technology
Existing polyurethane (PU) spheroid general following methods manufacture of foaming forms (as shown in Figure 1): the inner mould with the die cavity of predetermined sphere shape of preparation, then release agent spraying on mould, and then spray paint in mould, the urethane raw for foaming is poured in mould, matched moulds, shake mould and carry out foamable reaction, to make the foam filled whole die cavity of urethane raw, after die sinking, namely take out product.But manufacture polyurethane foam spheroid by the method and have urethane raw consumption greatly, production cost is high, and the shortcoming that the finished product spheroid obtained is heavier.
Publication number is CN1365882A publication date is on August 28th, 2002, the Chinese invention patent application that denomination of invention is " method of forming of foamed toy body " discloses a kind of method of forming of foamed toy body, it passes through following steps: the existing ethene-vinyl acetate copolymer base material of the one step foaming of looking ahead, through cutting into the toy body base material that several sections have predetermined amount, make toy body base material put into mould inside and carry out two degree of foaming, cool to suppress substrate surface to foam rapidly to mould afterwards after a predetermined time to grow up, thus obtain interior layer expansion, the toy structure of the smooth densification of superficial layer.Although the method for forming of this foamed toy body can reduce the raw-material consumption of foaming, the shaping of a toy body needs through second time of foaming, and whole manufacture process is easy not, also needs to control in time, and this kind of production method does not reduce human cost.
One had both saved foaming raw material usage, low production cost, can overcome again the heavier shortcoming of foaming spheroid itself, and manufacture process is simple, the manufacture method that is easy to the foamed hollow spheroid of control, does not also have report at present.
Summary of the invention
The manufacture method the present invention is directed to the deficiencies in the prior art, provide that a kind of urethane raw consumption is little, production cost is low and finished product spheroid is comparatively light, manufacture process is simple, being easy to the polyurethane foam hollow ball controlled.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions:
A manufacture method for polyurethane foam hollow ball, is characterized in that, comprises following step:
(1) foaming molding mold is opened, at mould inner surface spraying releasing agent;
(2) place several movable blocks at mould inner surface, an inflatable bladder is put into the position that mould is limited by several movable blocks described;
(3) urethane raw is injected in foaming molding mold;
(4) matched moulds and polymerisation;
(5) die sinking obtains product;
(6) take out described inflatable bladder and described movable block, get product.
Further, several movable blocks described are detachable is spaced reciprocally fixed on described mould inner surface.
Further, movable block is cylinder, and described mould inner surface is fixed in described cylinder bottom surface.
Further, also foaming molding mold is vacuumized between described (4) step and (5) step.
Further, also following steps are carried out between described (1) step and (2) step: spray in mould to the mould inner surface scribbling releasing agent and paint.
Particularly, described urethane raw comprises PPG, isocyanates and amines catalyst/organic tin catalyst.
Further, described inflatable bladder is rubber ball.
The invention provides a kind of finished product obtained by the manufacture method of described polyurethane foam hollow ball.
The manufacture method of polyurethane foam hollow ball of the present invention, its beneficial effect is:
(1) adopt the manufacture method of polyurethane foam hollow ball of the present invention, foaming urethane raw consumption greatly reduces, and greatly can reduce production cost;
(2) by hollow ball that the manufacture method of polyurethane foam hollow ball of the present invention is obtained, lighter in weight, and the size of product hollowness is adjustable, can requires to select different inflatable bladder and movable block according to the difference of hollow ball, produce different hollow balls thus;
(3) manufacture method of polyurethane foam hollow ball of the present invention, manufacture process is simple, is easy to operate and control.
Accompanying drawing explanation
Fig. 1 is the polyurethane foam spheroid manufacture method flow chart of prior art;
Fig. 2 is the polyurethane foam spheroid manufacture method flow chart of the embodiment of the present invention 1;
Fig. 3 is the schematic diagram that the present invention paints in mould inner surface spraying mould oil and spraying mould;
Fig. 4 is that the present invention places the schematic diagram of movable block to mould inner surface.
Fig. 5 is the schematic diagram that the present invention places inflatable bladder in mould.
Fig. 6 is the schematic diagram that the present invention injects urethane raw slurries.
Fig. 7 is the schematic diagram of matched moulds of the present invention and polymerisation.
Fig. 8 is the schematic diagram vacuumized mould after polymerisation of the present invention completes.
Fig. 9 is die sinking schematic diagram of the present invention;
Figure 10 is the schematic diagram that product after split cavity of the present invention takes out inflatable bladder and movable block;
Figure 11 is the finished product schematic diagram that polyurethane foam spheroid manufacture method of the present invention obtains.
Wherein, the implication that each Reference numeral represents is:
1-foaming molding mold, 2-mould inner surface, 3-movable block, 4-inflatable bladder, 5-product, 6-finished product.
Detailed description of the invention
Below in conjunction with accompanying drawing, the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
Embodiment 1
The manufacture method of the polyurethane foam hollow ball of the present embodiment, comprises following step:
(1) open foaming molding mold 1, spray releasing agent at mould inner surface 2;
(2) spray in mould to the mould inner surface 2 scribbling releasing agent again and paint;
(3) several movable blocks 3 are placed at mould inner surface 2;
(4) inflatable bladder 4 is put into the position that mould is limited by several movable blocks 3;
(5) urethane raw slurries are injected in foaming molding mold 1;
(6) matched moulds and polymerisation;
(7) foaming molding mold 1 inside is vacuumized;
(8) die sinking obtains product 5;
(9) take out inflatable bladder 4 and several movable blocks 3, get product 6.
Wherein, inflatable bladder 4 selects rubber ball, and several movable blocks 3 are the detachable inner surface being fixed on mould spaced reciprocally.Size and the movable block length of rubber ball can be selected in actual production as required, be used for regulating the hollowness of gained finished product 6.
Embodiment 2
The manufacture method of the polyurethane foam hollow ball of the present embodiment, comprises following step:
(1) open foaming molding mold 1, spray releasing agent at mould inner surface 2;
(2) several movable blocks 3 are placed at mould inner surface 2;
(3) inflatable bladder 4 is put into the position that mould is limited by several movable blocks 3 described;
(4) urethane raw is injected in foaming molding mold;
(5) matched moulds and polymerisation;
(6) die sinking obtains product;
(7) take out inflatable bladder 4 and movable block 3, get product.
Wherein, inflatable bladder 4 selects rubber ball, and several movable blocks 3 are detachable is spaced reciprocally fixed on mould inner surface 2, and movable block 3 is cylinder, and it is fixed on mould inner surface 2 by cylindrical bottom surface.Above-mentioned urethane raw comprises PPG, isocyanates and amines catalyst/organic tin catalyst.
Embodiment 3
The manufacture method of the polyurethane foam hollow ball of the present embodiment, comprises following step:
(1) open foaming molding mold 1, spray releasing agent at mould inner surface 2;
(2) several movable blocks 3 are placed at mould inner surface 2;
(3) inflatable bladder 4 is put into the position that mould is limited by several movable blocks 3 described;
(4) urethane raw is injected in foaming molding mold;
(5) matched moulds and polymerisation;
(6) foaming molding mold 1 inside is vacuumized;
(7) die sinking obtains product;
(8) take out inflatable bladder 4 and movable block 3, get product.
Wherein, several movable blocks 3 detachable inner surface being fixed on mould spaced reciprocally.Size and the movable block length of rubber ball can be selected in actual production as required, be used for regulating the hollowness of gained finished product 6.
Embodiment 4
The manufacture method of the polyurethane foam hollow ball of the present embodiment, comprises following step:
(1) open foaming molding mold 1, spray releasing agent at mould inner surface 2;
(2) spray in mould to the mould inner surface 2 scribbling releasing agent again and paint;
(3) several movable blocks 3 are placed at mould inner surface 2;
(4) inflatable bladder 4 is put into the position that mould is limited by several movable blocks 3;
(5) urethane raw slurries are injected in foaming molding mold 1;
(6) matched moulds and polymerisation;
(7) die sinking obtains product 5;
(8) take out inflatable bladder 4 and several movable blocks 3, get product 6.
Wherein, inflatable bladder 4 selects rubber ball, and several movable blocks 3 are detachable is spaced reciprocally fixed on mould inner surface 2, and movable block 3 is cylinder, and it is fixed on mould inner surface 2 by cylindrical bottom surface.Above-mentioned urethane raw comprises PPG, isocyanates and amines catalyst/organic tin catalyst.
Last it is noted that these are only the preferred embodiments of the present invention; be not limited to the present invention; although with reference to embodiment to invention has been detailed description; for a person skilled in the art; it still can be modified to the technical scheme described in previous embodiment; or equivalent replacement is carried out to wherein portion of techniques feature; but it is within the spirit and principles in the present invention all; any amendment of doing, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. a manufacture method for polyurethane foam hollow ball, is characterized in that, comprises following step:
(1) foaming molding mold is opened, at mould inner surface spraying releasing agent;
(2) several movable blocks are placed at mould inner surface, an inflatable bladder is put into the position that mould is limited by several movable blocks described, several movable blocks described are detachable is spaced reciprocally fixed on described mould inner surface, described movable block is cylinder, and described mould inner surface is fixed in cylinder bottom surface;
(3) urethane raw is injected in foaming molding mold;
(4) matched moulds and polymerisation;
(5) die sinking obtains product;
(6) take out described inflatable bladder and described movable block, get product.
2. the manufacture method of polyurethane foam hollow ball according to claim 1, is characterized in that, also vacuumizes foaming molding mold between described (4) step and (5) step.
3. the manufacture method of polyurethane foam hollow ball according to claim 1, is characterized in that, also carries out following steps between described (1) step and (2) step: spray in mould to the mould inner surface scribbling releasing agent and paint.
4., according to the manufacture method of the arbitrary described polyurethane foam hollow ball of claims 1 to 3, it is characterized in that, described urethane raw comprises PPG, isocyanates and amines catalyst/organic tin catalyst.
5., according to the manufacture method of the arbitrary described polyurethane foam hollow ball of claims 1 to 3, it is characterized in that, described inflatable bladder is rubber ball.
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CN201310136525.3A CN103252862B (en) | 2013-04-18 | 2013-04-18 | A kind of manufacture method of polyurethane foam hollow ball |
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CN201310136525.3A CN103252862B (en) | 2013-04-18 | 2013-04-18 | A kind of manufacture method of polyurethane foam hollow ball |
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CN103252862A CN103252862A (en) | 2013-08-21 |
CN103252862B true CN103252862B (en) | 2015-12-23 |
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Families Citing this family (4)
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CN103507196B (en) * | 2013-09-13 | 2015-11-18 | 湖南亚太实业有限公司 | A kind of large-scale foaming decoration part processing method |
CN106273183A (en) * | 2016-08-10 | 2017-01-04 | 南通辉宏康复器材有限公司 | A kind of PU fills tire manufacturing process |
CN107116814A (en) * | 2017-05-22 | 2017-09-01 | 蒋静华 | A kind of inflatable elastic spheroid and preparation method thereof |
CN113929868B (en) * | 2021-09-24 | 2023-04-07 | 北京理工大学 | Explosion-proof and impact-resistant structure based on flexible ball and preparation method of explosion-proof and impact-resistant flexible ball |
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US4550466A (en) * | 1982-05-14 | 1985-11-05 | Taprogge Gesellschaft Mbh | Cleaning elements for inside cleaning of the tubes of tube-type heat exchangers and method of manufacturing same |
CN1105929A (en) * | 1994-05-31 | 1995-08-02 | 何昌宪 | production method and device of safety helmet |
CN1344611A (en) * | 2000-09-28 | 2002-04-17 | 谢孟峰 | Hollow PU Foaming part-forming process and mold |
CN1671533A (en) * | 2002-07-29 | 2005-09-21 | 陶氏环球技术公司 | Molded parts with discontinuous fabric surface areas and processes for their production |
CN1843530A (en) * | 2006-04-30 | 2006-10-11 | 汪永国 | Solid spring ball and process for making same |
CN101137483A (en) * | 2005-07-07 | 2008-03-05 | 施密德建筑塑料有限公司 | Method for producing foam rubber moulded parts and moulded parts produced by this method |
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2013
- 2013-04-18 CN CN201310136525.3A patent/CN103252862B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4550466A (en) * | 1982-05-14 | 1985-11-05 | Taprogge Gesellschaft Mbh | Cleaning elements for inside cleaning of the tubes of tube-type heat exchangers and method of manufacturing same |
CN1105929A (en) * | 1994-05-31 | 1995-08-02 | 何昌宪 | production method and device of safety helmet |
CN1344611A (en) * | 2000-09-28 | 2002-04-17 | 谢孟峰 | Hollow PU Foaming part-forming process and mold |
CN1671533A (en) * | 2002-07-29 | 2005-09-21 | 陶氏环球技术公司 | Molded parts with discontinuous fabric surface areas and processes for their production |
CN101137483A (en) * | 2005-07-07 | 2008-03-05 | 施密德建筑塑料有限公司 | Method for producing foam rubber moulded parts and moulded parts produced by this method |
CN1843530A (en) * | 2006-04-30 | 2006-10-11 | 汪永国 | Solid spring ball and process for making same |
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Effective date of registration: 20170605 Address after: 526000 Guangdong city of Zhaoqing Province Gaoyao District Jiao Tang Zhen Sha Industrial Park (1-3 plant) Patentee after: Zhaoqing supreme Plastic Hardware Products Co.,Ltd. Address before: 526100 Guangdong city of Zhaoqing Province Gaoyao City Industrial Park, Sha Jiao Tang Zhen Gaoyao first plastic hardware products Co. Ltd. Patentee before: Zhou Guanglin |
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