A kind of method for the sheep known for its fine thick wool leather dyeing
Technical field
The present invention relates to the fur manufacturing field, be specifically related to a kind of method for the sheep known for its fine thick wool leather dyeing.
Background technology
The sheep known for its fine thick wool skin is one of local and special products commodity of China's tradition outlet, and it is solid with dermatotome, and light warming , Mao Hui smoothness is attractive in appearance, and undulations is crooked and have won fame both at home and abroad, and is that resource is produced in the advantageous herding in area, Ningxia.Existing sheep known for its fine thick wool leather dyeing is generally finished in rotary drum, because therefore uneven the and serious phenomenon that fades of dyeing appears in the particularity of sheep known for its fine thick wool skin institutional framework and its fur easily.So method that is necessary to provide a kind of even dyeing, is used for the sheep known for its fine thick wool leather dyeing.
Summary of the invention
The purpose of this invention is to provide a kind of method for the sheep known for its fine thick wool leather dyeing, it can dye uniformly to the sheep known for its fine thick wool skin.
For achieving the above object, the present invention adopts following technical scheme: a kind of technology for the sheep known for its fine thick wool leather dyeing, comprise the processing that eases back of sheep known for its fine thick wool skin after the tanning airing handled, ease back and successively the sheep known for its fine thick wool skin is carried out that retanning is handled and dyeing is handled after handling, described dyeing is handled and being included in once dye in the rotary drum processing and secondary dyeing processing, described once dyeing is handled and to be referred to that it is 1/2~3/5 rotary drum of the total consumption of dyestuff that the sheep known for its fine thick wool skin is placed the dyestuff dosage, under 30~32 ℃ of conditions, dye system 30~35min, once dyeing is carried out fixation treatment one time after handling, again the dyestuff of surplus is added after fixation treatment and carry out secondary dyeing to the rotary drum and handle, the temperature that secondary dyeing is handled is 60~65 ℃, carries out the secondary fixation treatment again after secondary dyeing is handled.
By, successively twice pair of sheep known for its fine thick wool skin dyes and fixation treatment, and can avoid dyeing inequality and the unsharp phenomenon of thick coating pore guarantee the soft and soggy look of sheep known for its fine thick wool evenly and the processing time of whole dyeing weak point.Here said " once dyeing handle to refer to the sheep known for its fine thick wool skin is placed the dyestuff dosage be 1/2~3/5 rotary drum of the total consumption of dyestuff " refers to once dye and handles dyestuff dosage war one, two dyeing and handle 1/2~3/5 of used dyestuff summation.
Further scheme is:
Once dyeing is handled rotary drum and is dyed the dyestuff that contains 0.008~0.016g/L in the slurry, and the PH that dyes slurry is 3.5~4, dyes the acetic acid of the salt that also comprises 6.0~7.5g/ml in the slurry, 1~2ml/L quaternary ammonium salt aldehyde-free colour stabilizer, 0.02g/L.
A described fixation treatment is to add formic acid handle 10~15min under 35~38 ℃ of conditions dying in the slurry, the formic acid that contains 0.1~0.15ml/L in the slurry after stain slurry is dyed in the formic acid adding in the fixation treatment, described secondary fixation treatment is to continue to add formic acid handle 15~20min under 25~30 ℃ of conditions dying in the slurry, and the formic acid addition is 1.5~2.5 times of formic acid addition in fixation treatment in the secondary fixation treatment.
The temperature that retanning is handled is 30~35 ℃, and the time is 10~12h, and retanning is handled used retanning agent and formed by fatty alcohol-polyoxyethylene ether, acetic acid, network tanning agent mixed preparing.
Described once dyeing is also carried out ungrease treatment to the sheep known for its fine thick wool skin before handling, and the solution of ungrease treatment comprises the washing powder of 0.6~0.7mol/L fatty alcohol-polyoxyethylene ether and 5~7g/L, and the time of ungrease treatment is 20~25min, and temperature is 40~45 ℃.
Utilize segmentation that the sheep known for its fine thick wool skin is dyeed among the application, guarantee even dyeing, passed through the dyeing control of process condition simultaneously, the processing time that shortens the whole technology of dyeing can be arranged, improve the efficient of sheep known for its fine thick wool skin production and the quality of finished product sheep known for its fine thick wool skin.
The specific embodiment
Below come by the specific embodiment that the invention will be further described, but it should not be construed as limiting the scope of the invention.Used retanning agent is made of the material of following constituent content among the embodiment 1~3: 20g/L acrylic resin retanning agent, 1.5mol/L acetic acid, 0.5mol/L fatty alcohol-polyoxyethylene ether and water; Retanning agent and water add according to the amount of 20ml/L.
Embodiment 1
A) at normal temperatures to the sheep known for its fine thick wool skin that tanning is dry after the handling processing that eases back;
B) the sheep known for its fine thick wool skin after easing back is carried out retanning and handle, the temperature that retanning is handled is 30 ℃, and the time is 12h;
C) the sheep known for its fine thick wool skin after the retanning processing is carried out ungrease treatment in degreaser, the solution of ungrease treatment comprises the washing powder of 0.6mol/L fatty alcohol-polyoxyethylene ether and 5g/L, and the time of ungrease treatment is 20min, and temperature is 45 ℃;
D) the sheep known for its fine thick wool skin after the ungrease treatment is washed, the processing of once dyeing after the washing, the processing controls temperature that once dyes is 32 ℃, time 35min, the PH that dyes slurry in the rotary drum is 3.5, rotary drum dyes the dyestuff that contains 0.01g/L in the slurry, dyes the acetic acid of the salt that also comprises 6.0g/ml in the slurry, 1ml/L quaternary ammonium salt aldehyde-free colour stabilizer, 0.02g/L.
E) add formic acid in the rotary drum after once dyeing is handled and carry out fixation treatment one time, the content that formic acid dyes in rotary drum in the oar is 0.1ml/L, and the temperature of a fixation treatment is 38 ℃, time 10min;
F) the sheep known for its fine thick wool skin after fixation treatment being carried out secondary dyeing handles, the temperature that secondary dyeing is handled is that 65 ℃, time are 35min, the dosage of dyestuff is 1 times that the dyestuff dosage is handled in once dyeing, adds an amount of salt, quaternary ammonium salt aldehyde-free colour stabilizer, acetic acid simultaneously;
G) add formic acid in the rotary drum after handling to secondary dyeing and carry out the secondary fixation treatment, the temperature of fixation treatment is 30 ℃, time 15min; The formic acid addition is 2.5 times of formic acid addition in fixation treatment in the secondary fixation treatment.
H) the sheep known for its fine thick wool skin after utilizing washing powder to fixation is soaped, and dries after the cleaning, carries out other process operations then.
Embodiment 2
A) at normal temperatures to the sheep known for its fine thick wool skin that tanning is dry after the handling processing that eases back;
B) the sheep known for its fine thick wool skin after easing back is carried out retanning and handle, the temperature that retanning is handled is 30 ℃, and the time is 12h;
C) the sheep known for its fine thick wool skin after the retanning processing is carried out ungrease treatment in degreaser, the solution of ungrease treatment comprises the washing powder of 0.7mol/L fatty alcohol-polyoxyethylene ether and 7g/L, and the time of ungrease treatment is 20min, and temperature is 40 ℃;
D) the sheep known for its fine thick wool skin after the ungrease treatment is washed, the processing of once dyeing after the washing, the processing controls temperature that once dyes is 30 ℃, time 35min, the PH that dyes slurry in the rotary drum is 4, rotary drum dyes the dyestuff that contains 0.008g/L in the slurry, dyes the acetic acid of the salt that also comprises 6.0g/ml in the slurry, 1ml/L quaternary ammonium salt aldehyde-free colour stabilizer, 0.02g/L.
E) add formic acid in the rotary drum after once dyeing is handled and carry out fixation treatment one time, the content that formic acid dyes in rotary drum in the oar is 0.1ml/L, and the temperature of a fixation treatment is 35 ℃, time 15min;
F) the sheep known for its fine thick wool skin after fixation treatment being carried out secondary dyeing handles, the temperature that secondary dyeing is handled is that 60 ℃, time are 35min, the dosage of dyestuff is 1 times that the dyestuff dosage is handled in once dyeing, adds an amount of salt, quaternary ammonium salt aldehyde-free colour stabilizer, acetic acid simultaneously;
G) add formic acid in the rotary drum after handling to secondary dyeing and carry out the secondary fixation treatment, the temperature of fixation treatment is 25 ℃, time 15min; The formic acid addition is 2.5 times of formic acid addition in fixation treatment in the secondary fixation treatment.
H) the sheep known for its fine thick wool skin after utilizing washing powder to fixation is soaped, and dries after the cleaning, carries out other process operations then.
Embodiment 3
A) at normal temperatures to the sheep known for its fine thick wool skin that tanning is dry after the handling processing that eases back;
B) the sheep known for its fine thick wool skin after easing back is carried out retanning and handle, the temperature that retanning is handled is 32 ℃, and the time is 10h;
C) the sheep known for its fine thick wool skin after the retanning processing is carried out ungrease treatment in degreaser, the solution of ungrease treatment comprises the washing powder of 0.6mol/L fatty alcohol-polyoxyethylene ether and 7g/L, and the time of ungrease treatment is 20min, and temperature is 40 ℃;
D) the sheep known for its fine thick wool skin after the ungrease treatment is washed, the processing of once dyeing after the washing, the processing controls temperature that once dyes is 30 ℃, time 35min, the PH that dyes slurry in the rotary drum is 4, rotary drum dyes the dyestuff that contains 0.016g/L in the slurry, dyes the acetic acid of the salt that also comprises 6.0g/ml in the slurry, 2ml/L quaternary ammonium salt aldehyde-free colour stabilizer, 0.02g/L.
E) add formic acid in the rotary drum after once dyeing is handled and carry out fixation treatment one time, the content that formic acid dyes in rotary drum in the oar is 0.1ml/L, and the temperature of a fixation treatment is 38 ℃, time 15min;
F) the sheep known for its fine thick wool skin after fixation treatment being carried out secondary dyeing handles, the temperature that secondary dyeing is handled is that 60 ℃, time are 40min, the dosage of dyestuff is 1 times that the dyestuff dosage is handled in once dyeing, adds an amount of salt, quaternary ammonium salt aldehyde-free colour stabilizer, acetic acid simultaneously;
G) add formic acid in the rotary drum after handling to secondary dyeing and carry out the secondary fixation treatment, the temperature of fixation treatment is 30 ℃, time 15min; The formic acid addition is 2.5 times of formic acid addition in fixation treatment in the secondary fixation treatment.
H) the sheep known for its fine thick wool skin after utilizing washing powder to fixation is soaped, and dries after the cleaning, carries out other process operations then.