CN103232907A - Ultrasonic water-based cleaning agent component and preparation method thereof - Google Patents

Abstract

The invention discloses an ultrasonic water-based cleaning agent component. The component comprises the following ingredients by mass percent: a composite surfactant, an organic biological cosolvent and additives, wherein the composite surfactant consists of alpha-olefin sodium sulfonate, deodecyl polyoxyethylene ether and alkylphenol polyoxyethylene ether; the organic biological cosolvent is absolute ethyl alcohol, borate is sodium borate and sodium gluconate; and the additives are water glass, benzotriazole, potassium benzoate, sodium carbonate and chelating agent urea. The cleaning agent is particularly suitable for washing the prismatic component with a complicated shape and complicated inner cavity, the high efficiency and the high cleaning degree can be simultaneously achieved, and the technological process such as the oil removal, the rust prevention and the phosphorization can be completed within a short time under the effect of the ultrasonic.

Description

Component of ultrasonic aqueous cleaning agent and preparation method thereof

Technical field

The present invention relates to component of a kind of ultrasonic aqueous cleaning agent and preparation method thereof.

Background technology

Cleaning industry is to produce along with the needs of industrialization and modernization process and social production and grow up, and it is auxilliary that present domestic cleaning is cleaned based on matting, physics.In physics cleaned, water jet cleaned and occupies an leading position, and is in Rapid development stage.Dry ice cleaning, PIG cleaning, ultrasonic cleaning etc. are pollution-free, and flexible operation, free from corrosion physics cleaning technique are promoted the use of just fast.

In industry cleaning field, compare other multiple situation modes, ultrasonic cleaning shows huge advantage, particularly in specialized, integrated manufacturing enterprise, gradually with ultrasonic cleaning replace that tradition is soaked, scrubbed, methods such as pressure washing, vibration cleaning and steam flushing.Its principle is that ultrasonic generator sends high-frequency oscillation signal, become the high frequency mechanical oscillation by energy transfer machine, when in medium, propagating, produce penetrance and cavitation shockwave, because cavitation bubble has produced the huge impact ripple when breaking, the part of schmutzband is under shock action, these class small bubbles are stripped from, dispersion, emulsification, come off, the synchronous expansion of acoustic pressure, contraction acts on schmutzband repeatedly in addition, schmutzband is stripped from from level to level, bubble is infiltration inwards progressively, is peeled off fully up to dirt.Here it is " cavitation secondary reaction ".In the ultrasonic cleaning, scavenging solution produces impact to dirt in ultrasonic vibration.To there be the component of complex configuration, inner chamber, pore and many ribs to clean up with regard to being easy to like this, while high-level efficiency and high cleaning degree, particularly in technological processs such as general oil removing, antirust, phosphatization, under action of ultrasonic waves, only need very short time just can finish cleaning, can improve 3-10 doubly than traditional method efficient.

Summary of the invention

The technical problem to be solved in the present invention provides a kind of component that can carry out the ultrasonic aqueous cleaning agent that high-level efficiency and high cleaning degree clean to the component that complex configuration is arranged and preparation method thereof.

The present invention solves the problems of the technologies described above with following technical scheme:

The component of ultrasonic aqueous cleaning agent of the present invention and mass percent are:

Component

Content (mass percent)

Complexed surfactant	30-40%
		The organic-biological solubility promoter	5-10%
Borate	1-3%
		Sunmorl N 60S	3-8%
Additive	3-5%
		Water	Residue

Wherein:

Complexed surfactant is made up of according to oxygen Vinyl Ether, 35-50% alkylphenol polyoxyethylene mass ratio 10-15% α-sodium olefin sulfonate, 35-50% dodecyl.

The organic-biological solubility promoter is dehydrated alcohol.

Borate is Sodium Tetraborate.

Additive is the water glass that accounts for clean-out system total mass 1-2.5%, the benzotriazole of 0.6-1.2%, the potassium benzoate of 0.2-0.3%, the yellow soda ash of 0.5-1.5%; The sequestrant urea that also has 0.7-1.1%.

The preparation method is:

1. used tensio-active agent and sequestrant urea are mixed 0.5h at 60 ℃, 180-200r/min under stirring;

2. yellow soda ash is added in the mixture of step 1 gained, under 200-220r/min, stir 0.5-1h, add with 50% of deionized water total amount;

3. water glass, benzotriazole, potassium benzoate are dissolved in 35～45% deionized water, 50-200r/min stirs, 60 ℃ of temperature, 0.5h;

4. after the organic-biological solubility promoter being dissolved in 15～5% remaining deionized waters, mix in the solution of equivalent adding above-mentioned steps 2 and step 3 gained respectively, then with two kinds of mixed solution remix, under 60 ℃ of temperature, 200-220r/min, stir 0.5-1h, obtain transparent flaxen liquid ultrasonic cleaning agent.

Clean-out system of the present invention is particularly suitable for cleaning the component of complex configuration, inner chamber and many ribs, can realize high-level efficiency and high cleaning degree simultaneously, particularly in technological processs such as general oil removing, antirust, phosphatization, under action of ultrasonic waves, only need very short time just can finish.

Embodiment

Embodiment 1:

Embodiment 2:

Embodiment 3:

。

The fundamental property index of the clean-out system that embodiment 1 obtains is:

1. the component of a ultrasonic aqueous cleaning agent is characterized in that being made up of following component and mass percent:

Component	Mass percentage content
		Complexed surfactant	30-40%
The organic-biological solubility promoter	5-10%
		Borate	1-3%
Sunmorl N 60S	3-8%
		Additive	3-5%
Water	Residue

2. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that complexed surfactant is that α-sodium olefin sulfonate of 10-15%, the dodecyl of 35-50% are formed according to the alkylphenol polyoxyethylene of oxygen Vinyl Ether, 35-50% by mass ratio.

3. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that the organic-biological solubility promoter is dehydrated alcohol.

4. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that borate is Sodium Tetraborate.

5. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that additive is the water glass that accounts for clean-out system total mass 1-2.5%, the benzotriazole of 0.6-1.2%, the potassium benzoate of 0.2-0.3%, the yellow soda ash 0.5-1.5% of 0.5-1.5%; The sequestrant urea that also has 0.7-1.1%.

6. ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that the preparation method is:

⑴ stir 0.5h with used tensio-active agent and urea under 60 ℃, 180-200r/min;

⑵ add yellow soda ash in the mixture of step 1 gained, stirs 0.5-1h under 200-220r/mi, adds half of deionized water total amount;

⑶ be dissolved in 35～45% deionized water to water glass, benzotriazole, potassium benzoate, stirs 0.5h under 60 ℃ of temperature, 50-200r/min;

⑷ after be dissolved in 15～5% remaining deionized waters to the organic-biological solubility promoter, mix in the solution of equivalent adding above-mentioned steps 2 and step 3 gained respectively, then with two kinds of mixed solution remix, under 60 ℃ of temperature, 200-220r/min, stir 0.5-1h, obtain transparent flaxen liquid ultrasonic cleaning agent.

The invention discloses a kind of ultrasonic aqueous cleaning agent component, be grouped into by the one-tenth of following mass percent: complexed surfactant is made up of according to oxygen Vinyl Ether, alkylphenol polyoxyethylene α-sodium olefin sulfonate, dodecyl; The organic-biological solubility promoter is dehydrated alcohol, and borate is Sodium Tetraborate, also has Sunmorl N 60S; Additive is water glass, benzotriazole, potassium benzoate, yellow soda ash and sequestrant urea.Clean-out system of the present invention is particularly suitable for cleaning the component of complex configuration, inner chamber and many ribs, can realize high-level efficiency and high cleaning degree simultaneously, particularly in technological processs such as general oil removing, antirust, phosphatization, under action of ultrasonic waves, only need very short time just can finish.

Claims (6)

1. the component of a ultrasonic aqueous cleaning agent is characterized in that being made up of following component and mass percent:

Component Mass percentage content Complexed surfactant 30-40% The organic-biological solubility promoter 5-10% Borate 1-3% Sunmorl N 60S 3-8% Additive 3-5% Water Residue.

2. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that complexed surfactant is that α-sodium olefin sulfonate of 10-15%, the dodecyl of 35-50% are formed according to the alkylphenol polyoxyethylene of oxygen Vinyl Ether, 35-50% by mass ratio.

3. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that the organic-biological solubility promoter is dehydrated alcohol.

4. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that borate is Sodium Tetraborate.

5. the component of ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that additive is the water glass that accounts for clean-out system total mass 1-2.5%, the benzotriazole of 0.6-1.2%, the potassium benzoate of 0.2-0.3%, the yellow soda ash 0.5-1.5% of 0.5-1.5%; The sequestrant urea that also has 0.7-1.1%.

6. ultrasonic aqueous cleaning agent as claimed in claim 1 is characterized in that the preparation method is:

⑴ stir 0.5h with used tensio-active agent and urea under 60 ℃, 180-200r/min;

⑵ add yellow soda ash in the mixture of step 1 gained, stirs 0.5-1h under 200-220r/mi, adds half of deionized water total amount;

⑶ be dissolved in 35～45% deionized water to water glass, benzotriazole, potassium benzoate, stirs 0.5h under 60 ℃ of temperature, 50-200r/min;

⑷ after be dissolved in 15～5% remaining deionized waters to the organic-biological solubility promoter, mix in the solution of equivalent adding above-mentioned steps 2 and step 3 gained respectively, then with two kinds of mixed solution remix, under 60 ℃ of temperature, 200-220r/min, stir 0.5-1h, obtain transparent flaxen liquid ultrasonic cleaning agent.