CN103214060A - Large-capacity reactor capable of initiatively distinguishing reaction endpoint and used for photocatalytic wastewater degradation - Google Patents

Abstract

The invention relates to a large-capacity reactor capable of initiatively distinguishing a reaction endpoint and used for photocatalytic wastewater degradation, which belongs to the technical field of wastewater treatment. Various problems of microwave energy waste, excessively small single-pot wastewater treatment capacity, insufficient intensity in large internal circulation, excessively short bubble rising path, low oxygen supply concentration ratio in a key region, excessively weak catalyst particle intercepting link, difficulty in distinguishing the ending time of degradation reaction, incapability of powerfully dissipating catalyst agglomerates in situ and the like exist in the conventional related technology. In order to solve the series problems, a metal cage is used for constraining microwaves for realizing the large capacity expansion of the reactor; due to adoption of the structure, the oxygen supply in the key reaction region is enhanced; the large-capacity reactor comprises an external cascaded tertiary reverse-washing filter for intercepting a catalyst; due to adoption of the structure, the catalyst agglomerates can be powerfully dissipated in situ, and simultaneously quartz tubes are incidentally subjected to ultrasound cleaning; and due to adoption of the structure, related power sources can be automatically and immediately turned off when the degradation reaction reaches the endpoint, and thus the energy waste and secondary pollution are avoided.

Description

Initiatively the photochemical catalysis waste water of recognition reaction terminal point is degraded and is used the large vol reactor

Technical field

The large vol reactor is used in the photochemical catalysis waste water degraded that the present invention relates to a kind of active recognition reaction terminal point, belongs to the CO2F technical field of waste water processing.

Background technology

Microwave and photo catalysis degradation treatment technology, is quite paid close attention to effectively at the innoxious process for treating that contains the organic pollutant trade effluent in recent years as a kind of.

About the microwave and photo catalysis degradation technique,, can referring to publication number the Chinese patent application case of CN102260003A as an example.

The disclosure number is the Chinese patent application case of CN102260003A, be as excitaton source with microwave, excite electrodeless ultraviolet lamp emission ultraviolet ray, be mixed with the suspension liquid of photocatalyst titanium dioxide in the liquid internal irradiation, this electrodeless ultraviolet lamp is shrouded by silica tube to be protected, there is pneumatic pump to continue to inject air to this silica tube inner chamber, the air that is overflowed by quartzy chamber is via pipeline and the micro porous aeration head UNICOM that is positioned at reactor bottom, the lower zone of this inside reactor is the aeration zone, the upper area of this inside reactor is the microwave and photo catalysis reaction zone, this scheme is also with the built-in membrane separation assemblies of reactor, carry the water of analysing after the purification, and realize that with this membrane separation assemblies holding back again of photocatalyst titanium dioxide fine particles use; This scheme is also set up dividing plate between electrodeless ultraviolet light source and membrane separation assemblies, be used to prevent the radiation injury of ultraviolet ray to the membrane separation assemblies of organic matter; Feed the air of inside reactor, part is participated in the photocatalytic degradation reaction that relies on photocatalyst titanium dioxide directly, some air, under the direct irradiation of UV-light, generate a certain amount of ozone, the ozone of this generation is also being brought into play the direct oxidative degradation at organic pollutant certainly.

The disclosure is number for the Chinese patent application case of CN102260003A has undoubtedly played very important pushing effect for the progress of microwave and photo catalysis waste water degradation technique, and its research staff is admirable in this field institute unfolded work.

Based on the meaning of sincere admiration, and, the common striving direction, what will talk below us is problem.

Below the problem that will speak of has ten; These ten problems are ten problems arranged side by side; The priority of its ordering only is to consider for discussing easily.

One of problem:

The disclosure number is the Chinese patent application case of CN102260003A, its membrane separation assemblies that is used to tackle the catalyzer titanium dioxide fine particles is to be placed in the reactor inner chamber, be immersed among the process object liquid, and rely on the ozone bubbles that contains of ascension to wash away membrane separation assemblies, it is adsorbed to remove its surface by this, the catalyst particles that is detained, reach the recovery of catalyst particles, utilize purpose again, simultaneously, membrane separation assemblies also is to rely on this mode self-cleaning and keep its separating power, so, based on this structure, can only select for use commercial with curtain formula hollow fiber film assembly or plate film assembly, and this membrane separation assemblies is need be immersed in the context of strong oxidizing property of ozone bubbles ascension, therefore, oxidation tolerance to membrane separation assemblies must have requirement, the organic membrane separation assembly of common material can not tolerate such environment for use, so can only select the membrane separation assemblies of PVDF material for use, this point clearly illustrates that in open the 0009th section literal of text of this case and claim 3; Its material cost of the filter membrane of the oxidation tolerance that this kind needs are special is higher, and its commercially available price also is higher than common organic micro-filtration membrane module of non-oxidation tolerance requirement certainly; In other words, the frame mode of this case causes the material of membrane separation assemblies to be limited to expensive PVDF material.Have again, UV-light possible in the device is revealed, may touch the organic membrane assembly, this also the organic membrane assembly material in the claimed apparatus can resist ultraviolet light irradiation, from this point, based on the organization plan of this device, the material of organic membrane separation assembly also can only be limited in expensive PVDF material.

The organic membrane assembly has its conspicuous advantage compared to the ceramic filter assemblies; About this point, for the personage of filtering technique specialty, be known, here do not launch to give unnecessary details.

Can so, under the prerequisite of using the organic material membrane module, bypass this PVDF filter membrane material limitation? this is the problem that needs solve, and this is one of problem.

Two of problem:

Scouring force in view of described ascension bubble, cleaning capacity is more weak, therefore, can only select other filter opening aperture of bigger micro-filtration level for use with its aperture of membrane separation assemblies that this cleaning mode is used, other filter opening aperture of this micro-filtration level is the 0.1-0.2 micron, about this point, in open the 0009th section literal of text of this case and claim 3, have clearly equally and limit, this kind filter opening aperture limits, type selecting from the such membrane separation assemblies of this case, built-in and soak use-pattern, the self-cleaning method of ascension bubble, be inevitable, can only limit its filter opening aperture in the micro-filtration rank.In other words, this its scouring force of mode that washes away with the ascension bubble, cleaning power too a little less than, to such an extent as to can't tackle the more filter membrane of small-bore at all, thus, in this case device, the filter membrane aperture is limited between 0.1 micron-0.2 micron, is the inevitable choice of not discussing leeway.

The filter opening aperture of so-called 0.1-0.2 micron, if change a measure unit, corresponding is exactly the filter opening aperture of 100-200 nanometer; Is what notion that? with 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can be tackled must be more than 100 nanometers, and can't be blocked less than the catalyst particles of 100 nanometers; In other words, less than the catalyst particles of 100 nanometers will directly penetrate, by the filter opening of membrane module, sneak among the so-called water purification that the DeR device exported.

The particle diameter and the photocatalyst dosage form selection of the related photocatalyst of the ultraviolet catalytic DeR of need having a talk now.

The professional person who is engaged in photocatalytic degradation research knows, with the photochemical degradation reaction of uv light induction, its catalyzer multiselect titanium dioxide fine particles catalyzer; At present, on laboratory level, developed the photodegradation particle catalyst based on the optically catalytic TiO 2 characteristic various in style, certainly, the photodegradation catalyzer that these different preparation methods form, its particle diameter also is various; Its particle diameter of photocatalyst that different preparation methods make is little of 20 nanometers, to also promptly 100 microns of 100000 nanometers, has greatly, wherein is no lack of the photocatalyst kind of excellent performance; But because the restriction of the evaluation of performance permanent stability, preparation cost and market expansion or the like aspect factor, most its deliverabilities of described photocatalyst only are confined to laboratory level, and do not have to form extensive commercially available production level; At present known can make a big purchase in large quantities commercially available can actual a large amount of photocatalysts that are used for the UV-light wave band that use be famous gas phase titanium dioxide P25; Its concrete art-recognized meanings of gas phase titanium dioxide P25, the insider knows, does not here launch to give unnecessary details; The median size of gas phase titanium dioxide P25 is 21 nanometers; Gas phase titanium dioxide P25 performance is not very optimum, but, its stable performance, key is can make a big purchase in large quantities to obtain on market, and can on technical scale, use in a large number, therefore, in the photochemical catalysis specialized laboratory also usually with the P25 catalyzer be used as weighing various self-made photocatalyst catalytic performances with reference to pointer or contrast pointer, in fact, characteristics in view of the ultraviolet catalytic DeR, the photocatalyst that dispersity is high more, be fit to the needs of this type reaction, that is to say, the photocatalyst of median size about 21 nanometers its catalyst interfacial area that can provide, anti-sedimentation capacity, catalytic performance permanent stability or the like aspect, comprehensive, be optimal.Say simply, at present good and cheap, the photocatalyst of the UV-light wave band of the ready-made commercially available commercial grade that can actually make a big purchase in large quantities, use, be exactly median size be the gas phase titanium dioxide P25 catalyzer of 21 nanometers; At plant-scale application, this median size is that the photocatalyst of 21 nanometers is actual first-selections.

Above address, the disclosure number is the Chinese patent application case of CN102260003A, it is used to tackle the membrane module of photocatalyst, be to wash away the stripping film assembly surface adsorbed with the ascension bubble, sedimentary catalyst particles, yet, its scouring force of mode that this kind washes away with the ascension bubble, cleaning power too a little less than, to such an extent as to can't tackle the more filter membrane of small-bore at all, therefore, in this case device, the filter membrane aperture is limited at micro-filtration filter opening rank between 0.1 micron-0.2 micron, change a measure unit, in this case device, the filter membrane aperture is limited at the micro-filtration filter opening rank between 100 nanometers-200 nanometer, and this is the inevitable choice of not discussing leeway; The micro-filtration filter opening that this case does not have between selectable 100 nanometers-200 nanometer can't be tackled the gas phase titanium dioxide P25 particle that aforesaid median size is 21 nanometers certainly; So, if use the P25 photocatalyst, this catalyzer will can't be tackled fully, and flows in the so-called water purification, forms secondary pollution, certain heavy losses that also cause catalyzer and unrenewable; Even if use other kind for this reason and the titanium dioxide optical catalyst of special big particle diameter, collide because of mutual collision or with wall in its use, must also can produce a large amount of small particle size fragments, wherein particle diameter is less than the fragment of 100 nanometers, can not be tackled by the micro-filtration filter opening between 100 nanometers-200 nanometer equally, these small shredss also can see through its membrane module and enter among the so-called water purification, form secondary pollution.

As seen, the disclosure number is the Chinese patent application case of CN102260003A, and its cleaning scheme at the interception structure scheme of photocatalyst particulate and related film assembly is all undesirable.

Therefore, how under the prerequisite of this case advantage of incorporating things of diverse nature, reaching at the meticulous interception of photocatalyst particulate and reclaim usefulness again, is an important topic very worth thinking deeply about, and this is two of a problem.

Three of problem:

We know, liquid water body itself also can absorb the energy of microwave, and cause itself temperature-rise effect of processed liquid water body, and this temperature-rise effect of following wastewater treatment process and occurring, it but not the situation that we expected, in other words, microwave energy from magnetron is not used to excite electrodeless ultraviolet lamp fully, and have quite a few should only be used to excite the microwave energy of electrodeless ultraviolet lamp to be dissipated in described temperature-rise effect, the temperature-rise effect that this kind is not fond of has caused unnecessary microwave energy to waste, in view of above-mentioned publication number is the apparatus structure scheme that the Chinese patent application case of CN102260003A is showed, its rational approach, can only be to reduce the purpose that single jar of processing capacity is reached the unnecessary dissipation of reduction microwave in other words by the volume that reduces the microwave and photo catalysis reactor, about this point, clear suitable size of having expressed in this its embodiment of CN102260003A application case about this apparatus structure integral body, the preferred size correspondence that it is expressed be exactly a device that profile is very little, so, thus, the distance of reactor wall and microwave radiation source is little, the wastewater flow rate that contacts with microwave is little, waste water institute microwave energy absorbed is also little relatively, with it accordingly, single jar wastewater treatment capacity is therefore also little, more particularly, the pairing internal capacity of device suitable size expressed in the embodiment is 40 liters, also be that single jar of wastewater treatment capacity is 40 liters, promptly 0.04 cube, in other words, it is once a complete set of, substantial length of operation has only solved 0.04 cubical trade effluent, so, just need carry out many times by the repetition of head to the operation of the complete set of tail, adding up of its treatment capacity just has plant-scale meaning, so to say, just individual analogy roughly, single jar of 0.04 cube of such wastewater treatment capacity that its preferred structure size of this case is roughly corresponding, need to repeat 1000 times by the complete set of head to tail, substantial length of operation, its accumulation amount, just can reach 40 cubes such one have industrial level wastewater treatment capacity, so excessively loaded down with trivial details repetitive operation will cause manpower, the serious waste of material resources, as seen, this kind may not be fully up to expectations by its actual waste water degradation treatment efficient of scheme that CN102260003A showed.Therefore, how not cause more microwave energy wastes or to reduce under the prerequisite of microwave energy waste, increase single jar of wastewater treatment capacity, reduce the unnecessary too many of this intermittent type wastewater treatment equipment by the repetitive operation number of times of head to tail, improve its waste water treatment efficiency, be a significant technical problem that merits attention, this is three of a problem.

Four of problem:

This kind be by the scheme that CN102260003A showed, the bubble of the inner dispersed ascension of its retort for the cyclic motion of the relative big scale of driving a reaction jar internal liquid, is contributed inadequate slightly; Certainly, this weak point, in fact corresponding small size, the low capacity device of clear expression in CN102260003A scheme such as its embodiment, the influence that almost has nothing observable.From plant-scale application demand, undersized device that can not the divergence process amount does not have great magnetism certainly; So, as a kind of possibility, if there is certain mode can realize the significantly expansion of treatment capacity, under this situation, its importance of the cyclic motion of the relative big scale of retort internal liquid will highlight naturally; Imagining the possibility that this treatment capacity is significantly expanded, so, how to strengthen the cyclic motion of the relative big scale of retort internal liquid, is exactly a problem certainly, and this is four of a problem.

Five of problem:

Photochemical catalysis oxidizing reaction for the UV-light wave band, there is following so several key element can have influence on the efficient of this kinds of oxidation reaction, first ultraviolet wavelength, intensity, it two is particle diameters of photocatalyst, the usage quantity of photocatalyst in the unit volume reaction solution, himself catalytic performance or the like of photocatalyst, it three is that oxidized object is an organic concentration in the water body, oxidation complexity that the organic molecule structure is determined himself or the like, it four is sufficient degree of oxygen atmosphere, under the identical situation of other condition, the sufficient degree of oxygen atmosphere will become a very important key element that influences photochemical catalysis oxidative degradation ability.

As the scheme that CN102260003A showed, its numerous micro porous aeration head disperseds that are placed in reactor inner chamber bottom are in the bottom, and by its alleged water distribution board, make the effect of this micro porous aeration head dispersed arrangement become more very, certainly, this is for the situation of using relatively easy settled oarse-grained micron-sized photocatalyst, really there is its favourable one side, but, from another side, the mode that this micro porous aeration head dispersed is arranged, the supply of oxygen atmosphere too disperses, and in fact need most enhanced oxygen blowing the zone be the effective area of photochemical catalysis oxidation, because the Effective depth penetration of short wave ultraviolet in liquid water body has only about 20 centimetres, therefore, needing most enhanced oxygen blowing in fact is exactly zone within peripheral about 20 cm distance of silica tube with the effective area that promotes photochemical catalysis oxidation process, in other words, zone within about 20 cm distance of silica tube periphery is really to need enriched with oxygen atmosphere to supply with the zone that ensures, this regional oxygen atmosphere is supplied with strong more, and oxidizing reaction is also just carried out soon more; Especially especially, produce electrodeless ultraviolet emission in the microwave excitation mode, its characteristics can be accomplished high-power, high strength exactly, this is the strong point of this lamp type of electrodeless ultraviolet lamp, yet, just because of the superpower of its uv-radiation, high strength just more need mate with powerful oxygen atmosphere supply capacity, otherwise, that powerful uv-radiation ability is that major part has been wasted really just.Above address, as the scheme that CN102260003A showed, many effects limit its reactor size, limited its actual treatment capacity, just as clearly illustrating that in its specific embodiment, that can only be that one single jar single treatment amount has only the little reactor about 40 liters, at so little reactor, under the situation of little inner chamber, because size itself is just very little, so, its shortcoming aspect photochemical catalysis oxidation effective area oxygen supply concentration degree just can not be so obvious, even can ignore, more even fully can regard a non-existent at all problem as, in the face of such undersized little reactor,, not may float mind about the shortcoming problem of oxygen supply concentration degree aspect; But, imagine, if can overcome described many limiting factors, if can there be one of way actual implementation large-scale, the reactor of high throughput, effective area oxygen supply reinforcement problem will show especially out within so above-mentioned silica tube periphery 20 cm distance, especially for the situation of using electrodeless ultraviolet lamp as UV source, effective area oxygen supply reinforcement problem is not allowed to despise more within above-mentioned silica tube periphery 20 cm distance, therefore, how among the structure of possible large-scale electrodeless ultraviolet light catalysis oxidative degradation device, strengthen the oxygen supply concentration degree of described effective area, improve the usefulness of waste water degraded equipment, the problem that individual exactly needs are kept a close watch on, this is five of a problem.

Six of problem:

This CN102260003A scheme pumps air within the silica tube that includes electrodeless ultraviolet lamp, reach the aeration-cooling of electrodeless ultraviolet lamp, cooling purpose, and those flow through the air of silica tube, because of being subjected to ultraviolet irradiation, some air can change ozone into, therefore, effusive air is exactly the air that contains some ozone certainly from silica tube, this scheme contains ozone-air with this and is transferred to and is positioned at reactor below micro porous aeration head, and disengage from micro porous aeration head, contain in the ozone bubbles ascension process from bottom to top at these, wherein contained ozone can meet with and take place redox reaction with the organic molecule that runs among the distance, this redox reaction can consume a part of ozone certainly, this does not have query, but, above address, as the scheme that CN102260003A showed, the many effects limit that can't ignore that certainly exist its reactor size, limited its actual treatment capacity, just as clearly illustrating that in its specific embodiment, that can only be that one single jar single treatment amount has only the little reactor about 40 liters, at so little reactor, under the situation of little inner chamber, because overall dimension itself is just very little, so, the longitudinal size of its reactor inner chamber or regard that to contain the liquid degree of depth also can only be a very little size as with reckoning in every item, this size is as clearly illustrating that among its embodiment, have only about 40 centimetres, the Sheng that the reckons in every item liquid degree of depth also just has only 40 centimetres, in fact contain the liquid degree of depth and be less than this number certainly, just analyze with 40 centimetres the Sheng liquid degree of depth, so, is this Sheng liquid degree of depth of 40 centimetres what notion? that is to say, contain the ozone-air ascension and have only short 40 centimetres by the path of waste water, this path is too short, containing the ozone-air bubble passes through at a gallop and only has only 40 centimetres of dark water bodys, too short duration of contact with water body, contained ozone in the bubble, can only there be a very little part to be used to the oxidative degradation organism, and most ozone is in fact just passed by liquid simply, from the liquid level effusion and through the exhaust port emptying, briefly, the oxygenizement potentiality major part of these ozone has been wasted, and, effusion, in fact the ozone that is wasted can cause unnecessary atmospheric pollution; The main contriver of this case once squeezed in one meter dark tank via micro porous aeration head with the normal domestic use ozone machine and contained ozone-air, reach in the depth of water degree of depth under one meter the situation, still can near the water surface, obviously smell the smell of ozone, as seen, the sort of 40 centimetres of dark Sheng liquid degree of depth obviously are to be not enough to utilize fully ozone; As seen, for the such equipment of electrodeless ultraviolet light chemical catalysis waste water DeR device, ozone utilizes incomplete problem also to need to pay close attention to, obviously, what people more expected is that the ozone utilization is more complete, contaminative exhaust emissions no extreme ultraviolet waste water DeR device still less, and this is six of a problem.

Seven of problem:

Its running of waste water catalytic degradation reaction device requires the expenditure of energy, and therefore, operator are bound to wish, when the waste water DeR proceeds to terminal point, can impartially, immediately not stop too early continuing to inject energy to inside reactor only lately; If it is too early to stop to inject the moment of energy, then the waste water degraded not exclusively; And if reach reaction end already, but still inject energy to inside reactor unceasingly, that undoubtedly is at the valuable energy of waste.Its structure of CN102260003A scheme as this case technical background can not provide any instant information constantly to waste water DeR terminal point, so, just can only estimate the terminal point of waste water DeR by experience; And estimate the terminal point of waste water DeR by experience, that obviously can not be satisfactory; So, how make neither in advance also undelayed instant information output constantly, and immediately close energy input reactor in the just right moment at waste water DeR terminal point, the technical threshold that can not despise exactly, this is seven of a problem.

Eight of problem:

Accept the described trade effluent of microwave and photo catalysis degradation treatment, the material that wherein is mingled with some metal particles that originate from mechanical system abrasion process and carbon granules and so on unavoidably, even if quantity is small, its existence almost is difficult to avoid, the disclosure number is installed in the microwave and photo catalysis reaction zone for the described organic membrane separation assemblies in the Chinese patent application case of CN102260003A, being used between silica tube and the membrane separation assemblies that be installed in wherein intercepts ultraviolet dividing plate and do not stop microwave certainly, so, the practical function zone of microwave must cover zone that organic membrane separation assemblies is installed described in this scheme, working mechanism based on membrane separation assemblies, its accumulation process on the organic top layer of membrane separation assemblies of the particulate of aforesaid metal particle and carbon granules and so on is difficult to avoid, and the particulate of this type of described metal particle and carbon granules and so on, the good absorption medium of microwave energy exactly, absorbed the particulate of the described metal particle of accumulation attitude of microwave energy and carbon granules and so on, nature can to the top layer of its organic membrane separation assemblies of being close to produce based on heat penetration erosion mechanism continue pierce destruction, as mentioned above, since the structures shape of this its device of CN102260003A application case can only select the polyvinylidene fluoride film material for use, about 140 degrees centigrade of this polyvinylidene fluoride film material heatproof, high really more many than general film material heatproof, yet, absorbed the heatproof temperature limit that its point-like of particulate of the described metal particle of accumulation attitude of microwave energy and carbon granules and so on is pierced very easy this polyvinylidene fluoride film material of breakthrough of heat penetration erosion effect of formula, for above-mentioned reasons, well imagine, pvdf membrane material in its device of this CN102260003A application case will be significantly less than the ideal work-ing life of being expected its actual service life, the structure of this its device of CN102260003A application case, determined that under this structural framing the heat penetration erosion destruction problem that above-mentioned point-like is pierced formula can't be avoided; Therefore, how to get around the heat penetration erosion destruction problem that this point-like is pierced formula, also need consider, this is eight of a problem.

Nine of problem:

The disclosure number is the Chinese patent application case of CN102260003A, open the 0008th section literal of text text of its specification sheets and claim the second, for its device catalyst particle size scope that can be suitable for, a qualification is arranged, this particle size range is defined as 20 nanometers to 100 micron.We know, under some pH value was regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles was reunited easily, and then influences its effective working interface area, influences its photochemical catalysis usefulness; Especially among this particle size range those relatively than the section of small particle size,, the pH value incorrect agglomeration traits that cause not in place because of pH value preset appears especially easily; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, carry out depolymerization running at coacervate; Yet we do not see that any helping immediately dissolve the structure of this problem or can immediately dissolve the scheme prompting of this problem among this CN102260003A scheme.For can only being the reactor of small scale structures just like that because of many effects limit as the CN102260003A scheme, still can manually directly mention reactor, topple over and inspect in the reactor outside, handle above-mentioned reunion situation, so, if might expand its capacity, just so to say, if be that several cubes are to large-scale reactor of dozens of cubical or huge reactor, that obviously be not manual topple over its operation the problem that can tackle, so, for the situation that this catalyst particles is reunited mutually, how to realize instant original position disposal, be exactly a technical problem, this is nine of a problem.

Ten of problem:

In the disclosure number is in the expressed apparatus structure of the Chinese patent application case of CN102260003A, be used to shield the silica tube that protects electrodeless ultraviolet lamp, its outer wall, refer to the outer wall of silica tube, through for a long time with the contacting of processed trade effluent, incrustation gradually unavoidably, the long-pending material of dirt mainly are difficult by mineral-type impurity that light-catalyzed reaction touched certainly, incrustation phenomenon because of this mechanism forms is easy to be observed after the equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, though be very thin one deck, also be enough to ultraviolet radiation to electrodeless ultraviolet lamp and cause significantly and stop, this will cause the actual treatment of this microwave and photo catalysis reaction treating device to be renderd a service significantly reducing; The bubble of dispersed ascension is because of too disperseing in its reactor, wash away strength a little less than, keep the bright and clean of silica tube surface if only rely on this comparison dispersive bubble, really undertake to do what is apparently beyond one's ability, in other words, this is dispersive bubble relatively, and it is more weak washes away the incrustation process that strength still is not enough to stop fully this silica tube surface; In the use of laboratory yardstick, above-mentioned incrustation problem is subtle, and still, on the industrial application yardstick, this incrustation problem undoubtedly will highlight; Therefore, how under the prerequisite of not tearing machine open, remove the dirty lamination on this silica tube outer wall immediately, effectively, keep the high-level efficiency that continues of this microwave and photo catalysis treatment unit, this problem is also very important, and this is ten of a problem.

Summary of the invention

Technical problem to be solved by this invention is at one of problem of above addressing, two, three, four, five, six, seven, eight, nine, ten, to research and develop a kind of novel waste water microwave and photo catalysis degradation treatment device that can solve described serial problem totally.

The present invention solve the technical problem by following scheme, this scheme provides a kind of photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point, the structure of this reactor comprises a container, its appearance profile of described container is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, the spherical or the ellipsoid bodily form, lower region at described container intracavity is equiped with many micro porous aeration heads, and, silica tube, this silica tube is erected at the inner chamber position of described container, the two ends of this silica tube are equiped with the shutoff headkerchief, and lay respectively on the described shutoff headkerchief at silica tube two ends and all offer the ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp are at least more than one, and this quantity all is erected at the inside of described silica tube at least at more than one electrodeless ultraviolet lamp, and, pneumatic pump, this pneumatic pump is installed in the outside of described container, and the ventilation interface on the described silica tube one end shutoff headkerchief connects with the air outlet of described pneumatic pump via breather line and through described wall of a container, ventilation interface on its other end shutoff headkerchief of described silica tube connects with the micro porous aeration head that is positioned at described container intracavity lower region via another breather line, and, microwave generator, this microwave generator is installed in the outside of described container, this microwave generator is a magnetron, and waveguide, this waveguide are the members that is used for Transmission Microwave, one end of this waveguide and described magnetron UNICOM, the other end of this waveguide sees through the inner chamber of described wall of a container towards described container, and, water pump, this water pump is used for containing to the inner chamber pumping of affiliated container the described waste water of organic pollutant, this water pump is positioned at the outside of described container, and the water outlet of this water pump is via ventilating water pipe and see through the inner chamber that described wall of a container leads to described container, and the top of described container offers exhaust port, it is characterized in that, that end that sees through described wall of a container of this waveguide extends much further into the inner chamber of described container, and this gos deep into that end of waveguide of described container intracavity and the inside that a shutoff headkerchief further seeing through described silica tube again probes into silica tube, and, the structure of this reactor also comprises the microwave constrainer of the cage shape of metal material, the microwave constrainer of cage shape is exactly a metal cage, contains many holes or mesh on the microwave constrainer of this cage shape, and the function of the microwave constrainer of this cage shape is the constraint microwave, contain its unhelpful dissipation, simultaneously, allow most of UV-light to penetrate, the installation position of the microwave constrainer of this cage shape is positioned at the inside of described silica tube, that end UNICOM that probes into silica tube of its inner chamber of microwave constrainer of this cage shape and described waveguide, described UNICOM refers to and connects on the microwave channel meaning and perforation, and the described electrodeless ultraviolet lamp that is erected at silica tube inside all is rolled in wherein by the microwave constrainer of described cage shape, and, topping-up pump, this topping-up pump is used for the degraded water afterwards that the supercharging pumping is mixed with a large amount of catalyst particles, and its water-in of this topping-up pump connects with the inner chamber of described container via another ventilating water pipe and through described wall of a container, and, the preposition prefilter of back flush type, its water-in of the preposition prefilter of this back flush type connects with the water outlet of described topping-up pump, and, back flush type tubular fibre membrane microfiltration strainer, its pure water inlet of the preposition prefilter of described back flush type connects via the water-in of first water purifying valve with this back flush type tubular fibre membrane microfiltration strainer, and, back flush type hollow-fibre membrane ultra filtration filter, described its pure water inlet of back flush type tubular fibre membrane microfiltration strainer connects via the water-in of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter, this its pure water inlet of back flush type hollow-fibre membrane ultra filtration filter connects with the entrance end of the 3rd water purifying valve, the water side of the 3rd water purifying valve is outlet terminal water purifying water side, and its sewage outlet of the preposition prefilter of described back flush type connects with the inner chamber of described container via first sewage valve, and described its sewage outlet of back flush type tubular fibre membrane microfiltration strainer connects with the inner chamber of described container via second sewage valve, described its sewage outlet of back flush type hollow-fibre membrane ultra filtration filter connects with the inner chamber of described container via the 3rd sewage valve, each described strainer all is used to hold back catalyst particles, and each its sewage outlet of described strainer is all migrated to the recovery of being held back catalyst particles with delivery port again or refluxed and use delivery port again, and, described many micro porous aeration heads are assembled formation cluster shape micro porous aeration head cluster mutually, this cluster shape micro porous aeration head cluster is erected at the lower region of described container intracavity vacantly, and the fore-and-aft distance of this cluster shape micro porous aeration head its bottom edge of cluster and described container intracavity bottom surface is between 10 centimetres and 50 centimetres, and the transverse distance of this cluster shape micro porous aeration head cluster edge and described container intracavity sidewall arround it is between 20 centimetres and 300 centimetres, this cluster shape micro porous aeration head its center of cluster or center of gravity be positioned at described silica tube under, and ozone sensor, the sampling port of this its stopple coupon of ozone sensor are close to described exhaust port or probe into the inside of described exhaust port, and, the ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, this ozone sensor is via article one cable and this ozone content indicating meter, ozone attention device or ozone content indicating meter connect with the composite structure of ozone attention device, and, power-supply controller of electric, its output electric signal of this ozone sensor connects with this power-supply controller of electric via the second cable, and this power-supply controller of electric connects with described magnetron via the 3rd cable, and this power-supply controller of electric connects with described pneumatic pump via the 4th cable, this power-supply controller of electric is the power-supply controller of electric that can carry out the power switch action according to the described electric signal that it received, and ultrasonic transducer, this ultrasonic transducer are bottom outside position or the bottom inside positions that is installed in this container, and, HF oscillation electric signal transmission cable, an end of this HF oscillation electric signal transmission cable connects with this ultrasonic transducer, and, HF oscillation electric signal producer, the other end of described HF oscillation electric signal transmission cable connects with this HF oscillation electric signal producer.

Itself art-recognized meanings of ultrasonic transducer one speech is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of HF oscillation electric signal transmission cable one speech also is known for the professional in ultrasonic technology field.

Ultrasonic transducer and HF oscillation electric signal transmission cable market are all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can be to ultrasonic transducer specialized factory and the customizations of cable specialized factory.

Itself art-recognized meanings of HF oscillation electric signal producer one speech also is known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.

Related ozone sensor market is on sale; Also can customize to ozone sensor specialized factory as required.

Related ozone content monitor market is on sale; Also can customize to ozone content indicating meter specialized factory as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.

Related ozone attention device refers to warn sound or caution flash of light or caution sound and to warn the mechanism that is used to warn that the flash phase bonded haves both at the same time; Ozone attention device market is on sale; Also can customize to ozone attention device specialized factory; Ozone sensor producer also can sell matching used ozone attention device usually.

Related this power-supply controller of electric is the power-supply controller of electric that can carry out the power switch action according to the described electric signal that it received; The power-supply controller of electric that can carry out power switch action according to the electric signal that it received is sophisticated, technique known only with regard to its circuit engineering itself; Described power-supply controller of electric market is on sale; Also can utilize commercially available power-supply controller of electric to change a social system as required; Described power-supply controller of electric also can be to the customization of power-supply controller of electric specialty manufacturers; Its professional manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.

Described metal material one speech, the art-recognized meanings of itself is known.

Described magnetron, and, waveguide device, its art-recognized meanings is known for the professional of microwave technical field.Described magnetron, and waveguide etc. all have commercially available; Described waveguide is self manufacture as required, and this making is for the professional of microwave technical field, and the making of waveguide device is simple.

Described silica tube, its art-recognized meanings is known; Described silica tube market is on sale; Described silica tube also can customize to specialized factory.

Described electrodeless ultraviolet lamp, its art-recognized meanings are known for the professional of light sources technical field; Described electrodeless ultraviolet lamp market is on sale; Described its shape of electrodeless ultraviolet lamp, size, inner institute blanketing gas, lamp wall material, lamp wall thickness, or the like, also can customize to electric light source manufacturing concern according to the specific design needs.Certainly, also can self manufacture.The making of electrodeless ultraviolet lamp is for the professional who possesses electric light source expertise, and its manufacturing technology is simple.

Its material of microwave constrainer of this cage shape can be any selected metal, but, residing in view of it by the formed ozone gas mixture of strong ultraviolet radiation environment, and, for exporting considering of the UV-light of being launched by electrodeless ultraviolet lamp to greatest extent by the specular reflection mechanism of complexity as much as possible, the preferred metal material that is suitable for making the microwave constrainer of this cage shape is the punching stainless steel of handling through mirror polish.

Can make described microwave constrainer through welding, splicing or mould pressing process with bright finished punching stainless steel plate.

Can certainly make the microwave constrainer of this cage shape with bright finished Stainless Steel Wire braiding.

Be runnings such as convenient cleaning of regularly carrying out at inside reactor and maintenance, can offer sewage draining exit in the bottom of described container, this sewage draining exit is used for deslagging, removes contamination, can be at this sewage draining exit position installing wash water valve, and described wash water valve is the valve that is used for blowdown control; In case of necessity, can utilize this sewage draining exit that is positioned at described container bottom that described internal tank liquid is emptied completely; This sewage draining exit and wash water valve are not necessarily.

Described water pump and topping-up pump all are the pumps that are used to carry clear or turbid all kinds of water, and certainly, its pumping pressure can be selected as required arbitrarily, and various pump market is all on sale; Different titles are adopted in this case, just statement for convenience, the convenient pump of distinguishing each different structure position.

Described water purifying valve, sewage valve, wash water valve all are water valves, and various water valve market is all on sale; About water valve, itself art-recognized meanings of this speech is known; Different titles is adopted in this case, just statement for convenience, the convenient water valve of distinguishing each different structure position.

The preferable range in its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, and certainly, it also is that this case allows that the preposition pre-filtering of other outside this preferable range aperture is selected; The preferable range in its filter opening aperture of described back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, and certainly, it also is that this case allows that other micro-filtration aperture outside this preferable range is selected; The preferable range in its filter opening aperture of described back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers, and certainly, it also is that this case allows that other ultrafiltration aperture outside this scope is selected.

The preposition prefilter of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type is known; The preposition prefilter of described back flush type market is on sale.

Described back flush type tubular fibre membrane microfiltration strainer is the strainer that is suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one speech is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer is known for the professional in membrane separation technique field; Described back flush type tubular fibre membrane microfiltration strainer market is on sale.

Described back flush type hollow-fibre membrane ultra filtration filter is the strainer that is suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one speech is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter is known for the professional in membrane separation technique field; Described back flush type hollow-fibre membrane ultra filtration filter market is on sale.

In the ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter can be that a back flush type hollow-fibre membrane ultra filtration filter monomer form is only arranged; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

Express a related speech in parallel, the art-recognized meanings that itself referred to is clearly.

Express related monomer one speech, refer to itself function and structure equipment individuality completely.

Similarly, in the micro-filtration link, this back flush type tubular fibre membrane microfiltration strainer can be that a back flush type tubular fibre membrane microfiltration strainer monomer form is only arranged; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

Can further install second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, this second topping-up pump is used to augment hydraulic pressure to satisfy the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This second topping-up pump not necessarily.

The microwave constrainer of described cage shape is exactly a metal cage; Be a mass of hole or mesh in himself structure of the microwave constrainer of this cage shape, the preferable range of described hole or its bore of mesh is between 0.5 centimetre and 3.0 centimetres; Certainly, if must select the hole or the mesh of other bore outside this preferable range for use, that also is that this case allows.

The structure of this case device can also comprise some annexes, described annex for example: the cooling water recirculation system or the air cooling system that are connected with the magnetron cooling duct; Described annex also for example is used for electrodeless ultraviolet lamp is fixed on fixed support within the microwave constrainer of described cage shape; Described annex for example is used for microwave constrainer with described cage shape again and is fixed on support member within the described silica tube; Described annex can certainly comprise described silica tube is fixed on support or anchor within the described container; Described annex for example is installed in the strainer that is used to tackle impurity of reactor influent waste water end again, or the like.

Advantage of the present invention is, microwave constrainer with the cage shape of the metal material that is placed in described silica tube inside, electrodeless ultraviolet lamp is wrapped among its inner chamber, its inner chamber of microwave constrainer of cage shape and with the waveguide UNICOM of going deep into described internal tank, described UNICOM refers to the UNICOM on the microwave channel meaning, by this structure, the microwave that will come via the waveguide transmission constrains within its effective workspace, the containment microwave is to the unhelpful dissipation of peripheral waste water water body, this case structure allows reactor significantly to expand its design volume, allow single jar of wastewater treatment capacity of reactor significantly to promote, and need not worry again that microwave energy dissipates too much in unhelpful waste water water body temperature-rise effect.

Make the microwave constrainer at the bright finished punching stainless steel of employing, perhaps, adopt under the situation of bright finished Stainless Steel Wire cylinder mould as the microwave constrainer, specular reflection mechanism via complexity, both all can transfer out the UV-light from electrodeless ultraviolet lamp to greatest extent, and remedy himself entity of described microwave constrainer to greatest extent light is blocked, absorbs the loss that is caused.

Based on the structure of this case, the DESIGN OF REACTOR volume is that single jar of wastewater treatment capacity can be expanded to several cubes to dozens of cube; Even single jar hundreds of cubical volumes, also allow; Based on this structure of this case, can reduce the frequency of a complete set, substantial length of operation significantly, help the saving of human and material resources.

This case reactor is among its operation, described its high-density ascension bubble flow that is discharged of cluster shape micro porous aeration head cluster, in the ascension that makes progress, and wrapped folder, carry, guided liquid-flow, form a kind of motion that is similar to the fountain form, in this kind motion, the high-density bubble flow wrapped folder that is derived from described cluster shape micro porous aeration head cluster liquid to the silica tube region gush and on, and then relatively the concentrated area is impacted, the effective area of the described photochemical catalysis oxidizing reaction by the silica tube periphery, be subjected to described high-density bubble flow wrapped folder, the liquid stream that carries is impacting, after the described effective area by the silica tube periphery, by the liquid layer of top area to around diffusion, sink via the neighboring area, arrive reactor intracavity bottom zone, again through the wrapped folder of described its high-density ascension bubble flow that is discharged of cluster shape micro porous aeration head cluster, carry, continue the motion that it is similar to the fountain form, so circulation endlessly; The liquid circulation campaign of this relative big scale that is guided helps to guarantee the homogenizing of inside reactor liquid degradation reaction process, and this is necessary for large-scale electrodeless ultraviolet light catalysis DeR device.

Its UV source of this case reactor is to rely on microwave excited electrodeless ultraviolet lamp, the uv-radiation characteristics of this lamp type can be accomplished high-power, high strength exactly, yet the Effective depth penetration of ultraviolet ray in liquid water body has only about 20 centimetres, therefore, zone within about 20 cm distance of silica tube periphery is the effective area, and this zone is exactly the efficient zone of photochemical catalysis oxidative degradation; This case method is to be positioned at the described cluster shape micro porous aeration head cluster under the silica tube, come the concentrated area to discharge highdensity ascension bubble flow, it is discharged towards silica tube periphery photochemical catalysis oxidation effective area as concentrated area as the fountain, the oxygen atmosphere that this method helps to improve the described effective area of silica tube periphery is supplied with intensity, helps accelerating ultraviolet catalyzing oxidizing degrading reaction process.

Based on this case structure, the capacity of reactor or treatment capacity can significantly be expanded, described significantly expansion, be that the design volume of irradiation zone realizes a little less than microwave zero irradiation zone or the microwave by significantly expanding, so, the lateral dimension of reactor, longitudinal size all is significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, for example, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, or the like, containing under the enough dark situation of the liquid degree of depth, contain ozone-air bubble ascension path sufficiently long, contain the time sufficiently long that the ozone-air bubble contacts with water body, in its ascension process just can with abundant reducing substances fortune, and thoroughly or be close to and exhaust ozone contained in the bubble up hill and dale, thus, contain that ozone composition oxidation potential utilizes incomplete problem to be solved in the ozone-air bubble, and,, just can not be entrained with the ozone that can cause environmental pollution again in the reactor tail gas because long ascension path causes ozone to exhaust.

This case is with external multistage filter, reach interception step by step from the collision fragment of the small scale of coacervate macrobead to ten number nanometers to catalyst particles, be close to recovery, reuse photocatalyst up hill and dale, be close to the secondary pollution of taking precautions against catalyst loss up hill and dale and causing; This is tackled scheme step by step and can protect secondary filter to make its filtration passage avoid the rigid obstruction of large particulate matter; Wherein the pre-filtering aperture of the first step is between 5 microns and 300 microns, and its aperture of partial micro-filtration is between 25 nanometers and 1000 nanometers, and its aperture of the ultrafiltration of the third stage is between 15 nanometers and 2 nanometers; Such interception scheme can fully be tackled nano level photocatalyst, and it can be close to certainly and tackle this median size of gas phase titanium dioxide P25 up hill and dale is the catalyzer of 21 nanometers; Preamble is addressed, the gas phase titanium deoxide catalyst of nano level P25 and so on, it is the commercially available catalyzer that to buy in a large number, also be weather resistance, stability, the known good photocatalyst of UV-light wave band photocatalysis performance, certainly, it also is in fact to pay the utmost attention to the photocatalyst of selecting for use in the industrial scale applications; This case catalyzer interception scheme is complementary with the virtual rating of catalyzer market supply, actual kind, merges mutually.

And, because this case catalyzer interception mechanism is external mechanism, its filter core just needn't be soaked in the liquid of the strong oxidation of inside reactor, strong uv irradiation, therefore, can needn't consider tolerance fully, like this, just not have restriction aspect the extraordinary tolerance selecting for use of filter core material to uv irradiation, strong oxidizing condition, can on more vast optional material kind, select, and need not be confined to the material of the PVDF and so on of comparison costliness fully again.

Related strainer at different levels all has commercially available, commercially available strainers at different levels, the discharge outlet of draining-off sewage when its sewage draining exit is exactly back flushing, this class back flush type equipment is used in this case, be to be used for tackling step by step catalyst particles, originally the sewage draining exit of commercially available relevant device, the recovery that is used as being held back catalyst particles in this case by migrating are again with delivery port or reflux and use delivery port again.

Above address, based on this case structure, the capacity of reactor or treatment capacity can significantly be expanded, described significantly expansion, be that the design volume of irradiation zone realizes a little less than microwave zero irradiation zone or the microwave by significantly expanding, so, from in appearance, the lateral dimension of reactor, longitudinal size all is significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, for example, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, or the like, containing under the enough dark situation of the liquid degree of depth, contain ozone-air bubble ascension path sufficiently long, contain the time sufficiently long that the ozone-air bubble contacts with water body, in its ascension process just can with abundant reducing substances fortune, and thoroughly or be close to and exhaust ozone contained in the bubble up hill and dale, thus, contain that ozone composition oxidation potential utilizes incomplete problem to be solved in the ozone-air bubble, and,, just can not be entrained with the ozone that can cause environmental pollution again in the reactor tail gas because long ascension path causes ozone to exhaust; Only ought be subject to processing that reducing substances is in organic pollutant is degraded totally in the water body, not had in the water body can be for the organic pollutant of ozone oxidation reaction again, and those redundant ozone just might no longer consume and see through long ascension path effusion liquid level; The front is spoken of, among some problems that this case solves simultaneously one, it is the circulation of the relative big scale of enhanced reactor internal liquid, this systemic circulation mechanism of having strengthened has been facilitated the uniformity of inside reactor liquid its contained organic pollutant degradation reaction process, thus, at several cubes that this case structure is allowed to the processing capacity framework of dozens of cube even hundreds of cube volume, above the inside reactor liquid level, have in the ozone effusion, the DeR that promptly shows inside reactor has reached terminal point, and be the terminal point that the whole uniformity of internal liquid ground reaches DeR, this terminal point determining factor is that the condition that can provide with this case organization plan is complementary; This case is at its exhaust port position installing ozone sensor of reactor, detect ozone in this locations of structures, just mean that the inside reactor DeR reaches home, ozone sensor and connect with the composite structure of ozone content indicating meter with ozone attention device or ozone content indicating meter or ozone attention device, be used for providing indication information accurately to operator, this case and the electric signal that ozone sensor is exported send power-supply controller of electric to by cable, this power-supply controller of electric also connects with magnetron and pneumatic pump respectively by cable, power-supply controller of electric carries out the power switch action according to its received described electric signal, certainly, its function mode is, receive in the signal that ozone that ozone sensor sends overflows at power-supply controller of electric, close the power supply that leads to magnetron and pneumatic pump automatically; This case is organization plan according to this, can in time know the terminal point of inside reactor DeR process; And organization plan according to this, when reaction reaches terminal point, close the power supply of magnetron and pneumatic pump automatically, in time stop to inject energy to inside reactor, so can avoid unnecessary energy dissipation; And, this case is structure according to this, in DeR reaches home, can in time close the power supply of described magnetron and pneumatic pump, this power-off action has also stopped the generation process of ozone synchronously, together in a flash, because ozone generation process is in time stopped, just do not have and disengage, thereby avoided unnecessary secondary pollution or said secondary pollution from described exhaust port above a large amount of ozone that need; Its framework of this case has determined it not have ozone more than needed can supply discharging.

Among this case structure, the microwave exposure spatial domain of its inside reactor is subjected to forcing to cut off, limit, this case and adopt the multistage backwash filter structure of external cascade to tackle catalyst particles subtly, back flush type hollow fiber microfiltration membrane assembly wherein and back flush type polysulfone hollow fiber ultrafiltration membrane system are all external and away from reactor core, microwave can not shine described membrane module fully, based on this structure of this case, got around described point-like fully and pierced the heat penetration erosion destruction problem of formula, this problem is settled properly thus.

Be installed in the ultrasonic transducer of reactor bottom in this case structure, can start at once where necessary; Above address, under some pH value was regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles was reunited easily, and then influences its effective working interface area, influences its photochemical catalysis usefulness; Especially among this particle size range those relatively than the section of small particle size,, the pH value incorrect agglomeration traits that cause not in place because of pH value preset appears especially easily; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, carry out depolymerization running at coacervate; Take place under the serious situation of reuniting at catalyst particles, the ultrasonic transducer that is positioned at reactor bottom in this case structure is OnNow easily, immediately implement the depolymerization running, realized thus disposing at the instant original position of this catalyst particles agglomeration traits.

Be used to shield the silica tube that protects electrodeless ultraviolet lamp in the structure, its outer wall, refer to the outer wall of silica tube, through for a long time with the contacting of processed trade effluent, incrustation gradually unavoidably, the long-pending material of dirt mainly is to be difficult for by the mineral-type impurity that light-catalyzed reaction touched certainly, and the incrustation phenomenon because of this mechanism forms is easy to be observed after the equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, though be very thin one deck, also be enough to ultraviolet radiation to electrodeless ultraviolet lamp and cause significantly and stop, this will cause the actual treatment of this microwave and photo catalysis reaction treating device to be renderd a service significantly reducing; Be positioned at the ultrasonic transducer of reactor bottom in this case structure, among the depolymerization running that the irregular situation of seriously reuniting at accidental catalyst particles is carried out, its radiating ultrasonic wave, certainly also can arrive silica tube place locations of structures, this ultrasonic wave is also being carried out the ultrasonic clean scale removal work at the long-pending thing of silica tube surface dirt in the lump when carrying out original position depolymerization running; And, the installation position of ultrasonic transducer is away from silica tube place locations of structures, decay to some extent when ultrasonic radiation arrives the silica tube position, therefore, the suffered ultrasonic impact in silica tube surface is low intensive ultrasonic impact, this low intensive ultrasonic impact scale removal leniently, can avoid again or significantly weaken ultrasonic cavitation its silica tube surface smoothness loss that may cause; Based on this structure of this case, can under the prerequisite of not tearing machine open, remove the dirty lamination on this silica tube outer wall immediately, effectively, safeguard the high-level efficiency that continues of this microwave and photo catalysis DeR device by this.

In brief, this case structure utilizes metal cage to retrain microwave more closely, has reached the target that allows the reactor design capacity significantly to expand; Simultaneously, this case structure has also been strengthened the cyclic motion of the relative big scale of inside reactor liquid; This case structure and to be set up in described its highdensity bubble flow that is discharged of cluster shape micro porous aeration head cluster under the silica tube realizes the significantly lifting at the oxygen supply concentration degree of emphasis reaction zone; This case structure and reached at the nm-class catalyst particulate from the collision fragment of its coacervate macrobead to ten number nanometers widely, meticulous interception; Its related filter core Material Selection face also thereby enlarged; Based on this case structure, its DeR endpoint information can in time be known; Can close energy input in its DeR terminal point automatically to reactor; In its DeR terminal point, also automatically in time stop the generation process of ozone, avoided unnecessary secondary pollution; Its structure and immediately original position dispose the accidental catalyst particles situation of seriously reuniting, also incidentally clean described silica tube surface simultaneously, keep its good UV-light transparent performance with ultrasonic wave through the low intensive gentleness after the reduction of teletransmission appropriateness.

This case structure of reactor has solved described serial problem totally.

Description of drawings

Fig. 1 is the brief perspective diagram of this case structure of reactor.

Among the figure, the 1st, described container, described container also is the main component of this reactor, 2,12 is respectively two different breather lines of locations of structures, 3,7 is respectively the shutoff headkerchief at silica tube two ends, the 4th, silica tube, the 5th, the microwave constrainer of the cage shape of metal material, the 6th, electrodeless ultraviolet lamp, the 8th, exhaust port, the 9th, waveguide, the 10th, magnetron, the 11st, pneumatic pump, 13 indicate this case reactor in the rough position of liquid level of containing under the liquid status, 14 indicate described internal tank microwave zero irradiation zone or the weak irradiation zone of microwave, 15 indicate micro porous aeration head, mark 15 only indicates micro porous aeration head individuality and individual morphology, the 16th, wash water valve, the 17th, sewage draining exit, the 18th, back flush type hollow-fibre membrane ultra filtration filter, the 19th, back flush type tubular fibre membrane microfiltration strainer, the 20th, the preposition prefilter of back flush type, the 21st, topping-up pump, the 22nd, water pump, the 23rd, the stopple coupon of ozone sensor, the 24th, ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, the 25th, ozone sensor, the 26th, power-supply controller of electric, the 27th, ultrasonic transducer, the 28th, HF oscillation electric signal transmission cable, the some arrows among the figure are indicated the liquid flow direction of its contiguous pipeline when being in on-state.

Embodiment

In this case embodiment that Fig. 1 showed, the structure of this reactor comprises a container 1, and described container 1 its appearance profile is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, the spherical or the ellipsoid bodily form, lower region at described container 1 inner chamber is equiped with many micro porous aeration heads 15, and this label 15 only indicates micro porous aeration head individuality and form thereof, and, silica tube 4, this silica tube 4 is erected at the inner chamber position of described container 1, and the two ends of this silica tube 4 are equiped with shutoff headkerchief 3,7, lay respectively at the described shutoff headkerchief 3 at silica tube two ends, all offer the ventilation interface on 7, and, electrodeless ultraviolet lamp 6, this electrodeless ultraviolet lamp 6 is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp 6 are at least more than one, and this quantity all is erected at the inside of described silica tube 4 at least at more than one electrodeless ultraviolet lamp 6, and, pneumatic pump 11, this pneumatic pump 11 is installed in the outside of described container 1, and the ventilation interface on the described silica tube 4 one end shutoff headkerchieves 7 connects with the air outlet of described pneumatic pump 11 via the wall that breather line 12 also sees through described container 1, ventilation interface on described silica tube 4 its other end shutoff headkerchieves 3 connects with the micro porous aeration head 15 that is positioned at described container 1 inner chamber lower region via another breather line 2, and, microwave generator, this microwave generator is installed in the outside of described container 1, this microwave generator is a magnetron 10, and, waveguide 9, this waveguide 9 is the members that are used for Transmission Microwave, one end of this waveguide 9 and described magnetron 10 UNICOMs, the other end of this waveguide 9 sees through the inner chamber of the wall of described container 1 towards described container 1, and, water pump 22, this water pump 22 is used for containing to the inner chamber pumping of affiliated container 1 the described waste water of organic pollutant, this water pump 22 is positioned at the outside of described container 1, and the water outlet of this water pump 22 is via ventilating water pipe and see through the inner chamber of the wall of described container 1 towards described container 1, and the top of described container 1 offers exhaust port 8, emphasis is, that end of the wall that sees through described container 1 of this waveguide 9 extends much further into the inner chamber of described container 1, and this gos deep into that end of waveguide 9 of described container 1 inner chamber and the inside that a shutoff headkerchief 7 further seeing through described silica tube 4 again probes into silica tube 4, and, the structure of this reactor also comprises the microwave constrainer 5 of the cage shape of metal material, the microwave constrainer 5 of cage shape is exactly a metal cage, contains many holes or mesh on the microwave constrainer 5 of this cage shape, and the function of the microwave constrainer 5 of this cage shape is the constraint microwave, contain its unhelpful dissipation, simultaneously, allow most of UV-light to penetrate, the installation position of the microwave constrainer 5 of this cage shape is positioned at the inside of described silica tube 4, microwave constrainer 5 its inner chambers of this cage shape and that end UNICOM that probes into silica tube 4 of described waveguide 9, described UNICOM refers to and connects on the microwave channel meaning and perforation, and the described electrodeless ultraviolet lamp 6 that is erected at silica tube 4 inside all is rolled in wherein by the microwave constrainer 5 of described cage shape, and, topping-up pump 21, this topping-up pump 21 is used for the degraded water afterwards that the supercharging pumping is mixed with a large amount of catalyst particles, and these topping-up pump 21 its water-ins connect with the inner chamber of described container 1 via the wall that another ventilating water pipe also sees through described container 1, and, the preposition prefilter 20 of back flush type, preposition prefilter 20 its water-ins of this back flush type connect with the water outlet of described topping-up pump 21, and, back flush type tubular fibre membrane microfiltration strainer 19, preposition prefilter 20 its pure water inlets of described back flush type connect via the water-in of first water purifying valve with this back flush type tubular fibre membrane microfiltration strainer 19, and, back flush type hollow-fibre membrane ultra filtration filter 18, described back flush type tubular fibre membrane microfiltration strainer 19 its pure water inlets connect via the water-in of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter 18, these back flush type hollow-fibre membrane ultra filtration filter 18 its pure water inlets connect with the entrance end of the 3rd water purifying valve, the water side of the 3rd water purifying valve is outlet terminal water purifying water side, and preposition prefilter 20 its sewage outlet of described back flush type connect via the inner chamber of first sewage valve with described container 1, and described back flush type tubular fibre membrane microfiltration strainer 19 its sewage outlet connect with the inner chamber of described container 1 via second sewage valve, described back flush type hollow-fibre membrane ultra filtration filter 18 its sewage outlet connect with the inner chamber of described container 1 via the 3rd sewage valve, each described strainer 20,19,18 all are used to hold back catalyst particles, each described strainer 20,19,18 its sewage outlet are all migrated to the recovery of being held back catalyst particles with delivery port again or are refluxed and use delivery port again, and, described many micro porous aeration heads 15 are assembled formation cluster shape micro porous aeration head cluster mutually, this cluster shape micro porous aeration head cluster is erected at the lower region of described container 1 inner chamber vacantly, and the fore-and-aft distance of this cluster shape micro porous aeration head its bottom edge of cluster and described container intracavity bottom surface is between 10 centimetres and 50 centimetres, and the selected arbitrarily distance value within this fore-and-aft distance scope all is an available enforcement value, this fore-and-aft distance value for example can be 10 centimetres, 20 centimetres, 30 centimetres, 40 centimetres, 50 centimetres, or the like, the transverse distance of this cluster shape micro porous aeration head cluster edge and described container intracavity sidewall arround it is between 20 centimetres and 300 centimetres, and any set point value within this transverse distance scope all is an available enforcement value, this transverse distance value for example can be 20 centimetres, 40 centimetres, 100 centimetres, 160 centimetres, 220 centimetres, 300 centimetres, or the like, this cluster shape micro porous aeration head its center of cluster or center of gravity be positioned at described silica tube under, and, ozone sensor 25, the sampling port of these ozone sensor 25 its stopple coupons 23 is close to described exhaust port 8 or probes into the inside of described exhaust port 8, and, the ozone content indicating meter, the composite structure 24 of ozone attention device or ozone content indicating meter and ozone attention device, this ozone sensor 25 is via article one cable and this ozone content indicating meter, ozone attention device or ozone content indicating meter connect with the composite structure 24 of ozone attention device, and, power-supply controller of electric 26, these ozone sensor 25 its output electric signals connect with this power-supply controller of electric 26 via the second cable, this power-supply controller of electric 26 connects with described magnetron 10 via the 3rd cable, this power-supply controller of electric 26 connects with described pneumatic pump 11 via the 4th cable, and this power-supply controller of electric 26 is the power-supply controller of electric that can carry out the power switch action according to the described electric signal that it received, and, ultrasonic transducer 27, this ultrasonic transducer 27 is bottom outside position or the bottom inside positions that are installed in this container 1, and what show in the legend is the situation that is installed in the bottom outside position, does not have diagram to be installed in the situation of bottom inside position in the legend, and, HF oscillation electric signal transmission cable 28, an end of this HF oscillation electric signal transmission cable 28 connects with this ultrasonic transducer 27, and, HF oscillation electric signal producer, the other end of described HF oscillation electric signal transmission cable 28 connects with this HF oscillation electric signal producer.Do not draw this HF oscillation electric signal producer in the legend.

Itself art-recognized meanings of related ultrasonic transducer one speech is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of related HF oscillation electric signal transmission cable one speech also is known for the professional in ultrasonic technology field.

Related ultrasonic transducer and HF oscillation electric signal transmission cable market are all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can be to ultrasonic transducer specialized factory and the customizations of cable specialized factory.

Itself art-recognized meanings of related HF oscillation electric signal producer one speech also is known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.

Related ozone sensor 25 markets are on sale; Also can customize to ozone sensor specialized factory as required.

Related ozone content monitor market is on sale; Also can customize to ozone content indicating meter specialized factory as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.

Related ozone attention device refers to warn sound or caution flash of light or caution sound and to warn the mechanism that is used to warn that the flash phase bonded haves both at the same time; Ozone attention device market is on sale; Also can customize to ozone attention device specialized factory; Ozone sensor producer also can sell matching used ozone attention device usually.

Related this power-supply controller of electric 26 is the power-supply controller of electric that can carry out the power switch action according to the described electric signal that it received; The power-supply controller of electric that can carry out power switch action according to the electric signal that it received is sophisticated, technique known only with regard to its circuit engineering itself; Described power-supply controller of electric market is on sale; Also can utilize commercially available power-supply controller of electric to change a social system as required; Described power-supply controller of electric also can be to the customization of power-supply controller of electric specialty manufacturers; Its professional manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.

Described metal material one speech, the art-recognized meanings of itself is known.

Microwave constrainer 5 its materials of this cage shape can be any selected metals, but, residing in view of it by the formed ozone gas mixture of strong ultraviolet radiation environment, and, for exporting considering of the UV-light of being launched by electrodeless ultraviolet lamp 6 to greatest extent by the specular reflection mechanism of complexity as much as possible, the preferred metal material that is suitable for making the microwave constrainer 5 of this cage shape is the stainless steel of handling through mirror polish.

Itself art-recognized meanings of described punching stainless steel one speech is known for stainless steel industry.

Can make described microwave constrainer 5 through welding, splicing or mould pressing process with bright finished punching stainless steel plate.

Also can make the microwave constrainer 5 of this cage shape with bright finished Stainless Steel Wire braiding.

Sewage draining exit 17 can be offered in bottom at described container 1, and this sewage draining exit 17 can be used for deslagging, remove contamination, and can install wash water valve 16 in these sewage draining exit 17 positions, and described wash water valve 16 is the valves that are used for blowdown control.Described sewage draining exit 17 and wash water valve 16 are not necessarily.

Described water pump 22 and topping-up pump 21 all are the pumps that are used to carry clear or turbid all kinds of water, and certainly, its pumping pressure can be selected as required arbitrarily, and various pump market is all on sale; Different titles are adopted in this case, just statement for convenience, the convenient pump of distinguishing each different structure position.

Described water purifying valve, sewage valve, wash water valve all are water valves, and various water valve market is all on sale; About water valve, itself art-recognized meanings of this speech is known; Different titles is adopted in this case, just statement for convenience, the convenient water valve of distinguishing each different structure position.

The preferable range in the preposition prefilter of described back flush type 20 its filter opening apertures is between 5 microns and 300 microns, any set point value within this scope all is preferred available enforcement value, certainly, other the preposition pre-filtering aperture selection outside this preferable range also is that this case allows; The preferable range in described back flush type tubular fibre membrane microfiltration strainer 19 its filter opening apertures is between 25 nanometers and 1000 nanometers, any set point value within this preferable range all is preferred available enforcement value, certainly, other micro-filtration aperture selection outside this preferable range also is that this case allows; The preferable range in described back flush type hollow-fibre membrane ultra filtration filter 18 its filter opening apertures is between 15 nanometers and 2 nanometers, any set point value within this preferable range all is preferred available enforcement value, certainly, other ultrafiltration aperture selection outside this scope also is that this case allows.

The preposition prefilter 20 of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type 20 is known; The preposition prefilter of described back flush type 20 markets are on sale.

Described back flush type tubular fibre membrane microfiltration strainer 19 is the strainers that are suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one speech is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer 19 is known for the professional in membrane separation technique field; Described back flush type tubular fibre membrane microfiltration strainer 19 markets are on sale.

Described back flush type hollow-fibre membrane ultra filtration filter 18 is the strainers that are suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one speech is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter 18 is known for the professional in membrane separation technique field; Described back flush type hollow-fibre membrane ultra filtration filter 18 markets are on sale.

In the ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter 18 can be that a back flush type hollow-fibre membrane ultra filtration filter monomer form is only arranged; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

Express a related speech in parallel, the art-recognized meanings that itself referred to is clearly.

Express related monomer one speech, refer to itself function and structure equipment individuality completely.

Similarly, in the micro-filtration link, this back flush type tubular fibre membrane microfiltration strainer 19 can be that a back flush type tubular fibre membrane microfiltration strainer monomer form is only arranged; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

Can further install second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration strainer 19 its pure water inlets and described back flush type hollow-fibre membrane ultra filtration filter 18, this second topping-up pump is used to augment hydraulic pressure to satisfy the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This second topping-up pump not necessarily.

The microwave constrainer of described cage shape is exactly a metal cage; Be a mass of hole or mesh in himself structure of the microwave constrainer of this cage shape, the preferable range of described hole or its bore of mesh is between 0.5 centimetre and 3.0 centimetres, any set point value within this preferable range all is preferred available bore value, this bore value for example can be 0.5 centimetre, 1.0 centimetres, 1.75 centimetres, 2.2 centimetres, 3.0 centimetres, or the like; Certainly, if must select the hole or the mesh of other bore outside this preferable range for use, that also is that this case allows.

The structure of this case device embodiment can also comprise some annexes, described annex for example: the cooling water recirculation system or the air cooling system that are connected with magnetron 10 cooling ducts; Described annex also for example is used for electrodeless ultraviolet lamp 6 is fixed on fixed support within the microwave constrainer 5 of described cage shape; Described annex for example is used for microwave constrainer 5 with described cage shape again and is fixed on support member within the described silica tube 4; Described annex can certainly comprise described silica tube 4 is fixed on support or anchor within the described container 1; Described annex for example is installed in the strainer that is used to tackle impurity of reactor influent waste water end again, or the like.

Implement not draw described annex in the legend.

The embodiment of this case is not limited to the legend mode.

Claims (9)

1. initiatively the photochemical catalysis waste water of recognition reaction terminal point is degraded and is used the large vol reactor, the structure of this reactor comprises a container, its appearance profile of described container is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, the spherical or the ellipsoid bodily form, lower region at described container intracavity is equiped with many micro porous aeration heads, and, silica tube, this silica tube are erected at the inner chamber position of described container, and the two ends of this silica tube are equiped with the shutoff headkerchief, lay respectively on the described shutoff headkerchief at silica tube two ends and all offer the ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp is at least more than one, this quantity all is erected at the inside of described silica tube at least at more than one electrodeless ultraviolet lamp, and, pneumatic pump, this pneumatic pump is installed in the outside of described container, ventilation interface on the described silica tube one end shutoff headkerchief connects with the air outlet of described pneumatic pump via breather line and through described wall of a container, and the ventilation interface on its other end shutoff headkerchief of described silica tube connects with the micro porous aeration head that is positioned at described container intracavity lower region via another breather line, and, microwave generator, this microwave generator is installed in the outside of described container, and this microwave generator is a magnetron, and, waveguide, this waveguide is the member that is used for Transmission Microwave, an end of this waveguide and described magnetron UNICOM, and the other end of this waveguide sees through the inner chamber of described wall of a container towards described container, and, water pump, this water pump are used for containing to the inner chamber pumping of affiliated container the described waste water of organic pollutant, and this water pump is positioned at the outside of described container, the water outlet of this water pump is via ventilating water pipe and see through the inner chamber that described wall of a container leads to described container, the top of described container offers exhaust port, it is characterized in that, that end that sees through described wall of a container of this waveguide extends much further into the inner chamber of described container, this gos deep into that end of waveguide of described container intracavity and the inside that a shutoff headkerchief further seeing through described silica tube again probes into silica tube, and the structure of this reactor also comprises the microwave constrainer of the cage shape of metal material, and the microwave constrainer of cage shape is exactly a metal cage, contain many holes or mesh on the microwave constrainer of this cage shape, the function of the microwave constrainer of this cage shape is the constraint microwave, contains its unhelpful dissipation, simultaneously, allow most of UV-light to penetrate, the installation position of the microwave constrainer of this cage shape is positioned at the inside of described silica tube, and that end UNICOM that probes into silica tube of its inner chamber of microwave constrainer of this cage shape and described waveguide, described UNICOM refer to and connect on the microwave channel meaning and perforation, the described electrodeless ultraviolet lamp that is erected at silica tube inside all is rolled in wherein by the microwave constrainer of described cage shape, and topping-up pump, this topping-up pump are used for the degraded water afterwards that the supercharging pumping is mixed with a large amount of catalyst particles, its water-in of this topping-up pump connects with the inner chamber of described container via another ventilating water pipe and through described wall of a container, and, the preposition prefilter of back flush type, its water-in of the preposition prefilter of this back flush type connects with the water outlet of described topping-up pump, and, back flush type tubular fibre membrane microfiltration strainer, its pure water inlet of the preposition prefilter of described back flush type connects via the water-in of first water purifying valve with this back flush type tubular fibre membrane microfiltration strainer, and, back flush type hollow-fibre membrane ultra filtration filter, described its pure water inlet of back flush type tubular fibre membrane microfiltration strainer connects via the water-in of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter, and this its pure water inlet of back flush type hollow-fibre membrane ultra filtration filter connects with the entrance end of the 3rd water purifying valve, and the water side of the 3rd water purifying valve is outlet terminal water purifying water side, its sewage outlet of the preposition prefilter of described back flush type connects with the inner chamber of described container via first sewage valve, described its sewage outlet of back flush type tubular fibre membrane microfiltration strainer connects with the inner chamber of described container via second sewage valve, and described its sewage outlet of back flush type hollow-fibre membrane ultra filtration filter connects with the inner chamber of described container via the 3rd sewage valve, and each described strainer all is used to hold back catalyst particles, each its sewage outlet of described strainer is all migrated to the recovery of being held back catalyst particles with delivery port again or is refluxed and use delivery port again, and described many micro porous aeration heads are assembled formation cluster shape micro porous aeration head cluster mutually, and this cluster shape micro porous aeration head cluster is erected at the lower region of described container intracavity vacantly, the fore-and-aft distance of this cluster shape micro porous aeration head its bottom edge of cluster and described container intracavity bottom surface is between 10 centimetres and 50 centimetres, the transverse distance of this cluster shape micro porous aeration head cluster edge and described container intracavity sidewall arround it between 20 centimetres and 300 centimetres, this cluster shape micro porous aeration head its center of cluster or center of gravity be positioned at described silica tube under, and, ozone sensor, the sampling port of this its stopple coupon of ozone sensor is close to described exhaust port or probes into the inside of described exhaust port, and, the ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, this ozone sensor is via article one cable and this ozone content indicating meter, ozone attention device or ozone content indicating meter connect with the composite structure of ozone attention device, and, power-supply controller of electric, its output electric signal of this ozone sensor connects with this power-supply controller of electric via the second cable, this power-supply controller of electric connects with described magnetron via the 3rd cable, this power-supply controller of electric connects with described pneumatic pump via the 4th cable, and this power-supply controller of electric is the power-supply controller of electric that can carry out the power switch action according to the described electric signal that it received, and, ultrasonic transducer, this ultrasonic transducer is bottom outside position or the bottom inside position that is installed in this container, and, HF oscillation electric signal transmission cable, one end of this HF oscillation electric signal transmission cable connects with this ultrasonic transducer, and, HF oscillation electric signal producer, the other end of described HF oscillation electric signal transmission cable connects with this HF oscillation electric signal producer.

2. the large vol reactor is used in the photochemical catalysis waste water degraded of active recognition reaction terminal point according to claim 1, it is characterized in that, its material of microwave constrainer of this cage shape is the punching stainless steel of handling through mirror polish.

3. the large vol reactor is used in the photochemical catalysis waste water degraded of active recognition reaction terminal point according to claim 1, it is characterized in that, the microwave constrainer of this cage shape is to be made by the braiding of mirror polish Stainless Steel Wire.

4. the photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point according to claim 1, it is characterized in that, bottom at described container offers sewage draining exit, this sewage draining exit is used for deslagging, removes contamination, be equiped with wash water valve in this sewage draining exit position, described wash water valve is the valve that is used for blowdown control.

5. the photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point according to claim 1, it is characterized in that, its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, its filter opening aperture of described back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, and its filter opening aperture of described back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers.

6. the photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point according to claim 1, it is characterized in that this back flush type hollow-fibre membrane ultra filtration filter is made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

7. the photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point according to claim 1, it is characterized in that this back flush type tubular fibre membrane microfiltration strainer is made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

8. the photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point according to claim 1, it is characterized in that, be equiped with second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, this second topping-up pump is used to augment hydraulic pressure to satisfy the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter.

9. the photochemical catalysis waste water degraded large vol reactor of active recognition reaction terminal point according to claim 1, it is characterized in that the hole that spreads all in the microwave constrainer self structure of this cage shape or its bore scope of mesh are between 0.5 centimetre and 3.0 centimetres.