CN102826628A - High-treatment-capacity reactor for degrading electrodeless ultraviolet light catalytic wastewater - Google Patents
High-treatment-capacity reactor for degrading electrodeless ultraviolet light catalytic wastewater Download PDFInfo
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- CN102826628A CN102826628A CN2012103520719A CN201210352071A CN102826628A CN 102826628 A CN102826628 A CN 102826628A CN 2012103520719 A CN2012103520719 A CN 2012103520719A CN 201210352071 A CN201210352071 A CN 201210352071A CN 102826628 A CN102826628 A CN 102826628A
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Abstract
The invention relates to a high-treatment-capacity reactor for degrading electrodeless ultraviolet light catalytic wastewater, belonging to the technical field of wastewater treatment. The existing electrodeless ultraviolet light catalytic degradation technology for the organic pollutant-containing industrial wastewater has the problem of the useless dissipation of the energy since a mass of the microwave energy is absorbed by the wastewater body, and the problem of the less treatment capacity of the single-jar wastewater of the reactor. In order to solve the problems, an electrodeless ultraviolet lamp is arranged in a cage-shaped nonopaque microwave restraining device made from metal material, the microwave is guided into the microwave restraining device to be restrained, the useless loss of the microwave can be stopped, and in the structure, an ultraviolet-permeable quartz tube for gas-liquid isolation is arranged at a structure position between the microwave restraining device and wastewater body. On the basis of the structure, the great expansion of the design volume of the reactor can be realized due to the design volume for greatly expanding a microwave irradiation-free airspace in the reactor, so that the single-jar wastewater treatment quantity of the reactor can be greatly improved.
Description
Technical field
The present invention relates to a kind of electrodeless ultraviolet light catalysis waste water degraded and use the high throughput reactor drum, belong to the C02F technical field of waste water processing.
Background technology
Microwave and photo catalysis degradation treatment technology, effectively to the innoxious process for treating that contains the organic pollutant trade effluent, development in recent years is swift and violent as a kind of.
About the microwave and photo catalysis degradation technique,, can referring to publication number the one Chinese patent application case of CN102260003A as an example.
This publication number is the one Chinese patent application case of CN102260003A; Be with microwave as excitaton source, excite electrodeless uv lamp emitted in ultraviolet line, be mixed with the suspension liquid of photocatalyst titanium oxide in liquid internal irradiation; This electrodeless uv lamp is shrouded by silica tube to be protected; Have pneumatic pump continue to inject air to this silica tube inner chamber, the air that is overflowed by quartzy chamber is via pipeline and the micro porous aeration head UNICOM that is positioned at reactor bottom, and the lower zone of this inside reactor is the aeration zone; The upper area of this inside reactor is the microwave and photo catalysis reaction zone; This scheme is also with the built-in membrane separation assemblies of reactor drum, carries the water of analysing after the purification, and realizes that with this membrane separation assemblies holding back again of photocatalyst titanium dioxide fine particles use; This scheme is also set up dividing plate between electrodeless ultraviolet light source and membrane separation assemblies, be used to prevent the radiation injury of ultraviolet ray to the membrane separation assemblies of organic matter; Feed the air of inside reactor; Part is participated in the photocatalytic degradation reaction that relies on photocatalyst titanium oxide directly; Some air; Under the direct irradiation of UV-light, generate a certain amount of ozone, the ozone of this generation is also being brought into play the direct oxidative degradation that is directed against organic pollutant certainly.
This publication number is that the one Chinese patent application case of CN102260003A has undoubtedly played very important pushing effect for the progress of microwave and photo catalysis waste water degradation technique, and its research staff is admirable in this field institute unfolded work.
Based on the meaning of sincere admiration, and, the common striving direction, what will talk below us is problem.
We know that itself also can absorb the energy of microwave liquid water body, and itself temperature-rise effect of the liquid water body that causes being processed; And this temperature-rise effect of following wastewater treatment process and occurring but is not the situation that we expected, in other words; Microwave energy from magnetron is not used to excite electrodeless uv lamp fully, and has quite a few should only be used to excite the microwave energy of electrodeless uv lamp to be dissipated in described temperature-rise effect, and the temperature-rise effect that this kind is not fond of has caused unnecessary microwave energy to waste; In view of above-mentioned publication number is the apparatus structure scheme that the one Chinese patent application case of CN102260003A is showed, its rational approach can only be to reduce the purpose that single jar of processing capacity is reached the unnecessary dissipation of reduction microwave in other words through the volume that reduces the microwave and photo catalysis reactor drum; About this point, the clear expression in this its embodiment of CN102260003A application case about the whole suitable size of this apparatus structure, what its expressed preferred size was corresponding is exactly a device that profile is very little; So, thus, the distance of reactor wall and microwave radiation source is little; The wastewater flow rate that contacts with microwave is little, and waste water institute microwave energy absorbed is also little relatively, with it accordingly; Single jar wastewater treatment capacity is therefore also little, and more particularly, the pairing internal capacity of device suitable size expressed in the embodiment is 40 liters; Also be that single jar of wastewater treatment capacity is 40 liters, promptly 0.04 cube, in other words; It is once a complete set of, substantial length of operation has only solved 0.04 cubical trade effluent, so, just need carry out the repetition of being operated to the complete set of tail by head many times; Adding up of its treatment capacity just has plant-scale meaning; So to say, just individual analogy roughly, single jar of corresponding 0.04 cube of such wastewater treatment capacity of its preferred structure general size of this case; Need repetition 1000 times by a complete set, the substantial length of operation of head to tail; Its accumulation amount, just can reach 40 cubes such one have industrial level wastewater treatment capacity, so excessively loaded down with trivial details repetitive operation will cause the serious waste of human and material resources; It is thus clear that this kind may not be fully up to expectations by its actual waste water degradation treatment efficient of scheme that CN102260003A showed.Therefore; How not cause more microwave energy wastes or to reduce under the prerequisite of microwave energy waste; Increase single jar of wastewater treatment capacity; Reducing the unnecessary too many by the repetitive operation number of times of head to tail of this intermittent type wastewater treatment equipment, improve its waste water treatment efficiency, is a significant technical problem that merits attention.
Summary of the invention
Technical problem to be solved by this invention is; To the weak point that exists in the above-mentioned CN102260003A application case; Promptly; Microwave energy utilizes the little problem of the undesirable and actual single jar of wastewater treatment capacity of situation, researches and develops a kind of novel waste water photochemical catalysis DeR device that can address the above problem.
The present invention solve the technical problem through following scheme, and this scheme provides the degraded of a kind of electrodeless ultraviolet light catalysis waste water to use high throughput reactor drum, the structure of this reactor drum to comprise a metal vessel, and that its appearance profile of said metal vessel is is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form; Bottom position at said metal vessel inner chamber is equiped with some micro porous aeration heads, and silica tube, this silica tube are erected at the inner chamber position of said metal vessel; The two ends of this silica tube are equiped with the shutoff headkerchief, and lay respectively on the said shutoff headkerchief at silica tube two ends and all offer the ventilation interface, and; That electrodeless uv lamp, this electrodeless uv lamp are is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, and the quantity of this electrodeless uv lamp is at least more than one; This quantity all is erected at the inside of said silica tube at least at more than one electrodeless uv lamp, and, pneumatic pump; This pneumatic pump is installed in the outside of said metal vessel, and the ventilation interface on the said silica tube one of which end shutoff headkerchief is via breather line and see through the wall of said metal vessel and the air outlet UNICOM of said pneumatic pump, and the ventilation interface on its other end shutoff headkerchief of said silica tube is via another breather line and the micro porous aeration head UNICOM that is positioned at said metal vessel intracavity bottom; And, microwave generator, this microwave generator is installed in the outside of said metal vessel; This microwave generator is a magnetron, and, waveguide; This waveguide is the member that is used for Transmission Microwave, an end of this waveguide and said magnetron UNICOM, and the other end of this waveguide sees through the wall of said metal vessel and the inner chamber UNICOM of said metal vessel; And membrane separation assemblies, this membrane separation assemblies are installed in the inner chamber position of said metal vessel; And, water pump, this water pump is used for the extracting water purification; This water pump is positioned at the outside of said metal vessel, and this membrane separation assemblies is via ventilating water pipe and see through the wall of said metal vessel and the water-in UNICOM of water pump, and; Another water pump, this another water pump is used for the said waste water that pumping contains organic pollutant, and this another water pump is positioned at the outside of said metal vessel; The water outlet of this another water pump is via another ventilating water pipe and see through the wall of said metal vessel and the inner chamber UNICOM of said metal vessel, and the top of said metal vessel offers exhaust port, and emphasis is; That end of the wall that sees through said metal vessel of this waveguide extends much further into the inner chamber of said metal vessel, and this gos deep into that end and the inside that a shutoff headkerchief further seeing through said silica tube again probes into silica tube of the waveguide of said metal vessel inner chamber, and; The structure of this reactor drum also comprises the microwave constrainer of the cage shape of metal material, contains many holes on the microwave constrainer of this cage shape, and the function of the microwave constrainer of this cage shape is the constraint microwave; Contain its unhelpful dissipation, simultaneously, allow most of UV-light to penetrate; The installation position of the microwave constrainer of this cage shape is positioned at the inside of said silica tube, that end UNICOM that probes into silica tube of its inner chamber of microwave constrainer of this cage shape and said waveguide, and the said inner electrodeless uv lamp of silica tube that is erected at all is rolled in wherein by the microwave constrainer of said cage shape.
Said metal material one speech, the art-recognized meanings of itself is known.
Said magnetron, and, waveguide device, its art-recognized meanings is known for the professional of microwave technical field.Said magnetron, and waveguide etc. all have commercially available; Said waveguide is self manufacture as required, and this making is for the professional of microwave technical field, and the making of waveguide device is simple.
Said silica tube, its art-recognized meanings is known; Said silica tube market is on sale.
Said electrodeless uv lamp, its art-recognized meanings are known for the professional of light sources technical field; Said electrodeless uv lamp market is on sale; Said its shape of electrodeless uv lamp, size, inner institute blanketing gas, lamp wall material, lamp wall thickness, or the like, also can customize to electric light source manufacturing concern according to concrete design demand.Certainly, also can self manufacture.The making of electrodeless uv lamp is for the professional who possesses electric light source expertise, and its manufacturing technology is simple.
Said water pump, pneumatic pump, micro porous aeration head, membrane separation assemblies or the like, its art-recognized meanings, all is known, and all has commercially available separately for the professional in corresponding techniques field for it.
The said quantity that includes the silica tube of electrodeless uv lamp is not limit.
The quantity of said membrane module is not limit.
Its material of microwave constrainer of this cage shape can be any selected metal; But; Residing in view of it by the formed ozone gas mixture of strong ultraviolet radiation environment; And from exporting considering of the UV-light launched by electrodeless uv lamp to greatest extent through the specular reflection mechanism of complicacy as much as possible, the preferred metal material that is suitable for making the microwave constrainer of this cage shape is the punching stainless steel of handling through mirror polish.
Can process said microwave constrainer through welding, splicing or mould pressing process with bright finished punching stainless steel plate.
Can certainly process the microwave constrainer of this cage shape with bright finished Stainless Steel Wire braiding.
Be runnings such as convenient cleaning of regularly carrying out to inside reactor and maintenance; Can offer sewage draining exit in the bottom of said metal vessel; This sewage draining exit is used for deslagging, removes contamination, can be at this sewage draining exit position installing wash water valve, and said wash water valve is the valve that is used for blowdown control; In case of necessity, can utilize this sewage draining exit that is positioned at said metal vessel bottom that inside reactor liquid is emptied completely.
The structure of this case device can also comprise some annexes, said annex for example: the cooling water recirculation system or the air cooling system that are connected with the magnetron cooling duct; Said annex also for example is used for electrodeless uv lamp is fixed on the fixed support within the microwave constrainer of said cage shape; Said annex for example is used for the microwave constrainer of said cage shape is fixed on the support member within the said silica tube again; Said annex can certainly comprise said silica tube is fixed on support or anchor within the said metal vessel; Said annex for example is installed in switch and other valve on each flow and the airflow line again, or the like.
Advantage of the present invention is; Microwave constrainer with the cage shape that is placed in the inner metal material of said silica tube; Electrodeless uv lamp is wrapped among its inner chamber, its inner chamber of microwave constrainer of cage shape and with going deep into said metal vessel inner waveguide UNICOM, said UNICOM refers to the UNICOM on the microwave channel meaning; By this structure; The microwave that will come via the waveguide transmission constrains within its effective WS, and the containment microwave is to the unhelpful dissipation of peripheral waste water water body, and this case structure allows reactor drum significantly to expand its design volume; Allow single jar of wastewater treatment capacity of reactor drum significantly to promote, and need not worry again that microwave energy too much dissipates in unhelpful waste water water body temperature-rise effect.
Process under the situation of microwave constrainer at the bright finished punching stainless steel of employing; And; Adopting under the situation of bright finished Stainless Steel Wire cylinder mould as the microwave constrainer; Via the specular reflection of complicacy mechanism, both all can transfer out the UV-light from electrodeless uv lamp to greatest extent, and remedy himself entity of said microwave constrainer to greatest extent light is blocked, absorbs the loss that is caused.
Based on the structure of this case, the DESIGN OF REACTOR volume is that single jar of wastewater treatment capacity can be expanded to several cubes to dozens of cube; Even single jar hundreds of cubical volumes, also allow; Based on this structure of this case, can reduce the frequency of a complete set, substantial length of operation significantly, help the saving of human and material resources.
Description of drawings
Fig. 1 is the brief perspective diagram of this case structure of reactor.
Among the figure, the 1st, said metal vessel, 2,7 is respectively two water pumps that installation position is different, the 3rd, micro porous aeration head; The 4th, sewage draining exit, the 5th, wash water valve, the 6th, membrane separation assemblies, the 8th, silica tube; 9,19 is respectively two breather lines that installation position is different, the 10th, and pneumatic pump, the 11st, magnetron, the 12nd, go deep into the inner waveguide of said metal vessel; 13,18 is respectively the shutoff headkerchief at silica tube two ends, the 14th, and exhaust port, the 15th, the microwave constrainer of the cage shape of metal material; The 16th, electrodeless uv lamp, the 17th, the spatial domain that said metal vessel inside does not receive microwave exposure, the arrow among the figure indicate respectively different liqs into and out of direction.
Embodiment
In this case embodiment that Fig. 1 showed, the structure of this reactor drum comprises a metal vessel 1, and that said metal vessel 1 its appearance profile is is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, is equiped with some micro porous aeration heads 3 at the bottom position of said metal vessel 1 inner chamber; And, silica tube 8, this silica tube 8 is erected at the inner chamber position of said metal vessel 1, and the two ends of this silica tube 8 are equiped with the shutoff headkerchief; Said shutoff headkerchief is respectively shutoff headkerchief 13 and shutoff headkerchief 18, lays respectively on the said shutoff headkerchief 13,18 at silica tube 8 two ends and all offers the ventilation interface, and, electrodeless uv lamp 16; That this electrodeless uv lamp 16 is is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, and the quantity of this electrodeless uv lamp 16 is at least more than one, and this quantity all is erected at the inside of said silica tube 8 at least at more than one electrodeless uv lamp 16; And, pneumatic pump 10, this pneumatic pump 10 is installed in the outside of said metal vessel 1; Ventilation interface on the said silica tube 8 one of which end shutoff headkerchieves 13 is via breather line 9 and see through the wall and the air outlet UNICOM of said pneumatic pump 10 of said metal vessel 1, and the ventilation interface on said silica tube 8 its other end shutoff headkerchieves 18 is via another breather line 19 and be positioned at micro porous aeration head 3 UNICOMs of said metal vessel 1 intracavity bottom, and; Microwave generator, this microwave generator is installed in the outside of said metal vessel 1, and this microwave generator is a magnetron 11; And waveguide, this waveguide are the members that is used for Transmission Microwave; One end of this waveguide and said magnetron 11 UNICOMs, the other end of this waveguide sees through the wall of said metal vessel 1 and the inner chamber UNICOM of said metal vessel 1, and; Membrane separation assemblies 6, this membrane separation assemblies 6 is installed in the inner chamber position of said metal vessel 1, and; Water pump 7, this water pump 7 is used for the extracting water purification, and this water pump 7 is positioned at the outside of said metal vessel 1; This membrane separation assemblies 6 is via ventilating water pipe and see through the wall of said metal vessel 1 and the water-in UNICOM of water pump 7, and, another water pump 2; This another water pump 2 is used for the said waste water that pumping contains organic pollutant, and this another water pump 2 is positioned at the outside of said metal vessel 1, and the water outlet of this another water pump 2 is via another ventilating water pipe and see through the wall of said metal vessel 1 and the inner chamber UNICOM of said metal vessel 1; The top of said metal vessel 1 offers exhaust port 14, and emphasis is that end of the wall that sees through said metal vessel 1 of this waveguide 12 extends much further into the inner chamber of said metal vessel 1; This gos deep into that end and the inside that a shutoff headkerchief 13 further seeing through said silica tube 8 again probes into silica tube 8 of the waveguide 12 of said metal vessel 1 inner chamber, and the structure of this reactor drum also comprises the microwave constrainer 15 of the cage shape of metal material; Contain many holes on the microwave constrainer 15 of this cage shape, the function of the microwave constrainer 15 of this cage shape is the constraint microwave, contains its unhelpful dissipation; Simultaneously, allow most of UV-light to penetrate, the installation position of the microwave constrainer 15 of this cage shape is positioned at the inside of said silica tube 8; Microwave constrainer 15 its inner chambers of this cage shape and that end UNICOM that probes into silica tube 8 of said waveguide 12, said UNICOM refers to the UNICOM on the microwave channel meaning, and the said silica tube 8 inner electrodeless uv lamps 16 that are erected at all are rolled in wherein by the microwave constrainer 15 of said cage shape.
Said metal material one speech, the art-recognized meanings of itself is known.
Microwave constrainer 15 its materials of this cage shape can be any selected metals; But; Residing in view of it by the formed ozone gas mixture of strong ultraviolet radiation environment; And from exporting considering of the UV-light launched by electrodeless uv lamp 16 to greatest extent through the specular reflection mechanism of complicacy as much as possible, the preferred metal material that is suitable for making the microwave constrainer 15 of this cage shape is the stainless steel of handling through mirror polish.
Itself art-recognized meanings of said punching stainless steel one speech is known for stainless steel industry.
Can process said microwave constrainer 15 through welding, splicing or mould pressing process with bright finished punching stainless steel plate.
Also can process the microwave constrainer 15 of this cage shape with bright finished Stainless Steel Wire braiding.
Be routine preventive maintenance or the cleaning that makes things convenient for equipment, can offer sewage draining exit 4, certainly install wash water valve 5 in the position of sewage draining exit 4 in the bottom of said metal vessel 1.
Implement not draw said other annex in the legend.
The embodiment of this case is not limited to the legend mode.
Claims (4)
1. electrodeless ultraviolet light catalysis waste water degraded uses high throughput reactor drum, the structure of this reactor drum to comprise a metal vessel, and that its appearance profile of said metal vessel is is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, is equiped with some micro porous aeration heads at the bottom position of said metal vessel inner chamber; And silica tube, this silica tube are erected at the inner chamber position of said metal vessel; The two ends of this silica tube are equiped with the shutoff headkerchief, and lay respectively on the said shutoff headkerchief at silica tube two ends and all offer the ventilation interface, and; That electrodeless uv lamp, this electrodeless uv lamp are is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, and the quantity of this electrodeless uv lamp is at least more than one; This quantity all is erected at the inside of said silica tube at least at more than one electrodeless uv lamp, and, pneumatic pump; This pneumatic pump is installed in the outside of said metal vessel, and the ventilation interface on the said silica tube one of which end shutoff headkerchief is via breather line and see through the wall of said metal vessel and the air outlet UNICOM of said pneumatic pump, and the ventilation interface on its other end shutoff headkerchief of said silica tube is via another breather line and the micro porous aeration head UNICOM that is positioned at said metal vessel intracavity bottom; And, microwave generator, this microwave generator is installed in the outside of said metal vessel; This microwave generator is a magnetron, and, waveguide; This waveguide is the member that is used for Transmission Microwave, an end of this waveguide and said magnetron UNICOM, and the other end of this waveguide sees through the wall of said metal vessel and the inner chamber UNICOM of said metal vessel; And membrane separation assemblies, this membrane separation assemblies are installed in the inner chamber position of said metal vessel; And, water pump, this water pump is used for the extracting water purification; This water pump is positioned at the outside of said metal vessel, and this membrane separation assemblies is via ventilating water pipe and see through the wall of said metal vessel and the water-in UNICOM of water pump, and; Another water pump, this another water pump is used for the said waste water that pumping contains organic pollutant, and this another water pump is positioned at the outside of said metal vessel; The water outlet of this another water pump is via another ventilating water pipe and see through the wall of said metal vessel and the inner chamber UNICOM of said metal vessel, and the top of said metal vessel offers exhaust port, it is characterized in that; That end of the wall that sees through said metal vessel of this waveguide extends much further into the inner chamber of said metal vessel, and this gos deep into that end and the inside that a shutoff headkerchief further seeing through said silica tube again probes into silica tube of the waveguide of said metal vessel inner chamber, and; The structure of this reactor drum also comprises the microwave constrainer of the cage shape of metal material, contains many holes on the microwave constrainer of this cage shape, and the function of the microwave constrainer of this cage shape is the constraint microwave; Contain its unhelpful dissipation, simultaneously, allow most of UV-light to penetrate; The installation position of the microwave constrainer of this cage shape is positioned at the inside of said silica tube, that end UNICOM that probes into silica tube of its inner chamber of microwave constrainer of this cage shape and said waveguide, and the said inner electrodeless uv lamp of silica tube that is erected at all is rolled in wherein by the microwave constrainer of said cage shape.
2. the high throughput reactor drum is used in electrodeless ultraviolet light catalysis waste water degraded according to claim 1, it is characterized in that, its material of microwave constrainer of this cage shape is the punching stainless steel of handling through mirror polish.
3. the high throughput reactor drum is used in electrodeless ultraviolet light catalysis waste water degraded according to claim 1, it is characterized in that, the microwave constrainer of this cage shape is to be processed by the braiding of mirror polish Stainless Steel Wire.
4. the high throughput reactor drum is used in electrodeless ultraviolet light catalysis waste water degraded according to claim 1; It is characterized in that; Bottom at said metal vessel offers sewage draining exit; This sewage draining exit is used for deslagging, removes contamination, and is equiped with wash water valve in this sewage draining exit position, and said wash water valve is the valve that is used for blowdown control.
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