CN103209926A - 改进的合成金红石的方法b - Google Patents
改进的合成金红石的方法b Download PDFInfo
- Publication number
- CN103209926A CN103209926A CN2011800278045A CN201180027804A CN103209926A CN 103209926 A CN103209926 A CN 103209926A CN 2011800278045 A CN2011800278045 A CN 2011800278045A CN 201180027804 A CN201180027804 A CN 201180027804A CN 103209926 A CN103209926 A CN 103209926A
- Authority
- CN
- China
- Prior art keywords
- coal
- ilmenite
- content
- reduction
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 44
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 230000008569 process Effects 0.000 title claims abstract description 8
- 239000003245 coal Substances 0.000 claims abstract description 108
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 53
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical group O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 claims abstract description 52
- 230000009467 reduction Effects 0.000 claims abstract description 32
- 238000002309 gasification Methods 0.000 claims abstract description 27
- 229910052742 iron Inorganic materials 0.000 claims abstract description 25
- 230000002829 reductive effect Effects 0.000 claims abstract description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010936 titanium Substances 0.000 claims abstract description 13
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 13
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 23
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 239000005864 Sulphur Substances 0.000 claims description 15
- 239000003610 charcoal Substances 0.000 claims description 11
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- 238000005342 ion exchange Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 4
- 239000003077 lignite Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 239000003476 subbituminous coal Substances 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 8
- 230000009257 reactivity Effects 0.000 abstract description 7
- 235000013980 iron oxide Nutrition 0.000 abstract 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 abstract 2
- 239000003039 volatile agent Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 14
- 238000004458 analytical method Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- 230000004075 alteration Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 101150059062 apln gene Proteins 0.000 description 3
- 239000002802 bituminous coal Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000004484 Briquette Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002864 coal component Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1204—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 preliminary treatment of ores or scrap to eliminate non- titanium constituents, e.g. iron, without attacking the titanium constituent
- C22B34/1209—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 preliminary treatment of ores or scrap to eliminate non- titanium constituents, e.g. iron, without attacking the titanium constituent by dry processes, e.g. with selective chlorination of iron or with formation of a titanium bearing slag
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/10—Dry methods smelting of sulfides or formation of mattes by solid carbonaceous reducing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2010901440 | 2010-04-06 | ||
AU2010901440A AU2010901440A0 (en) | 2010-04-06 | Improved synthetic rutile process B | |
PCT/AU2011/000391 WO2011123889A1 (en) | 2010-04-06 | 2011-04-06 | Improved synthetic rutile process b |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103209926A true CN103209926A (zh) | 2013-07-17 |
Family
ID=44761921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2011800278045A Pending CN103209926A (zh) | 2010-04-06 | 2011-04-06 | 改进的合成金红石的方法b |
Country Status (5)
Country | Link |
---|---|
US (1) | US20130022521A1 (de) |
EP (1) | EP2556027A1 (de) |
CN (1) | CN103209926A (de) |
AU (1) | AU2011238420B2 (de) |
WO (1) | WO2011123889A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10674476B1 (en) | 2017-03-10 | 2020-06-02 | Wells Fargo Bank, N.A. | Contextual aware electronic alert system |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4085190A (en) * | 1975-04-29 | 1978-04-18 | Chyn Duog Shiah | Production of rutile from ilmenite |
AU639178B2 (en) * | 1991-04-19 | 1993-07-15 | Rgc Mineral Sands Limited | Conversion of ilmenite to synthetic rutile e.g. by the becher process |
CN1923703A (zh) * | 2005-09-01 | 2007-03-07 | 中南大学 | 岩矿型钛铁矿精矿制取人造金红石的方法 |
CN101244841A (zh) * | 2008-03-25 | 2008-08-20 | 攀钢集团攀枝花钢铁研究院有限公司 | 人造金红石的生产方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7315931A (de) * | 1972-12-04 | 1974-06-06 | ||
US4187117A (en) * | 1976-04-12 | 1980-02-05 | Quebec Iron And Titanium Corporation - Fer Et Titane Du Quebec, Inc. | Titanium slag-coke granules suitable for fluid bed chlorination |
US5403379A (en) * | 1992-05-15 | 1995-04-04 | Rgc Mineral Sands Limited | Reduction of titaniferous ores and apparatus |
US5524635A (en) * | 1992-09-14 | 1996-06-11 | Interventional Technologies Inc. | Apparatus for advancing a guide wire |
JP4153281B2 (ja) * | 2002-10-08 | 2008-09-24 | 株式会社神戸製鋼所 | 酸化チタン含有スラグの製造方法 |
-
2011
- 2011-04-06 EP EP11764946A patent/EP2556027A1/de not_active Withdrawn
- 2011-04-06 US US13/639,572 patent/US20130022521A1/en not_active Abandoned
- 2011-04-06 WO PCT/AU2011/000391 patent/WO2011123889A1/en active Application Filing
- 2011-04-06 AU AU2011238420A patent/AU2011238420B2/en not_active Ceased
- 2011-04-06 CN CN2011800278045A patent/CN103209926A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4085190A (en) * | 1975-04-29 | 1978-04-18 | Chyn Duog Shiah | Production of rutile from ilmenite |
AU639178B2 (en) * | 1991-04-19 | 1993-07-15 | Rgc Mineral Sands Limited | Conversion of ilmenite to synthetic rutile e.g. by the becher process |
CN1923703A (zh) * | 2005-09-01 | 2007-03-07 | 中南大学 | 岩矿型钛铁矿精矿制取人造金红石的方法 |
CN101244841A (zh) * | 2008-03-25 | 2008-08-20 | 攀钢集团攀枝花钢铁研究院有限公司 | 人造金红石的生产方法 |
Non-Patent Citations (2)
Title |
---|
张家驹: ""攀矿直接还原用煤的选择"", 《冶金能源》, vol. 11, no. 5, 30 September 1992 (1992-09-30), pages 9 - 12 * |
戴和武等: "《褐煤利用技术》", 28 February 1999, article "《褐煤利用技术》", pages: 55 * |
Also Published As
Publication number | Publication date |
---|---|
EP2556027A1 (de) | 2013-02-13 |
US20130022521A1 (en) | 2013-01-24 |
AU2011238420A1 (en) | 2012-11-01 |
WO2011123889A1 (en) | 2011-10-13 |
AU2011238420B2 (en) | 2013-03-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130717 |