CN103205288A - Clean synthetic diesel and synthetic process thereof - Google Patents
Clean synthetic diesel and synthetic process thereof Download PDFInfo
- Publication number
- CN103205288A CN103205288A CN2013100892470A CN201310089247A CN103205288A CN 103205288 A CN103205288 A CN 103205288A CN 2013100892470 A CN2013100892470 A CN 2013100892470A CN 201310089247 A CN201310089247 A CN 201310089247A CN 103205288 A CN103205288 A CN 103205288A
- Authority
- CN
- China
- Prior art keywords
- diesel
- diesel oil
- synthetic
- oil
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to synthetic diesel, in particular to clean synthetic diesel and a synthetic process thereof. The clean synthetic diesel is made by synthetizing raw water, nonionic surfactant, high alkalinity calcium sulfonate, lower alcohol, high alcohol, stabilizer, fatty acid, base oil, crude benzene, diesel, preservative, cetane number improver nitrate series, methylcyclopentadienyl manganese tricarbonyl, and antioxygen according to the certain weight percentage. The synthetic process includes steps of mixing the materials, stirring, allowing for settling, allowing for standing, heating, holding the temperature and the like. The clean synthetic diesel has the advantages that the clean synthetic diesel is well stable and able to infinitely mutually soluble with any diesel, is long in shelf life with no layering, fine in combustion performance, environmentally friendly, and saves energy, and the cost of the diesel is lowered. The clean synthetic diesel is especially suitable for various places in China in international shortage of energy resources.
Description
One, technical field
The present invention relates to a kind of combined diesel oil, relate in particular to a kind of cleaning combined diesel oil and synthesis technique thereof.
Two, background technology
At present domestic have a lot of a lot of about the report of water-base diesel-oil, but problems such as ubiquity quality instability: the fuel oil viscosity increases the influence atomizing and burns when temperature reduces; Winter, the internal combustion engine start difficulty can't be used; Bad and other fuel oil of stability demixing phenomenon of becoming turbid when mixing; Oil quality is not up to standard, and ash content is big, and carbon residue exceeds standard; Shelf-time grows existing emulsification demixing phenomenon.
Three, summary of the invention
The object of the present invention is to provide a kind of good stability, can infinitely dissolve each other with various diesel, the shelf-time is long not stratified; And have good burning performance, not only a kind of cleaning combined diesel oil and the synthesis technique thereof of environmental protection but also save energy.
The present invention is by raw material: water 10-15%, non-ionic surfactant Tween or sapn 1-5%, high alkaline calcium sulfonate 0.1-2%, low-carbon alcohol 3-8%, higher alcohols 2-6%, stablizer 1.5-5% is thanomin, diethanolamine, trolamine, sodium oleate, lipid acid 10-30%, the base oil coal 200# solvent oil 10-20% that namely navigates, crude benzol 10-20%, GB diesel oil 30-50%, sanitas 0.1%, cetane number improving agent nitric ether series 0.1-0.3% is isoamyl nitrate or different monooctyl ester, methyl cyclopentyl-dialkyl-tricarbon manganium 0.1-0.5%, oxidation inhibitor 0.05-0.1%.
The synthesis technique of cleaning combined diesel oil is: (1), water 10-15% is added the tween 80 of nonionogenic tenside 1-5% or polysorbate60 or sorbester p17 or sorbester p18 leave standstill through precipitation and handled 24 hours becomes water mixed liquid; (2), get low-carbon alcohol 3-8%, higher alcohols 2-6% synthesizes one through stirring, add stablizer and be thanomin or diethanolamine or trolamine or sodium oleate appoint a kind of 1.5-5% that gets thanomin or diethanolamine or trolamine or sodium oleate be stirred to evenly limpid bright after, join in the water mixed liquid of above-mentioned operation gained and heat, being heated to temperature is 30-50 ℃, in the time of 30-50 ℃, thermostatic hold-time is 60-80 minute, stir 10 minutes to limpid bright, form synthetic fluid; (3), add 10-30% lipid acid in the above-mentioned synthetic fluid, the homogenizer with 2000-3000 rev/min stirred 30 minutes; Add boat coal 200# solvent oil 10-20%, stirred 10 minutes, add GB diesel oil 30-50% again, stirred 30 minutes; (4), be that the isoamyl nitrate of nitric ether series or different monooctyl ester, methyl cyclopentyl-dialkyl-tricarbon manganium 0.1-0.5%, oxidation inhibitor 0.05-0.1% join in the material of technology (4) gained at last with crude benzol 10-20%, sanitas 0.1%, cetane number improving agent 0.1-0.3%, stir, namely get the cleaning combined diesel oil; (5), above-mentioned gained cleaning combined diesel oil sheared through high-speed shearing machine after, enter precipitation and leave standstill jar, precipitate after 48 hours, filtration enters the finished product jar and detects the adjustment index as requested.
Be subjected to the trust of Han Fusheng, national tractor mass supervision and inspection center has been carried out the use properties test on October 30th, 2006 to its SXH-1030-2 combined diesel oil that provides, and whether satisfies service requirements to estimate it.Experiment is carried out in discharging laboratory, national tractor mass supervision and inspection center.
Three test basis
1.GB 19756-2005 " tricar and low-speed truck diesel exhaust gas pollutant emission limit and measuring method (Chinese I, II stage) "
2.GB 9486-1988 " diesel engine stable state exhaust smoke and measuring method "
3.GB/T 17692-1999 " engine for automobile pure horsepower testing method "
The used key instrument equipment of four tests
Five engine basic specifications
Six test combined diesel oil main ingredients
Seven test conditionss
1. test the combined diesel oil that is respectively the 0# solar oil and prepares with the 0# solar oil with fuel oil, the component data of combined diesel oil has the consigner to provide.
2. test is CD40 bavin machine oil with lubricating oil.
3. atmospheric condition in the process of the test:
Envrionment temperature: 25 ℃
Relative humidity: 50%
Barometric point: 100.0kPa
Eight assay summary sheets
The present invention possesses six big effects: the one, and cracking energization effect: water is made up of hydrogen and oxygen, can cracking go out the hydrogen participation burning higher 3.52 times than diesel oil energy under the High Temperature High Pressure; The 2nd, the confession oxygen effect: the oxygen of cracking makes burning more abundant for burning has increased comburant oxygen; The 3rd, effect of micro-explosion: when producing the steam than self big 1700 times of volume during water vapor, can break through oil film oil is atomized once again, thus more abundant burning; The 4th, water coal vapour effect: water vapor is converted into CO2 and a large amount of heat release with the CO that fails to burn; The 5th, equal heat effect: steam can reduce cylinder body localized hyperthermia effectively and protect body, the resistance of reducing friction, alleviate coking; The 6th, environmental protection effect: emulsifying combustion can reduce the flue gas blowdown flow rate more than 30%.The invention has the advantages that the diesel oil good stability that is synthesized, can infinitely dissolve each other with various diesel that the shelf-time is long not stratified, have good burning performance that not only environmental protection but also energy-conservation has also reduced the cost of diesel oil simultaneously.It is particularly suitable for promoting the use of in China various places under the situation of current international energy anxiety.
(4) embodiment
Be described in further detail below in conjunction with the present invention of embodiment:
The present invention is by raw material: water 10-15%, non-ionic surfactant Tween or sapn 1-5%, high alkaline calcium sulfonate 0.1-2%, low-carbon alcohol 3-8%, higher alcohols 2-6%, stablizer 1.5-5% is thanomin, diethanolamine, trolamine, sodium oleate, lipid acid 10-30%, the base oil coal 200# solvent oil 10-20% that namely navigates, crude benzol 10-20%, GB diesel oil 30-50%, sanitas 0.1%, cetane number improving agent nitric ether series 0.1-0.3% is isoamyl nitrate or different monooctyl ester, methyl cyclopentyl-dialkyl-tricarbon manganium 0.1-0.5%, oxidation inhibitor 0.05-0.1%.
The synthesis technique of cleaning combined diesel oil is: (1), get material according to above-mentioned percent by weight, water 10-15% is added the tween 80 of nonionogenic tenside 1-5% or polysorbate60 or sorbester p17 or sorbester p18 leave standstill through precipitation and handled 24 hours, become water mixed liquid; (2), get low-carbon alcohol 3-8%, higher alcohols 2-6% synthesizes one through stirring, add stablizer and be thanomin or diethanolamine or trolamine or sodium oleate appoint a kind of 1.5-5% that gets thanomin or diethanolamine or trolamine or sodium oleate be stirred to evenly limpid bright after, join in the water mixed liquid of above-mentioned operation gained and heat, being heated to temperature is 30-50 ℃, in the time of 30-50 ℃, thermostatic hold-time is 60-80 minute, mix 10 minutes to limpid bright, form synthetic fluid; (3), add 10-30% lipid acid in the above-mentioned synthetic fluid, the homogenizer with 2000-3000 rev/min stirred 30 minutes; Add boat coal 200# solvent oil 10-20%, stirred 10 minutes, add GB diesel oil 30-50% again, stirred 30 minutes; (4), be that the isoamyl nitrate of nitric ether series or different monooctyl ester, methyl cyclopentyl-dialkyl-tricarbon manganium 0.1-0.5%, oxidation inhibitor 0.05-0.1% join in the material of technology (4) gained at last with crude benzol 10-20%, sanitas 0.1%, cetane number improving agent 0.1-0.3%, stir, namely get the cleaning combined diesel oil; (5), above-mentioned gained cleaning combined diesel oil sheared through high-speed shearing machine after, enter precipitation and leave standstill jar, precipitate after 48 hours, filtration enters the finished product jar and detects the adjustment index as requested.
Claims (2)
1. one kind is cleaned combined diesel oil, it is characterized in that by raw material: water 10-15%, non-ionic surfactant Tween or sapn 1-5%, high alkaline calcium sulfonate 0.1-2%, low-carbon alcohol 3-8%, higher alcohols 2-6%, stablizer 1.5-5% is thanomin, diethanolamine, trolamine, sodium oleate, lipid acid 10-30%, the base oil coal 200# solvent oil 10-20% that namely navigates, crude benzol 10-20%, GB diesel oil 30-50%, sanitas 0.1%, cetane number improving agent nitric ether series 0.1-0.3% is isoamyl nitrate or different monooctyl ester, methyl cyclopentyl-dialkyl-tricarbon manganium 0.1-0.5%, oxidation inhibitor 0.05-0.1% forms according to certain operation is synthetic.
2. a kind of synthesis technique that cleans combined diesel oil according to claim 1, it is characterized in that described cleaning combined diesel oil synthesis technique is: (1), water 10-15% is added the tween 80 of nonionogenic tenside 1-5% or polysorbate60 or sorbester p17 or sorbester p18 leave standstill through precipitation and handled 24 hours becomes water mixed liquid; (2), get low-carbon alcohol 3-8%, higher alcohols 2-6% synthesizes one through stirring, add stablizer and be thanomin or diethanolamine or trolamine or sodium oleate appoint a kind of 1.5-5% that gets thanomin or diethanolamine or trolamine or sodium oleate be stirred to evenly limpid bright after, join in the water mixed liquid of above-mentioned operation gained and heat, being heated to temperature is 30-50 ℃, in the time of 30-50 ℃, thermostatic hold-time is 60-80 minute, stir 10 minutes to limpid bright, form synthetic fluid; (3), add 10-30% lipid acid in the above-mentioned synthetic fluid, the homogenizer with 2000-3000 rev/min stirred 30 minutes; Add boat coal 200# solvent oil 10-20%, stirred 10 minutes, add GB diesel oil 30-50% again, stirred 30 minutes; (4), be that the isoamyl nitrate of nitric ether series or different monooctyl ester, methyl cyclopentyl-dialkyl-tricarbon manganium 0.1-0.5%, oxidation inhibitor 0.05-0.1% join in the material of technology (4) gained at last with crude benzol 10-20%, sanitas 0.1%, cetane number improving agent 0.1-0.3%, stir, namely get the cleaning combined diesel oil; (5), above-mentioned gained cleaning combined diesel oil sheared through high-speed shearing machine after, enter precipitation and leave standstill jar, precipitate after 48 hours, filtration enters the finished product jar and detects the adjustment index as requested.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310089247.0A CN103205288B (en) | 2013-03-06 | 2013-03-06 | A kind of clean combined diesel oil and synthesis technique thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310089247.0A CN103205288B (en) | 2013-03-06 | 2013-03-06 | A kind of clean combined diesel oil and synthesis technique thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103205288A true CN103205288A (en) | 2013-07-17 |
| CN103205288B CN103205288B (en) | 2016-01-20 |
Family
ID=48752697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310089247.0A Active CN103205288B (en) | 2013-03-06 | 2013-03-06 | A kind of clean combined diesel oil and synthesis technique thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103205288B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449889A (en) * | 2014-10-31 | 2015-03-25 | 新疆亿科林新能源科技有限公司 | Modified clean diesel oil and preparation method thereof |
| CN104877715A (en) * | 2015-04-20 | 2015-09-02 | 刘敏 | Synthetic diesel oil and synthesis process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050005506A1 (en) * | 2003-07-08 | 2005-01-13 | Henly Timothy J. | Distillate fuel compositions for improved combustion and engine cleanliness |
| CN1632066A (en) * | 2004-12-03 | 2005-06-29 | 刘少君 | Condensed emulsified diesel and its preparation method and application |
| CN102643692A (en) * | 2012-05-08 | 2012-08-22 | 刘少君 | Concentrated emulsified diesel fuel and preparation method thereof |
-
2013
- 2013-03-06 CN CN201310089247.0A patent/CN103205288B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050005506A1 (en) * | 2003-07-08 | 2005-01-13 | Henly Timothy J. | Distillate fuel compositions for improved combustion and engine cleanliness |
| CN1632066A (en) * | 2004-12-03 | 2005-06-29 | 刘少君 | Condensed emulsified diesel and its preparation method and application |
| CN102643692A (en) * | 2012-05-08 | 2012-08-22 | 刘少君 | Concentrated emulsified diesel fuel and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449889A (en) * | 2014-10-31 | 2015-03-25 | 新疆亿科林新能源科技有限公司 | Modified clean diesel oil and preparation method thereof |
| CN104877715A (en) * | 2015-04-20 | 2015-09-02 | 刘敏 | Synthetic diesel oil and synthesis process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103205288B (en) | 2016-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Bhuiya et al. | Prospects of 2nd generation biodiesel as a sustainable fuel–Part 2: Properties, performance and emission characteristics | |
| Hazrat et al. | A mini review on the cold flow properties of biodiesel and its blends | |
| CN101886003B (en) | Vehicle fuel oil environmentally-friendly and energy-saving agent | |
| US20090235573A1 (en) | Methods of making hybrid fuel and fuel additives | |
| CN104164258B (en) | Alcohol-based biological fuel oil by taking swill-cooked dirty oil as raw material | |
| CN102260554A (en) | Microemulsified biodiesel and preparation technique thereof | |
| CN102504890A (en) | Composite methanol diesel and preparation method thereof | |
| CN101348738A (en) | Emulsified biomass oil additive, emulsified biomass oil using the emulsified biomass oil additive and preparation thereof | |
| CN106609168A (en) | Coal based biofuel | |
| CN101921634A (en) | Energy-saving fuel oil composition | |
| CN103205288A (en) | Clean synthetic diesel and synthetic process thereof | |
| CN109897676A (en) | A kind of soybean oil/ethyl alcohol/tetrahydrofuran fuel combination suitable for diesel engine | |
| CN108546575A (en) | Biological alcohol-based fuel oil hydrotropy solubilizer | |
| CN102127477B (en) | Petrochemical additive and preparation method thereof | |
| CN101210204A (en) | Additive and its vehicular methanol diesel oil and preparing method | |
| CN112899046A (en) | Composite plateau fuel additive and preparation method thereof | |
| CN101445751A (en) | Non-shear-form environment-friendly and energy-saving watered procetane | |
| WO2002092731A1 (en) | Compositions for non-polluting fuels, preparation processes and use thereof | |
| CN106701219A (en) | Navigation alcohol fuel combustion-supporting additive for automobile and manufacturing method thereof | |
| CN1948444B (en) | Alcohol kind blended gasoline and its preparation method | |
| US8882860B2 (en) | Emulsifier for water-in-oil emulsion fuel | |
| CN101418242B (en) | Energy-saving fuel oil and preparation method thereof | |
| CN101434875A (en) | Ethanol-diesel mixed fuel formula | |
| CN101200657A (en) | Combustion engine composite fuel and preparation method thereof | |
| Vibhanshu et al. | Experimental investigation of diesel engine fueled with Jatropha oil blend with ethanol |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |