CN103193518A - Coating controlled-release carbon dioxide air fertilizer and preparation method thereof - Google Patents
Coating controlled-release carbon dioxide air fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN103193518A CN103193518A CN2013101564204A CN201310156420A CN103193518A CN 103193518 A CN103193518 A CN 103193518A CN 2013101564204 A CN2013101564204 A CN 2013101564204A CN 201310156420 A CN201310156420 A CN 201310156420A CN 103193518 A CN103193518 A CN 103193518A
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- Prior art keywords
- add
- preparation
- calcium carbonate
- carbon dioxide
- ace
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 17
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000011248 coating agent Substances 0.000 title claims abstract description 12
- 238000000576 coating method Methods 0.000 title claims abstract description 12
- 239000003337 fertilizer Substances 0.000 title abstract description 14
- 238000013270 controlled release Methods 0.000 title abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 37
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 19
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 15
- 239000003814 drug Substances 0.000 claims description 9
- 229940079593 drug Drugs 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 9
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 102000011759 adducin Human genes 0.000 claims description 3
- 108010076723 adducin Proteins 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 235000011089 carbon dioxide Nutrition 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention discloses a coating controlled-release carbon dioxide air fertilizer and a preparation method thereof, which belongs to fertilizers and fertilizer preparation methods, particularly fertilizers capable of producing carbon dioxide and preparation methods thereof. According to the preparation method, aluminum sulfate and light calcium carbonate are respectively pelleted and coated and then are uniformly mixed in parts by weight ratio of 2.2:1, the mixture is packaged in a sealing manner, and the two raw materials of the product are respectively coated so as to be separated in the storage and transportation process and be prevented from reacting, so that the storage time of the product can be effectively prolonged. The coating controlled-release carbon dioxide air fertilizer is uniform in particle and long in quality guarantee period and can react to give off pure carbon dioxide when encountering water. The preparation method has the characteristics of time and labor saving, economy, practicability and the like.
Description
Technical field
The invention belongs to the preparation method of fertilizer and fertilizer, particularly produce fertilizer of carbonic acid gas and preparation method thereof.
Background technology
Carbon-dioxide gasfertilizer is the indispensable fertilizer of modern protection ground cultivation; the inventor has formerly invented a kind of preparation method CN1807361 of granular CO 2 gas fertilizer; this invention provides the method that Tai-Ace S 150 is prepared carbon-dioxide gasfertilizer with the calcium carbonate bonding granulation of mixture heat by a certain percentage; though having, the method that the carbonic acid gas of this method preparation uses liquid acid and carbonate to prepare carbonic acid gas is convenient to the advantage transporting, preserve, use; find in practice still to exist and self react the shortcoming that the quality guaranteed period falls short of easily.
Summary of the invention
The objective of the invention is to overcome the shortcoming that carbon-dioxide gasfertilizer self reacts easily in the prior art, the shelf time is short, provide a kind of coated slow release carbon-dioxide gasfertilizer another object of the present invention to provide the preparation method of this gas fertilizer.
Technical scheme of the present invention is, a kind of preparation method of coated slow release carbon-dioxide gasfertilizer, it is characterized in that: comprise the steps: the granulation of A. light calcium carbonate: the lime white that light calcium carbonate is added weight 1-3% moisture 80% evenly carries out extruder grain after the stirring, granularity 1.5-2mm, dry for standby;
B. prepare Drug coating: in container, add 95 kg of water, at first open agitator, under fully stirring, slowly add Xylo-Mucine, continue again to be added into after transparent up to dissolving fully, add 5 kilograms altogether, after adding, also will continue to stir 2 hours, placed 10-20 hour, stand-by
C. dressing: calcium carbonate granule is added agitator, add the Drug coating of step B gained under whipped state, add-on is the 1-2% of calcium carbonate granule weight, stirs and make muddy and evenly namely finishes dressing, dry standby,
The Tai-Ace S 150 particle of granularity 1.5-2mm is added agitator, add the Drug coating of step B gained under whipped state, add-on is the 1-2% of Tai-Ace S 150 particle weight, stirs and make muddy and evenly namely finishes dressing, dry standby,
D. mixed preparing: the Tai-Ace S 150 that dressing is good and calcium carbonate granule mix by 2.2: 1 ratio of weight and number, pack, and get product;
Described Tai-Ace S 150 is Al
2(SO
4)
3+ 18H
2O.
The present invention carries out remix behind granulation and the dressing respectively with Tai-Ace S 150 and light calcium carbonate, and this dressing can cut off two kinds of raw materials in storage and transportation process, prevent that both from reacting, and can effectively prolong the storage time of product.
When needs use, spray clear water at gas fertilizer, after this product touches water, the dressing dissolving, hydrolysis reaction takes place to Tai-Ace S 150 in contact with water, generates aluminium hydroxide and sulfuric acid, and sulfuric acid generates carbonic acid gas and water with calcium carbonate reaction, and driving a reaction moves right.Emit great amount of carbon dioxide, for the crop photosynthesis effect is supplied raw materials.
Security: what this reaction raw materials was used is acid salt, all very safe to skin and crop, and reacted residue is good little fertilizer owing to contain trace elements such as a large amount of sulphur, calcium, wherein sulphur can promote crop to the absorption of nitrogen, phosphorus, potassium, and calcium can improve crop disease-resistant power.
Characteristics: uniform particles, long quality-guarantee period is met water and can be reacted, and emits pure carbon dioxide.Have characteristics such as save time, laborsaving, economical and practical.
Embodiment
The specific embodiment of the present invention is:
Embodiment 1, a kind of preparation method of coated slow release carbon-dioxide gasfertilizer, comprise the steps: the granulation of A. light calcium carbonate: carry out extruder grain, granularity 1.5-2mm, dry for standby after moisture 80% the lime white that light calcium carbonate is added weight 1-3% evenly stirs;
B. prepare Drug coating: in container, add 95 kg of water, at first open agitator, under fully stirring, slowly add Xylo-Mucine, continue again to be added into after transparent up to dissolving fully, add 5 kilograms altogether, after adding, also will continue to stir 2 hours, placed 10-20 hour, stand-by
C. dressing: calcium carbonate granule is added agitator, add the Drug coating of step B gained under whipped state, add-on is the 1-2% of calcium carbonate granule weight, stirs and make muddy and evenly namely finishes dressing, dry standby,
The Tai-Ace S 150 particle of granularity 1.5-2mm is added agitator, add the Drug coating of step B gained under whipped state, add-on is the 1-2% of Tai-Ace S 150 particle weight, stirs and make muddy and evenly namely finishes dressing, dry standby,
D. mixed preparing: the Tai-Ace S 150 that dressing is good and calcium carbonate granule mix by 2.2: 1 ratio of weight and number, pack, and get product;
Described Tai-Ace S 150 is Al2 (SO4) 3+18H2O.
Claims (2)
1. the preparation method of a coated slow release carbon-dioxide gasfertilizer is characterized in that: comprise the steps:
A. light calcium carbonate granulation: carry out extruder grain, granularity 1.5-2mm, dry for standby after moisture 80% the lime white that light calcium carbonate is added weight 1-3% evenly stirs;
B. prepare Drug coating: in container, add 95 kg of water, at first open agitator, under fully stirring, slowly add Xylo-Mucine, continue again to be added into after transparent up to dissolving fully, add 5 kilograms altogether, after adding, also will continue to stir 2 hours, placed 10-20 hours, stand-by
C. dressing: calcium carbonate granule is added agitator, add the Drug coating of step B gained under whipped state, add-on is 1-2% of calcium carbonate granule weight, stirs and make muddy and evenly namely finishes dressing, dry standby,
The Tai-Ace S 150 particle of granularity 1.5-2mm is added agitator, add the Drug coating of step B gained under whipped state, add-on is 1-2% of Tai-Ace S 150 particle weight, stirs and make muddy and evenly namely finishes dressing, dry standby,
D. mixed preparing: the Tai-Ace S 150 that dressing is good and calcium carbonate granule mix by 2.2: 1 ratio of weight and number, pack, and get product;
Described Tai-Ace S 150 is Al
2(SO
4)
3+ 18H
2O.
2. by the preparation method's of the described coated slow release carbon-dioxide gasfertilizer of claim 1 the coated slow release carbon-dioxide gasfertilizer that makes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310156420.4A CN103193518B (en) | 2013-04-28 | 2013-04-28 | Coating controlled-release carbon dioxide air fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310156420.4A CN103193518B (en) | 2013-04-28 | 2013-04-28 | Coating controlled-release carbon dioxide air fertilizer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103193518A true CN103193518A (en) | 2013-07-10 |
| CN103193518B CN103193518B (en) | 2014-07-16 |
Family
ID=48716360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310156420.4A Active CN103193518B (en) | 2013-04-28 | 2013-04-28 | Coating controlled-release carbon dioxide air fertilizer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103193518B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105165763A (en) * | 2015-08-06 | 2015-12-23 | 广西柳州昊邦日化有限公司 | Method for manufacturing mosquito sucking mat for mosquito sucking device |
| CN106699330A (en) * | 2016-08-19 | 2017-05-24 | 中国科学院华南植物园 | Preparation method and application of sustained and controlled release hydrogen fertilizer or compound hydrogen fertilizer |
| CN108947640A (en) * | 2017-08-07 | 2018-12-07 | 石河子大学 | It is sustained CO 2 gas fertilizer and preparation method thereof and purposes |
| CN113545344A (en) * | 2021-07-23 | 2021-10-26 | 安徽省通源环境节能股份有限公司 | Submerged plant growth-promoting sustained-release tablet and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1149568A (en) * | 1996-08-14 | 1997-05-14 | 赵国强 | CO2 gas fertilizer solid producer |
| CN1296934A (en) * | 2000-01-22 | 2001-05-30 | 王晓宇 | CO2 gas fertilizer |
| CN1400196A (en) * | 2001-07-31 | 2003-03-05 | 王兆荣 | Granular CO2 gas fertilizer and its preparation method |
| CN1807361A (en) * | 2006-02-22 | 2006-07-26 | 王维超 | Granular carbon dioxide and its preparation method |
-
2013
- 2013-04-28 CN CN201310156420.4A patent/CN103193518B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1149568A (en) * | 1996-08-14 | 1997-05-14 | 赵国强 | CO2 gas fertilizer solid producer |
| CN1296934A (en) * | 2000-01-22 | 2001-05-30 | 王晓宇 | CO2 gas fertilizer |
| CN1400196A (en) * | 2001-07-31 | 2003-03-05 | 王兆荣 | Granular CO2 gas fertilizer and its preparation method |
| CN1807361A (en) * | 2006-02-22 | 2006-07-26 | 王维超 | Granular carbon dioxide and its preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 严金: "塑料大棚专用二氧化碳颗粒气肥", 《农业知识》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105165763A (en) * | 2015-08-06 | 2015-12-23 | 广西柳州昊邦日化有限公司 | Method for manufacturing mosquito sucking mat for mosquito sucking device |
| CN106699330A (en) * | 2016-08-19 | 2017-05-24 | 中国科学院华南植物园 | Preparation method and application of sustained and controlled release hydrogen fertilizer or compound hydrogen fertilizer |
| CN108947640A (en) * | 2017-08-07 | 2018-12-07 | 石河子大学 | It is sustained CO 2 gas fertilizer and preparation method thereof and purposes |
| CN108947640B (en) * | 2017-08-07 | 2021-06-25 | 石河子大学 | Slow-release carbon dioxide gas fertilizer and preparation method and application thereof |
| CN113545344A (en) * | 2021-07-23 | 2021-10-26 | 安徽省通源环境节能股份有限公司 | Submerged plant growth-promoting sustained-release tablet and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103193518B (en) | 2014-07-16 |
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| ASS | Succession or assignment of patent right |
Owner name: SHANDONG ZOETICLAND BIOLOGICAL TECHNOLOGY CO., LTD Free format text: FORMER OWNER: WANG WEICHAO Effective date: 20140605 |
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Free format text: CORRECT: ADDRESS; FROM: 250031 JINAN, SHANDONG PROVINCE TO: 250409 JINAN, SHANDONG PROVINCE |
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Effective date of registration: 20140605 Address after: Ancheng Pingyin County of Ji'nan City, Shandong province 250409 Township West Village Applicant after: Shandong Zoeticland Biotechnology Co., Ltd. Address before: Flyover District of Shandong province 250031 Ji'nan Lishan Road No. 189 Huang business center area B Room 405 Ji'nan Kim Wai Yip Co. Applicant before: Wang Weichao |
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| C14 | Grant of patent or utility model | ||
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Denomination of invention: Coated slow-release carbon dioxide gas fertilizer and its preparation method Effective date of registration: 20220124 Granted publication date: 20140716 Pledgee: Shandong Pingyin Rural Commercial Bank Co.,Ltd. Pledgor: SHANDONG ZOETICLAND BIOLOGICAL TECHNOLOGY CO.,LTD. Registration number: Y2022980000932 |
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