CN101003450A - Composite boric fertilizer, and producing technical method - Google Patents
Composite boric fertilizer, and producing technical method Download PDFInfo
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- CN101003450A CN101003450A CN 200710010107 CN200710010107A CN101003450A CN 101003450 A CN101003450 A CN 101003450A CN 200710010107 CN200710010107 CN 200710010107 CN 200710010107 A CN200710010107 A CN 200710010107A CN 101003450 A CN101003450 A CN 101003450A
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- zinc
- fertilizer
- boron
- concentrated solution
- iron
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Abstract
This invention discloses a method for producing compound boron fertilizer, which is white or light green crystal, and mainly composed of: B 1.0-1.2 wt.%, Zn 0.2-0.5 wt.%, Fe 0.6-1.0 wt.%, and Mg more than 7.0 wt.%. The method comprises: preparing concentrated solution, preparing Zn-Fe mixed solution, preparing semi-finished product, and preparing the final product. The compound boron fertilizer contains Fe and Zn that are necessary for the growth of cotton and rape. Thus, the compound boron fertilizer can compensate the defects of B-Mg fertilizer, promote the development of cotton and rape root systems, improve the ability to absorb nutrients, stimulate the development of gynoecia germens, accelerate the growth, promote photosynthesis, shorten the growth period, advance the mature time, and prevent deficiency symptom. The compound boron fertilizer has increased yield (by 15-25%), simple process, easy application, and no pollution.
Description
Technical field
The present invention relates to a kind of inorganic chemical fertilizer, relate to a kind of boric magnesium fertilizer specifically.
Background technology
The boric acid that utilizes that follows is for a long time produced waste liquid manufacturing crystalline boron fertiliser containing magnesium, be mainly used in cotton, rapeseed cultivation, its consumption is 70% of the total consumption of boric magnesium fertilizer, but because crystalline boron fertiliser containing magnesium composition only contains boron and magnesium, can not satisfy cotton, growth of rape to other micro-demand, cause cotton, yield of rape to be difficult to improve.Have not yet to see the boric magnesium fertilizer that contains zinc, ferro element and the report of manufacturing process.
Summary of the invention
The present invention is directed to the deficiency of present boric magnesium fertilizer composition, propose the compound boron fertilizer and the method for manufacturing technology of a kind of suitable cotton, growth of rape needs.
The technical scheme that the present invention takes is: a kind of compound boron fertilizer and method of manufacturing technology is characterized in that: outward appearance is white or little green crystal, its main component (% is in the element quality): boron 1.0～1.2, zinc 0.2～0.5, iron 0.6～1.0, magnesium＞7.0; Above-mentioned compound boron fertilizer method of manufacturing technology:
Concentrated solution preparation: boric acid waste liquid is neutralized to pH 6～7 with light-burning magnesium powder under stirring at normal temperature, and neutralizer is through the pressure filter press filtration, and gained filtrate is carried out vacuum concentration under 100～110 ℃, 0.3～0.4MPa, makes relative density and be 1.350～1.360 concentrated solution;
Zinc-iron mixed solution preparation: in reactor, add concentrated solution, sulfuric acid, iron filings, oxide powder and zinc in stirring at normal temperature down to the dissolving that fully reacts completely of iron filings, zinc oxide;
The work in-process preparation: the zinc-iron mixed solution is joined in the crystallizer, add concentrated solution, stir, leave standstill crystallization under 20～25 ℃, crystal is separated out after whizzer is isolated secondary mother liquid, and the crystal work in-process are 60～70 ℃ of dryings;
Finished product is composite: in the exsiccant work in-process, add boric acid according to boron content, promptly get compound boron fertilizer after mixing.
The effective constituent of compound boron fertilizer is boric acid, magnesium sulfate heptahydrate, iron vitriol, Zinc Sulphate Heptahydrate, its proportioning is to select according to controlling of production process and field fertilization requirement, when effective composition low, can obtain effect of increasing production though increase rate of fertilizer application, but rate of fertilizer application heightens and adds the fertilising burden, and the low product of production effective constituent, not only invalid components influences packing, the transportation increase cost that fertilizer efficiency also is a product more in the product.Produce high effective constituent product owing to be subjected to the restriction of invalid components content in the raw material, should not improve effective constituent, use pure chemistry product formulated product cost too high, the user is difficult to accept.
Prove that in cotton, rapeseed cultivation field experiment result compound boron fertilizer can promote cotton, rape root prosperity, strengthen it and absorb the nutrient ability, can stimulate the gynoecium ovary development, accelerating growth, improve light and effect, shorten vegetative period, early flowering, solid and ripe, prevent and treat the flower bud of cotton effectively and the flower and the colored and unreal nutritional deficiency disease of rape, its effect of increasing production is than crystalline boron fertiliser containing magnesium improve 15%～25%.
The manufacturing of compound boron fertilizer mainly is the waste liquid that utilizes in the boric acid production process, main component is in the waste liquid: boric acid 4%～5%, sulfuric acid 0.2%～0.5%, magnesium sulfate heptahydrate 23%～28%, its mesoboric acid, sal epsom are the effective constituent of compound boron fertilizer, excessive sulfuric acid adopts the light burnt powder neutralization, and the light burnt powder main component is a magnesium oxide, and its reaction formula is:
MgO+H
2SO
4→MgSO
4+H
2O
The sal epsom that the neutralization back produces is as the effective constituent utilization, waste liquid after the neutralization carries out press filtration to remove water-insoluble impurity, filtrate concentrating removed excessive moisture, makes the filtrate relative density reach 1.350～1.360 (37～38Be °), helps crystallization operation thereafter.
Zinc-iron composition in the compound boron fertilizer is that iron filings and zinc oxide are generated FeSO with sulfuric acid reaction in reactor
4And ZnSO
4, its reaction formula is:
Fe+H
2SO
4→FeSO
4+H
2
ZnO+H
2SO
4→ZnSO
4+H
2O
Above-mentioned reactant mixes with the boric acid waste liquid concentrated solution and carries out crystallization, carries out centrifugation after the crystallization, and drying is carried out in isolated crystallization, and isolated mother liquor contains boric acid and sal epsom, and can to return boric acid waste liquid storage pond stand-by.
The above-mentioned crystallization work in-process that make add a certain amount of boric acid, because boron-containing quantity difference in the raw material waste liquid generally is lower than the effective constituent amount of requirement, thereby need adds boric acid, Mg content is higher in the waste liquid, generally within the effective constituent amount, need not to adjust.
The invention has the beneficial effects as follows: compound boron fertilizer is owing to contain iron, the zinc element of plant growth needs, boron make-up fertiliser containing magnesium defective, can promote cotton rape well developed root system, strengthen it and absorb the nutrient ability, can stimulate the gynoecium ovary development, accelerating growth, improve light and effect, shorten vegetative period, early flowering, solid and ripe, prevent and treat the flower bud of cotton effectively and the flower and the colored and unreal nutritional deficiency disease of rape, its effect of increasing production is than crystalline boron fertiliser containing magnesium improve 15%～25%.
The manufacturing of the compound boron fertilizer of the present invention is based on the waste liquid in the boric acid production, helps environment protection and reduces product cost, and its production technique is simple, and is easy to implement.
Embodiment:
Main raw material: boric acid waste liquid: from the boric acid production plant
Magnesia unslacked: Dashiqiao City, industrial goods Liaoning prosperous space breeze factory
Sulfuric acid: industrial goods 93%
Iron filings: industrial goods
Zinc oxide: industrial goods
Boric acid: industrial goods one-level
Embodiment 1 from the waste liquid main component of boric acid production is: boric acid 4.8%, sulfuric acid 0.4%, sal epsom 24.1%.
To make per hundred kilograms of compound boron fertilizers, the 300kg boric acid waste liquid is neutralized to pH6 with the 4kg light-burning magnesium powder, and neutralization back press filtration is concentrated into 240kg with filtrate under 100～110 ℃, and concentrated solution is stand-by; In reactor, add 1.1kg iron filings, 0.5 kg zinc oxide and 30kg concentrated solution, drip 1.4kg sulfuric acid at normal temperatures, to the dissolving that fully reacts completely of iron filings, zinc oxide, reaction solution is sent into crystallizer, add the 210kg concentrated solution, in crystallization below 25 ℃, centrifugation after the crystallization, the gained crystallization makes work in-process 60～70 ℃ of dryings.Through check boron content is 0.62, adds boric acid 3.3kg by boracic 1.2% and mixes and make the compound boron fertilizer of finished product.
Product through the check active constituent content is: in the element quality, and boron 1.2%, magnesium 7.2%, zinc 0.5%, iron 1%.
Consisting of of embodiment 2 boric acid waste liquids: boric acid 4%, sulfuric acid ' 0.4%, sal epsom 25.6%, according to
The method of embodiment 1 changes proportioning, produces effective constituent: boron 1%, magnesium＞7%, zinc 0.2%, the compound boron fertilizer of iron 0.6%.
Boric acid waste liquid 300kg, magnesia unslacked 4kg neutralization also is concentrated into 160kg, iron zinc mixed solution: iron filings 0.7kg zinc oxide 0.3kg concentrated solution 30kg sulfuric acid 0.8kg crystallizer adds concentrated solution 130kg.
The work in-process boron-containing quantity of producing is 0.4% to add boric acid 3.4kg.Actual measurement effective constituent is: boron 1.02%, magnesium 7.8%, zinc 0.21%, iron 0.59%.
Consisting of of embodiment 3 boric acid waste liquids: boric acid 5%, sulfuric acid ' 0.2%, sal epsom 27.6% changes proportioning according to the method for embodiment 1, produces effective constituent and is: boron 1.2%, magnesium＞7%, zinc 0.1%, the compound boron fertilizer of iron 0.4%.
Boric acid waste liquid 300kg, magnesia unslacked 2kg neutralization also is concentrated into 160kg, iron zinc mixed solution: iron filings 0.46kg
Zinc oxide 0.15kg concentrated solution 30kg sulfuric acid 0.48kg crystallizer adds concentrated solution 130kg.
The work in-process boron-containing quantity of producing is 0.48% to add boric acid 4kg.Actual measurement effective constituent is: boron 1.2%, magnesium 7.9%, zinc 0.21%, iron 0.59%.
Reference examples is selected the crystallization boric magnesium fertilizer of existing market sale for use, and its effective constituent is: boron 1% magnesium 8% carries out cotton, rape field manurial experiment by the compound boron fertilizer and the reference examples crystallization boric magnesium fertilizer of embodiment 1, embodiment 2 and embodiment 3 manufacturings:
Fertilizer application period base manure: rate of fertilizer application 3kg/ mu
Leaf fertilizer: the 5-6 leaf phase is obtain solution according to a conventional method, carries out foliage spray
Rate of fertilizer application 400g/ mu
The fertilizer efficiency determination data is as follows:
| Embodiment | Output of cotton (kilogram/mu) | Yield of rape (kilogram/mu) |
| Embodiment 1 | 225 | 248 |
| Embodiment 2 | 210.5 | 238.9 |
| Embodiment 3 | 206 | 214.3 |
| Reference examples | 182 | 197.4 |
Claims (2)
1 one kinds of compound boron fertilizers and method of manufacturing technology is characterized in that: outward appearance is white or little green crystal, its main component (% is in the element quality): boron 1.0～1.2, zinc 0.2～0.5, iron 0.6～1.0, magnesium＞7.0.
2 according to the said method of manufacturing technology of claim 1, it is characterized in that:
Concentrated solution preparation: boric acid waste liquid is neutralized to pH6～7 with light-burning magnesium powder under stirring at normal temperature, and neutralizer is through the pressure filter press filtration, and gained filtrate is carried out vacuum concentration under 100～110 ℃, 0.3～0.4MPa, makes relative density and be 1.350～1.360 concentrated solution;
Zinc-iron mixed solution preparation: in reactor, add concentrated solution, sulfuric acid, iron filings, oxide powder and zinc in stirring at normal temperature down to the dissolving that fully reacts completely of iron filings, zinc oxide;
The work in-process preparation: the zinc-iron mixed solution is joined in the crystallizer, add concentrated solution, stir, leave standstill crystallization under 20～25 ℃, crystal is separated out after whizzer is isolated secondary mother liquid, and the crystal work in-process are 60～70 ℃ of dryings;
Finished product is composite: in the exsiccant work in-process, add boric acid according to boron content, promptly get compound boron fertilizer after mixing.
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|---|---|---|---|
| CN 200710010107 CN101003450A (en) | 2007-01-19 | 2007-01-19 | Composite boric fertilizer, and producing technical method |
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|---|---|---|---|
| CN 200710010107 CN101003450A (en) | 2007-01-19 | 2007-01-19 | Composite boric fertilizer, and producing technical method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101337848B (en) * | 2008-08-11 | 2010-07-14 | 爱沃(北京)农业技术有限公司 | Granule type boron-magnesium fertilizer and method for preparing same |
| CN105693505A (en) * | 2014-11-27 | 2016-06-22 | 江苏华尔化工有限公司 | Treatment method of 1,4-dihydroxyanthraquinone industrial wastewater |
| CN108911797A (en) * | 2018-08-17 | 2018-11-30 | 营口菱镁化工集团有限公司 | A kind of ascharite fertilizer and preparation method thereof |
| CN109650947A (en) * | 2019-02-15 | 2019-04-19 | 夏念冉 | A kind of method of industrial waste sulfuric acid production hydrogen sulfate potash fertilizer |
-
2007
- 2007-01-19 CN CN 200710010107 patent/CN101003450A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101337848B (en) * | 2008-08-11 | 2010-07-14 | 爱沃(北京)农业技术有限公司 | Granule type boron-magnesium fertilizer and method for preparing same |
| CN105693505A (en) * | 2014-11-27 | 2016-06-22 | 江苏华尔化工有限公司 | Treatment method of 1,4-dihydroxyanthraquinone industrial wastewater |
| CN108911797A (en) * | 2018-08-17 | 2018-11-30 | 营口菱镁化工集团有限公司 | A kind of ascharite fertilizer and preparation method thereof |
| CN109650947A (en) * | 2019-02-15 | 2019-04-19 | 夏念冉 | A kind of method of industrial waste sulfuric acid production hydrogen sulfate potash fertilizer |
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