CN103174051B - A kind of manufacture method of light basis weight distillation bat printing body paper - Google Patents

A kind of manufacture method of light basis weight distillation bat printing body paper Download PDF

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CN103174051B
CN103174051B CN201310084551.6A CN201310084551A CN103174051B CN 103174051 B CN103174051 B CN 103174051B CN 201310084551 A CN201310084551 A CN 201310084551A CN 103174051 B CN103174051 B CN 103174051B
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body paper
basis weight
bat printing
wet strength
printing body
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CN103174051A (en
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徐喜中
林宏
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ZHEJIANG JIAWEIKANG SPECIAL PAPER CO Ltd
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ZHEJIANG JIAWEIKANG SPECIAL PAPER CO Ltd
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Abstract

The invention discloses the manufacture method of a kind of light basis weight distillation bat printing body paper, first by needlebush pulpboard and leaf wood pulpboard mixing pulping, through double plate mill mixing defibrination, successively wet strength agent and many sizing agents is added in pond with slurry, mix, through screening, purification, Top wire former, squeezing, oven dry, press polish, batch obtained distillation bat printing body paper, this patent is by controlling pulp furnish and mixing beating process, optimize the interpolation of Recompounded multielement wet strength agent and sizing agent, obtained a kind of light basis weight distillation bat printing body paper.

Description

A kind of manufacture method of light basis weight distillation bat printing body paper
Technical field
The invention belongs to pulp technology for making paper, relate to the manufacture method of a kind of light basis weight distillation bat printing body paper.
Background technology
Digital thermal transfer printing technology originates from the U.S. the earliest, and in the state such as Korea S, Italy, development is very fast, and we have become digital trans-printing consumption maximum in the world at present and have added building site.Current China is every year from the ground import such as Korea S, Holland about 1300 tons of heat sublimation transfer printing papers, and heat sublimation transfer printing paper only has AW company of the U.S., the Hansol company of ATT company and Korea S and Dutch product to be consumer acceptance.
Heat transfer printing paper is called for short heat-transferring printing paper, also known as hot transfer paper, xylopyrography paper.Hot transfer paper printing is by pattern printing on a kind of special paper, by applying uniform temperature and pressure, by design transfer on stock (as cotton, chemical fibre kind fabric, vessel etc.), forms complete, bright-coloured, that stereovision is strong pattern.In this process, the paper of transfer printing carrier function is played heat-transferring printing paper.According to its transfer printing principle, heat-transferring printing paper can be divided into thermosol glue-type and heat sublimation type.Thermosol glue-type transfer printing calico paper also claims glued membrane heat-transferring printing paper, and its surface has one deck hot melt to play the coating of cohesive action.
It is cotton textiles, silk, crudefiber crop material that thermosol transfer printing paper is suitable for stock, its action method be by the pattern of thermosol transfer printing paper with printed fabric and merged mutually, suitably heat pressurization at the paper back side, this coating is cohered together with pattern and is transferred on fabric.
By pattern good for computer photograph, word printing of inkjet printer on paper (printing ink used is a kind of special water fever sublimation transfer sole pigment ink), again paper and stock are overlaped, under uniform temperature and pressure, the ink of paper is sublimed into gas phase state and transfers on stock and form continuous whole pattern, in this process, the paper of carrier and transferance is played heat sublimation transfer printing paper.
The quality requirement of heat sublimation transfer printing paper and performance evaluation:
Heat sublimation transfer printing paper all uses certain requirement to image printing quality, transfer quality and paper shaped stability etc., and the transfer printing paper of heat sublimation simultaneously needs resistance to certain high temperature.
Heat sublimation transfer printing paper requires that face coat absorbency is good, ink droplet infiltration rate fast, and when printing complete, image is without obviously piling ink and color bleeding phenomenon.Should meet the curling deformation phenomenon that waits under common room temperature environment little, heat-resisting quantity will be got well in addition, and temperature is 250 DEG C time, and paper is without being obviously out of shape and carbonization phenomenon.
Body paper, except possessing the basic demand of general coated paper, there are certain requirements body paper density, air permeability etc.Body paper tightness is generally at 0.9g/cm 3above, air permeability is less; Body paper also needs good tensile strength and heat resistance, and especially after the heating, body paper still needs to keep some strength.When all with needlebush and hardwood chemical pulp join copy heat sublimation transfer printing paper body paper time, body paper heat resistance is better, and when particularly softwood pulp is more, the heat resistance of body paper can be better.
Needlebush pulpboard, leaf wood pulpboard and CTMP chemi-mechanical pulp are raw material, add wet strength agent Polyamide Epoxy (PAE), alum and sizing agent cationic rosin size respectively after making beating to stir and obtain heat sublimation transfer printing paper body paper by papermaking process flow again, and improve paper properties by optimizing beating degree, the use amount of the various additive of paper-making process and the parameter of manufacturing paper with pulp of paper machine.
Heat sublimation transfer printing paper is used for outdoor advertising, with regular price-line advertising with compared with material (as paper etc.), has obviously advantage.At present, the producer of domestic production heat sublimation transfer printing paper is considerably less, there is certain gap between product quality and foreign paper, large-tonnage product mainly from imports such as Korea S, Italy, Holland, price comparison costliness (about 30,000 ~ 60,000 yuan/ton).
Light basis weight is current paper industry development trend, can save papermaking raw material, and reduce the cost of papermaking and hot transfer printing, hot transfer printing marble paper domestic at present can accomplish quantitative 32 g/m 2, the minimum of import transfer printing paper quantitatively can accomplish 35 g/m 2.And the paper good toughness of this light basis weight, tensile strength is good, and the evenness of paper is good.
Along with the development of thermal dye sublimation transfer printing technology and people are to the accreditation of thermal dye sublimation transfer printing product and dependence, the market demand of heat sublimation transfer printing paper increases considerably in a short time, break the trade monopoly situation of import heat sublimation transfer printing paper, solve during domestic heat sublimation transfer printing paper light basis weightization is produced the technical bottleneck problem produced, improving domestic heat sublimation transfer printing paper quality has been current top priority, and research and development light basis weight high-quality heat sublimation transfer printing paper is imperative.
Summary of the invention
Existing distillation bat printing body paper is in light basis weight manufacture process, there is easy print through, tensile strength technical barrier that is poor, easily fold, for this technology difficult problem and deficiency, the object of the invention is to manufacture a kind of light basis weight distillation bat printing body paper, by kind and the consumption of Recompounded multielement wet strength agent, internal sizing agent, the indices of obtained light basis weight distillation bat printing body paper can reach the technical requirement of high-grade heat sublimation bat printing body paper.
To achieve these goals, the present invention adopts following technical scheme to realize:
A kind of manufacture method of light basis weight distillation bat printing body paper
(1) slurry preparation: be that the ratio mixing of 1:1 ~ 3:1 adds hydrabrusher and carries out size degradation with mass ratio by softwood pulp, hardwood pulp, pulping mass concentration controlled 3% ~ 4%, when the slurries in pulper are dispersed to without lodicule;
(2) pull an oar: pulled an oar by double disc refiner by the slurries of step (1) gained, controlling beating degree is 50 ~ 60 ° of SR, weight in wet base 2.5 ~ 3.5g, and sends into blending chest;
(3) slurry will mixed in blending chest, is pumped to stuff box, and in stock proportioner, add wet strength agent and sizing agent, stirs;
(4) after being uniformly mixed, control online slurry dense 7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, through squeezing, oven dry, press polish, batch, the operation such as to cut and obtain light basis weight and to distil bat printing body paper.
Wherein, softwood pulp adopts south and north pine slurry, and hardwood pulp adopts the wood pulp of poplar and Eucalyptus.
Wherein, the order of addition of wet strength agent and sizing agent for first to add wet strength agent, then adds sizing agent.To ensure better paper strength and Surface absorption intensity.
Wherein, wet strength agent comprises amphoteric starch and modified polyamide epoxy resin, and wherein the mass ratio of amphoteric starch and modified polyamide epoxy resin is 1:1 ~ 1:4, and the addition of wet strength agent is 0.5% ~ 3% of mixed slurry quality.
Wherein, sizing agent is that AKD, cationic rosin size and alum are mixed to form, and the mass ratio of AKD, cationic rosin size, alum is 1:5:10 ~ 1:10:20, and the addition of sizing agent is 0.05% ~ 0.20% of mixed slurry quality.
Compared with existing technology, advantage of the present invention is by optimizing wet strength agent, the kind of sizing agent and consumption and controlling online slurry dense 7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, through squeezing, oven dry, press polish, batch, the operation such as to cut obtained quantitatively for rise 28g/m 2following magnificent bat printing body paper all technical all meets the technical requirement of high-grade heat sublimation transfer printing.
concrete embodiment
Embodiment one
A manufacture method for light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (Southern Pine) and hardwood pulp (Eucalyptus) are softwood pulp according to weight ratio: hardwood pulp=1:1, mixing defibrination to 60 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:1, and the addition of double base wet strength agent A is 3% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:5:10, is 0.20% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment two
A kind of light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (north pine) and hardwood pulp (poplar) are softwood pulp according to weight ratio: hardwood pulp=3:1, mixes defibrination to 50 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:2, and the addition of double base wet strength agent A is 2% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:5:10, is 0.10% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment three
A kind of light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (Southern Pine) and hardwood pulp (poplar) are softwood pulp according to weight ratio: hardwood pulp=1:1, mixing defibrination to 55 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:3, and the addition of double base wet strength agent A is 1% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:10:20, is 0.10% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment four
A kind of light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (north pine) and hardwood pulp (Eucalyptus) are softwood pulp according to weight ratio: hardwood pulp=3:1, mixes defibrination to 55 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:4, and the addition of double base wet strength agent A is 0.5% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:10:20, is 0.05% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment five
A manufacture method for light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (Southern Pine) and hardwood pulp (Eucalyptus) are softwood pulp according to weight ratio: hardwood pulp=1:1, mixing defibrination to 52 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:1, and the addition of double base wet strength agent A is 2% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:5:10, is 0.15% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment six
A kind of light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (north pine) and hardwood pulp (poplar) are softwood pulp according to weight ratio: hardwood pulp=2:1, mixes defibrination to 52 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:1, and the addition of double base wet strength agent A is 3% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:8:16, is 0.10% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment seven
A kind of light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (Southern Pine) and hardwood pulp (poplar) are softwood pulp according to weight ratio: hardwood pulp=1:1, mixing defibrination to 60 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:3, and the addition of double base wet strength agent A is 2% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:10:20, is 0.15% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
Embodiment eight
A kind of light basis weight distillation bat printing body paper, comprises the steps:
Softwood pulp (north pine) and hardwood pulp (Eucalyptus) are softwood pulp according to weight ratio: hardwood pulp=2:1, mixes defibrination to 55 by step one 0sR;
Step 2, adds double base wet strength agent A in stuff box, comprises amphoteric starch and modified polyamide epoxy resin, amphoteric starch: modified polyamide epoxy resin=1:3, and the addition of double base wet strength agent A is 1% of over dry stock quality.
Step 3, adds multiple elements design wet strength agent AKD, cationic rosin size and alum, AKD: cationic rosin size: alum=1:8:20, is 0.10% of over dry stock quality and mixes for addition in stuff box.
Step 4, regulates slurry to head box online slurry dense 0.7%, head box quantity of reflux 10%, speed of a motor vehicle 250m/min, online, shapings, dehydration, squeezing, oven dry, press polish, batches and namely obtains light basis weight and to distil bat printing body paper.
In the present invention, the interpolation of the proportioning of different slurry kind, wet strength agent, sizing agent, mainly based on the paper properties of light basis weight distillation bat printing body paper, such as, softwood pulp and wet strength agent are for promoting into the tensile strength of paper; Hardwood pulp, for improving into the shortcoming of paper print through, fold, is given to the less gas permeability of paper and expansion and contraction; Plasm-glue-blending is for being given to the suitable water suction ink absorption of paper, little to printing-ink absorption affinity, promotes the rate of transform of ink in transfer printing production.

Claims (4)

1. a manufacture method for light basis weight distillation bat printing body paper, is characterized in that comprising following steps:
(1) slurry preparation: softwood pulp, hardwood pulp are mixed in proportion and adds hydrabrusher and carry out size degradation, pulping mass concentration is controlled 3% ~ 4%, when the slurries in pulper are dispersed to without lodicule;
(2) pull an oar: the slurries of step (1) gained are pulled an oar by double disc refiner, and sends into blending chest;
(3) slurry will mixed in blending chest, is pumped to stuff box, and in stock proportioner, add wet strength agent and sizing agent, stirs;
(4) after being uniformly mixed, control online slurry mass concentration 7%, head box quantity of reflux is 10%, speed of a motor vehicle 250m/min, obtains light basis weight distillation bat printing body paper successively through post processing;
Wherein in step (3), wet strength agent comprises amphoteric starch and modified polyamide epoxy resin, wherein the mass ratio of amphoteric starch and modified polyamide epoxy resin is 1:1 ~ 1:4, the addition of wet strength agent is 0.5% ~ 3% of mixed slurry quality, sizing agent is that AKD, cationic rosin size and alum are mixed to form, the mass ratio of AKD, cationic rosin size, alum is 1:5:10 ~ 1:10:20, and the addition of sizing agent is 0.05% ~ 0.20% of mixed slurry quality;
The beating degree controlling double disc refiner in described step (2) is 50 ~ 60 ° of SR, weight in wet base 2.5 ~ 3.5g.
2. according to the manufacture method of a kind of light basis weight distillation bat printing body paper described in claim 1, it is characterized in that: described softwood pulp, hardwood pulp are that the ratio mixing of 1:1 ~ 3:1 adds hydrabrusher with mass ratio.
3., according to the manufacture method of a kind of light basis weight distillation bat printing body paper described in claim 1, it is characterized in that, softwood pulp adopts south and north pine slurry, and hardwood pulp adopts the wood pulp of poplar and Eucalyptus.
4., according to the manufacture method of a kind of light basis weight distillation bat printing body paper described in claim 1, it is characterized in that, the order of addition of wet strength agent and sizing agent for first to add wet strength agent, then adds sizing agent.
CN201310084551.6A 2013-03-18 2013-03-18 A kind of manufacture method of light basis weight distillation bat printing body paper Active CN103174051B (en)

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CN108725061B (en) * 2017-04-18 2020-08-28 王子控股株式会社 Base paper and heat transfer paper for heat transfer paper
CN109385925A (en) * 2017-08-02 2019-02-26 浙江佳维康特种纸有限公司 A kind of paper wet manufacturing process of high dimensional stability
CN116463882A (en) * 2023-05-09 2023-07-21 浙江哲丰新材料有限公司 Sizing agent treatment process of transfer printing base paper

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US20050070186A1 (en) * 2003-09-29 2005-03-31 Georgia-Pacific Resins, Inc. Urea-formaldehyde binder composition and process
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CN102154923A (en) * 2010-12-22 2011-08-17 山东华泰纸业股份有限公司 Manufacture technology of sub-quality paper
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