CN103173978A - Desizing liquid for brocade silk fabric and desizing method of brocade silk fabric - Google Patents
Desizing liquid for brocade silk fabric and desizing method of brocade silk fabric Download PDFInfo
- Publication number
- CN103173978A CN103173978A CN2013100519023A CN201310051902A CN103173978A CN 103173978 A CN103173978 A CN 103173978A CN 2013100519023 A CN2013100519023 A CN 2013100519023A CN 201310051902 A CN201310051902 A CN 201310051902A CN 103173978 A CN103173978 A CN 103173978A
- Authority
- CN
- China
- Prior art keywords
- desizing
- silk
- weaving
- picture
- desizing liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 62
- 238000009990 desizing Methods 0.000 title claims abstract description 48
- 239000007788 liquid Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000011572 manganese Substances 0.000 claims abstract description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 9
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims abstract description 7
- 238000009941 weaving Methods 0.000 claims description 32
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 238000006424 Flood reaction Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- FFFFQADKKUIYDO-UHFFFAOYSA-J [Na+].[Fe+3].C(=O)([O-])CN(C)CC(=O)[O-].C(=O)([O-])CN(C)CC(=O)[O-] Chemical compound [Na+].[Fe+3].C(=O)([O-])CN(C)CC(=O)[O-].C(=O)([O-])CN(C)CC(=O)[O-] FFFFQADKKUIYDO-UHFFFAOYSA-J 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 4
- MSXHSNHNTORCAW-GGLLEASOSA-M sodium;(2s,3s,4s,5r,6s)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O MSXHSNHNTORCAW-GGLLEASOSA-M 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 159000000000 sodium salts Chemical class 0.000 abstract description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 abstract 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 abstract 1
- 108010077895 Sarcosine Proteins 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 abstract 1
- 239000000176 sodium gluconate Substances 0.000 abstract 1
- 229940005574 sodium gluconate Drugs 0.000 abstract 1
- 235000012207 sodium gluconate Nutrition 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 10
- 238000004513 sizing Methods 0.000 description 9
- 230000014759 maintenance of location Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- -1 softener Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000009955 starching Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XWSGEVNYFYKXCP-UHFFFAOYSA-N 2-[carboxymethyl(methyl)amino]acetic acid Chemical compound OC(=O)CN(C)CC(O)=O XWSGEVNYFYKXCP-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000003230 hygroscopic agent Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses desizing liquid for brocade silk fabric and a desizing method of the brocade silk fabric. The pH value of the desizing liquid for the brocade silk fabric is 11-12; and the desizing liquid consists of the following components: 1-3g/L of sodium gluconate, 4-8g/L of hydrogen peroxide, 2-4mumol/L of a dinuclear manganese complex, 1-3g/L of 4-(2-nonanoyloxyethoxycarbonyloxy) sodium benzene sulfonate, 0.5-1.5g/L of N-carboxymethyl-N-iron methylglycine (III) sodium salt and a proper amount of sodium hydroxide. By adopting the desizing liquid disclosed by the invention to perform desizing treatment on the brocade silk fabric, the desizing rate is high, the obtained desized fabric has a high capillary effect and a high mechanical performance and is favorable for performing successive dyeing and finishing technologies, and the successive dyeing and finishing quality is guaranteed; and moreover, the hand feeling of the fabric is improved since size is effectively removed.
Description
Technical field
The present invention relates to a kind of fabric with the desizing method of desizing liquid and fabric, relate in particular to a kind of picture-weaving in silk silk fabrics with the desizing method of desizing liquid and picture-weaving in silk silk fabrics.
Background technology
In weave dyeing and finishing technique, the fabric take yarn as warp all must be processed through starching before weaving, and with brute force, ABRASION RESISTANCE and the smooth degree of raising warp thread, thereby reduces warp end break, and guaranteeing weaves cotton cloth carries out smoothly.Warp sizing oar material used has natural slurry such as starch, wild starch, chemical sizwe such as polyvinyl alcohol (PVA), polyacrylic acid (PAA), cellulose preparation such as carboxymethyl cellulose (CMC) etc.Also add other composition such as preservative agent, softener, hygroscopic agent, anti-friction composition etc. in sizing liquor.The height of warp sizing rate and the quality of fiber, yarn count, density etc. are relevant, the fabric that yarn count is thin, density is large, and the warp sizing rate is high, the general fabrics rate of sizing 4%～8%.
The grey cloth spreading mass is unfavorable to dyeing and printing process, because the existence of slurry can be stain the dyeing and finishing working solution, expends and dyes material, even can hinder and dye contacting of material and fiber, affects the quality of dyeing and printing products.Therefore, fabric just must be processed through destarch at the beginning of dyeing and finishing processing, removes as much as possible the grey cloth spreading mass.It is different and different according to the kind of following process that destarch requires, and for example is used for the fabric of dyeing, stamp, and destarch is had relatively high expectations, and can slightly hang down the destarch requirement of BLEACHED FABRIC.
Warp thread institute spreading mass kind is relevant with the fiber species that fabric uses, and starch slurry is multiplex in cellulose base fiber fabric, and as COTTON FABRIC, linen etc., chemical sizwe is multiplex in closing fine fabric.Sometimes also use the mixed slurry starching.Destarch is to carry out destarch under desizing agent and certain effect condition.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of picture-weaving in silk silk fabrics with the desizing method of desizing liquid and picture-weaving in silk silk fabrics.The method flow process is simple, applicable large production; Less to the fabric strength damage, environmental protection.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of picture-weaving in silk silk fabrics desizing liquid, pH value 11-12, formed by following component: gluconic acid sodium salt 1-3g/L, hydrogen peroxide 4-8g/L, double-core manganese complex 2-4 μ mol/L, 4-(2-nonanoyl oxygen base oxethyl ketonic oxygen base) benzene sulfonic acid sodium salt 1-3g/L, N-carboxymethyl-sarcosine iron (III) sodium salt 0.5-1.5g/L, NaOH is appropriate.
Double-core manganese complex, molecular formula are [Mn
2 IV(μ-O)
3(Me
3TACN)
2] [PF
6]
2H
2O。Its preparation method was documented in interim " activation of double-core manganese complex in cold bleaching " literary composition in " printing and dyeing " in 2011 the 21st.
N-carboxymethyl-sarcosine iron (III) sodium salt, CAS accession number: 98063-75-3, English name: N-Carboxymethyl-N-methylglycine ferric sodium salt.
4-(2-nonanoyl oxygen base oxethyl ketonic oxygen base) benzene sulfonic acid sodium salt, molecular structural formula is as follows:
4-(2-nonanoyl oxygen base oxethyl ketonic oxygen base) benzene sulfonic acid sodium salt, molecule is comprised of two parts, and the one end is long nonpolar hydrocarbon chain, i.e. a hydrophobic group; The other end is a shorter polar group, and namely hydrophilic group, be a kind of surfactant of benzenesulfonates.
Picture-weaving in silk silk fabrics of the present invention is as follows with the preparation method of desizing liquid: under room temperature, gluconic acid sodium salt, hydrogen peroxide, double-core manganese complex, 4-(2-nonanoyl oxygen base oxethyl ketonic oxygen base) benzene sulfonic acid sodium salt and N-carboxymethyl-sarcosine iron (III) sodium salt are added to the water, add again NaOH, regulate the pH value to 11-12, stir, can make.
Picture-weaving in silk silk fabrics desizing liquid of the present invention can adopt the conventional method of this area to carry out destarch to fabric, as filling-steaming process, pressurization boiling process, padding method or the similar approach such as infusion process in 60-100 ℃ of scope.
Further,
The present invention also provides a kind of desizing method of picture-weaving in silk silk fabrics, comprises dipping desizing liquid, decatize and water-washing step,
Wherein, the desizing liquid in described dipping desizing liquid step adopts above-mentioned picture-weaving in silk silk fabrics desizing liquid.
Preferably,
At room temperature the picture-weaving in silk silk fabrics is immersed in desizing liquid, bath raio is 1:15-1:25, is warming up to 60-80 ℃, floods 45-75min under heat-retaining condition; At 100-102 ℃ of decatize 45-60min, then wash 20-60min.
The advantage of technical solution of the present invention is mainly reflected in:
Adopt desizing liquid of the present invention to carry out destarch to the picture-weaving in silk silk fabrics and process, the destarch rate is high, and the fabric that obtains has higher capillary effect and mechanical property, is conducive to the carrying out of follow-up dyeing and printing process, has guaranteed follow-up printing quality; And because of effective removal of slurry, improved the feel of fabric.
The specific embodiment
Embodiment 1
Table 1: picture-weaving in silk silk fabrics desizing liquid (aqueous solution) formula table
Press the corresponding data of table 1, take each raw material.Under room temperature with double-core manganese complex [Mn
2 IV(μ-O)
3(Me
3TACN)
2] [PF
6]
2H
2O, gluconic acid sodium salt, hydrogen peroxide, 4-(2-nonanoyl oxygen base oxethyl ketonic oxygen base) benzene sulfonic acid sodium salt and N-carboxymethyl-sarcosine iron (III) sodium salt are added to the water, add again NaOH, regulate pH value to 12, stir, can make described picture-weaving in silk silk fabrics desizing liquid.
At room temperature the picture-weaving in silk silk fabrics is immersed in the above-mentioned desizing liquid that makes, bath raio is 1:20, is warming up to 70 ℃, floods 60min maintaining the temperature under the condition of 70 ℃; At 100 ℃ of decatize 50min, then wash 40min, drying.
Comparative Examples 1
Press the corresponding data of table 1, take each raw material, press the method for embodiment 1, can make picture-weaving in silk silk fabrics desizing liquid.
At room temperature the picture-weaving in silk silk fabrics is immersed in the above-mentioned desizing liquid that makes, bath raio is 1:20, is warming up to 70 ℃, floods 60min maintaining the temperature under the condition of 70 ℃; At 100 ℃ of decatize 50min, then wash 40min, drying.
Comparative Examples 2
Press the corresponding data of table 1, take each raw material, press the method for embodiment 1, can make picture-weaving in silk silk fabrics desizing liquid.
At room temperature the picture-weaving in silk silk fabrics is immersed in the above-mentioned desizing liquid that makes, bath raio is 1:20, is warming up to 70 ℃, floods 60min maintaining the temperature under the condition of 70 ℃; At 100 ℃ of decatize 50min, then wash 40min, drying.
Comparative Examples 3
Press the corresponding data of table 1, take each raw material, press the method for embodiment 1, can make picture-weaving in silk silk fabrics desizing liquid.
At room temperature the picture-weaving in silk silk fabrics is immersed in the above-mentioned desizing liquid that makes, bath raio is 1:20, is warming up to 70 ℃, floods 60min maintaining the temperature under the condition of 70 ℃; At 100 ℃ of decatize 50min, then wash 40min, drying.
Comparative Examples 4
A kind of picture-weaving in silk silk fabrics desizing liquid consists of:
Hydrogen peroxide 2.4g/L,
Double-core manganese complex [Mn
2 IV(μ-O)
3(Me
3TACN)
2] [PF
6]
2H
2O10 μ mol/L,
Fast penetrant T 1g/L,
Stabilizing agent DTA1g/L.
Regulate pH to 12 with NaOH.
At room temperature the picture-weaving in silk silk fabrics is immersed in the above-mentioned desizing liquid that makes, bath raio is 1:20, is warming up to 70 ℃, floods 60min maintaining the temperature under the condition of 70 ℃; At 100 ℃ of decatize 50min, then wash 40min, drying.
Test case
To the picture-weaving in silk silk fabrics of the embodiment 1 after destarch and Comparative Examples 1-4, detect destarch rate and mechanical property strength retention.
Concrete method of testing is as follows:
The destarch rate represents a basic technical indicator of textile sizing material removal degree, and available following formula calculates:
Destarch rate=[fabric sizing percentage before (fabric sizing percentage after the front fabric sizing percentage-destarch of destarch)/destarch] * 100%.
Tear tester test strength retention with Elmendorf.With a specimen two ends clamping that is of a size of 6.5cm * 10cm, the otch of a 2cm is vertically cut at the position therebetween, tearing to the shown maximum grams of 4.5cm place's this point of measurement, measure 3 times, average, and with the measured value of this mean value divided by undressed sample, its quotient is strength retention.Strength retention is larger, illustrates that the destarch operation is less to the damage of fabric.
Test data sees the following form 2.
Table 2: test data table
| Test event | Embodiment 1 | Comparative Examples 1 | Comparative Examples 2 | Comparative Examples 3 | Comparative Examples 4 |
| The destarch rate, % | 88.5 | 71.7 | 72.4 | 73.6 | 69.2 |
| Strength retention, % | 91.2 | 86.5 | 85.3 | 88.4 | 90.7 |
By table 2 data relatively, can obviously draw, the destarch effect of embodiment 1 and strength retention all obviously are better than Comparative Examples 1-4.
Claims (4)
1. picture-weaving in silk silk fabrics desizing liquid, pH value 11-12, it is characterized in that, formed by following component: gluconic acid sodium salt 1-3g/L, hydrogen peroxide 4-8g/L, double-core manganese complex 2-4 μ mol/L, 4-(2-nonanoyl oxygen base oxethyl ketonic oxygen base) benzene sulfonic acid sodium salt 1-3g/L, N-carboxymethyl-sarcosine iron (III) sodium salt 0.5-1.5g/L, NaOH is appropriate.
2. picture-weaving in silk silk fabrics desizing liquid as claimed in claim 1, it is characterized in that: described double-core manganese complex, molecular formula are [Mn
2 IV(μ-O)
3(Me
3TACN)
2] [PF
6]
2H
2O。
3. the desizing method of a picture-weaving in silk silk fabrics, comprise dipping desizing liquid, decatize and water-washing step, it is characterized in that: the desizing liquid in described dipping desizing liquid step adopts the described picture-weaving in silk silk fabrics of claim 1 or 2 desizing liquid.
4. the desizing method of picture-weaving in silk silk fabrics as claimed in claim 3, it is characterized in that: at room temperature the picture-weaving in silk silk fabrics is immersed in desizing liquid, bath raio is 1:15-1:25, is warming up to 60-80 ℃, floods 45-75min under heat-retaining condition; At 100-102 ℃ of decatize 45-60min, then wash 20-60min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310051902.3A CN103173978B (en) | 2013-02-14 | 2013-02-14 | Desizing liquid for brocade silk fabric and desizing method of brocade silk fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310051902.3A CN103173978B (en) | 2013-02-14 | 2013-02-14 | Desizing liquid for brocade silk fabric and desizing method of brocade silk fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103173978A true CN103173978A (en) | 2013-06-26 |
| CN103173978B CN103173978B (en) | 2015-05-27 |
Family
ID=48634137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310051902.3A Expired - Fee Related CN103173978B (en) | 2013-02-14 | 2013-02-14 | Desizing liquid for brocade silk fabric and desizing method of brocade silk fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103173978B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106283596A (en) * | 2016-08-30 | 2017-01-04 | 苏州紫澜实业有限公司 | The desizing processing method of velvet stuff |
| CN106381678A (en) * | 2016-08-31 | 2017-02-08 | 常熟市周行毛巾厂 | Desizing method of wool fabric |
-
2013
- 2013-02-14 CN CN201310051902.3A patent/CN103173978B/en not_active Expired - Fee Related
Non-Patent Citations (2)
| Title |
|---|
| 孔祥文等: "新型过氧化氢漂白活化剂4-(2-壬酰氧基乙氧基羰基氧基)苯磺酸钠的合成", 《中华纸业》 * |
| 秦新波等: "双核锰配合物在低温漂白中的活化作用", 《印染》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106283596A (en) * | 2016-08-30 | 2017-01-04 | 苏州紫澜实业有限公司 | The desizing processing method of velvet stuff |
| CN106381678A (en) * | 2016-08-31 | 2017-02-08 | 常熟市周行毛巾厂 | Desizing method of wool fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103173978B (en) | 2015-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103410005B (en) | Cotton fabric pretreatment working solution, and preparation method and application thereof | |
| CN103173976B (en) | Desizing liquid and desizing method for pure cotton fabric | |
| CN101899754A (en) | Process for dyeing check for cross-stitch | |
| CN103469538B (en) | Low-temperature less-alkali pretreatment method for modified polyester/cotton blended knitted fabric | |
| CN103173981B (en) | Desizing liquid and desizing method for linen fabric | |
| CN103173982B (en) | Desizing liquid and desizing method for dacron fabric | |
| CN103173980B (en) | Desizing liquid and desizing method for polyvinyl alcohol cotton blended fabric | |
| CN109576975A (en) | A kind of heavy cotton fabric short route pre-treating method | |
| CN103173978B (en) | Desizing liquid for brocade silk fabric and desizing method of brocade silk fabric | |
| CN105937189A (en) | High-count and high-density fine denier Tencel fabric dyeing and finishing processing method | |
| CN104389075A (en) | Preparation method of antistatic radiation-proof fabric | |
| CN103173977B (en) | Desizing liquid for ramie fabric and desizing method of ramie fabric | |
| CN106498709A (en) | A kind of dyeing pretreating process of synthetic fiber fabric | |
| CN103173984B (en) | Desizing liquid and desizing method for acrylic cotton blended fabric | |
| CN103173975B (en) | Desizing liquid and desizing method for mulberry noil silk fabric | |
| CN103173979B (en) | Desizing liquid and desizing method for soybean protein fiber fabric | |
| CN103243566B (en) | Bio-enzyme pretreatment method of vinylon-cotton blend fabric | |
| CN103173983B (en) | Desizing liquid and desizing method for dacron cotton blended fabric | |
| CN103088625A (en) | Heavy pure cotton fabric corona discharge plasma and enzyme cold padding and stacking pretreatment method | |
| CN104032602B (en) | Anti-REACTIVE DYES staining agent | |
| CN103173993B (en) | Bleaching liquid and bleaching method for dacron cotton blended fabric | |
| CN109944055B (en) | Environment-friendly desizing method for fabric | |
| CN106436279A (en) | Dyeing pretreatment process of cotton fabric garment cloth | |
| CN103173986B (en) | Bleaching liquid and bleaching method for linen fabric | |
| CN101532251A (en) | Technology and device for producing cotton and flax wrinkle fabrics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180914 Address after: 244000 Tongling suburb industrial park in Anhui Patentee after: ANHUI TONGLING CITY TONGDOU SPECIAL CABLE CO.,LTD. Address before: 201111 room 271, thirtieth building, 280 Shuguang Road, Minhang District, Shanghai. Patentee before: SHANGHAI QIUCHENG NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150527 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |