CN103173295A - Smokeless environment-friendly birthday candle with color flame - Google Patents
Smokeless environment-friendly birthday candle with color flame Download PDFInfo
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Abstract
The invention discloses a smokeless environment-friendly birthday candle with a color flame and a preparation method of the smokeless environment-friendly birthday candle. The preparation method comprises the following steps of: with trimethyl citrate as a main combustible ingredient and octadecanamide, stearic acid and tristearin as a plasticizer, an emulsifying agent, a releasing agent and a dispersing agent, additionally adding erucamide, oleamide, propyl gallate, 2-hydroxy-4-n-octyloxybenzophenone, triclosan, 10,10'-oxybisphenoxarsine and an alcohol solubility pigment, melting all the materials at the temperature of 90-95 DEG C, and uniformly mixing the melted materials to obtain a candle material; dissolving a color flame color former in purified water to prepare a color forming liquid with the mass concentration of 3-6%, placing a cotton thread into the color forming liquid to soak for 2-24hours, then, taking the cotton thread out and drying the cotton thread to obtain a wick; and threading the wick on a candle machine, pouring the candle material on the machine, introducing cooling water, solidifying the candle material, then, forming and carrying out mould stripping. The preparation method is simple in production process, low in cost, labor-saving and suitable for large-scale mechanical production; and the produced candle with the flame is stable in flame, bright and pure in color of the flame, free of smoke and lachrymation in combustion and long in quality guarantee period.
Description
Technical field
The present invention relates to a kind of color flame candles and preparation method thereof, specifically coloured flame birthday candle of a kind of smokeless environment-friendly and preparation method thereof.
Background technology
Color flame candles technology in the market substantially with trimethyl citrate as main fuel, as softening agent, emulsifying agent, releasing agent, dispersion agent and ignition dope are with the activator of oil color as outward appearance with stearic amide, stearic acid or Tristearoylglycerol etc., with lithium, potassium, sodium, copper, calcium, magnesium, boron, the metal-salts such as barium are as chromogenic reagent.Wick mainly adopts two, as patent documentation CN102559397A, sends the bright-coloured flame color such as red, yellow, blue, green, purple, white in order to make candle, has adopted the twin-core processing, and color development core of a burning core is kneaded into wick.
Though the document about color flame candles is many, but rare color flame candles product on the market, trace it to its cause, be mainly the problem that has following aspect: (1) poor stability: existing color flame candles generally is affected by climate change larger, storage time is short, the storage time of some half a year all can't realize, especially southern humid area.Usually can due to occur efflorescence, mouldy, fade, the problem such as the moisture absorption, thereby seriously restricted the sale of product.(2) complex process: wick is generally processed through multiple working procedure, and as the CN100557004C of patent documentation, wick has passed through alkali, sour repeatedly soaking for a long time, and length consuming time also needs to expend a large amount of labor forces.(3) mechanization degree is low: because the present cold contraction of color flame candles formula material is smaller, determined that it must complete making processes by splitting mould, this just needs a large amount of labor forces, under the environment that labor cost increases severely at present, is not suitable for batch production and also is unfavorable for promoting.(4) quality is unsecured: be mainly reflected in the following aspects: at first, in making the color flame candles technology at present, Tristearoylglycerol and stearic acid separately use often, namely only use Tristearoylglycerol or stearic acid.When only using Tristearoylglycerol, because its oiliness is large, therefore often swim in above wax material in a large number, and be difficult for being dissolved in fully in wax material, cause wax material to mix inhomogeneous, cause the color flame candles of upper strata wax material preparation defective, and send yellow flame.When only using stearic acid, consumption is wayward, and when consumption was very few, toughness was inadequate, and is easily crisp, when consumption is too much, can form the sour phenomenon of spray, causes the color flame candles yellow core of appearance and surface colour inhomogeneous.(5) the appearance looks elegant degree is inadequate, not easy coloring and painted inhomogeneous.Oil color is nearly all adopted in many document records, as: document CN102268330A and CN101870928A etc.But through the overtesting oil color and the trimethyl citrate mutual solubility is poor is difficult to painted or some pigment is painted hardly, or painted inequality, the formula poor heat resistance of present color flame candles, easily even coking of oxidation, easily variable color is rotten in long heating production process, and product strength is died down, and aberration is serious, outward appearance is barely satisfactory, thereby the product appearance quality of producing can not be guaranteed.(6) many documents are to mouldy, and the phenomenons such as rotten efflorescence do not have basic solution yet.In addition, naturally dry, air-dry or dry in the shade, need the oversize time of consumption, and gravitation will make the chromogenic reagent of immersion pile up toward lower, the candle of working it out through the wick that dries or natural air drying obtains again, some part color development is good especially and have what look of part all can not send out, and forms stone incrustation shape after piling up color flame agent part moisture and doing and can't operate.The quality that therefore can't guarantee every candle in batch production is balanced.And can make the wick weave construction be subject to havoc to the processing repeatedly of wick, and make it easily broken, oil absorption weakens greatly, affects combustion efficacy, therefore need to add in addition a burning wick, has not only increased cost but also expended time in.
Summary of the invention
For the problems referred to above, the invention provides coloured flame birthday candle of a kind of smokeless environment-friendly and preparation method thereof, its reliable in quality, stability is high, technique is simple, with low cost, be suitable for mass mechanized production.
Smokeless environment-friendly coloured flame birthday candle of the present invention is become by the preparation of raw material of following mass percent:
(1) all batchings are mixed in proportion, 90-95 ℃ of thawing mixes, and makes wax material;
(2) required color flame chromogenic material directly is dissolved in the color development liquid of making mass concentration 3-6% in pure water, adopt single Zhi Putong cotton thread to do wicking, cotton thread is placed in color development liquid soaked 2-24 hour, taking-up keeps flat, and puts the air blast dryer into and at once dries moisture and namely obtain wick;
(3) wick has been measured size on demand around pipe, then directly be through candle mechanically, the wax material that above thawing is good casts directly over mechanically, and logical upper water coolant namely makes smokeless environment-friendly coloured flame birthday candle of the present invention after solidifying.
The invention has the beneficial effects as follows with respect to prior art:
(1) the present invention is combined with Tristearoylglycerol with stearic acid, the problem that perfection has existed when having solved independent the use, the color flame candles that makes all is improved largely in hardness, intensity and flexibility, simultaneously the wax material homogeneous media, very easily toning, and chromaticness is even.
(2) added the erucicamide of 0.2-0.8% and the amine hydroxybenzene of 0.2-0.6% in wax material, candle has been had better high temperature resistantly anti-ly repeat to heat, anti-oxidant and hydrophobic function, extended the shelf life.
In addition, interact between material, cause the contraction ratio of candle to increase, be convenient to the depanning of candle in machinery production, guaranteed integrity and the qualification rate of product.Making need not specific installation, mechanically can process and produce suitable mass mechanized production at common candle.
(3) Tenox PG of 0.2-0.6%, the Octabenzone of 0.2-0.8% have been added in wax material, guaranteed candle and melted down for a long time and repeatedly to heat and preserved the pigment nondiscoloration and never degenerate and make appearance looks elegant, color homogeneous, not easy to change, not efflorescence, thereby greatly extended the quality guaranteed period, the physico-chemical property change can not occur more than 1 year yet even deposit.
(4) add in wax material and 0.1-0.5% 10, the triclosan of the two phenoxazine arsenic of 10 '-oxo and 0.1-0.5%, thereby not only effectively raise mould fungus inhibition and other bacteriums the solution of growing essence the mouldy bad phenomenon such as rotten and efflorescence that cause, and triclosan can play in blue flame and excites copper to send more stable blue flame in combustion processes and do not go out peculiar smell.
(5) replace oil color as the outward appearance activator with pure dissolubility pigment, painted easy and uniform coloring in making processes, the color flame candles appearance looks elegant that makes.
(6) it is generally acknowledged that wick must will have burning core and color development core to exist simultaneously, in the time of the guarantee trouble-free burning, flame sends color, but the present invention only can address this problem with a wick, and yellow, green also need not to process.Not because lacked a wick or do not processed wick and affect burning and color development effect.
(7) wick making processes is simple, do not need repeatedly to process, when saving cost and labor force, can be to the wick structure injury, therefore wick burning and the color development produced are respond well, and the flash baking after immersion has guaranteed the even distribution of chromogenic reagent on the wick, makes the quality balance of product consistent, even yellow, green waits wick to need not to process and also can complete.
(8) flame stabilization of colour candle, bright-colored, pure, do not exist the phenomenons such as " Huang Xin " " do branch " (through produce and research to find to produce the phenomenon such as Huang Xin be that the interpolation such as softening agent is improper and produce).
(9) environment protection smokeless, one's eyes drop millstones in the time of therefore on being inserted in cake, can not pollute cake, and is harmless.
(10) preparation technology simple, save the labor force, efficient is high, with low cost, 10 workmans are example take the our factory, producing candle per year can be over 1,500 ten thousand.
Embodiment
The present invention will be further described below in conjunction with specific embodiment.
Embodiment 1
The blushed flame candle
Trimethyl citrate 94.6 grams, stearic amide 2.8 grams, Tristearoylglycerol 0.6 gram, stearic acid 0.6 gram, erucicamide 0.4 gram, amine hydroxybenzene 0.3 gram, Tenox PG 0.2 gram, Octabenzone 0.2 gram, 10, two phenoxazine arsenic 0.15 grams of 10 '-oxo, triclosan 0.14 gram, pure dissolubility Pigment red 0.01 gram.With 90 ℃ of thawings of above-mentioned materials, mix, make wax material.
Red chromogenic reagent adopts lithium chloride 5 grams, fully is dissolved in the pure water of 100 grams, and wick was soaked 4 hours, takes out oven dry, has measured as required size standby around pipe.The wick that winds directly is through candle mechanically, disposablely can wears 200, the wax material that above thawing is good casts directly over mechanically, and logical upper water coolant can the moulding depanning after solidifying.
By this production method, a people just can produce 200 candles voluntarily at 5 minutes.And the wax material that produces the wax material be not finished down and condense in the mould outside also can again be refunded wax melting tank and continued to heat and reuse.The blushed flame candle flame of producing is stable, bright-colored, pure, smokeless, one's eyes drop millstones in burning.Confirm through practice, normal temperature was preserved after 1 year, and its outward appearance and burning chromophoric characteristic are without any change.
Embodiment 2
The yellow flame candle
Trimethyl citrate 88.98 grams, stearic amide 5.6 grams, Tristearoylglycerol 1.2 grams, stearic acid 1.0 grams, erucicamide 0.8 gram, amine hydroxybenzene 0.5 gram, Tenox PG 0.4 gram, Octabenzone 0.7 gram, 10, two phenoxazine arsenic 0.4 grams of 10 '-oxo, triclosan 0.4 gram, pure dissolubility Pigment Yellow 73 0.02 gram.With 93 ℃ of thawings of above-mentioned materials, mix, make wax material.
Yellow wick need not special processing, sends yellow flame color because wick own just contains sodium.Measured as required the wick size standby around pipe.The wick that winds directly is through candle mechanically, disposablely can wears 200, the wax material that above thawing is good casts directly over mechanically, and logical upper water coolant can the moulding depanning after solidifying.
By this production method, a people just can produce 200 candles voluntarily at 5 minutes.And the wax material that produces the wax material be not finished down and condense in the mould outside also can again be refunded wax melting tank and continued to heat and reuse.The yellow flame candle flame of producing is stable, bright-colored, pure, smokeless, one's eyes drop millstones in burning.Confirm through practice, normal temperature was preserved after 1 year, and its outward appearance and burning chromophoric characteristic are without any change.
Embodiment 3
The purple flame candle
Trimethyl citrate 89.99 grams, stearic amide 4.9 grams, Tristearoylglycerol 1.0 grams, stearic acid 1.0 grams, erucicamide 0.7 gram, amine hydroxybenzene 0.5 gram, Tenox PG 0.5 gram, Octabenzone 0.8 gram, 10, two phenoxazine arsenic 0.3 grams of 10 '-oxo, triclosan 0.3 gram, pure dissolubility pigment violet 0.01 gram.With 95 ℃ of thawings of above-mentioned materials, mix, make wax material.
The purple chromogenic reagent adopts the Repone K of 5 grams and the lithium nitrate of 1 gram, fully is dissolved in the pure water of 100 grams, soaks 24 hours, and the taking-up oven dry is standby around pipe.The wick that winds directly is through candle mechanically, disposablely can wears 200, the wax material that above thawing is good casts directly over mechanically, and logical upper water coolant can the moulding depanning after solidifying.
By this production method, a people just can produce 200 candles voluntarily at 5 minutes.And the wax material that produces the wax material be not finished down and condense in the mould outside also can again be refunded wax melting tank and continued to heat and reuse.The purple flame candle flame stabilization of producing, bright-colored, pure, smokeless, one's eyes drop millstones in burning.Confirm through practice, normal temperature was preserved after 1 year, and its outward appearance and burning chromophoric characteristic are without any change.
Embodiment 4
The blue flame candle
Trimethyl citrate 94.98 grams, stearic amide 1.4 grams, Tristearoylglycerol 0.4 gram, stearic acid 0.4 gram, erucicamide 0.3 gram, amine hydroxybenzene 0.3 gram, zellon 0.2 gram, clorafin 0.1 gram, Tenox PG 0.4 gram, Octabenzone 0.5 gram, 10, two phenoxazine arsenic 0.5 grams of 10 '-oxo, triclosan 0.5 gram, pure dissolubility Pigment blue 0.02 gram.With 94 ℃ of thawings of above-mentioned materials, mix, make wax material.
Blue chromogenic reagent adopts the venus crystals of 4 grams, and the cupric chloride of 2 grams fully is dissolved in the pure water of 100 grams, soaks that can to take out oven dry in 2 hours standby around managing.The wick that winds directly is through candle mechanically, disposablely can wears 200, the wax material that above thawing is good casts directly over mechanically, and logical upper water coolant can the moulding depanning after solidifying.
By this production method, a people just can produce 200 candles voluntarily at 5 minutes.And the wax material that produces the wax material be not finished down and condense in the mould outside also can again be refunded wax melting tank and continued to heat and reuse.The blue flame candle flame of producing is stable, bright-colored, pure, smokeless, one's eyes drop millstones in burning.Confirm through practice, normal temperature was preserved after 1 year, and its outward appearance and burning chromophoric characteristic are without any change.
Embodiment 5
The green flame candle
Trimethyl citrate 89.99 grams, stearic amide 3.6 grams, Tristearoylglycerol 0.9 gram, stearic acid 0.9 gram, erucicamide 0.6 gram, amine hydroxybenzene 0.4 gram, Tenox PG 0.6 gram, Octabenzone 0.6 gram, 10, two phenoxazine arsenic 0.4 grams of 10 '-oxo, boric acid 1.5 grams, triclosan 0.5 gram, pure dissolubility Pigment green 0.01 gram.With 92 ℃ of thawings of above-mentioned materials, mix, make wax material.
By this production method, a people just can produce 200 candles voluntarily at 5 minutes.Also can again refund wax melting tank and continue to heat and reuse and produce the wax material be not finished down and condense in wax material above mould.The green flame candle flame of producing is stable, bright-colored, pure, smokeless, one's eyes drop millstones in burning.Confirm through practice, normal temperature was preserved after 1 year, and its outward appearance and burning chromophoric characteristic are without any change.
Yellow, the wick of green flame candle all need not processing, through all distinguishing without obvious aspect every quality that practice confirms and processed.
Claims (8)
1. a smokeless environment-friendly coloured flame birthday candle, comprise candle body and wick, it is characterized in that candle body is become by the preparation of raw material of following mass percent:
2. smokeless environment-friendly coloured flame birthday candle according to claim 1, it is characterized in that wick is one, the preparation method is: color flame chromogenic material is dissolved in the color development liquid of making mass concentration 3-6% in pure water, adopt single Zhi Putong cotton thread to do wicking, cotton thread is placed in color development liquid to be soaked 2-24 hour, taking-up keeps flat, and puts into the air blast dryer and at once dries moisture and namely obtain wick.
3. the preparation method of a smokeless environment-friendly coloured flame birthday candle is characterized in that comprising the following steps:
(1) the described batching of claim 1 is mixed in proportion, 90-95 ℃ of thawing mixes, and makes wax material;
(2) prepare wick claimed in claim 2;
(3) wick has been measured size on demand around pipe, then directly be through candle mechanically, cast directly over mechanically melting good wax material, logical upper water coolant namely makes smokeless environment-friendly coloured flame birthday candle of the present invention after solidifying.
4. a smokeless environment-friendly blushed flame birthday candle, is characterized in that, candle body is become by the preparation of raw material of following mass percent:
Above-mentioned raw materials is melted mixing in 90-95 ℃ get wax material;
Lithium chloride 5 grams are dissolved in 100 gram pure water make color development liquid, adopt single Zhi Putong cotton thread to do wicking, cotton thread is placed in color development liquid soaked 4 hours, taking-up keeps flat, and puts into the air blast dryer and at once dries moisture and namely obtain wick;
Described wick is through candle mechanically, melts good wax material and cast directly over mechanically, logical upper water coolant solidifies the aftershaping depanning and obtains the blushed flame birthday candle.
5. a smokeless environment-friendly yellow flame birthday candle, is characterized in that, candle body is become by the preparation of raw material of following mass percent:
Above-mentioned raw materials is melted mixing in 90-95 ℃ get wax material;
Common wick is through candle mechanically, melts good wax material and cast directly over mechanically, logical upper water coolant solidifies the aftershaping depanning and obtains the yellow flame birthday candle.
6. a smokeless environment-friendly purple flame birthday candle, is characterized in that, candle body is become by the preparation of raw material of following mass percent:
Above-mentioned raw materials is melted mixing in 90-95 ℃ get wax material;
5 gram Repone K and 1 gram lithium nitrate are dissolved in 100 gram pure water make color development liquid, adopt single Zhi Putong cotton thread to do wicking, cotton thread is placed in color development liquid soaked 24 hours, taking-up keeps flat, and puts into the air blast dryer and at once dries moisture and namely obtain wick;
Described wick is through candle mechanically, melts good wax material and cast directly over mechanically, logical upper water coolant solidifies the aftershaping depanning and obtains purple flame birthday candle.
7. a smokeless environment-friendly blue flame birthday candle, is characterized in that, candle body is become by the preparation of raw material of following mass percent:
Above-mentioned raw materials is melted mixing in 90-95 ℃ get wax material;
The venus crystals of 6 grams or cupric chloride or its mixture are dissolved in 100 gram pure water make color development liquid, adopt single Zhi Putong cotton thread to do wicking, cotton thread is placed in color development liquid soaked 2 hours, taking-up keeps flat, and puts into the air blast dryer and at once dries moisture and namely obtain wick;
Described wick is through candle mechanically, melts good wax material and cast directly over mechanically, logical upper water coolant solidifies the aftershaping depanning and obtains the blue flame birthday candle.
8. a smokeless environment-friendly green flame birthday candle, is characterized in that, candle body is become by the preparation of raw material of following mass percent:
Above-mentioned raw materials is melted mixing in 90-95 ℃ get wax material;
Common wick is through candle mechanically, melts good wax material and cast directly over mechanically, logical upper water coolant solidifies the aftershaping depanning and obtains the green flame birthday candle.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310135152.8A CN103173295B (en) | 2013-04-18 | 2013-04-18 | Smokeless environment-friendly birthday candle with color flame |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310135152.8A CN103173295B (en) | 2013-04-18 | 2013-04-18 | Smokeless environment-friendly birthday candle with color flame |
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| CN103173295B CN103173295B (en) | 2014-06-25 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143566A (en) * | 2020-10-12 | 2020-12-29 | 南京信息工程大学 | Biomass-based lamp core material and preparation method and application thereof |
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| EP1686159A1 (en) * | 2001-06-04 | 2006-08-02 | Arizona Chemical Company | Coated candles and coating compositions |
| US20060272199A1 (en) * | 2005-06-02 | 2006-12-07 | Bmc Manufacturing, Llc | Aqueous gel candle for use with a warming device |
| CN101825230A (en) * | 2009-03-05 | 2010-09-08 | 范卸妹 | Novel artistic cup candle |
| CN102191136A (en) * | 2010-03-08 | 2011-09-21 | 建德市嘉轩工艺品有限公司 | Candle with color flame and manufacturing method thereof |
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Patent Citations (8)
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| EP0265976A1 (en) * | 1986-09-25 | 1988-05-04 | Unilever N.V. | Fatty acid composition suitable for candle pressing |
| CN1145945A (en) * | 1995-09-07 | 1997-03-26 | 王明凤 | Prodn process of color-flame candle |
| CN1343246A (en) * | 1999-03-11 | 2002-04-03 | 雷克特本克斯尔(英国)有限公司 | Candle composition |
| EP1686159A1 (en) * | 2001-06-04 | 2006-08-02 | Arizona Chemical Company | Coated candles and coating compositions |
| KR20040052552A (en) * | 2004-03-24 | 2004-06-23 | 씨.에프. 주식회사 | An candle containing a soy and wax and that composing method |
| US20060272199A1 (en) * | 2005-06-02 | 2006-12-07 | Bmc Manufacturing, Llc | Aqueous gel candle for use with a warming device |
| CN101825230A (en) * | 2009-03-05 | 2010-09-08 | 范卸妹 | Novel artistic cup candle |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143566A (en) * | 2020-10-12 | 2020-12-29 | 南京信息工程大学 | Biomass-based lamp core material and preparation method and application thereof |
| CN112143566B (en) * | 2020-10-12 | 2023-06-27 | 南京信息工程大学 | Biomass-based wick material and preparation method and application thereof |
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| CN103173295B (en) | 2014-06-25 |
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