CN103173157A - Hydrophobic masking tape and preparation method thereof - Google Patents
Hydrophobic masking tape and preparation method thereof Download PDFInfo
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- CN103173157A CN103173157A CN2013100982000A CN201310098200A CN103173157A CN 103173157 A CN103173157 A CN 103173157A CN 2013100982000 A CN2013100982000 A CN 2013100982000A CN 201310098200 A CN201310098200 A CN 201310098200A CN 103173157 A CN103173157 A CN 103173157A
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Abstract
The invention provides a hydrophobic masking tape and a preparation method thereof. The hydrophobic masking tape comprises a masking tape layer and an adhesive layer which is coated on the surface of the masking tape layer, wherein the adhesive formula of the adhesive layer comprises the following components in parts by weight: 200-300 parts of butyl acrylate, 100-200 parts of 2-ethylhexyl acrylate, 2-10 parts of acrylic acid, 2-10 parts of 2-hydroxyethyl acrylate, 30-60 parts of styrene-acrylic emulsion, 5-10 parts of sodium benzene sulfonate, 300-500 parts of water, 2-7 parts of ammonium persulfate and 0.1-0.5 part of sodium bicarbonate. A hydrophobic adhesive is adopted in a preparation process to remove the conventional organic solvent, and the masking tape is subjected to ultraviolet pretreatment, so that the produced masking tape is pollution-free and environment-friendly and has an outdoor use function.
Description
Technical field
The present invention relates to U.S. line paper self-adhesive tape of a kind of not solvent-laden water-based and preparation method thereof.
Background technology
U.S. line paper self-adhesive tape is that a kind of high-tech is decorated, spraying paper using (because of the property of its purposes, claiming again a minute ribbon paper), is widely used in spraying paint and the spraying of high-grade limousine of upholstery, household electrical appliance.U.S. line paper self-adhesive tape is take U.S. line paper and tackiness agent as main raw material, adhesive coating on U.S. line paper, another side is coated with non-stick material and the web-like sealing tape made, its minute chromatic effect boundary line is clear, bright and clear, have again the camber line art effect concurrently, give to decorate, the spraying industry brought once new technological revolution, the life that the sector is shone make new advances.But the tackiness agent of present U.S. line paper is generally to make solvent by volatile organic compoundss such as benzene, toluene, all can produce toxic substance to environment in manufacturing and use procedure, and human body is damaged.In addition, existing U.S. line paper self-adhesive tape lacks uvioresistant (anti-UV) function, does not possess outdoor use function.
For defects, be badly in need of invention a kind of brand-new U.S. line paper self-adhesive tape and preparation method and solve the deficiencies in the prior art.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides U.S. line paper self-adhesive tape of water-based and preparation method thereof, the U.S. line paper self-adhesive tape of producing by this preparation method does not contain solvent and possesses outdoor use function.
The technical solution adopted for the present invention to solve the technical problems is:
The U.S. line paper self-adhesive tape of a kind of water-based comprises U.S. line ply of paper and the adhesive layer of coating U.S. line ply of paper surface, and the glue component proportioning of this adhesive layer is as follows:
The butyl acrylate of 200-300 part,
The vinylformic acid isooctyl of 100-200 part,
The vinylformic acid of 2-10 part,
The vinylformic acid hydroxyl second fat of 2-10 part,
The benzene emulsion of 30-60 part,
The benzene sulfonic acid sodium salt of 5-10 part,
The water of 300-500 part,
The ammonium persulphate of 2-7 part,
0.1-0.5 the sodium bicarbonate of part.
As a further improvement on the present invention, described butyl acrylate, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate, benzene emulsion, benzene sulfonic acid sodium salt, ammonium persulphate, sodium bicarbonate are technical grade product.
The preparation method of the U.S. line paper self-adhesive tape of a kind of water-based specifically comprises the following steps:
Described butyl acrylate, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate, benzene emulsion, benzene sulfonic acid sodium salt, ammonium persulphate, sodium bicarbonate are technical grade product.
The preparation method of the U.S. line paper self-adhesive tape of a kind of water-based specifically comprises the following steps:
A, add the benzene sulfonic acid sodium salt of 80-90% in described formula in the pre-emulsification still, mix and stir with the water of 30-50%, and add whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, and stir, make pre-emulsion;
B, add the water of sodium bicarbonates whole in described formula, 50-70% and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 80-85 ℃, add the ammonium persulphate of 50-70%, and whole benzene emulsions;
C, insulation 8～12 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2～3 hours; After dripping off, be incubated 45～75 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out neutralizing treatment and output glue;
D, with the glue application of output on U.S. line paper, after glue dries, namely make the U.S. line paper self-adhesive tape of described water-based.
As a further improvement on the present invention, after described in step c, the elimination process is specifically eliminated unreacted residual monomer with rongalite and tertbutyl peroxide.
As a further improvement on the present invention, neutralizing treatment described in step c is specifically 8.5～9.5 with the pH value of ammoniacal liquor adjusting glue.
As a further improvement on the present invention, be 30～50 μ m with the gluing thickness of glue application on U.S. line paper in steps d.
As a further improvement on the present invention, U.S. line paper described in steps d is for pretreated through anti-UV.
The present invention compared with prior art has following beneficial effect:
U.S. line paper self-adhesive tape of water-based provided by the invention and preparation method thereof adopts aqueous adhesive, removed organic solvent in the past, and U.S. line paper is carried out anti-UV pre-treatment, make that the U.S. line paper self-adhesive tape of producing is pollution-free, environmental protection, possess simultaneously outdoor use function.
Embodiment
In order better to explain invention main points of the present invention, the below provides several better embodiments.
Embodiment 1
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 300 parts,
The vinylformic acid isooctyl of 100 parts,
The vinylformic acid of 2 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 40 parts,
The benzene sulfonic acid sodium salt of 6 parts,
The water of 450 parts,
The ammonium persulphate of 4 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 85% benzene sulfonic acid sodium salt in the pre-emulsification still, and 45% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 55% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 70% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 9.0, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 50 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 2
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 280 parts,
The vinylformic acid isooctyl of 120 parts,
The vinylformic acid of 4 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 40 parts,
The benzene sulfonic acid sodium salt of 6 parts,
The water of 400 parts,
The ammonium persulphate of 4 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 88% benzene sulfonic acid sodium salt in the pre-emulsification still, and 40% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 60% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 82 ℃, add 65% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 8.5, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 45 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 3
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 260 parts,
The vinylformic acid isooctyl of 140 parts,
The vinylformic acid of 3 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 50 parts,
The benzene sulfonic acid sodium salt of 6 parts,
The water of 450 parts,
The ammonium persulphate of 5 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 90% benzene sulfonic acid sodium salt in the pre-emulsification still, and 50% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 50% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 60% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 9.0, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 45 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 4
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 250 parts,
The vinylformic acid isooctyl of 150 parts,
The vinylformic acid of 3 parts,
The vinylformic acid hydroxyl second fat of 3 parts,
The benzene emulsion of 45 parts,
The benzene sulfonic acid sodium salt of 7 parts,
The water of 450 parts,
The ammonium persulphate of 3 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 84% benzene sulfonic acid sodium salt in the pre-emulsification still, and 38% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 62% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 84 ℃, add 55% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 9.5, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 30 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 5
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 260 parts,
The vinylformic acid isooctyl of 140 parts,
The vinylformic acid of 3 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 50 parts,
The benzene sulfonic acid sodium salt of 6 parts,
The water of 450 parts,
The ammonium persulphate of 5 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 90% benzene sulfonic acid sodium salt in the pre-emulsification still, and 40% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 60% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 65% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 9.0, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 40 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 6
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 240 parts,
The vinylformic acid isooctyl of 160 parts,
The vinylformic acid of 3 parts,
The vinylformic acid hydroxyl second fat of 3 parts,
The benzene emulsion of 40 parts,
The benzene sulfonic acid sodium salt of 8 parts,
The water of 500 parts,
The ammonium persulphate of 4 parts,
0.3 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 85% benzene sulfonic acid sodium salt in the pre-emulsification still, and 35% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 65% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 70% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 8.5, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 40 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 7
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 220 parts,
The vinylformic acid isooctyl of 170 parts,
The vinylformic acid of 3 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 50 parts,
The benzene sulfonic acid sodium salt of 6 parts,
The water of 450 parts,
The ammonium persulphate of 5 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 88% benzene sulfonic acid sodium salt in the pre-emulsification still, and 30% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 70% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 50% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 9.2, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 40 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 8
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 220 parts,
The vinylformic acid isooctyl of 180 parts,
The vinylformic acid of 4 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 42 parts,
The benzene sulfonic acid sodium salt of 7 parts,
The water of 420 parts,
The ammonium persulphate of 6 parts,
0.3 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 81% benzene sulfonic acid sodium salt in the pre-emulsification still, and 48% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 52% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 80 ℃, add 55% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 8.8, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 45 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 9
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 210 parts,
The vinylformic acid isooctyl of 180 parts,
The vinylformic acid of 3 parts,
The vinylformic acid hydroxyl second fat of 2 parts,
The benzene emulsion of 50 parts,
The benzene sulfonic acid sodium salt of 6 parts,
The water of 450 parts,
The ammonium persulphate of 5 parts,
0.2 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 83% benzene sulfonic acid sodium salt in the pre-emulsification still, and 42% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 58% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 60% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 9.5, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 30 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
Embodiment 10
Formula for the preparation of U.S. line paper sizing agent is as follows:
The butyl acrylate of 200 parts,
The vinylformic acid isooctyl of 190 parts,
The vinylformic acid of 6 parts,
The vinylformic acid hydroxyl second fat of 3 parts,
The benzene emulsion of 40 parts,
The benzene sulfonic acid sodium salt of 8 parts,
The water of 450 parts,
The ammonium persulphate of 6 parts,
0.4 the sodium bicarbonate of part.
Concrete preparation method is as follows:
A, add in described formula 86% benzene sulfonic acid sodium salt in the pre-emulsification still, and 35% water mix and stir, and adding whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, stirring, making pre-emulsion;
B, add sodium bicarbonates whole in described formula, 65% water and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 85 ℃, add 65% ammonium persulphate, and whole benzene emulsions;
C, insulation 10 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2 hours; After dripping off, be incubated 60 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out regulating glue pH value to 8.5, then output glue with ammoniacal liquor;
D, with the glue application of output on U.S. line paper, gluing thickness is 45 μ m, after glue dries, namely makes the U.S. line paper self-adhesive tape of described water-based.
In above-mentioned embodiment, all relate to a rear elimination process in step c, eliminate unreacted residual monomer with rongalite and tertbutyl peroxide in the present invention and realize.U.S. line paper self-adhesive tape of water-based provided by the invention and preparation method thereof adopts aqueous adhesive in addition, removed organic solvent in the past, and U.S. line paper is carried out anti-UV pre-treatment, make that the U.S. line paper self-adhesive tape of producing is pollution-free, environmental protection, possess simultaneously outdoor use function.
Although be the example purpose, the preferred embodiment of the present invention is disclosed, but those of ordinary skill in the art will recognize, in the situation that do not break away from by the disclosed scope and spirit of the present invention of appending claims, various improvement, increase and replacement are possible.
Claims (7)
1. the U.S. line paper self-adhesive tape of water-based, comprise U.S. line ply of paper and the adhesive layer of coating U.S. line ply of paper surface, and it is characterized in that: the glue formula of this adhesive layer is as follows:
The butyl acrylate of 200-300 part,
The vinylformic acid isooctyl of 100-200 part,
The vinylformic acid of 2-10 part,
The vinylformic acid hydroxyl second fat of 2-10 part,
The benzene emulsion of 30-60 part,
The benzene sulfonic acid sodium salt of 5-10 part,
The water of 300-500 part,
The ammonium persulphate of 2-7 part,
0.1-0.5 the sodium bicarbonate of part.
2. the U.S. line paper self-adhesive tape of 1 described water-based as requested, it is characterized in that: described butyl acrylate, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate, benzene emulsion, benzene sulfonic acid sodium salt, ammonium persulphate, sodium bicarbonate are technical grade product.
3. the preparation method of the U.S. line paper self-adhesive tape of water-based as claimed in claim is characterized in that: specifically comprise the following steps:
A, add the benzene sulfonic acid sodium salt of 80-90% in described formula in the pre-emulsification still, mix and stir with the water of 30-50%, and add whole butyl acrylates, Isooctyl acrylate monomer, vinylformic acid, Hydroxyethyl acrylate in formula, and stir, make pre-emulsion;
B, add the water of sodium bicarbonates whole in described formula, 50-70% and remain whole benzene sulfonic acid sodium salts in reactor; Be warming up to 80-85 ℃, add the ammonium persulphate of 50-70%, and whole benzene emulsions;
C, insulation 8～12 minutes begin to drip whole pre-emulsions and remaining ammonium persulphate, drip off in 2～3 hours; After dripping off, be incubated 45～75 minutes, then carry out rear elimination process, and be cooled to below 45 ℃, carry out neutralizing treatment and output glue;
D, with the glue application of output on U.S. line paper, after glue dries, namely make the U.S. line paper self-adhesive tape of described water-based.
4. the preparation method of the U.S. line paper self-adhesive tape of water-based according to claim 3, it is characterized in that: after described in step c, the elimination process is specifically eliminated unreacted residual monomer with rongalite and tertbutyl peroxide.
5. the preparation method of the U.S. line paper self-adhesive tape of water-based according to claim 3 is characterized in that: neutralizing treatment described in step c is specifically 8.5～9.5 with the pH value that ammoniacal liquor is regulated glue.
6. the preparation method of the U.S. line paper self-adhesive tape of water-based according to claim 3, is characterized in that: be 30～50 μ m with the gluing thickness of glue application on U.S. line paper in steps d.
7. the preparation method of the U.S. line paper self-adhesive tape of the described water-based of any one according to claim 3 or 6, it is characterized in that: U.S. line paper described in steps d is for pretreated through anti-UV.
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| CN104877577A (en) * | 2015-06-23 | 2015-09-02 | 周美琴 | Antioxidative binding agent combination with ultraviolet absorption function |
| CN105086852A (en) * | 2015-09-17 | 2015-11-25 | 天津市利顺达粘合剂有限公司 | Environment-friendly water-soluble adhesive and preparation method thereof |
| CN106189903A (en) * | 2016-07-21 | 2016-12-07 | 苏州泰仑电子材料有限公司 | The height with firmoviscosity glues protecting film |
| CN106752977A (en) * | 2016-11-10 | 2017-05-31 | 嘉善弘欣化工厂（普通合伙） | A kind of high viscosity can U.S. line paper self-adhesive tape and its preparation technology |
| CN107663435A (en) * | 2017-11-14 | 2018-02-06 | 福建友谊胶粘带集团有限公司 | A kind of adhesive and its processing technology for glue belt of paper case |
| CN112080233A (en) * | 2020-09-27 | 2020-12-15 | 江苏晶华新材料科技有限公司 | Water-based acrylate masking tape, water-based acrylic pressure-sensitive adhesive and preparation process thereof |
| CN112662346A (en) * | 2020-12-21 | 2021-04-16 | 四川开物华包装材料有限公司 | Glue for masking tape and preparation method thereof |
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| CN102206476A (en) * | 2011-05-11 | 2011-10-05 | 宝利时(深圳)胶粘制品有限公司 | PE (polyurethane) protective film glue and preparation method thereof |
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