CN103173133B - Adhesive for decoration materials - Google Patents
Adhesive for decoration materials Download PDFInfo
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- CN103173133B CN103173133B CN201310059918.9A CN201310059918A CN103173133B CN 103173133 B CN103173133 B CN 103173133B CN 201310059918 A CN201310059918 A CN 201310059918A CN 103173133 B CN103173133 B CN 103173133B
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Abstract
The invention discloses an adhesive for decoration materials. The adhesive is prepared from the raw materials in parts by weight: 100-120 parts of styrene, 100-150 parts of ethyl acetate, 20-25 parts of neoprene CR121, 15-20 parts of dimethylbenzene, 1-2 parts of 4,4'-diphenylmethane diisocyanate, 8-12 parts of polyisobutylene, 2-3 parts of 3-aminopropyl trimethoxysilane, 2-3 parts of polytetrahydrofuran ether glycol, 3-5 parts of SG-2 PVC (Polyvinyl Chloride) resin, 1-2 parts of ferrocene, 8-12 parts of epichlorohydrin rubber H75, 5-8 parts of styrene butadiene rubber, 2-3 parts of zinc oxide and the like. The adhesive disclosed by the invention has excellent heat resistance and water resistance, is high in adhesive strength, good in storage stability, good in environmental protection performance, good in use effect and convenient to use and is water-resistant and dampproof.
Description
Technical field
The present invention relates to a kind of sizing agent, be specifically related to a kind of finishing material sizing agent.
Background technology
At present, the sizing agent that laminating finishing material is used is just in widespread use.The sizing agent that chloroprene rubber class sizing agent and the SBS of take are main body is central main Types.Wherein neoprene sizing agent characteristic is: initial viscous force is large, bonding strength is high, good endurance, glue-line are pliable and tough, elasticity is good, shock-resistant with vibration, there are good oil resistant, water-fast, alkaline-resisting, acidproof, solvent resistance, multiple material is had to good cementability, easy to use, cheap, but its thermotolerance is poor, water tolerance is not good, and package stability is poor.Poor in order to overcome traditional neoprene sizing agent thermotolerance, the shortcoming such as water tolerance is not good, and package stability is poor, and toxicity is large, fills a prescription by improvement, thereby produces a kind of high-performance sizing agent.
Summary of the invention
The object of this invention is to provide that a kind of temperature tolerance is good, cohesive strength is high, excellent storage stability
finishing material is usedchloroprene rubber sizing agent.
The technical solution used in the present invention is as follows:
A finishing material sizing agent, is made by the raw material of following weight part: vinylbenzene 100-120, ethyl acetate 100-150, chloroprene rubber CR121 20-25, dimethylbenzene 15-20, 4,4 '-diphenylmethanediisocyanate 1-2, polyisobutene 8-12, 3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, SG-2 type polyvinyl chloride resin 3-5, ferrocene 1-2, chlorohydrin rubber H75 8-12, styrene-butadiene rubber(SBR) 5-8, zinc oxide 2-3, nano quartz sand 10-15, ground barium sulfate 5-8, antioxidant NBC 1-2, anti-aging agent TPPD 1-2, polyamide wax micropowder 8-12, accelerant CZ 1-2, accelerant N a-22 1-2, trioctyl trimellitate 8-12, aminopropyl triethoxysilane 2-3, linking agent TAIC 1-2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 1-2, irgasfos 168 1-2, the fast carbon black N660 1-2 that extrudes, high abrasion furnace carbon black N330 15-20, Zinic stearas 1-2, tributyl citrate 5-8, epoxy Toenol 1140 5-8, epoxyoleic acid butyl ester 8-12, modification trees ashes 1-2.
Described modification trees ashes are made by following steps: first use 10-15% salt acid soak trees ashes 3-4h, deionized water wash is clean, with 10-12% sodium hydroxide solution, soak 3-4h again, extremely neutral with deionized water wash again, dry, add and be equivalent to the sodium lignosulfonate of trees ashes weight 2-3%, the glycerol glycerinate of the paregal O of 1-2%, 2-3%, the activated alumina of 3-5%, high speed 1200-1500r/min stirs 1-2h, dry, pulverize and grind to form ultrafine powder.
The preparation method of sizing agent for finishing material, comprises the following steps:
(1) by chloroprene rubber CR121, dimethylbenzene, 4,4 '-diphenylmethanediisocyanate, polyisobutene, 3-aminopropyl trimethoxysilane, PTMG, SG-2 type polyvinyl chloride resin, ferrocene, chlorohydrin rubber H75, styrene-butadiene rubber(SBR) mix, and at 100-120 ℃, react 1-2h;
(2) other material is mixed with reactant, stir 30-40min, obtain finished product, packing.
Beneficial effect of the present invention:
The present invention, by trees ashes are carried out to modification, has improved it at the dispersing uniformity in sizing agent component, use bonding strength and the water tolerance of high-performance sizing agent, and it is low to have cost, the feature that effect is good thereby can obviously improve shoemaking by high-performance.Sizing agent of the present invention has good thermotolerance, water tolerance, and cohesive strength is high, water-fast protection against the tide, and excellent storage stability, the feature of environmental protection is good, and result of use is good and convenient.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment
A finishing material sizing agent, is made by the raw material of following weight part: 115 parts of vinylbenzene, 108 parts of ethyl acetate, 22 parts of chloroprene rubber CR121, 18 parts of dimethylbenzene, 4,1.6 parts of 4 '-diphenylmethanediisocyanates, 6 parts of polyisobutene, 2 parts of 3-aminopropyl trimethoxysilane, 3 parts of PTMG, 4 parts of SG-2 type polyvinyl chloride resins, 1.7 parts of ferrocene, 11 parts of chlorohydrin rubber H75, 6 parts, styrene-butadiene rubber(SBR), 2.5 parts, zinc oxide, 12 parts of nano quartz sand, 7 parts of ground barium sulfates, 1.8 parts of antioxidant NBCs, 1.2 parts of anti-aging agent TPPD, 10 parts of polyamide wax micropowders, 1.6 parts of accelerant CZs, 1.5 parts of accelerant N a-22, 10 parts of trioctyl trimellitates, 2.4 parts of aminopropyl triethoxysilanes, 1.6 parts of linking agent TAIC, 1.8 parts of sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, 1.5 parts of irgasfos 168s, fast 2 parts of the carbon black N660 that extrude, 18 parts of high abrasion furnace carbon black N330s, 2 parts of Zinic stearass, 8 parts of tributyl citrates, 6 parts of epoxy Toenol 1140s, 10 parts of epoxyoleic acid butyl esters, 2 parts, modification trees ashes.
Wherein, described modification trees ashes are made by following steps: first use 15% salt acid soak trees ashes 4h, deionized water wash is clean, with 12% sodium hydroxide solution, soak 4h again, more extremely neutral with deionized water wash, dry, add and be equivalent to the sodium lignosulfonate of trees ashes weight 3%, 2% paregal O, 3% glycerol glycerinate, 5% activated alumina, high speed 1500r/min stirs 2h, dries, and pulverizes and grinds to form ultrafine powder.
The preparation method of sizing agent for finishing material, comprises the following steps:
(1) by chloroprene rubber CR121, dimethylbenzene, 4,4 '-diphenylmethanediisocyanate, polyisobutene, 3-aminopropyl trimethoxysilane, PTMG, SG-2 type polyvinyl chloride resin, ferrocene, chlorohydrin rubber H75, styrene-butadiene rubber(SBR) mix, and at 115 ℃, react 2h;
(2) other material is mixed with reactant, stir 40min, obtain finished product, packing.
The salient features of the sizing agent that the present embodiment makes is as following table 1.
Table 1
Water-fast, in water, to soak 12 months, stripping strength declines 4%.
Claims (2)
1. a finishing material sizing agent, is characterized in that, by the raw material of following weight part, is made: vinylbenzene 100-120, ethyl acetate 100-150, chloroprene rubber CR121 20-25, dimethylbenzene 15-20, 4,4 '-diphenylmethanediisocyanate 1-2, polyisobutene 8-12, 3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, SG-2 type polyvinyl chloride resin 3-5, ferrocene 1-2, chlorohydrin rubber H75 8-12, styrene-butadiene rubber(SBR) 5-8, zinc oxide 2-3, nano quartz sand 10-15, ground barium sulfate 5-8, antioxidant NBC 1-2, anti-aging agent TPPD 1-2, polyamide wax micropowder 8-12, accelerant CZ 1-2, accelerant N a-22 1-2, trioctyl trimellitate 8-12, aminopropyl triethoxysilane 2-3, linking agent TAIC 1-2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 1-2, irgasfos 168 1-2, the fast carbon black N660 1-2 that extrudes, high abrasion furnace carbon black N330 15-20, Zinic stearas 1-2, tributyl citrate 5-8, epoxy Toenol 1140 5-8, epoxyoleic acid butyl ester 8-12, modification trees ashes 1-2,
Described modification trees ashes are made by following steps: first use 10-15% salt acid soak trees ashes 3-4h, deionized water wash is clean, with 10-12% sodium hydroxide solution, soak 3-4h again, extremely neutral with deionized water wash again, dry, add and be equivalent to the sodium lignosulfonate of trees ashes weight 2-3%, the glycerol glycerinate of the paregal O of 1-2%, 2-3%, the activated alumina of 3-5%, high speed 1200-1500r/min stirs 1-2h, dry, pulverize and grind to form ultrafine powder.
2. a preparation method for sizing agent for finishing material as claimed in claim 1, is characterized in that comprising the following steps:
(1) by chloroprene rubber CR121, dimethylbenzene, 4,4 '-diphenylmethanediisocyanate, polyisobutene, 3-aminopropyl trimethoxysilane, PTMG, SG-2 type polyvinyl chloride resin, ferrocene, chlorohydrin rubber H75, styrene-butadiene rubber(SBR) mix, and at 100-120 ℃, react 1-2h;
(2) other material is mixed with reactant, stir 30-40min, obtain finished product, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310059918.9A CN103173133B (en) | 2013-02-26 | 2013-02-26 | Adhesive for decoration materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310059918.9A CN103173133B (en) | 2013-02-26 | 2013-02-26 | Adhesive for decoration materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103173133A CN103173133A (en) | 2013-06-26 |
| CN103173133B true CN103173133B (en) | 2014-04-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310059918.9A Active CN103173133B (en) | 2013-02-26 | 2013-02-26 | Adhesive for decoration materials |
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| CN (1) | CN103173133B (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3746606A (en) * | 1971-06-17 | 1973-07-17 | Ncr | Off-line process for laminating magnetic tape to tab stock |
| US7589145B2 (en) * | 2004-04-15 | 2009-09-15 | Exxonmobil Chemical Patents Inc. | Syndiotactic rich polyolefins |
| CN101921551B (en) * | 2009-09-08 | 2013-05-01 | 上海科建化工有限公司 | High temperature resistant vacuum bag sealing adhesive tape |
| CN102190994A (en) * | 2010-03-15 | 2011-09-21 | 张耀华 | Production method for chloroprene rubber adhesive |
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- 2013-02-26 CN CN201310059918.9A patent/CN103173133B/en active Active
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Effective date of registration: 20161216 Address after: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee after: GUANGXI HUIZHI PRODUCTIVITY PROMOTION CENTER Co.,Ltd. Address before: Wu Song Zhen Tongling County of Anhui province Tongling 244100 Union City Village Patentee before: Anhui Mingzhu Dope Technology Co.,Ltd. |
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Effective date of registration: 20200615 Address after: 437400 No. 398, Tongcheng Avenue, junshui Town, Tongcheng County, Xianning City, Hubei Province Patentee after: Hubei Tongcheng high tech materials Co.,Ltd. Address before: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee before: GUANGXI HUIZHI PRODUCTIVITY PROMOTION CENTER Co.,Ltd. |
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Denomination of invention: An adhesive for decorative materials Effective date of registration: 20230303 Granted publication date: 20140430 Pledgee: Bank of China Limited Xianning branch Pledgor: Hubei Tongcheng high tech materials Co.,Ltd. Registration number: Y2023420000087 |
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