CN103170759A - Aluminum welding powder and welding method thereof - Google Patents

Aluminum welding powder and welding method thereof Download PDF

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Publication number
CN103170759A
CN103170759A CN2013101192358A CN201310119235A CN103170759A CN 103170759 A CN103170759 A CN 103170759A CN 2013101192358 A CN2013101192358 A CN 2013101192358A CN 201310119235 A CN201310119235 A CN 201310119235A CN 103170759 A CN103170759 A CN 103170759A
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welding
aluminium
powder
aluminum
welded
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CN103170759B (en
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杨辉
张国栋
王晴晴
赖梓扬
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Shenzhen City Jin Penggui material science and Technology Co Ltd
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Wuhan University WHU
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Abstract

The invention relates to aluminum welding powder and a welding method thereof, and belongs to the technical field of aluminum and aluminum alloy welding. The aluminum welding powder comprises the following components: by weight, copper oxide 17%-19%, vanadium pentoxide 12%-14%, stannic oxide 13%-15%, lithium sulfate 1%-2%, boron powder 3%-4%, calcium fluoride 2.5%-3%, and the balance is aluminum powder. According to the aluminum welding powder, heat-released welding of aluminum parent metal is achieved. The welding method of the aluminum welding powder has the advantages that power sources or gas sources or hot sources or energy sources are not required for welding, and the aluminum welding powder belongs to typical environment-friendly electricity-less welding materials; and the welding device is compact, light in weight, easy to carry, suitable for field operation, aerial operation and the like, and especially suitable for emergency repairing of aluminum conductors after disasters such as an earthquake and a snow disaster.

Description

A kind of aluminium welding powder and welding method thereof
Technical field
The present invention relates to a kind of aluminium welding powder and welding method thereof, belong to aluminium and aluminum alloy solder technology field.
Background technology
aluminium busbar is one of most important part in whole electrolytic aluminium factory building, direct current after rectification is incorporated into electrolytic cell by aluminium busbar, electrolytic cell has negative busbar, anode bus, riser bus bar and soft band bus, be in series by aluminium busbar between groove and groove, also has interbus between factory building and factory building, but the conductive aluminum bus often can unexpectedly damage aborning, need in time repair welding to the bus that damages, produce in order to avoid impact is normal, and the existence in magnetic field has produced very large negative effect to the enforcement with electric welding, cause whole welding process difficulty, appearance of weld is of poor quality, welding process can't be implemented.In addition, also there is certain defect in the connectivity problem of aluminum conductor, often adopts traditional method of attachment at present: electric welding, bolts and nuts connection, line ear and crimping.The shortcomings such as these interconnection techniques and product exist complex operation, connection is lack of standardization, quality is lower, unreliable conductor overheating easily occurs, line drop is excessive in the transmission of electricity process, and then cause that various electric faults even open circuit.
For effectively overcoming the above problems, relevant enterprise and professional person have carried out a large amount of test and study work to the welding procedure of aluminium and aluminium alloy both at home and abroad, and make some progress.The main method of repairing at present aluminium busbar is to adopt carbon arc welding to weld after falling electric current or power failure.Have a power failure and not only cause the minimizing of electrolytic aluminium output, energy consumption significantly to increase, also can increase noxious gas emission, cause environmental pollution.Denomination of invention is a kind of method of cast aluminium braze-welding, application number is that 94119278.4 patent discloses a kind of braze-welding method with all kinds of Birmasils of oxy-acetylene flame welding, although the method can realize the welding of aluminium alloy, but its complex operation, course of reaction is difficult to hold, and need extra heating, the requirement that discontented podomere can weld, and be not suitable for field work and the welding when emergent.
Along with the development of welding procedure, in recent years, heat release is welded into for study hotspot.The heat release welding is also referred to as the chamotte welding.Need not external power source or thermal source, be to utilize the chemical reaction of sweat soldering to produce high temperature solution, and discharge a kind of method that high heat is completed welding.Heat release welding chemical reaction velocity is very fast, only just can complete welding in several seconds.The heat of its generation is high, can effectively conduct to the welding position, and it is fused into one, and makes copper/copper, and copper/aluminium forms firmly molecule combination between copper/steel, aluminium/aluminium.
The heat release welding is in fact a kind of new technique that combines with solder technology from epidemic techniques, belongs to the category from the spreading welding technology, and it is simple and convenient that it has welding, high efficiency; Welding effect is good, and Weld Performance is good; The advantage such as applied widely.Although the heat release welding is widely applied, it but is subject to great restriction in welding of aluminum and field of aluminum alloys.This is to be that copper or the iron that adopts reproducibility active metal metal oxide as another kind of in reduction such as aluminium, magnesium (being generally the oxide of copper or iron) exothermic reaction to generate melting is realized welding as weld metal because welding powder is realized the principle of welding.Because aluminium itself is very active, be difficult to by other metal replacement out, and aluminum mother plate has rapid heat dissipation, the easy characteristic such as oxidation, to be considered to difficulty very large always from spreading exothermic reaction welding of aluminum and aluminium alloy mother metal so adopt.
Based on this, the present invention is intended to research and develop the novel aluminum welding powder, seeks new reaction system, realizes the moment heat release, rely on the excessive aluminium powder of heat melts, and product is discharged as welding slag, thus realization aluminium truly and the heat release welding of aluminium alloy.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of aluminium welding powder that can realize the aluminum and its alloy welding.
Aluminium welding powder of the present invention uses excessive aluminium powder, and emits large calorimetric by moment, melts excessive aluminium powder, as weld metal, thereby realizes heat release welding to aluminum and its alloy.
For reaching above purpose, composition and mass percent in novel aluminum welding powder of the present invention are: cupric oxide 17 ~ 19%, and vanadic anhydride 12 ~ 14%, tin ash 13 ~ 15%, lithium sulfate 1 ~ 2%, boron powder 3 ~ 4%, calcirm-fluoride 2.5 ~ 3%, all the other are aluminium powder.
It is better that the order number is all 200 ~ 300 order welding effects.
In this formula, redox reaction all can occur with aluminium powder in three kinds of oxides, realizes the moment heat release, and the heat release welding heat is large, and reduzate all has alloying action, improves welding point hardness; Reduzate copper can guarantee the electric conductivity that welding point is good in addition; Vanadium can increase the mobility of molten metal; Tin can reduce alloy melting point, strengthens the mobility of aluminium alloy, and tin has good wetability with aluminium, realizes good metallurgical binding between assurance weld seam and aluminum mother plate; Lithium sulfate has good hygroscopicity, can reduce or eliminate the defectives such as pore that cause because of a small amount of moisture in welding powder, and lithium sulfate and the aluminium powder heat of reaction larger, make weld penetration larger, metallurgical binding is more firm; Boron can reduce the fragility of weld metal, improves welding point toughness; Calcirm-fluoride plays fluxing effect, and reaction alundum (Al2O3) slag is afterwards effectively separated with aluminium alloy, purifies weld metal; In formula, aluminium powder is excessive, part aluminium and oxide reaction, and unnecessary aluminium dilutes thermite on the one hand, and absorption portion heat during fusing reduces the exothermic reaction liberated heat, prevents splash; Aluminium is also filled weld seam as weld metal on the other hand, makes the composition of weld metal similar as far as possible to mother metal.
Use the method for aluminium welding powder welding aluminum or aluminum alloy of the present invention, specifically comprise the following steps:
1) the preparation aluminium welding powder, stir;
2) aluminium to be welded is carried out pre-welding treatment, remove surface and oil contaminant and oxide-film;
3) bottom is opened foraminate charging mould and aluminium to be welded and assemble, require charging mould small hole at bottom part and aluminium region alignment to be welded;
4) aluminium is preheating to 200-300 ℃, and oven dry charging mould;
5) put catch at the charging mold bottom, cover aperture, with the welding powder mould of packing into, slightly flatten compacting;
6) sprinkle starting mix on welding powder, igniting, after the fusing of catch in the mould of feeding, high temperature fluent metal flow into aluminium zone to be welded by charging mould small hole at bottom part, can form good metallurgical binding after cooling.
Described aluminium to be welded can be placed on graphite base.The graphite base heat accumulation is more, can slow down the heat consume of aluminium, is beneficial to welding.
Described catch is tinfoil paper.
The composition of described starting mix is gunpowder.
The pre-welding treatment of described aluminium to be welded, concrete method for cleaning is first to wipe aluminium material surface greasy dirt to be welded with organic solvents such as acetone, gasoline, then brush the aluminium welding surface with brass wire brush or stainless steel wire brush, or with scraper, file cleaning welding surface, until aluminium exposes metallic luster.
Also can adopt following method: first remove the greasy dirt of aluminium material surface with organic solvents such as acetone, gasoline, kerosene, embathe the 10min left and right with 5%~10wt%NaOH solution of 40 ℃~70 ℃, then rinse with the clear water that flows, then use 30wt%HNO 3Solution pickling 3min cleans air-dry or low temperature drying with absolute ethyl alcohol after the clear water that flows rinses.
Adopt the modes such as oxy-acetylene rifle, electric furnace, tracklayer heater to the aluminium preheating.
When aluminium welding powder welding of aluminum of the present invention and aluminium alloy, relate to four kinds of exothermic reactions, be respectively aluminium and cupric oxide reaction displacement copper, aluminium and vanadic anhydride reaction displace vanadium, and aluminium and tin ash reaction displace tin, lithium sulfate and reactive aluminum heat release.
Aluminium powder in aluminium welding powder of the present invention is reducing agent, cupric oxide, and vanadic anhydride, tin ash, lithium sulfate is oxidant.
The present invention has following beneficial effect:
1, aluminium welding powder of the present invention is green welding material without the electricity cleaning, relies on the welding powder id reaction to produce high heat, effectively conducts to the welding position, and it is fused into one, and forms intermolecular combination.Welding powder based on the interface soakage principle, certainly spread principle and compound metallurgical principle and realize welding, need not other any power supplys, source of the gas, thermal source, the energy, belong to typical green without the electric welding material.
2, method of operating equipment is simple.During the welding of aluminum mother metal without any need for power supply and miscellaneous equipment; Need not high pressure, also need not protective atmosphere, only rely on mixed-powder combustion reaction liberated heat just can weld, high efficiency.Small volume and less weight, simple to operate.
3, applied widely.Due to the equipment small volume and less weight, easily carry.Therefore be applicable to the field, work high above the ground etc. also are specially adapted to earthquake, the emergency first-aid repair of the aluminum conductor after the disasters such as snow disaster.
Description of drawings
Fig. 1 is the reaction unit schematic diagram.Comprise charging mould (3), catch (4), aluminium to be welded (5) and graphite base (6).Be welding powder (2) and starting mix (1) in the charging mould.
The specific embodiment
To help to understand by the following description of the embodiments the present invention, but not limit content of the present invention.
Embodiment one:
At first the mass ratio according to 43:19:14:15:2:4:3 takes chemical pure Al (200 order), CuO (200 order), V successively 2O 5(200 order), SnO 2(200 order), Li 2SO 4(300 order), B (300 order), CaF 2(200 order) powder, and it is mixed, namely make aluminium welding powder.Then wipe aluminum mother plate surface and oil contaminant to be welded with acetone, then clear up welding surface with file, until mother metal exposes metallic luster.To feed mould and aluminum mother plate assembled, and aluminum mother plate is preheating to 300 ℃ afterwards, and oven dry charging mould.Put catch at the charging mold bottom, cover aperture, with the welding powder mould of packing into, slightly flatten compacting.Sprinkle starting mix on welding powder, igniting, after the fusing of catch in the mould of feeding, high temperature fluent metal flow into aluminum mother plate zone to be welded by charging mould small hole at bottom part, can form good metallurgical binding after to be cooled.
Embodiment two:
At first the mass ratio according to 43:19:14:15:2:4:3 takes chemical pure Al (200 order), CuO (200 order), V successively 2O 5(200 order), SnO 2(200 order), Li 2SO 4(300 order), B (300 order), CaF 2(200 order) powder, and it is mixed, namely make aluminium welding powder.Remove the greasy dirt on aluminium busbar surface with acetone, embathe aluminum mother plate welding surface 10min left and right with the 10%NaOH solution of 40 ℃, then use 30%HNO 3Then solution pickling 3min rinses with the clear water that flows, and cleans with absolute ethyl alcohol after the clear water that flows rinses, air-dry.To feed mould and aluminum mother plate assembled, and aluminum mother plate is preheating to 300 ℃ afterwards, and oven dry charging mould.Put catch at the charging mold bottom, cover aperture, with the welding powder mould of packing into, slightly flatten compacting.Sprinkle starting mix on welding powder, igniting, after the fusing of catch in the mould of feeding, high temperature fluent metal flow into aluminum mother plate zone to be welded by charging mould small hole at bottom part, can form good metallurgical binding after to be cooled.
Embodiment three:
At first the mass ratio according to 103:34:24:26:2:6:5 takes chemical pure Al (200 order), CuO (200 order), V successively 2O 5(200 order), SnO 2(200 order), Li 2SO 4(300 order), B (300 order), CaF 2(200 order) powder, and it is mixed, namely make aluminium welding powder.Then wipe aluminum mother plate surface and oil contaminant to be welded with acetone, then clear up welding surface with file, until mother metal exposes metallic luster.To feed mould and aluminum mother plate assembled, and aluminum mother plate is preheating to 300 ℃ afterwards, and oven dry charging mould.Put catch at the charging mold bottom, cover aperture, with the welding powder mould of packing into, slightly flatten compacting.Sprinkle starting mix on welding powder, igniting, after the fusing of catch in the mould of feeding, high temperature fluent metal flow into aluminum mother plate zone to be welded by charging mould small hole at bottom part, can form good metallurgical binding after to be cooled.
Embodiment four:
At first the mass ratio according to 103:34:24:26:2:6:5 takes chemical pure Al (200 order), CuO (200 order), V successively 2O 5(200 order), SnO 2(200 order), Li 2SO 4(300 order), B (300 order), CaF 2(200 order) powder, and it is mixed, namely make aluminium welding powder.Remove the greasy dirt on aluminium busbar surface with acetone, embathe aluminum mother plate welding surface 10min left and right with the 10%NaOH solution of 40 ℃, then use 30%HNO 3Then solution pickling 3min rinses with the clear water that flows, and cleans with absolute ethyl alcohol after the clear water that flows rinses, air-dry.To feed mould and aluminum mother plate assembled, and aluminum mother plate is preheating to 300 ℃ afterwards, and oven dry charging mould.Put catch at the charging mold bottom, cover aperture, with the welding powder mould of packing into, slightly flatten compacting.Sprinkle starting mix on welding powder, igniting, after the fusing of catch in the mould of feeding, high temperature fluent metal flow into aluminum mother plate zone to be welded by charging mould small hole at bottom part, can form good metallurgical binding after to be cooled.

Claims (7)

1. an aluminium welding powder, is characterized in that, composition wherein and mass percent are: cupric oxide 17 ~ 19%, and vanadic anhydride 12 ~ 14%, tin ash 13 ~ 15%, lithium sulfate 1 ~ 2%, boron powder 3 ~ 4%, calcirm-fluoride 2.5 ~ 3%, all the other are aluminium powder.
2. aluminium welding powder according to claim 1, is characterized in that, all one-tenth subhead numbers are all 200 ~ 300 orders.
3. right to use requires the method for 1 described aluminium welding powder welding aluminum or aluminum alloy, it is characterized in that, comprises the following steps:
1) the preparation aluminium welding powder, stir;
2) aluminium to be welded is carried out pre-welding treatment, remove surface and oil contaminant and oxide-film;
3) bottom is opened foraminate charging mould and aluminium to be welded and assemble, require charging mould small hole at bottom part and aluminium region alignment to be welded;
4) aluminium is preheating to 200-300 ℃, and oven dry charging mould;
5) put catch at the charging mold bottom, cover aperture, with the welding powder mould of packing into, slightly flatten compacting;
6) sprinkle starting mix on welding powder, igniting, after the fusing of catch in the mould of feeding, high temperature fluent metal flow into aluminium to be welded zone to be welded by charging mould small hole at bottom part, can form good metallurgical binding after cooling.
4. method according to claim 3, is characterized in that, described aluminium to be welded is placed on graphite base.
5. method according to claim 3, is characterized in that, described catch is tinfoil paper.
6. method according to claim 3, is characterized in that, the composition of described starting mix is gunpowder.
7. method according to claim 3, is characterized in that, adopts oxy-acetylene rifle, electric furnace or tracklayer heater to aluminium preheating to be welded.
CN201310119235.8A 2013-04-08 2013-04-08 Aluminum welding powder and welding method thereof Expired - Fee Related CN103170759B (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103406661A (en) * 2013-08-22 2013-11-27 武汉大学 Aluminum-steel self-propagating welding method
CN103706967A (en) * 2013-12-20 2014-04-09 王洪亮 Solder and welding method
CN103943973A (en) * 2014-04-18 2014-07-23 励土峰 Gunpowder quick wire connector
CN103938548A (en) * 2014-04-23 2014-07-23 宁波邦和新材料有限公司 Welding ball for suspension bridge main cable wrapping wires
CN104043913A (en) * 2014-06-24 2014-09-17 国家电网公司 Exothermic welding powder for welding novel grounding grid materials
CN104057216A (en) * 2014-05-12 2014-09-24 昆山福易雅自动化科技有限公司 Novel heat emitting welding flux and welding method
CN105040031A (en) * 2015-08-27 2015-11-11 武汉大学 Non-power-outage repairing method for aluminum electrolysis cell short circuit busbar
CN106392302A (en) * 2016-12-14 2017-02-15 武汉大学 Vertical aluminium bus welding method
CN106541246A (en) * 2016-09-27 2017-03-29 新疆众和股份有限公司 The method that aluminum cell bus-bar sweat soldering is repaired under electromagnetic field environment
CN107186375A (en) * 2017-07-29 2017-09-22 安徽华众焊业有限公司 A kind of aluminium welding powder
CN107378302A (en) * 2017-07-31 2017-11-24 安徽华众焊业有限公司 A kind of non-corrosive aluminium welding powder
CN107378301A (en) * 2017-07-31 2017-11-24 安徽华众焊业有限公司 A kind of non-corrosive aluminium welding powder
CN107457500A (en) * 2017-09-19 2017-12-12 浙江昌泰电力电缆有限公司 A kind of heat release welding powder and its welding method suitable for copper conductor welding
CN107790915A (en) * 2017-11-15 2018-03-13 广西塔锡科技有限公司 A kind of aluminium welding powder and preparation method thereof
CN110932049A (en) * 2019-11-15 2020-03-27 东莞市输变电工程公司 Combustion connection method for cable
CN113399866A (en) * 2021-06-11 2021-09-17 武汉大学 Aluminum electrolysis cell horizontal bus hot-line repair welding flux and preparation method thereof

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103406661B (en) * 2013-08-22 2016-05-25 武汉大学 A kind of aluminium-steel is from spreading welding method
CN103406661A (en) * 2013-08-22 2013-11-27 武汉大学 Aluminum-steel self-propagating welding method
CN103706967A (en) * 2013-12-20 2014-04-09 王洪亮 Solder and welding method
CN103706967B (en) * 2013-12-20 2016-06-15 王洪亮 A kind of welding compound and welding method
CN103943973A (en) * 2014-04-18 2014-07-23 励土峰 Gunpowder quick wire connector
CN103938548A (en) * 2014-04-23 2014-07-23 宁波邦和新材料有限公司 Welding ball for suspension bridge main cable wrapping wires
CN104057216A (en) * 2014-05-12 2014-09-24 昆山福易雅自动化科技有限公司 Novel heat emitting welding flux and welding method
CN104043913A (en) * 2014-06-24 2014-09-17 国家电网公司 Exothermic welding powder for welding novel grounding grid materials
CN104043913B (en) * 2014-06-24 2016-05-25 国家电网公司 A kind of aluminothermy welding powder for novel grounded net materials welding
CN105040031A (en) * 2015-08-27 2015-11-11 武汉大学 Non-power-outage repairing method for aluminum electrolysis cell short circuit busbar
CN106541246A (en) * 2016-09-27 2017-03-29 新疆众和股份有限公司 The method that aluminum cell bus-bar sweat soldering is repaired under electromagnetic field environment
CN106392302A (en) * 2016-12-14 2017-02-15 武汉大学 Vertical aluminium bus welding method
CN106392302B (en) * 2016-12-14 2018-11-13 武汉大学 A kind of welding method of vertical aluminium busbar
CN107186375A (en) * 2017-07-29 2017-09-22 安徽华众焊业有限公司 A kind of aluminium welding powder
CN107378302A (en) * 2017-07-31 2017-11-24 安徽华众焊业有限公司 A kind of non-corrosive aluminium welding powder
CN107378301A (en) * 2017-07-31 2017-11-24 安徽华众焊业有限公司 A kind of non-corrosive aluminium welding powder
CN107457500A (en) * 2017-09-19 2017-12-12 浙江昌泰电力电缆有限公司 A kind of heat release welding powder and its welding method suitable for copper conductor welding
CN107790915A (en) * 2017-11-15 2018-03-13 广西塔锡科技有限公司 A kind of aluminium welding powder and preparation method thereof
CN110932049A (en) * 2019-11-15 2020-03-27 东莞市输变电工程公司 Combustion connection method for cable
CN113399866A (en) * 2021-06-11 2021-09-17 武汉大学 Aluminum electrolysis cell horizontal bus hot-line repair welding flux and preparation method thereof
CN113399866B (en) * 2021-06-11 2022-02-15 武汉大学 Aluminum electrolysis cell horizontal bus hot-line repair welding flux and preparation method thereof

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Address before: 518000, Guangdong Province, Yantian District, Shenzhen, seamounts street, deep salt road, Pacific Industrial Zone 1, building 7, 5-6 span

Patentee before: SHENZHEN YUANSIDACHENG TECHNOLOGY CO., LTD.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150304

Termination date: 20180408