CN103160107A - Polyphenylene oxide/polyamide 6 blend alloy as well as preparation method and application for same - Google Patents
Polyphenylene oxide/polyamide 6 blend alloy as well as preparation method and application for same Download PDFInfo
- Publication number
- CN103160107A CN103160107A CN2011104072289A CN201110407228A CN103160107A CN 103160107 A CN103160107 A CN 103160107A CN 2011104072289 A CN2011104072289 A CN 2011104072289A CN 201110407228 A CN201110407228 A CN 201110407228A CN 103160107 A CN103160107 A CN 103160107A
- Authority
- CN
- China
- Prior art keywords
- nylon
- blend alloy
- parts
- alloy material
- polyphenylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a polyphenylene oxide/polyamide 6 blend alloy. The polyphenylene oxide/polyamide 6 blend alloy is prepared from the components in the following parts by weight: 20-80 parts of polyphenylene oxide, 10-40 parts of polyamide 6, 5-35 parts of compatilizer, 5-15 parts of toughener, 0.2-0.5 parts of antioxidant, 0.2-0.7 parts of lubricant, and 3-35.5 parts of auxiliaries. The invention further discloses a preparation method for the polyphenylene oxide/polyamide 6 blend alloy and an application for the polyphenylene oxide/polyamide 6 blend alloy as an extruded profile material. The PPO/PA6 (polyphenylene oxide/polyamide 6) blend alloy material disclosed by the invention is high in strength, good in toughness, excellent in corrosion resistance and insulativity, capable of replacing a steel plate or a special engineering plastic, thus realizing the purpose of replacing steel by plastic. Moreover, the PPO/PA6 blend alloy material can be popularized to extruded profiles, as well as is good in wear resistance, heat resistance and dimensional stability, easy to machine and form, and capable of being used by replacing the profiles of stainless steel, PEEK (poly ether ether ketone) and the like in a very large range, thus greatly reducing cost.
Description
Technical field
The present invention relates to technical field of polymer materials, relate in particular to a kind of polyphenyl ether/nylon 6 (PPO/PA6) blend alloy material and preparation method thereof and application.
Background technology
Along with the progress of society, the development of science and technology, people's life are more and more convenient, and people are also more and more higher to the attention rate of environment simultaneously.Polyphenylene oxide (PPO) is a kind of thermoplastic engineering plastic of excellent performance, has following advantage: the Physical and mechanical properties that (1) is good.The mechanical strength that density is little, nontoxic, higher, creep resistance is good, molding shrinkage is low; (2) good resistance toheat.Second-order transition temperature (T
g) the highest in thermoplastics, approximately 210 ℃, approximately 260 ℃ of fusing points, it can non-stop run in the temperature range of 160-190 ℃, and the creep resistant under high temperature is comparatively excellent in thermoplastic engineering plastic; (3) good electrical property.In the PPO molecular structure, without strong polar group, electric performance stablity can keep good electrical property in temperature and range of frequency widely.Its specific inductivity and tangent of the dielectric loss angle are minimum in engineering plastics, are subjected to hardly the impact of temperature, humidity and frequency; (4) difficult combustion, have self-extinguishing.Its oxygen index is 29%, and flame retardant resistance is good; (5) good resistance to acids and bases, proof stress relax and fatigue performance and good dimensional stability.Wherein high creep resistance can be its most outstanding characteristics, so PPO is particularly suitable for making the industrial structural part that bears long-duration load.But PPO also has some shortcomings, as poor solvent resistance, goods, stress cracking, notched Izod impact strength occurs easily low etc.The PPO photostabilization is poor, uses for a long time product easy to change under sunlight or luminescent lamp, the color jaundice, and reason is the chain combination division that ultraviolet ray can make aromatic oxide; The fatal shortcoming of another one is poor fluidity, the forming process difficulty, and because PPO molecular chain rigidity is larger, melt viscosity is high, and this has affected applying of PPO.
Polyamide (PA) is a kind of engineering plastics of excellent property, and it makes it have that solvent resistance is good, the advantages such as mechanical strength is high, easy processing because degree of crystallinity is higher.But it exists, and shock strength is low, thermotolerance is relatively poor, because of the shortcomings such as product size poor stability that high-hydroscopicity causes, make its application be restricted.
The PPO/PA alloy had both kept the advantages such as the good heat resistance, dimensional stabilizing of PPO, had circulated again wear resistance and the organic solvent resistance of PA.In some special electronic apparatuss and main equipment, need to have the section bars such as gear, bar of property (as little in insulativity, erosion resistance, density etc.), and in industry, shape commonly used can't meet the demands.
Summary of the invention
Problems such as the present invention is exactly that the PPO notched Izod impact strength that above-mentioned prior art exists is low in order to solve, poor solvent resistance, price are higher and a kind of polyphenyl ether/nylon 6 blend alloy material is provided.
Another object of the present invention is to provide above-mentioned polyphenyl ether/nylon 6 blend alloy material preparation method.
A further object of the present invention is to provide the purposes of above-mentioned polyphenyl ether/nylon 6 blend alloy material.
Purpose of the present invention is achieved through the following technical solutions:
A kind of polyphenyl ether/nylon 6 blend alloy material, made by the component that comprises following weight part:
Polyphenylene oxide 20-80 part,
Nylon 6 10-40 parts,
Compatilizer 5-35 part,
Toughner 5-15 part,
Oxidation inhibitor 0.2-0.5 part,
Lubricant 0.2-0.7 part,
Auxiliary agent 3-35.5 part.
Preferably, described compatilizer is selected from one or more in polyphenylene oxide grafted maleic anhydride, styrene-maleic anhydride copolymer, POE grafted maleic anhydride.
Preferably, described toughner is selected from one or more in the segmented copolymer (SBS), (hydrogenated styrene/Butadiene/Styrene) segmented copolymer (SEBS), maleic anhydride graft styrene-ethylene-butadiene-styrene block copoly merization elastomerics (SEBS-g-MAH) of vinylbenzene and divinyl.
Preferably, described oxidation inhibitor be selected from antioxidant 1010 (four [
-(3,5-di-tert-butyl-hydroxy phenyl) propionic ester] pentaerythritol ester), antioxidant 1076 (
The positive octadecanol ester of-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid), one or more in irgasfos 168 (three ［ 2.4-di-tert-butyl-phenyl ］ phosphorous acid ester).
Preferably, described lubricant is selected from one or more in calcium stearate, silicone, paraffin, low-molecular-weight polypropylene, polyethylene wax, Zinic stearas.
Preferably, the molecular weight of described low-molecular-weight polypropylene is 3000-8000.
Preferably, described auxiliary agent is selected from one or more in filler, coupling agent.
Preferably, described filler is selected from one or more in glass fibre, calcium carbonate, Calucium Silicate powder, talcum powder, titanium dioxide; Described glass fibre is selected from long glass fibres or short glass fiber.
Preferably, described coupling agent is
-aminopropyl triethoxysilane (silane resin acceptor kh-550).
A kind of polyphenyl ether/nylon 6 blend alloy material preparation method, the method comprises the following steps:
Take by weight 20-80 part polyphenylene oxide, 10-40 part nylon 6,5-35 part compatilizer, 5-15 part toughner, 0.2-0.5 part oxidation inhibitor, 0.2-0.7 part lubricant and 3-35.5 part auxiliary agent, through high mixer high speed mixing, then mixture is poured in screw extrusion press, can be obtained product through the pelletizing of screw extrusion press tie rod.
Preferably, described high mixer rotating speed is 800-1000rpm, and mixing temperature is 40-80 ℃, and mixing time is 3-10min.
Preferably, described screw extrusion press is single screw extrusion machine or twin screw extruder, and extrusion temperature is 240-290 ℃.
Polyphenyl ether/nylon 6 blend alloy material of the present invention, its performance meets the performance requriements of extrusion profile material, therefore, technical scheme of the present invention comprises that also polyphenyl ether/nylon 6 blend alloy material of the present invention is as the application of extrusion profile material (as bar, sheet material etc.).
Compared with prior art, the present invention has following beneficial effect:
The present invention is PA6 and PPO blending and modifying, and adds other auxiliary agents, and the PPO/PA6 blend alloy material that obtains can replace steel plate or special engineering plastics.At first, PA6 adds the processing characteristics that can improve PPO, and the PPO/PA6 alloy material is for metal, and cost is lower, and save energy realized moulding the purpose of Dai Gang, and polyblend has fabulous erosion resistance and insulativity; By adding the filler bulk strength of strongthener greatly, can improve the notched Izod impact strength of material by adding toughner simultaneously.Secondly, PPO/PA6 alloy material extruding-out process is simple, saves tooling cost, reduces energy waste.
At last, PPO/PA6 alloy material of the present invention can extend to extrusion profile, has good erosion resistance, insulativity, good intensity, toughness and wear resistance, and therefore light weight can be used as the component in the special main equipments such as electronic apparatus, of many uses.The section bar that utilizes the PPO/PA6 alloy material to make has enough intensity and rigidity, and possess simultaneously PPO thermotolerance and good stability of the dimension and PA6 organic solvent resistance and the good advantage of wear resistance, be easy to machine-shaping, can in very large range replace stainless steel and PEEK(polyether-ether-ketone) etc. section bar use, greatly reduce cost.
Embodiment
Describe the present invention in detail below in conjunction with each embodiment.
Embodiment 1
(1) take each component raw material by following weight part:
30 parts of polyphenylene oxide,
6 40 parts of nylon,
30 parts of compatilizer PPO-g-MAH,
10 parts of toughner SEBS,
0.2 part of antioxidant 1010,
0.1 part of irgasfos 168,
0.2 part of calcium stearate
3 parts, calcium carbonate;
(2) with above-mentioned raw materials through high mixer high speed mixing, controlling high mixer speed is 800rmp, mixing temperature is 40 ℃, mixes 10min; Then mixture can be obtained product through the pelletizing of twin screw extruder tie rod, the temperature in each district is controlled at 260-290 ℃.
Embodiment 2
(1) take each component raw material by following weight part:
50 parts of polyphenylene oxide,
6 40 parts of nylon,
5 parts of compatilizer POE-g-MAH,
10 parts of toughner SBS,
0.1 part of antioxidant 1010,
0.1 part of irgasfos 168,
0.2 part of silicone,
5 parts of Calucium Silicate powder;
(2) with above-mentioned raw materials through high mixer high speed mixing, controlling high mixer speed is 800rmp, mixing temperature is 80 ℃, mixes 3min; Mixture can be obtained product through the pelletizing of twin screw extruder tie rod, and the temperature in each district is controlled at 240-265 ℃.
Embodiment 3
(1) take each component raw material by following weight part:
75 parts of polyphenylene oxide,
6 15 parts of nylon,
10 parts of compatilizer SMAH,
10 parts of toughner SEBS-g-MAH,
0.2 part of antioxidant 1010,
0.2 part of irgasfos 168,
0.2 part, paraffin,
7 parts of talcum powder;
(2) with above-mentioned raw materials through high mixer high speed mixing, controlling high mixer speed is 1000rmp, mixing temperature is 60 ℃, mixes 6min; Mixture can be obtained product through the pelletizing of twin screw extruder tie rod, and the temperature in each district is controlled at 250-280 ℃.
Embodiment 4
(1) take each component raw material by following weight part:
80 parts of polyphenylene oxide,
6 10 parts of nylon,
5 parts of compatilizer SMAH,
15 parts of toughner SBS,
0.3 part of antioxidant 1010,
0.2 part of irgasfos 168,
0.2 part of low-molecular-weight polypropylene,
5 parts of titanium dioxides;
(2) with above-mentioned raw materials through high mixer high speed mixing, its high mixer speed is 1000rmp, mixing temperature is 60 ℃, mixes 5min; Mixture can be obtained product through the pelletizing of twin screw extruder tie rod, and the temperature in each district is controlled at 260-280 ℃.
Embodiment 5
(1) take each component raw material by following weight part:
20 parts of polyphenylene oxide,
6 30 parts of nylon,
20 parts of compatilizer PPO-g-MAH,
5 parts of toughner SEBS,
0.2 part of antioxidant 1010,
0.1 part of irgasfos 168,
0.3 part of polyethylene wax,
25 parts of short glass fibers (diameter 18 μ m),
0.5 part of coupling agent KH-550;
(2) with above-mentioned raw materials through high mixer high speed mixing, controlling high mixer speed is 900rmp, mixing temperature is 60 ℃, mixes 6min; Mixture can be obtained product through the pelletizing of twin screw extruder tie rod, and the temperature in each district is controlled at 260-280 ℃.
Embodiment 6
(1) take each component raw material by following weight part:
40 parts of polyphenylene oxide,
6 15 parts of nylon,
10 parts of compatilizer POE-g-MAH,
5 parts of toughner SEBS-g-MAH,
0.1 part of antioxidant 1010,
0.1 part of irgasfos 168,
0.5 part of Zinic stearas,
35 parts of long glass fibress,
0.5 part of coupling agent KH-550;
(2) with above-mentioned raw materials through high mixer high speed mixing, its high mixer speed is 950rmp, mixing temperature is 40 ℃, mixes 5min; Mixture can be obtained product through the pelletizing of single screw extrusion machine tie rod, and the temperature in each district is controlled at 250-270 ℃.
Embodiment 7
(1) take each component raw material by following weight part:
35 parts of polyphenylene oxide,
6 20 parts of nylon,
35 parts of compatilizer PPO-g-MAH,
10 parts of toughner SEBS,
0.2 part of antioxidant 1010,
0.1 part of irgasfos 168,
0.7 part of Zinic stearas,
3 parts of titanium dioxides;
(2) with above-mentioned raw materials through high mixer high speed mixing, its high mixer speed is 850rmp, mixing temperature is 40 ℃, mixes 5min; Mixture can be obtained product through the pelletizing of twin screw extruder tie rod, and the temperature in each district is controlled at 250-280 ℃.
Embodiment 8
(1) take each component raw material by following weight part:
35 parts of polyphenylene oxide,
6 25 parts of nylon,
5 parts of compatilizer SMAH,
15 parts of toughner SEBS,
0.2 part of antioxidant 1076,
0.2 part of polyethylene wax,
20 parts of long glass fibress,
0.5 part of coupling agent KH-550;
(2) with above-mentioned raw materials through high mixer high speed mixing, its high mixer speed is 850rmp, mixing temperature is 80 ℃, mixes 4min; Mixture can be obtained product through the pelletizing of twin screw extruder tie rod, and the temperature in each district is controlled at 250-280 ℃.
Product to embodiment 1 carries out performance test, and test result sees Table 1.
Table 1
PPO/PA6 blend alloy material of the present invention, intensity or toughness all are enough to satisfy the service requirements of extrusion profile, polyblend has well corrosion-resistant and insulativity simultaneously, cost is much lower than shape, its density is also much lower, can reduce costs greatly, save energy realizes to mould the purpose of Dai Gang.Polyphenyl ether/nylon 6 blend alloy material of the present invention, its performance meets the performance requriements of extrusion profile material, can be used as the extrusion profile material and makes the section bars such as bar, sheet material.
Above disclosed be only several specific embodiments of the application, but the application is not limited thereto, the changes that any person skilled in the art can think of all should drop in the application's protection domain.
Claims (10)
1. a polyphenyl ether/nylon 6 blend alloy material, is characterized in that, made by the component that comprises following weight part:
Polyphenylene oxide 20-80 part,
Nylon 6 10-40 parts,
Compatilizer 5-35 part,
Toughner 5-15 part,
Oxidation inhibitor 0.2-0.5 part,
Lubricant 0.2-0.7 part,
Auxiliary agent 3-35.5 part.
2. polyphenyl ether/nylon 6 blend alloy material as claimed in claim 1, is characterized in that, described compatilizer is selected from one or more in polyphenylene oxide grafted maleic anhydride, styrene-maleic anhydride copolymer, POE grafted maleic anhydride.
3. polyphenyl ether/nylon 6 blend alloy material as claimed in claim 1, it is characterized in that, described toughner is selected from one or more in the segmented copolymer, (hydrogenated styrene/Butadiene/Styrene) segmented copolymer, maleic anhydride graft styrene-ethylene-butadiene-styrene block copoly merization elastomerics of vinylbenzene and divinyl.
4. polyphenyl ether/nylon 6 blend alloy material as claimed in claim 1, is characterized in that, described oxidation inhibitor is selected from one or more in antioxidant 1010, antioxidant 1076, irgasfos 168.
5. polyphenyl ether/nylon 6 blend alloy material as claimed in claim 1, is characterized in that, described lubricant is selected from one or more in calcium stearate, silicone, paraffin, low-molecular-weight polypropylene, polyethylene wax, Zinic stearas.
6. polyphenyl ether/nylon 6 blend alloy material as claimed in claim 1, is characterized in that, described auxiliary agent is selected from one or more in filler, coupling agent.
7. polyphenyl ether/nylon 6 blend alloy material as claimed in claim 6, is characterized in that, described filler is selected from one or more in glass fibre, calcium carbonate, Calucium Silicate powder, talcum powder, titanium dioxide; Described glass fibre is selected from long glass fibres or short glass fiber; Described coupling agent is
-aminopropyl triethoxysilane.
8. a polyphenyl ether/nylon 6 blend alloy material preparation method as described in any one in claim 1 to 7, is characterized in that, the method comprises the following steps:
Take by weight 20-80 part polyphenylene oxide, 10-40 part nylon 6,5-35 part compatilizer, 5-15 part toughner, 0.2-0.5 part oxidation inhibitor, 0.2-0.7 part lubricant and 3-35.5 part auxiliary agent, through high mixer high speed mixing, then mixture is poured in screw extrusion press, can be obtained product through the pelletizing of screw extrusion press tie rod.
9. polyphenyl ether/nylon 6 blend alloy material preparation method as claimed in claim 8, is characterized in that, described high mixer rotating speed is 800-1000rpm, and mixing temperature is 40-80 ℃, and mixing time is 3-10min; Described screw extrusion press is single screw extrusion machine or twin screw extruder, and extrusion temperature is 240-290 ℃.
10. a polyphenyl ether/nylon 6 blend alloy material as described in any one in claim 1 to 7 is as the application of extrusion profile material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104072289A CN103160107A (en) | 2011-12-09 | 2011-12-09 | Polyphenylene oxide/polyamide 6 blend alloy as well as preparation method and application for same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104072289A CN103160107A (en) | 2011-12-09 | 2011-12-09 | Polyphenylene oxide/polyamide 6 blend alloy as well as preparation method and application for same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103160107A true CN103160107A (en) | 2013-06-19 |
Family
ID=48583655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104072289A Pending CN103160107A (en) | 2011-12-09 | 2011-12-09 | Polyphenylene oxide/polyamide 6 blend alloy as well as preparation method and application for same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103160107A (en) |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289367A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | High-temperature-resistant heat-conductive PA/PPO/PP composite material and preparation method thereof |
| CN103333486A (en) * | 2013-06-27 | 2013-10-02 | 金发科技股份有限公司 | Composition of polyphenyl ether and nylon and preparation method thereof |
| CN103627315A (en) * | 2013-11-22 | 2014-03-12 | 包头市丰达石油机械有限责任公司 | Nylon modified anticorrosive coating and application thereof |
| CN103980692A (en) * | 2014-05-22 | 2014-08-13 | 深圳市沃特新材料股份有限公司 | Polyphenyl ether resin alloy material for pillow inner framework of massage chair and preparation method thereof |
| CN104046013A (en) * | 2014-05-19 | 2014-09-17 | 安徽安缆模具有限公司 | Fatigue-resistant automobile fender nylon composite and preparation method thereof |
| CN105440665A (en) * | 2015-12-11 | 2016-03-30 | 合肥会通新材料有限公司 | Low-filling high-heat conductivity insulating nylon/polyphenyl ether alloy and preparation method thereof |
| CN105694423A (en) * | 2014-11-28 | 2016-06-22 | 上海杰事杰新材料(集团)股份有限公司 | A modified polyphenylene oxide material with high strength and low dielectric loss and a preparing method thereof |
| CN106751784A (en) * | 2017-03-23 | 2017-05-31 | 贵州省材料产业技术研究院 | High rigidity, corrosion resistance nylon alloy special material for pipeline and preparation method thereof |
| CN107418186A (en) * | 2017-08-25 | 2017-12-01 | 广州找塑料新材料科技有限公司 | A kind of vinal enhancing PPO/PA6 alloys of high-modulus and preparation method thereof |
| CN107674403A (en) * | 2017-11-03 | 2018-02-09 | 贵州高塑环保新材料有限公司 | Weather resistant fire prevention PPO composite material and preparation method thereof |
| CN107722596A (en) * | 2017-11-03 | 2018-02-23 | 贵州高塑环保新材料有限公司 | The cold-resistant high strength PPO composite material of height and its application |
| WO2018053782A1 (en) * | 2016-09-23 | 2018-03-29 | 张旭东 | Plastic and preparation method therefor |
| CN109054339A (en) * | 2018-09-21 | 2018-12-21 | 浙江伟星实业发展股份有限公司 | A kind of resin chain tooth, resin teeth zipper and preparation method thereof |
| CN109777079A (en) * | 2019-01-18 | 2019-05-21 | 扬州工业职业技术学院 | A kind of modified polyphenylene oxide alloy material and the preparation method and application thereof |
| CN110373015A (en) * | 2019-08-28 | 2019-10-25 | 深圳市罗湖区亨业纳米新材料研究院 | A kind of new material and preparation method thereof of cold-resistant heat-resisting flame-retardant |
| CN110591332A (en) * | 2019-10-21 | 2019-12-20 | 广东圆融新材料有限公司 | Polyphenylene ether/polyamide 66 composition and method for making same |
| CN110628202A (en) * | 2019-11-08 | 2019-12-31 | 广东圆融新材料有限公司 | High dielectric constant polyphenylene ether/polyamide 66 composition and preparation method thereof |
| CN110643167A (en) * | 2019-10-25 | 2020-01-03 | 广东圆融新材料有限公司 | Flame-retardant reinforced polyphenyl ether/polyamide 66 composition and preparation method thereof |
| CN110643175A (en) * | 2019-11-11 | 2020-01-03 | 广东圆融新材料有限公司 | High dielectric constant polyamide 6/polyphenyl ether composition and preparation method thereof |
| CN110724374A (en) * | 2019-10-24 | 2020-01-24 | 广东圆融新材料有限公司 | Flame-retardant polyphenyl ether/polyamide 66 composition and preparation method thereof |
| CN111040414A (en) * | 2019-12-31 | 2020-04-21 | 贵州凯科特材料有限公司 | SEBS (styrene-ethylene-butadiene-styrene) toughened PPO/PA6 composite material with low dielectric constant and preparation method thereof |
| CN112159588A (en) * | 2020-09-04 | 2021-01-01 | 镇江三的新材料有限公司 | Low-warpage 3D printing PA/PPO alloy consumable and preparation method thereof |
| CN112961432A (en) * | 2021-02-06 | 2021-06-15 | 广州辰东新材料有限公司 | Injection molding thermoplastic material for replacing metal card taking needle and card taking needle prepared from thermoplastic material |
| CN113265139A (en) * | 2020-09-25 | 2021-08-17 | 广东奇德新材料股份有限公司 | High-oxygen-index glass fiber reinforced PA/PPO composite material and preparation method thereof |
| CN114149683A (en) * | 2021-12-08 | 2022-03-08 | 江苏博云塑业股份有限公司 | Polyphenyl ether and nylon composition and preparation method thereof |
| CN115703928A (en) * | 2021-08-17 | 2023-02-17 | 中蓝晨光化工研究设计院有限公司 | Modified resin for portable seawater filter and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580099A (en) * | 2003-08-11 | 2005-02-16 | 上海杰事杰新材料股份有限公司 | Continuous fiber reinforced thermoplastic composite material |
| US20060073302A1 (en) * | 2004-10-01 | 2006-04-06 | Daicel Polymer, Ltd. | Laser weldable resin composition and composite article |
| CN101302336A (en) * | 2008-05-21 | 2008-11-12 | 深圳市科聚新材料有限公司 | Flame-retardant PPO/PA alloy and preparation thereof |
| US20090283724A1 (en) * | 2006-05-12 | 2009-11-19 | Asahi Kasei Chemicals Corporation | Conductive master batch |
| CN101759992A (en) * | 2008-12-23 | 2010-06-30 | 金发科技股份有限公司 | Reinforced halogen-free flame-retardant polyphenyl ether composition and preparation method and application thereof |
-
2011
- 2011-12-09 CN CN2011104072289A patent/CN103160107A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580099A (en) * | 2003-08-11 | 2005-02-16 | 上海杰事杰新材料股份有限公司 | Continuous fiber reinforced thermoplastic composite material |
| US20060073302A1 (en) * | 2004-10-01 | 2006-04-06 | Daicel Polymer, Ltd. | Laser weldable resin composition and composite article |
| US20090283724A1 (en) * | 2006-05-12 | 2009-11-19 | Asahi Kasei Chemicals Corporation | Conductive master batch |
| CN101302336A (en) * | 2008-05-21 | 2008-11-12 | 深圳市科聚新材料有限公司 | Flame-retardant PPO/PA alloy and preparation thereof |
| CN101759992A (en) * | 2008-12-23 | 2010-06-30 | 金发科技股份有限公司 | Reinforced halogen-free flame-retardant polyphenyl ether composition and preparation method and application thereof |
Cited By (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289367B (en) * | 2013-06-24 | 2015-06-10 | 苏州新区佳合塑胶有限公司 | High-temperature-resistant heat-conductive PA/PPO/PP composite material and preparation method thereof |
| CN103289367A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | High-temperature-resistant heat-conductive PA/PPO/PP composite material and preparation method thereof |
| CN103333486A (en) * | 2013-06-27 | 2013-10-02 | 金发科技股份有限公司 | Composition of polyphenyl ether and nylon and preparation method thereof |
| CN103333486B (en) * | 2013-06-27 | 2016-03-02 | 金发科技股份有限公司 | The composition and method of making the same of polyphenylene oxide and nylon |
| CN103627315A (en) * | 2013-11-22 | 2014-03-12 | 包头市丰达石油机械有限责任公司 | Nylon modified anticorrosive coating and application thereof |
| CN104046013A (en) * | 2014-05-19 | 2014-09-17 | 安徽安缆模具有限公司 | Fatigue-resistant automobile fender nylon composite and preparation method thereof |
| CN103980692B (en) * | 2014-05-22 | 2016-07-27 | 江苏沃特新材料科技有限公司 | Polyphenylether resin alloy material for massage armchair pillow core skeleton and preparation method thereof |
| CN103980692A (en) * | 2014-05-22 | 2014-08-13 | 深圳市沃特新材料股份有限公司 | Polyphenyl ether resin alloy material for pillow inner framework of massage chair and preparation method thereof |
| CN105694423A (en) * | 2014-11-28 | 2016-06-22 | 上海杰事杰新材料(集团)股份有限公司 | A modified polyphenylene oxide material with high strength and low dielectric loss and a preparing method thereof |
| CN105440665B (en) * | 2015-12-11 | 2018-03-20 | 会通新材料股份有限公司 | A kind of low filling high heat conductive insulating nylon/polyphenylene oxide alloy and preparation method thereof |
| CN105440665A (en) * | 2015-12-11 | 2016-03-30 | 合肥会通新材料有限公司 | Low-filling high-heat conductivity insulating nylon/polyphenyl ether alloy and preparation method thereof |
| WO2018053782A1 (en) * | 2016-09-23 | 2018-03-29 | 张旭东 | Plastic and preparation method therefor |
| CN106751784A (en) * | 2017-03-23 | 2017-05-31 | 贵州省材料产业技术研究院 | High rigidity, corrosion resistance nylon alloy special material for pipeline and preparation method thereof |
| CN107418186A (en) * | 2017-08-25 | 2017-12-01 | 广州找塑料新材料科技有限公司 | A kind of vinal enhancing PPO/PA6 alloys of high-modulus and preparation method thereof |
| CN107674403A (en) * | 2017-11-03 | 2018-02-09 | 贵州高塑环保新材料有限公司 | Weather resistant fire prevention PPO composite material and preparation method thereof |
| CN107722596A (en) * | 2017-11-03 | 2018-02-23 | 贵州高塑环保新材料有限公司 | The cold-resistant high strength PPO composite material of height and its application |
| CN109054339A (en) * | 2018-09-21 | 2018-12-21 | 浙江伟星实业发展股份有限公司 | A kind of resin chain tooth, resin teeth zipper and preparation method thereof |
| CN109777079B (en) * | 2019-01-18 | 2023-06-16 | 扬州工业职业技术学院 | Modified polyphenyl ether alloy material and preparation method and application thereof |
| CN109777079A (en) * | 2019-01-18 | 2019-05-21 | 扬州工业职业技术学院 | A kind of modified polyphenylene oxide alloy material and the preparation method and application thereof |
| CN110373015A (en) * | 2019-08-28 | 2019-10-25 | 深圳市罗湖区亨业纳米新材料研究院 | A kind of new material and preparation method thereof of cold-resistant heat-resisting flame-retardant |
| CN110591332A (en) * | 2019-10-21 | 2019-12-20 | 广东圆融新材料有限公司 | Polyphenylene ether/polyamide 66 composition and method for making same |
| CN110591332B (en) * | 2019-10-21 | 2022-03-25 | 广东圆融新材料有限公司 | Polyphenylene ether/polyamide 66 composition and method for making same |
| CN110724374A (en) * | 2019-10-24 | 2020-01-24 | 广东圆融新材料有限公司 | Flame-retardant polyphenyl ether/polyamide 66 composition and preparation method thereof |
| CN110643167A (en) * | 2019-10-25 | 2020-01-03 | 广东圆融新材料有限公司 | Flame-retardant reinforced polyphenyl ether/polyamide 66 composition and preparation method thereof |
| CN110643167B (en) * | 2019-10-25 | 2022-03-25 | 广东圆融新材料有限公司 | Flame-retardant reinforced polyphenyl ether/polyamide 66 composition and preparation method thereof |
| CN110628202B (en) * | 2019-11-08 | 2022-03-25 | 广东圆融新材料有限公司 | High dielectric constant polyphenylene ether/polyamide 66 composition and preparation method thereof |
| CN110628202A (en) * | 2019-11-08 | 2019-12-31 | 广东圆融新材料有限公司 | High dielectric constant polyphenylene ether/polyamide 66 composition and preparation method thereof |
| CN110643175A (en) * | 2019-11-11 | 2020-01-03 | 广东圆融新材料有限公司 | High dielectric constant polyamide 6/polyphenyl ether composition and preparation method thereof |
| CN110643175B (en) * | 2019-11-11 | 2022-04-15 | 广东圆融新材料有限公司 | High dielectric constant polyamide 6/polyphenyl ether composition and preparation method thereof |
| CN111040414A (en) * | 2019-12-31 | 2020-04-21 | 贵州凯科特材料有限公司 | SEBS (styrene-ethylene-butadiene-styrene) toughened PPO/PA6 composite material with low dielectric constant and preparation method thereof |
| CN112159588A (en) * | 2020-09-04 | 2021-01-01 | 镇江三的新材料有限公司 | Low-warpage 3D printing PA/PPO alloy consumable and preparation method thereof |
| CN113265139A (en) * | 2020-09-25 | 2021-08-17 | 广东奇德新材料股份有限公司 | High-oxygen-index glass fiber reinforced PA/PPO composite material and preparation method thereof |
| CN112961432A (en) * | 2021-02-06 | 2021-06-15 | 广州辰东新材料有限公司 | Injection molding thermoplastic material for replacing metal card taking needle and card taking needle prepared from thermoplastic material |
| CN115703928A (en) * | 2021-08-17 | 2023-02-17 | 中蓝晨光化工研究设计院有限公司 | Modified resin for portable seawater filter and preparation method thereof |
| CN114149683A (en) * | 2021-12-08 | 2022-03-08 | 江苏博云塑业股份有限公司 | Polyphenyl ether and nylon composition and preparation method thereof |
| CN114149683B (en) * | 2021-12-08 | 2024-02-02 | 江苏博云塑业股份有限公司 | Polyphenyl ether and nylon composition and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103160107A (en) | Polyphenylene oxide/polyamide 6 blend alloy as well as preparation method and application for same | |
| CN103059550B (en) | A kind of PPO/PS blend alloy material, preparation method and application thereof | |
| CN103160108A (en) | Halogen-free flame-retardant polyphenylene oxide/polyamide 6 blend alloy as well as preparation and application for same | |
| CN101195707B (en) | Glass fiber-reinforced nylon 6-polypropylene alloy material | |
| CN103102673A (en) | Halogen-free flame retardant polyphenyl ether/polystyrene alloy material and preparation method thereof | |
| CN103172997A (en) | Low-density polyphenylether/polystyrene (PPO/PS) blend alloy material and preparation method thereof | |
| CN103421298A (en) | Polyphenyl ether / polystyrene blending alloy material and preparation method thereof | |
| CN103421297A (en) | Polyphenyl ether / polystyrene blending alloy material and preparation method thereof | |
| CN108034215A (en) | A kind of high-low temperature resistant alternation modified poly ester alloy material and preparation method thereof | |
| CN103694564A (en) | PP/PMMA (polypropylene/polymethyl methacrylate) alloy material and preparation method thereof | |
| CN101880451B (en) | Halogen-free fire-retardant polyphenyl ether compound and method for preparing same | |
| CN106947247A (en) | Composite modified semi-aromatic nylon/polyphenylene oxide composite material of glass fibre-mineral and preparation method thereof | |
| CN103205105A (en) | Super-weather resistant polyphenylene oxide/polyphenylene sulfide alloy material, its preparation method and application | |
| CN105907095A (en) | Thermoplastic resin composite material and preparation method thereof | |
| CN102942736B (en) | High-glass fiber content reinforced polypropylene material and preparation method thereof | |
| CN104277459A (en) | Polyphenylene sulfide/semi-aromatic nylon composite material and preparation method thereof | |
| CN103421296A (en) | PPO/PS blend alloy material and preparation method thereof | |
| CN102329454B (en) | Polypropylene composite material as well as preparation method and application thereof | |
| CN107955367B (en) | High-fatigue-resistance nylon composite material for office chair and preparation method thereof | |
| CN101875772A (en) | Glass fiber reinforced PC composite material and preparation method thereof | |
| CN113604038A (en) | Ultrahigh-flow high-impact PPO/PA66 alloy material and preparation method thereof | |
| CN103724979B (en) | A kind of high flowing heatproof LED PPO/PA composition and method of making the same | |
| CN107501718B (en) | Reinforced modified polypropylene reclaimed material and preparation method thereof | |
| CN103849131B (en) | A kind of ultra-toughness is modified MPPO materials and preparation method thereof | |
| CN104277446A (en) | Polyphenyl ether/polypropylene copolymer blended alloy material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130619 |
|
| RJ01 | Rejection of invention patent application after publication |