CN103160068A - Phenolic glass fiber reinforced plastic composite material - Google Patents
Phenolic glass fiber reinforced plastic composite material Download PDFInfo
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- CN103160068A CN103160068A CN201110422319XA CN201110422319A CN103160068A CN 103160068 A CN103160068 A CN 103160068A CN 201110422319X A CN201110422319X A CN 201110422319XA CN 201110422319 A CN201110422319 A CN 201110422319A CN 103160068 A CN103160068 A CN 103160068A
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- reinforced plastics
- matrix material
- fiberglass reinforced
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Abstract
The invention provides a phenolic glass fiber reinforced plastic composite material, belonging to the technical field of high-molecular materials. The material is composed of the following raw materials by weight parts: 36-40 parts of phenolic resins, 2.8-5.5 parts of a curing agent, 1.1-2.2 parts of a curing accelerator, 1.1-2.0 parts of a mold lubricant, 45-50 parts of filling materials, 19-23 parts of reinforced fiber, and 5-10 parts of cellulose. The phenolic glass fiber reinforced plastic composite material has characteristics of good hear resistance and high intensity.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of phenolic fiberglass reinforced plastics matrix material.
Background technology
Because the phenolic fiberglass reinforced plastics moulding compound has preferably that thermotolerance, intensity are high, convenient formation, the multiple advantage such as cheap, be widely used in all trades and professions.Along with electric and electronic component microminiaturization day by day, also more and more higher to the phenolic fiberglass reinforced plastics material requirements, therefore, having good integrated application performance such as flexural strength, heat-resistant deforming and insulating property is directions that industry is pursued.
Summary of the invention
Task of the present invention is that a kind of phenolic aldehyde mould glass fiber reinforced plastics composite material will be provided, and it has integrated application performances such as flexural strength, thermotolerance and electric insulation preferably.
The object of the present invention is achieved like this, a kind of phenolic fiberglass reinforced plastics matrix material, and its raw material by following parts by weight forms:
36～40 parts, resol;
2.8～5.5 parts, solidifying agent;
1.1～2.2 parts of curing catalysts;
1.1～2.0 parts of releasing agents;
45～50 parts of fillers;
19～23 parts of fortifying fibres;
5～10 parts of Mierocrystalline celluloses.
In one embodiment of the present of invention, described resol refers to the resol that acid system is produced.
In an alternative embodiment of the invention, described solidifying agent refers to hexamethylene tetramine.
In another embodiment of the present invention, described curing catalyst magnesium oxide.
In another embodiment of the present invention, described releasing agent is calcium stearate.
Of the present invention also have in an embodiment, and described filler is kaolin.
More of the present invention and in embodiment, described fortifying fibre is glass fibre.
In of the present invention and then embodiment, described Mierocrystalline cellulose is lignocellulose.
Phenolic fiberglass reinforced plastics matrix material provided by the invention has good heat resistance, the characteristics that intensity is high.Through test, flexural strength 80MPa, 240 ℃ of heat-drawn wires.
Embodiment
Embodiment 1
36 parts, resol;
2.8 parts of hexamethylene tetramines;
1.2 parts, magnesium oxide;
1.1 parts of calcium stearates;
45 parts of kaolin;
19 parts, glass fibre;
5 parts of lignocelluloses.
During concrete enforcement, accurate weighing above-mentioned raw materials, then mix at first successively, be transferred in mill heat and mixed 6 minutes, then pulling-on piece, cooling, pulverize, namely get the phenolic fiberglass reinforced plastics matrix material of true qualities.
Embodiment 2
37 parts, resol;
3.7 parts of hexamethylene tetramines;
1.5 parts, magnesium oxide;
1.4 parts of calcium stearates;
47 parts of kaolin;
21 parts, glass fibre;
7 parts of lignocelluloses;
1 part of carbon black.
During concrete enforcement, accurate weighing above-mentioned raw materials, then mix at first successively, be transferred in mill heat and mixed 6 minutes, then pulling-on piece, cooling, pulverize, namely get the phenolic fiberglass reinforced plastics matrix material of black.
Embodiment 3
39 parts, resol;
4.8 parts of hexamethylene tetramines;
1.7 parts, magnesium oxide;
1.8 parts of calcium stearates;
49 parts of kaolin;
22 parts, glass fibre;
8 parts of lignocelluloses;
Blue 2 parts of phthalein cyanogen.
During concrete enforcement, accurate weighing above-mentioned raw materials, then mix at first successively, is transferred to hot the mixing 6 minutes in mill, and then pulling-on piece, cooling, pulverizing, namely get blue phenolic fiberglass reinforced plastics matrix material.
Embodiment 4
40 parts, resol;
5.3 parts of hexamethylene tetramines;
2.1 parts, magnesium oxide;
1.9 parts of calcium stearates;
50 parts of kaolin;
23 parts, glass fibre;
9 parts of lignocelluloses;
Green 2 parts of phthalein cyanogen.
During concrete enforcement, accurate weighing above-mentioned raw materials, then mix at first successively, is transferred to hot the mixing 6 minutes in mill, and then pulling-on piece, cooling, pulverizing, namely get green phenolic fiberglass reinforced plastics matrix material.
Through test, above-mentioned phenolic fiberglass reinforced plastics matrix material has following performance:
Claims (8)
1. phenolic fiberglass reinforced plastics matrix material is characterized in that its raw material by following parts by weight forms:
36 ~ 40 parts, resol;
2.8 ~ 5.5 parts, solidifying agent;
1.1 ~ 2.2 parts of curing catalysts;
1.1 ~ 2.0 parts of releasing agents;
45 ~ 50 parts of fillers;
19 ~ 23 parts of fortifying fibres;
5～10 parts of Mierocrystalline celluloses.
2. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described resol refers to the resol that acid system is produced.
3. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described solidifying agent refers to hexamethylene tetramine.
4. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described curing catalyst magnesium oxide.
5. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described releasing agent is calcium stearate.
6. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described filler is kaolin.
7. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described fortifying fibre is glass fibre.
8. a kind of phenolic fiberglass reinforced plastics matrix material according to claim 1, is characterized in that described Mierocrystalline cellulose is lignocellulose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110422319XA CN103160068A (en) | 2011-12-16 | 2011-12-16 | Phenolic glass fiber reinforced plastic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110422319XA CN103160068A (en) | 2011-12-16 | 2011-12-16 | Phenolic glass fiber reinforced plastic composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103160068A true CN103160068A (en) | 2013-06-19 |
Family
ID=48583621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110422319XA Pending CN103160068A (en) | 2011-12-16 | 2011-12-16 | Phenolic glass fiber reinforced plastic composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103160068A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104198134A (en) * | 2014-08-26 | 2014-12-10 | 宁波工程学院 | Detection device and detection method for sealing performances of expansion tanks |
| CN106967283A (en) * | 2017-05-19 | 2017-07-21 | 汪建军 | A kind of fireproof glass steel composite material |
| CN108980182A (en) * | 2017-05-31 | 2018-12-11 | 江苏海川新材料科技有限公司 | A kind of novel anchor rod is with determining torque nut |
| CN108979004A (en) * | 2017-05-31 | 2018-12-11 | 江苏海川新材料科技有限公司 | A kind of ring-like glass-fiber reinforcement material |
| US10751981B2 (en) | 2017-12-04 | 2020-08-25 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
| US10766239B2 (en) | 2017-12-04 | 2020-09-08 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
| US10780686B2 (en) | 2017-12-04 | 2020-09-22 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781441A (en) * | 2009-01-21 | 2010-07-21 | 上海欧亚合成材料有限公司 | Phenolic moulding plastics for commutator |
| CN101787176A (en) * | 2010-04-02 | 2010-07-28 | 沙县宏盛塑料有限公司 | Phenolic molding material using emulsion prepared from cashew nut oil and water as plasticizer and preparation method thereof |
-
2011
- 2011-12-16 CN CN201110422319XA patent/CN103160068A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781441A (en) * | 2009-01-21 | 2010-07-21 | 上海欧亚合成材料有限公司 | Phenolic moulding plastics for commutator |
| CN101787176A (en) * | 2010-04-02 | 2010-07-28 | 沙县宏盛塑料有限公司 | Phenolic molding material using emulsion prepared from cashew nut oil and water as plasticizer and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104198134A (en) * | 2014-08-26 | 2014-12-10 | 宁波工程学院 | Detection device and detection method for sealing performances of expansion tanks |
| CN104198134B (en) * | 2014-08-26 | 2015-07-29 | 宁波工程学院 | A kind of expansion tank leak-testing apparatus and detection method thereof |
| CN106967283A (en) * | 2017-05-19 | 2017-07-21 | 汪建军 | A kind of fireproof glass steel composite material |
| CN108980182A (en) * | 2017-05-31 | 2018-12-11 | 江苏海川新材料科技有限公司 | A kind of novel anchor rod is with determining torque nut |
| CN108979004A (en) * | 2017-05-31 | 2018-12-11 | 江苏海川新材料科技有限公司 | A kind of ring-like glass-fiber reinforcement material |
| US10751981B2 (en) | 2017-12-04 | 2020-08-25 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
| US10766239B2 (en) | 2017-12-04 | 2020-09-08 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
| US10780686B2 (en) | 2017-12-04 | 2020-09-22 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
| US11407214B2 (en) | 2017-12-04 | 2022-08-09 | Annexair Inc. | Composite panel, composite material, impregnator and method for manufacturing a composite panel |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130619 |