CN103155921A - Plant disease control composition containing fluopicolide - Google Patents
Plant disease control composition containing fluopicolide Download PDFInfo
- Publication number
- CN103155921A CN103155921A CN2011104376138A CN201110437613A CN103155921A CN 103155921 A CN103155921 A CN 103155921A CN 2011104376138 A CN2011104376138 A CN 2011104376138A CN 201110437613 A CN201110437613 A CN 201110437613A CN 103155921 A CN103155921 A CN 103155921A
- Authority
- CN
- China
- Prior art keywords
- fluopicolide
- tpn
- active ingredient
- composition
- hectares
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a plant disease control composition containing fluopicolide. Effective constituents of the plant disease control composition containing the fluopicolide are the fluopicolide and chlorothalonil. The composition is mainly used for preventing and treating diseases of an epidemic disease, late blight, damping-off, downy mildew and the like which are caused by oomycetes funguses on crops of cucumbers, grapes, litchis, tomatoes, potatoes, brassicaceous vegetables and the like.
Description
Technical field
The present invention relates to a kind of control of plant disease composition, especially contain the crop disease control composition of fluopicolide.
Background technology
Fluopicolide, English general by name: Fluopicolide, chemical name is: 2,6-, two chloro-N-[(3-chloro-5-trifluoromethyl-2-pyridine radicals) methyl] benzamide is a kind of the Oomycete fungi to be had very highly active material.Differential protein between fluopicolide major effect cell membrane and cytoskeleton has good protection, therapeutic action concurrently.It has outstanding infiltration and conducting power in the plant body, can permeate downwards from leaf surface, also can conduct to blade tip from phyllopodium, also can transport to whole strain through xylem from root.It both can be used for spraying processes, and also can fill with root and use.The fluopicolide mechanism of action is unique, with the bactericide of using in agricultural production without cross resistance.
The epidemic disease, late blight, damping off, the downy mildew that are caused by Oomycete are class diseases very harmful in agricultural production, that be difficult to prevent and treat, have had a strong impact on output and the quality of crop.This type of disease to the control medicament particularly in absorption, medicative medicament such as metalaxyl, dimethomorph etc. be easy to produce resistance, from this respect, the interior suction therapeutic action that fluopicolide has be advantage be also shortcoming.For avoiding fluopicolide similar resistance to occur, need carry out itself and the composition of different mechanism of action rationally composite, effectively to delay the genesis of disease resistance.
Summary of the invention
The object of the invention is to: a kind of corps diseases composition that reduces cost accounting, improves control efficiency is provided.In order to reach goal of the invention, the inventor through in a large number, compound screening test widely, unexpected find that the proper proportion combination of fluopicolide and tpn has outstanding synergistic effect to epidemic disease, downy mildew, it is combined in situation lower than the single dose consumption, can show the good result that is better than single dose.Research or application about fluopicolide and chlorothalonil compound at present has no open.
Technical scheme of the present invention is:
A kind of control of plant disease composition, active ingredient is comprised of fluopicolide and tpn.
Described composition is characterized in that in composition, the percentage by weight of active ingredient fluopicolide and tpn is 50: 1～1: 50, and better percentage by weight is 10: 1～1: 50, and better percentage by weight is 5: 1～1: 50.
Described composition is characterized in that active ingredient accounts for 1%～90% of composition total weight.
Described composition is characterized in that said composition can be made into suspending agent, aqueous emulsion, microemulsion, missible oil, wetting powder or water dispersible granules, and can use corresponding solvent, carrier and auxiliary agent according to the exploitation needs.
Suitable solvent, auxiliary agent comprise: as one or more combinations of toluene, dimethylbenzene, carrene, chloroform, paraffin, kerosene, diesel oil, methyl alcohol, ethanol, propyl alcohol, butanols, amylalcohol, cyclohexanol, phenmethylol, cyclohexanone, isophorone, pyrrolidones, ethyl acetate, butyl acetate, ethylene acetate, methyl-sulfoxide etc.
One or more combinations of carrier such as clay, bentonite, attapulgite, calcium sulphate, precipitated calcium carbonate, sucrose, industrial chitin, silica gel, talcum powder, white carbon, sericite in powder etc.;
available auxiliary agent comprises phosphoric acid salt, the hydrochloric acid salt, lignosulphonates, naphthalenesulfonate, the phenolsulfonic acid salt, the succinic acid Sulfonates, polystyrene-based phenol polyethenoxy ether sulfate, Pluronic PE 6800, molecular weight is the macromolecular grafted copolymer of 20000-30000, the triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, polystyrene-based phenol polyethenoxy ethers, the polyoxyethylene nonylphenol ether class, the polystyrene-based polyethenoxy ether class, the alkyl naphthalene sulfonic acid salt, fatty alcohol polyethenoxy ether class, the dialkyl succinylsuccinate Sulfonates, the branched fatty alcohol polyethenoxy ether class, the alkyl polyoxyethylene ether class, the carboxyl alkyl cellulose class, the hydroxy alkyl cellulose class, Magnesiumaluminumsilicate, xanthans, poly-alkyl silicon ethylene oxide, phosphoric acid, glacial acetic acid, citric acid, maleic acid, butylated hydroxy-a alkane, butylated hydroxy anisole, ditert-butylhydro quinone, one or more combinations in n-propyl gallate etc.
Embodiment
Different compounds are carried out Combination application, are one of effective control measures of administering the disease-resistant problem of damage by disease and insect.Combination with synergistic effect can improve the control efficiency of medicament significantly, reduces the usage amount of agricultural chemicals.By a large amount of concrete composite tests, learn that fluopicolide and tpn have significant synergies.The embodiment that the below provides is used for elaborating the present invention, and does not consist of limiting the scope of the invention.If embodiment experimental technique used without specified otherwise, is conventional method; If percentage composition in embodiment without specified otherwise, is weight percentage.
Biologicall test example 1: fluopicolide and the chlorothalonil compound Toxicity Determination to capsicum epidemic disease
Subjects: capsicum epidemic disease (Phytophthora capsici Leonian)
Adopt leaf dish floating method to measure.With sporangia suspension concentration adjustment to 4 * 10
4Put into the refrigerator 15min of 5～8 ℃ after individual/mL, then place 30min in about 25 ℃ of room temperatures and stimulate Zoospore liberations.The configuration medicament, 6 concentration gradients are set, add respectively the liquid of 20mL variable concentrations in the culture dish of diameter 9cm, to add the sterilization deionized water as contrast, the Pepper Leaves back side that is 14mm with diameter is placed in liquid up, 10, every ware, after soaking 2h, blade is taken out slightly dry, 15 μ L zoospore suspension are dripped in every leaf disk center, put under 22 ℃, 12h illumination condition and cultivate 7d.Depending on the blank incidence investigation state of an illness, according to the disease index of lesion area computing, calculate disease index and control efficiency.
Control efficiency (%)=(blank disease index-chemicals treatment disease index)/blank disease index * 100
Add up the control efficiency of each gradient, with concentration EC in the inhibition of method of least squares calculating medicament
50, then calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.When CTC＜80, the composition performance is for antagonism, and when 80＜CTC＜120, the composition performance is for summation action, and when CTC＞120, the composition performance is synergistic effect.
Actual measurement toxicity index (ATI)=(standard medicament EC
50/ reagent agent EC
50) * 100
The percentage composition of B in the percentage composition of A+B medicament toxicity index * mixture in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/theoretical toxicity index (TTI) of mixture] * 100
Toxicity test the results are shown in Table 1.
Table 1 fluopicolide and the chlorothalonil compound Toxicity Determination result to capsicum epidemic disease
| Process | EC 50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| Fluopicolide | 0.71 | 100.00 | / | / |
| Tpn | 58.2 | 1.22 | / | / |
| Fluopicolide 50: tpn 1 | 0.51 | 139.22 | 98.06 | 141.97 |
| Fluopicolide 20: tpn 1 | 0.43 | 165.12 | 95.30 | 173.27 |
| Fluopicolide 10: tpn 1 | 0.33 | 215.15 | 91.02 | 236.38 |
| Fluopicolide 5: tpn 1 | 0.22 | 322.73 | 83.54 | 386.33 |
| Fluopicolide 1: tpn 1 | 0.39 | 182.05 | 50.61 | 359.71 |
| Fluopicolide 1: tpn 5 | 1.11 | 63.96 | 17.68 | 361.72 |
| Fluopicolide 1: tpn 10 | 2.06 | 34.47 | 10.20 | 337.90 |
| Fluopicolide 1: tpn 20 | 3.78 | 18.78 | 5.92 | 317.08 |
| Fluopicolide 1: tpn 50 | 7.14 | 9.94 | 3.16 | 315.00 |
Biologicall test example 2: fluopicolide and the chlorothalonil compound Toxicity Determination to cucumber downy mildew
Subjects: bacterium of downy mildew of cucumber (Pseudoperonospora cubensis)
Test adopts pot-culture method to measure.Choose two consistent leaf period cucumber seedlings of growth, each processing selects 10 basins for examination melon seedling, numbers standby.Spray under 50PSI pressure with the Potter spray tower, every basin 5mL.Each medicament arranges 6 concentration gradients, to spray the blank that is treated to of equivalent clear water.Get the downy mildew leaf that picks up from the field, the distilled water that dips 10 ℃ of left and right with writing brush washes the sporangium at the back side, and being made into concentration is 3 * 10
5The sporangia suspension of individual/mL.Spray inoculation sporangium liquid after chemicals treatment 24h, after inoculation, cucumber seedling is placed in climatic cabinate (relative moisture 100%, 15～20 ℃ of temperature) cultivate, keep 15～24 ℃ of temperature, relative moisture 90% left and right moisturizing to bring out after 24h, 10d " Invest, Then Investigate " record incidence calculates disease index and control efficiency.Calculate concentration EC in inhibition with method of least squares
50, then calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.
When CTC＜80, the composition performance is for antagonism, and when 80＜CTC＜120, the composition performance is for summation action, and when CTC＞120, the composition performance is synergistic effect.
Actual measurement toxicity index (ATI)=(standard medicament EC50/ reagent agent EC50) * 100
The percentage composition of B in the percentage composition of A+B medicament toxicity index * mixture in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/theoretical toxicity index (TTI) of mixture] * 100
Toxicity test the results are shown in Table 2.
The Toxicity Determination result of table 2 fluopicolide and tpn pairing cucumber downy mildew
| Process | EC 50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| Fluopicolide | 0.77 | 100.00 | / | / |
| Tpn | 60.3 | 1.28 | / | / |
| Fluopicolide 50: tpn 1 | 0.59 | 130.51 | 98.06 | 133.08 |
| Fluopicolide 20: tpn 1 | 0.44 | 175.00 | 95.30 | 183.63 |
| Fluopicolide 10: tpn 1 | 0.38 | 202.63 | 91.03 | 222.61 |
| Fluopicolide 5: tpn 1 | 0.29 | 265.52 | 83.55 | 317.81 |
| Fluopicolide 1: tpn 1 | 0.47 | 163.83 | 50.64 | 323.53 |
| Fluopicolide 1: tpn 5 | 1.27 | 60.63 | 17.73 | 341.95 |
| Fluopicolide 1: tpn 10 | 2.49 | 30.92 | 10.25 | 301.64 |
| Fluopicolide 1: tpn 20 | 4.18 | 18.42 | 5.98 | 308.15 |
| Fluopicolide 1: tpn 50 | 7.85 | 9.81 | 3.21 | 305.32 |
Table 1,2 points out, fluopicolide and tpn have good synergistic effect to epidemic disease, downy mildew, especially have obvious synergistic effect at 10: 1～1: 50, and co-toxicity coefficient is more than 200.
Bactericidal composition of the present invention can be prepared into known method suspending agent, aqueous emulsion, microemulsion, missible oil, wetting powder, the water dispersible granules that is fit to agricultural use.Below describe with specific embodiment, in formula, percentage is mass percent.In present specification, active component refers to fluopicolide and tpn compounded combination in varing proportions, below repeats no more.
Embodiment 1:51% fluopicolide tpn suspending agent
Fluopicolide 50%, tpn 1%, methyl naphthalene sulfonate formaldehyde condensate 8%, sodium lignosulfonate 15%, xanthans 3%, silicone oil 5%, glycerine 8%, all the other water complement to 100%.Active component, dispersant, wetting agent and water etc. are mixed, through wet grinding or high speed shear, namely get 51% fluopicolide tpn suspending agent.
This embodiment is applied to prevent and treat cucumber downy mildew.(effective dose of fluopicolide is about 44 g/has by 45 gram active ingredient/hectares with 51% fluopicolide tpn suspending agent, the effective dose of tpn is about 1 g/ha) the dilution spraying, every dispenser in 7 days once, dispenser is three times continuously, and control efficiency is respectively 91.2%.20% fluopicolide suspending agent is in kind processed by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 80.9%, 76.1%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than the single dose consumption to the preventive effect of cucumber downy mildew significantly better than single dose.
Embodiment 2:42% fluopicolide tpn suspending agent
Fluopicolide 40%, tpn 2%, nonyl phenol PVOH ether 6%, sodium lignosulfonate 10%, Magnesiumaluminumsilicate 1%, bentonite 1%, ethylene glycol 4%, water complements to 100%.Active component, dispersant, wetting agent and water etc. are mixed, through wet grinding or high speed shear, namely get 42% fluopicolide tpn suspending agent.
This embodiment is applied to prevent and treat downy mildew of garpe.(effective dose of fluopicolide is about 52 g/has by 55 gram active ingredient/hectares with 42% fluopicolide tpn suspending agent, the effective dose of tpn is about 3 g/has) the thin up spraying, every dispenser in 7 days once, continuously the control efficiency after dispenser three times is 92.0%.20% fluopicolide suspending agent in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 83.6%, 81.2%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than the single dose consumption to the preventive effect of downy mildew of garpe significantly better than single dose.
Embodiment 3:11% fluopicolide tpn aqueous emulsion
Fluopicolide 10%, tpn 1%, 1-METHYLPYRROLIDONE 10%, calcium dodecyl benzene sulfonate 5%, agriculture breast 600# 5%, water complements to 100%.Former medicine, solvent, emulsifier are added together, make to be dissolved into even oil phase; Water-soluble component and water mixing are made water; Under high-speed stirred, oil phase is mixed with water, make 11% fluopicolide tpn aqueous emulsion.
This embodiment is applied to prevent and treat wild cabbage downy mildew.(effective dose of fluopicolide is about 55 g/has by 60 gram active ingredient/hectares with 11% fluopicolide tpn aqueous emulsion, the effective dose of tpn is about 5 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and the control efficiency after medicine is 91.6%.20% fluopicolide suspending agent in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 78.8%, 70.2%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than the single dose consumption to the preventive effect of wild cabbage downy mildew significantly better than single dose.
Embodiment 4:3% fluopicolide chlorothalonil microemulsion
Fluopicolide 2.5%, tpn 0.5%, 1-METHYLPYRROLIDONE 10%, isopropyl alcohol 10%, agriculture breast 500#5%, agriculture breast 1601#5%, water complements to 100%.Former medicine, solvent, emulsifier are added together, make to be dissolved into even oil phase; Water-soluble component and water mixing are made water; Under high-speed stirred, oil phase is mixed with water, make 3% fluopicolide chlorothalonil microemulsion.
This embodiment is applied to prevent and treat potato late blight.(effective dose of fluopicolide is about 58 g/has by 70 gram active ingredient/hectares with 3% fluopicolide chlorothalonil microemulsion, the effective dose of tpn is about 12 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and the control efficiency after medicine is 98.2%.20% fluopicolide suspending agent in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 71.3%, 70.3%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than the single dose consumption to the preventive effect of potato late blight significantly better than single dose.
Embodiment 5:2% fluopicolide tpn missible oil
Fluopicolide 1%, tpn 1%, Nongru-700 #10%, agriculture breast 2201#5%, methyl alcohol 10%, cyclohexanone 5%, dimethylbenzene complements to 100%.Active component, emulsifier and the auxiliary agent ratio in formula is added in mixing kettle successively, stir, make 2% fluopicolide tpn missible oil.
This embodiment is applied to cucumber blight disease.(effective dose of fluopicolide is 50 g/has by 100 gram active ingredient/hectares with 2% fluopicolide tpn missible oil, the effective dose of tpn is 50 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and the control efficiency after medicine is 97.8%.20% fluopicolide suspending agent in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 85.8%, 80.7%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than the single dose consumption to the preventive effect of Cucumber Blight significantly better than single dose.
Embodiment 6:54% fluopicolide tpn suspending agent
Fluopicolide 9%, tpn 45%, nonyl phenol PVOH ether 6%, sodium lignosulfonate 10%, Magnesiumaluminumsilicate 1%, bentonite 1%, ethylene glycol 4%, water complements to 100%.Active component, dispersant, wetting agent and water etc. are mixed, through wet grinding or high speed shear, namely get 54% fluopicolide tpn suspending agent.
This embodiment is applied to peronophythora litchi.(effective dose of fluopicolide is 50 g/has by 300 gram active ingredient/hectares with 54% fluopicolide tpn aqueous emulsion, the effective dose of tpn is 250 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and the control efficiency after medicine is 98.1%.20% fluopicolide suspending agent in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 83.1%, 80.0%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, and each active ingredient is in the situation that be better than single dose lower than the single dose consumption to the preventive effect of peronophythora litchi.
Embodiment 7:1.1% fluopicolide tpn missible oil
Fluopicolide 0.1%, tpn 1%, 1-METHYLPYRROLIDONE 10%, agriculture breast 500#5%, soybean oil complements to 100%.Active component, emulsifier and the auxiliary agent ratio in formula is added in mixing kettle successively, stir, make 1.1% fluopicolide tpn missible oil.
This embodiment is applied to prevent and treat the capsicum damping off.(effective dose of fluopicolide is about 45 g/has by 500 gram active ingredient/hectares with 1.1% fluopicolide tpn missible oil, the effective dose of tpn is about 455 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and control efficiency is respectively 98.9%.20% fluopicolide suspending agent is in kind processed by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 40% tpn suspending agent, and the preventive effect after medicine is respectively 84.5%, 80.1%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than single dose to the preventive effect of capsicum damping off significantly better than single dose.
Embodiment 8:84% fluopicolide tpn wetting powder
Fluopicolide 4%, tpn 80% pulls open powder 0.5%, lauryl sodium sulfate 2%, white carbon 5%, attapulgite complements to 100%.The ratio of each components such as active component, dispersant, wetting agent in formula mixed, namely get 84% fluopicolide tpn wetting powder after air-flow shatters.
This embodiment is applied to prevent and treat the three-coloured amaranth white blister.(effective dose of fluopicolide is about 43 g/has by 900 gram active ingredient/hectares with 84% fluopicolide tpn wetting powder, the effective dose of tpn is about 857 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and the control efficiency after medicine is 97.5%.80% fluopicolide wetting powder in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 75% tpn wetting powder, and the preventive effect after medicine is respectively 85.6%, 80.5%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, each active ingredient in the situation that lower than single dose to the preventive effect of three-coloured amaranth white blister significantly better than single dose.
Embodiment 9:90% fluopicolide chlorothalonil water dispersible granule
Fluopicolide 1.76%, tpn 88.23%, lauryl sodium sulfate 1.5%, sodium lignin sulfonate 1.5%, ammonium alginate 0.5%, starch 1.5%, bentonite complements to 100%.Active component, auxiliary agent and filler are mixed with ratio, through air-flow crushing, by kneading, granulation, drying, sieving namely gets 90% fluopicolide chlorothalonil water dispersible granule.
This embodiment is applied to tomato late blight.(effective dose of fluopicolide is about 20 g/has to 90% fluopicolide chlorothalonil water dispersible granule by 1000 gram active ingredient/hectares, the effective dose of tpn is about 980 g/has) the thin up spraying, every dispenser in 7 days once, dispenser is three times continuously, and the control efficiency after medicine is 97.4%.80% fluopicolide wetting powder in kind uses by 1000 gram active ingredient/hectares by 65 gram active ingredient/hectares, 70% tpn wetting powder, and the preventive effect after medicine is respectively 82.1%, 79.7%.After fluopicolide and chlorothalonil compound synergistic effect is obvious, and each active ingredient is in the situation that be better than single dose lower than single dose to the preventive effect of tomato late blight.
Claims (5)
1. control of plant disease composition, active ingredient is comprised of fluopicolide and chlorothalonil compound, and the percentage by weight of fluopicolide and tpn is 50: 1～1: 50.
2. composition according to claim 1 is characterized in that in composition, the percentage by weight of active ingredient fluopicolide and tpn is 10: 1～1: 50.
3. composition according to claim 2 is characterized in that in composition, the percentage by weight of active ingredient fluopicolide and tpn is 5: 1～1: 50.
4. the described composition of according to claim 1 to 3 any one, is characterized in that active ingredient accounts for 1%～90% of composition total weight.
5. composition according to claim 4, its feature is made suspending agent, aqueous emulsion, microemulsion, missible oil, wetting powder or water dispersible granules in said composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104376138A CN103155921A (en) | 2011-12-18 | 2011-12-18 | Plant disease control composition containing fluopicolide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104376138A CN103155921A (en) | 2011-12-18 | 2011-12-18 | Plant disease control composition containing fluopicolide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103155921A true CN103155921A (en) | 2013-06-19 |
Family
ID=48579850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104376138A Pending CN103155921A (en) | 2011-12-18 | 2011-12-18 | Plant disease control composition containing fluopicolide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103155921A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107125246A (en) * | 2017-07-07 | 2017-09-05 | 广西南宁乐蕊生物科技有限责任公司 | A kind of bactericidal composition containing Inokopolyose and fluopicolide |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1311742C (en) * | 2003-04-15 | 2007-04-25 | 拜尔农科股份有限公司 | Flexible radiation curable compositions. |
| EP2245934A2 (en) * | 2007-09-12 | 2010-11-03 | Bayer CropScience AG | Post-harvest treatment |
-
2011
- 2011-12-18 CN CN2011104376138A patent/CN103155921A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1311742C (en) * | 2003-04-15 | 2007-04-25 | 拜尔农科股份有限公司 | Flexible radiation curable compositions. |
| EP2245934A2 (en) * | 2007-09-12 | 2010-11-03 | Bayer CropScience AG | Post-harvest treatment |
Non-Patent Citations (3)
| Title |
|---|
| WILLIAM V.SIGLER 等: "The impact of chlorothalonil application on soil bacterial and fungal populations as assessed by denaturing gradient gel electrophoresis", 《APPLIED SOIL ECOLOGY》, 31 December 2002 (2002-12-31), pages 107 * |
| 吉训聪 等: "海南省甜瓜霜霉病药剂防治试验", 《长江蔬菜》, no. 18, 28 September 2009 (2009-09-28), pages 79 - 80 * |
| 王丽 等: "几种新杀菌剂对马铃薯晚疫病的控制作用", 《农药》, vol. 49, no. 04, 10 April 2010 (2010-04-10) * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107125246A (en) * | 2017-07-07 | 2017-09-05 | 广西南宁乐蕊生物科技有限责任公司 | A kind of bactericidal composition containing Inokopolyose and fluopicolide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103155936B (en) | Plant disease control composition containing phenazino-1-carboxylic acid | |
| CN101595882B (en) | Pesticide composition containing methoxyl acrylic ester bactericide | |
| CN101653118A (en) | Compound synergistic bactericidal composition | |
| CN105211075B (en) | Bactericidal composition and its application | |
| CN103120171B (en) | Composition for preventing and controlling plant diseases | |
| CN101647451A (en) | Sterilization combination containing cyazofamid | |
| CN101642118A (en) | Composition for plant protection | |
| CN103918658B (en) | A kind of combination sterilization composition containing cyazofamid | |
| CN101697725A (en) | Pesticide composition containing protective bactericide | |
| CN101700027B (en) | Synergistic bactericidal composition and application | |
| CN103120169A (en) | Sterilizing composition containing fluopicolide | |
| CN105532675A (en) | Prothioconazole and tebuconazole compound suspending agent and preparing method thereof | |
| CN103329905B (en) | Sterilization composition containing penflufen and validamycin | |
| CN101669512A (en) | Pyrimorph-containing bactericide composition | |
| CN103190420B (en) | Propiconazole-containing bactericidal composition | |
| CN102349524A (en) | Sterilizing composition containing Cyflufenamid | |
| CN102308804A (en) | Sterilization composition | |
| CN101642130B (en) | Bactericidal composition containing iprovalicarb | |
| CN103155921A (en) | Plant disease control composition containing fluopicolide | |
| CN104542611A (en) | Bactericidal composition containing mandipropamid | |
| CN103081925A (en) | Fenamidone-containing bactericidal composition | |
| CN103355309A (en) | Sterilization composition and preparation thereof | |
| CN101647447B (en) | Sterilizing composition | |
| CN101700015A (en) | Bactericidal composition containing cyazofamid and kasugamycin and application thereof | |
| CN101647466B (en) | Sterilization combination |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130619 |