CN1031511C - Non-polar adhesive - Google Patents
Non-polar adhesive Download PDFInfo
- Publication number
- CN1031511C CN1031511C CN 91107255 CN91107255A CN1031511C CN 1031511 C CN1031511 C CN 1031511C CN 91107255 CN91107255 CN 91107255 CN 91107255 A CN91107255 A CN 91107255A CN 1031511 C CN1031511 C CN 1031511C
- Authority
- CN
- China
- Prior art keywords
- weight
- polar
- oxide
- rubber
- aging agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 14
- 239000000853 adhesive Substances 0.000 title claims abstract description 11
- 229920002681 hypalon Polymers 0.000 claims abstract description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 7
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 5
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- 239000003960 organic solvent Substances 0.000 claims abstract description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 7
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 14
- 239000003292 glue Substances 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 4
- 229920001971 elastomer Polymers 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 239000005997 Calcium carbide Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical group C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides an electrodeless glue, which comprises 12-45 wt% of chlorosulfonated polyethylene, 19-50 wt% of chloroprene rubber, 22-27 wt% of p-tert-butylphenol resin, 3-5.5 wt% of metal oxide, 1.0-1.5 wt% of anti-aging agent, 0.5-1.1 wt% of accelerator, 0.2-3.0 wt% of sulfur and 0.5-2.5 wt% of 210 modified rosin ester, and is prepared by matching with organic solvent. The adhesive is solidified at normal temperature, has good bonding effect on non-polar, weak and strong-polar materials, and is particularly used for bonding leather-rubber, leather-SBS materials and the like in the shoe industry.
Description
The present invention relates to a kind of binding agent, particularly relate to a kind of non-polar adhesive.
At present to low-pole and non-polar material, be difficult to bonding as materials such as polyvinyl chloride, polystyrene, ABS, SBS, only can adopt thermosol or be with self material that the solution glue of matrix comes bonding, and need carry out the complex surfaces processing bonding before.Japanese Patent 78108132 has been reported a kind of tackiness agent, comprises chlorosulfonated polyethylene, chloroprene rubber, right-dinitrosobenzene, phthalic acid lead salt, N, N-1,3-penylene, two maleinamides, carbon black, silicon-dioxide.This glue is used for bonding steel plate and sulfurized natural rubber, but will be heating and curing more than 100 ℃, is a kind of hot melt adhesive.
The object of the present invention is to provide a kind of initial bonding strength strong, but cold bonding, and chlorosulfonated polyethylene-chloroprene rubber that polarity and non-polar material are all had a bonds well effect is the compound non-polar adhesive of tertiary butyl phenol urea formaldehyde one to one.
Non-polar adhesive component of the present invention comprises, chlorosulfonated polyethylene 12-45% (weight), chloroprene rubber 19-50% (weight), to a tertiary butyl phenol urea formaldehyde 22-27% (weight), metal oxide 3-5.5% (weight) anti-aging agent 1.0-1.5% (weight), promotor 0.5-1.1% (weight), Sulfur 0.2-3.0% (weight), 210 modified rosin fat 0.5-2.5% (weight), and cooperate and make with organic solvent.Wherein metal oxide is in magnesium oxide, zinc oxide, the plumbous oxide any two kinds, and anti-aging agent is N-phenyl-β-naphthylamines, N-cyclohexyl-N '-diphenyl-para-phenylene diamine etc., and promotor is α-benzothiazolyl mercaptan, dibenzothiazyl disulfide etc.
The organic solvent that non-polar adhesive of the present invention uses is generally benzene and homologue thereof, as in toluene, the dimethylbenzene etc. one or more.The solid content of glue is 20-27%.
Non-polar adhesive of the present invention has increased the initial stage cohesive strength of this glue owing to added a tertiary butyl phenol urea formaldehyde, has also increased the elasticity of glue simultaneously, and it is crosslinked also to be beneficial to chlorosulfonated polyethylene, the crosslinked of chlorosulfonated polyethylene is carried out reposefully after adding 210 modified rosin fat.
Non-polar adhesive of the present invention has cohesive force widely, to low-pole and non-polar material, as materials such as polyethylene, polyvinyl chloride, polystyrene, synthetic glass, ABS, SBS, SBS-the leather that particularly is used to bond in shoe industry has good effect, bond after 30 minutes, the initial stage stripping strength reaches 16.4N/cm, can enter down the road production process.Adjust chloroprene rubber in this glue and,, good bond effect is all arranged as metal, glass, pottery, cement products, building stones, timber, leather and the vulcanized rubber except that silicon rubber to strong polar material to the content of a tertiary butyl phenol urea formaldehyde.Non-polar adhesive of the present invention belongs to the cold bonding type, and normal temperature solidifies down, uses very convenient.
Describe the embodiment of the invention below in detail.
Embodiment 1:
Prescription: chlorosulfonated polyethylene (chlorosulfonated polyethylene 40, Jilin 3g
Calcium carbide factory produces)
Chloroprene rubber (chloroprene rubber 2442, long-lived chemical industry 12g
Factory produces)
Right-tertiary butyl phenol urea formaldehyde 6.3g
Zinc oxide, magnesium oxide 2.04g
Anti-aging agent (N-phenyl β-naphthylamines) 0.3g
Promotor (α-benzothiazolyl mercaptan) 0.18g
Sulfur 0.07g
210 modified rosin fat (210 phenol-modified rosin 0.15g
Fat, Chengdu are made the lacquer head factory
Produce)
Will be to a tertiary butyl phenol urea formaldehyde and small amounts reactive magnesium, generate and give reacting resin, all the other each material on rubber mixing machine mixing evenly, stripping and slicing, adding 88ml toluene, and stir with giving reacting resin, be mixed with the glue of solid content 24%.This glue strong polar material that can bond, as leather-rubber, its adhesive property is as shown in table 1.
Embodiment 2:
Prescription: chlorosulfonated polyethylene (chlorosulfonated polyethylene 40, lucky 11g
Woods calcium carbide factory produces)
Chloroprene rubber (chloroprene rubber 2442, long-lived chemical industry 4g
Factory produces)
Right-power fourth resol 5.2g
Magnesium oxide, plumbous oxide 2.1g
Anti-aging agent (N-phenyl β-naphthylamines amine) 0.3g
Promotor (α-benzothiazolyl mercaptan) 0.18g
Sulfur 0.09g
2 10 modified rosin fat (210 phenol-modified loose 0.15g
Face cream, lacquer is made in Chengdu
Head factory is produced)
Compound method is with embodiment 1, its solid content 24%.This glue is used for the bonding of strong polar material and low-pole storeroom, and as scytoblastema-SBS, its adhesive property is as shown in table 1.
Table 1: material adhesive property
Matrix material time stripping strength
Leather-rubber bound is 25.4N/cm after 30 minutes
60.0N/cm after 48 hours bonds
Rubber is destroyed, not
Peel off from the abutting edge.
Leather-SBS bonding 16.4N/cm after 30 minutes
40.0N/cm after 48 hours bonds
The SBS material is destroyed,
Do not peel off from the abutting edge.
Annotate: according to QB/JZ001-90 standard test.
Claims (1)
1, a kind of non-polar adhesive, its component comprises chlorosulfonated polyethylene 12-45% (weight), chloroprene rubber 19-50% (weight), to a tertiary butyl phenol urea formaldehyde 22-27% (weight), metal oxide 3-5.5% (weight), anti-aging agent 1.0-1.5% (weight), promotor 0.5-1.1% (weight), Sulfur 0.2-3.0% (weight), 210 modified rosin fat 0.5-2.5% (weight), wherein metal oxide is a magnesium oxide, zinc oxide, in the plumbous oxide any two kinds, anti-aging agent is N-phenyl β-naphthylamines and N-cyclohexyl-N '-diphenyl-para-phenylene diamine, promotor is α-benzothiazolyl mercaptan and dibenzothiazyl disulfide, cooperate with organic solvent, making its solid content is 20-27% again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107255 CN1031511C (en) | 1991-07-26 | 1991-07-26 | Non-polar adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107255 CN1031511C (en) | 1991-07-26 | 1991-07-26 | Non-polar adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1059354A CN1059354A (en) | 1992-03-11 |
| CN1031511C true CN1031511C (en) | 1996-04-10 |
Family
ID=4908610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91107255 Expired - Fee Related CN1031511C (en) | 1991-07-26 | 1991-07-26 | Non-polar adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1031511C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816543B (en) * | 2012-09-12 | 2014-06-11 | 广东金万得胶粘剂有限公司 | Plastic-rubber high molecular composite synthetic resin adhesive |
| CN103254852A (en) * | 2013-05-08 | 2013-08-21 | 安徽艳阳电气集团有限公司 | Chlorosulfonated polyethylene rubber waterproof daub for underwater fluorescent lamp and preparation method of chlorosulfonated polyethylene rubber waterproof daub |
| CN103254850A (en) * | 2013-05-08 | 2013-08-21 | 安徽艳阳电气集团有限公司 | High-strength outdoor sealant and preparation method thereof |
| CN103450826B (en) * | 2013-08-23 | 2015-09-30 | 吴江骏达电梯部件有限公司 | A kind of metal pressure sensitive sizing agent and preparation method thereof |
| CN104109497B (en) * | 2014-07-08 | 2017-03-22 | 湖北三江航天江河化工科技有限公司 | Single-component rubber adhesive and preparation method thereof |
-
1991
- 1991-07-26 CN CN 91107255 patent/CN1031511C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1059354A (en) | 1992-03-11 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |