CN103145451A - Zirconium silicate coated cadmium yellow ceramic pigment and preparation method thereof - Google Patents
Zirconium silicate coated cadmium yellow ceramic pigment and preparation method thereof Download PDFInfo
- Publication number
- CN103145451A CN103145451A CN201310108577XA CN201310108577A CN103145451A CN 103145451 A CN103145451 A CN 103145451A CN 201310108577X A CN201310108577X A CN 201310108577XA CN 201310108577 A CN201310108577 A CN 201310108577A CN 103145451 A CN103145451 A CN 103145451A
- Authority
- CN
- China
- Prior art keywords
- zirconium silicate
- ceramic pigment
- cadmium yellow
- preparation
- yellow ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a method for preparing a zirconium silicate coated cadmium yellow ceramic pigment. The method comprises the following steps of: (1) dissolving zirconium oxychloride and cadmium sulfate into water in the molar ratio of (1.3-1.5):(0.13-0.15) to prepare a 27-45% solution A; (2) dissolving sodium sulfide, sodium metasilicate pentahydrate and sodium hydroxide in the molar ratio of (0.25-0.35 ):(1.13-1.23):(0.31-0.35) into water to prepare a 7-15% solution B; (3) stirring the solution B, titrating by using the solution A, and carrying out neutralization reaction until the pH value reaches 8.0-8.5; (4) filtering by pressing after the reaction finishes, and drying until the content of water is less than 4%; (5) grinding the dried substance until the finesses reaches 400-500 meshes; (6) mixing 100 parts by weight of ground dried substance with 3-5 parts by weight of a mineralizing agent uniformly, calcining at the temperature of 1,000-1,050 DEG C, mixing 45-55 parts by weight of a calcination product with 25-35 parts by weight of 45-55% sulfuric acid, soaking the mixture for 20-48 hours, washing with water until the mixture is neutral, grinding until the finesses D90 reaches 22-28mum, and drying to obtain the zirconium silicate coated cadmium yellow ceramic pigment.
Description
Technical field
The present invention relates to the preparation method of ceramic pigment, relate in particular to a kind of zirconium silicate parcel cadmium yellow ceramic pigment and preparation method thereof.
Background technology
Along with socioeconomic development, decoration market needs a large amount of ceramic products and people to require also more and more higher to decorative effect.Cadmium yellow has color development below 800 ℃ in ceramic glaze in the market, but the problem of the poor easy oxidation blackout of existence and stability, when also existing simultaneously working conditions to surpass 800 ℃, and complete oxidation in ceramic and the problem of color development not.
This shows, how to carry out technological improvement, a kind of zirconium silicate parcel cadmium yellow ceramic pigment and preparation method thereof is provided, the zirconium silicate parcel cadmium yellow ceramic pigment color development power that obtains is strong, high temperature resistant, good stability, can be widely used on market, this is the present technical issues that need to address in this area.
Summary of the invention
The object of the invention is to, a kind of preparation method of zirconium silicate parcel cadmium yellow ceramic pigment is provided, the zirconium silicate that makes parcel cadmium yellow ceramic pigment color development ability is strong, high temperature resistant.Based on this, the present invention also provides a kind of zirconium silicate parcel cadmium yellow ceramic pigment.
For solving above technical problem, technical scheme of the present invention is:
A kind of preparation method of zirconium silicate parcel cadmium yellow ceramic pigment comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate (1.3-1.5) in molar ratio: (0.13-0.15) water-solublely be mixed with the molten night of A that mass concentration is 27%-45%;
2) again with sodium sulphite and metasilicate pentahydrate sodium and sodium hydroxide (0.25-0.35) in molar ratio: (1.13-1.23): (0.31-0.35) the water-soluble B solution that is mixed with mass concentration 7%-15%;
3) stir B solution, carry out neutralization reaction with the titration of A solution simultaneously, until pH value is 8.0～8.5 namely to complete reaction;
4) carry out press filtration after reaction is completed, then be dried to water ratio less than 4%;
5) dry thing is pulverized, making fineness is 400～500 orders, obtains dry thing;
6) mineralizer with the dry thing after the pulverizing of 100 weight parts and 3～5 weight parts mixes, temperature lower calcination at 1000 ℃-1050 ℃, obtain calcined material, be that 45%～55% sulfuric acid mixes with the calcined material of 45～55 weight parts and the concentration of 25～35 weight parts, soaked 20-48 hour, and be washed to neutrality, then being ground to fineness D90 is 22～28 μ m, dry again, obtain zirconium silicate parcel cadmium yellow ceramic pigment.
Preferably, the reaction times of the neutralization reaction of step 3) is 4～6 hours.
Preferably, the drying in step 4) is carried out in the temperature environment below 250 ℃.
Preferably, described mineralizer is halogenide.
Preferably, described mineralizer is any one or the two or more mixture in lithium fluoride, sodium-chlor, Repone K, Sodium Fluoride.
Preferably, being ground in step 6) adopts ball mill to carry out ball milling.
Preferably, the zirconium silicate parcel cadmium yellow ceramic pigment that obtains is crossed 325 orders.
A kind of zirconium silicate parcel cadmium yellow ceramic pigment of the present invention is made by aforesaid preparation method.
Preferably, zirconium silicate parcel cadmium yellow ceramic pigment of the present invention has following proterties:
Outward appearance: yellow powder; Lightness: 70≤L≤80; Form and aspect: 2≤a≤12; Form and aspect: 60≤b≤85; Granularity: D90 is 22 μ m～28 μ m.
With utilize single solid phase method that various raw materials are directly mixed the traditional method that is prepared in prior art to compare, the preparation method of zirconium silicate parcel cadmium yellow ceramic pigment of the present invention utilizes soluble compound to pass through liquid-phase chemical reaction, fineness and the activity of reactant have greatly been improved, after passing through again the solid state reaction of high-temperature calcination, obtain resistance to elevated temperatures good, the zirconium silicate parcel cadmium yellow ceramic pigment that the color development ability is strong can adapt to the firing temperature up to 1300 ℃, can be widely used on market.
Embodiment
Of the present invention being contemplated that: in preparation process, first raw material is carried out liquid phase reaction, again at high temperature carry out solid state reaction thereafter, so just make the zirconium silicate parcel cadmium yellow ceramic pigment that obtains in the application in later stage, the color development ability is strong, the product color that obtains is bright, high thermal resistance is good, and glaze is smooth.
Resistance to elevated temperatures and the color development ability of zirconium silicate parcel cadmium yellow ceramic pigment are by force to detect ZrSiO
4An important symbol of crystal parcel CdS particle encapsulation ratio.In prior art, traditional method utilizes single solid phase method that direct mixing of various raw materials is prepared relatively, the present invention utilizes soluble compound to pass through liquid-phase chemical reaction, fineness and the activity of reactant have greatly been improved, after passing through high-temperature calcination simultaneously, can obtain resistance to elevated temperatures good, the bright red ceramic pigment of the strong parcel of color development ability.The zirconium silicate parcel cadmium yellow ceramic pigment of the present invention's preparation, the color development ability is strong in ceramic colour glaze, color and luster bright, resistance to elevated temperatures is good, and single solid phase method more in the market synthesizes Red pigment, can more be widely used.
In order to make those skilled in the art understand better technical scheme of the present invention, below in conjunction with the present invention is described in further detail by specific embodiment.
The preparation method of zirconium silicate parcel cadmium yellow ceramic pigment of the present invention comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate (1.3-1.5) in molar ratio: (0.13-0.15) water-solublely be mixed with the molten night of A that mass concentration is 27%-45%;
2) again with sodium sulphite and metasilicate pentahydrate sodium and sodium hydroxide (0.25-0.35) in molar ratio: (1.13-1.23): (0.31-0.35) water-solublely be mixed with the B solution that mass concentration is 7%-15%;
3) stir B solution, carry out neutralization reaction with the titration of A solution simultaneously, until pH value is 8.0～8.5 namely to complete reaction;
4) carry out press filtration after reaction is completed, then be dried to water ratio less than 4%, obtain dry thing;
5) dry thing is pulverized, making fineness is 400～500 orders;
6) mineralizer with the dry thing after the pulverizing of 100 weight parts and 3～5 weight parts mixes, temperature lower calcination at 1000 ℃-1050 ℃, obtain calcined material, be that 45%～55% sulfuric acid mixes with the calcined material of 45～55 weight parts and the concentration of 25～35 weight parts, soaked 20-48 hour, and be washed to neutrality, then being ground to fineness D90 is 22～28 μ m, dry again, obtain zirconium silicate parcel cadmium yellow ceramic pigment.
Zirconium silicate parcel cadmium yellow ceramic pigment by above preparation method makes has following characteristic:
Outward appearance: yellow powder;
Chemical formula: ZrO
2.SiO
2.CdS
Lightness L satisfies 70≤L≤80;
Form and aspect a satisfies 2≤a≤12;
Form and aspect b satisfies 60≤b≤75
D90:22-28μm。
Below be elaborated by specific embodiment:
Embodiment one
The preparation method of the zirconium silicate parcel cadmium yellow ceramic pigment in the present embodiment comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate in molar ratio the water-soluble mass concentration that is mixed with of the ratio of 1.3:0.15 be molten night of A of 27%, mix;
2) again with sodium sulphite, metasilicate pentahydrate sodium and sodium hydroxide in molar ratio the water-soluble mass concentration that is mixed with of 0.25:1.13:0.31 be 15% B solution, mix;
3) B solution is placed in the stirring reaction bucket, with the titration of A solution, carries out neutralization reaction when stirring, the reaction times is 4 hours, and after reaction is completed, the detection pH value is 8.0;
4) after reaction is completed, the work in-process that obtain are carried out press filtration, be dried to water ratio less than 4% under the temperature environment of 250 ℃;
5) dried work in-process are pulverized, fineness is controlled between the 400-500 order;
6) work in-process after pulverizing and mineralizer mix by the weight ratio of 100:5;
7) with the material that the mixes temperature lower calcination at 1000 ℃, be that 50% sulfuric acid mixes by weight 55:35 with the calcined material that obtains and concentration, soaked 20 hours, then be washed to neutrality, add again the ball mill ball milling, be 22 μ m-28 μ m until fineness reaches D90, dry rear 325 mesh sieves of crossing are made finished product.
The colorant that the present embodiment is made carries out following detection contrast simultaneously with the simple colorant that adopts solid phase method to make of tradition:
1, fineness test
Prior art (adopting merely solid phase method) D90:25.5
The present embodiment: D90:22.5
2, the color development ability detects
The basic glaze formula of the glaze colours that uses:
0.248K
2O 0.003Fe
2O
3 3.56Si
2O 0.021BaO
0.073Na
2O 0.504Al
2O
3 0.003ZnO 0.12CaO
Add massfraction in the parent glaze and be 3% synthetic colorant, temperature of glaze firing is 1300 ℃, and firing time is 70 minutes, soaking time 15-30 minute.
The data that record:
Prior art (adopting merely solid phase method): L:86.25 a:2.5 b:56.45;
The present embodiment: L:75.19 a:6.46 b:70.20;
By above-mentioned detected result contrast, two kinds of colorants can be found out at Ceramic glaze, colorant glaze foaming when using that the available technology adopting conventional solid-state method is synthetic, and color development is partially dark, and color development is very shallow and unstable; And the colorant of the present embodiment glaze when using is smooth, can find out that from value of chromatism the colorant color development of the present embodiment is strong and highly stable.
In the present embodiment, the mass percent concentration of the A solution of making is 27%, in other embodiments, can be any value of 27%～45%, as 28%, 33%, 38%, 41%, 44%, 45% etc.; In the present embodiment, the mass percent concentration of B solution is 15%, in other embodiments, also can be any value in 7%～15%, as 8%, 10%, 12%, 14%, 15% etc.
Embodiment two
The preparation method of the zirconium silicate parcel cadmium yellow ceramic pigment in the present embodiment comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate in molar ratio the water-soluble mass concentration that is mixed with of 1.5:0.15 ratio be molten night of A of 27%, mix;
2) again with sodium sulphite and metasilicate pentahydrate sodium and sodium hydroxide in molar ratio the ratio of 0.25:1.13:0.31 be dissolved in water to be mixed with mass concentration be 15% B solution, mix;
3) B solution is placed in the stirring reaction bucket, with the titration of A solution, carries out neutralization reaction when stirring, the reaction times is 5 hours, and after reaction is completed, the detection pH value is 9;
4) after reaction is completed, the work in-process that obtain are carried out press filtration, be dried to water ratio less than 4% under the temperature environment of 250 ℃;
5) dried work in-process are pulverized, fineness is controlled between the 400-500 order;
6) work in-process after pulverizing and mineralizer mix by the weight ratio of 100:5;
7) with the material that the mixes temperature lower calcination at 1050 ℃, with calcined material and 50% sulfuric acid by mass percentage 55:35 mix, soaked 20 hours, then be washed to neutrality, adding the ball mill ball milling, is 22 μ m-28 μ m until fineness reaches D90 again, and dry rear 325 mesh sieves of crossing are made finished product.
The colorant that the colorant that the present embodiment is made and embodiment one make carries out following detection contrast simultaneously:
1, fineness test
The colorant that embodiment one makes: D90:22.5um
The present embodiment: D90:21.8um
2, the color development ability detects
The basic glaze formula of the glaze colours that uses:
0.248K
2O 0.003Fe
2O
3 3.56Si
2O 0.021BaO
0.073Na
2O 0.504Al
2O
3 0.003ZnO 0.12CaO
Add massfraction in the parent glaze and be 3% synthetic colorant, temperature of glaze firing is 1300 ℃, and firing time is 70 minutes, soaking time 15-30 minute.
The data that record:
Embodiment one: L:75.19 a:6.46 b:70.20;
The present embodiment: L:80.19 a:5.12 b:60.20;
by above-mentioned detected result contrast, two kinds of colorants can be found out at Ceramic glaze, the colorant color development of embodiment one preparation is partially deeply partially yellow, and embodiment two color developments are very shallow and unstable, hence one can see that, the solution hybrid reaction is regulated the too high meeting of pH value and is caused the scarce Huang of final colorant color development partially shallow, because the PH height can cause the silicic acid precipitation that the Starso reaction gets again to be dissolved, make that the required zr element of zirconium silicate carrier is many and the few ratio of element silicon is inconsistent, thereby the colorant that causes forming is watered down color development by unnecessary zirconium white (colour glaze opacifying agent: the effect that colorant is shoaled is arranged).
Embodiment three
The preparation method of the zirconium silicate parcel cadmium yellow ceramic pigment in the present embodiment comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate in molar ratio the water-soluble mass concentration that is mixed with of 1.4:0.15 ratio be molten night of 50%A, mix;
2) the 0.25:1.13:0.31 ratio dissolving in molar ratio of sodium sulphite, metasilicate pentahydrate sodium, sodium hydroxide being mixed with mass concentration is 15% B solution again, mixes;
3) B solution is placed in the stirring reaction bucket, with the titration of A solution, carries out neutralization reaction when stirring, the reaction times is 6 hours, and after reaction is completed, the detection pH value is 8.0;
4) after reaction is completed, the work in-process that obtain are carried out press filtration, be dried to water ratio less than 4% under the temperature environment of 250 ℃;
5) dried work in-process are pulverized, fineness is controlled between the 400-500 order;
6) work in-process after pulverizing and mineralizer mix by the weight ratio of 100:5;
7) with the material that the mixes temperature lower calcination at 1020 ℃, with calcined material and 50% sulfuric acid by mass percentage 50:30 mix, quiet bubble 20 hours, then be washed to neutrality, adding the ball mill ball milling, is 22-28 μ m until fineness reaches D90 again, and dry rear 325 mesh sieves of crossing are made finished product.
The colorant that the colorant that the present embodiment is made and embodiment one make carries out following detection contrast simultaneously:
1, fineness test
The colorant that embodiment one makes: D90:22.5
The present embodiment: D90:23.1
2, the color development ability detects
The basic glaze formula of the glaze colours that uses:
0.248K
2O 0.003Fe
2O
3 3.56Si
2O 0.021BaO
0.073Na
2O 0.504Al
2O
3 0.003ZnO 0.12CaO
Add massfraction in the parent glaze and be 3% synthetic colorant, temperature of glaze firing is 1300 ℃, and firing time is 70 minutes, soaking time 15-30 minute.
The data that record:
Embodiment one: L:75.19 a:6.46 b:70.20;
The present embodiment: L:79.21 a:5.36 b:67.39;
By the contrast of above-mentioned detected result, two kinds of colorants can find out at Ceramic glaze, and the colorant color development that embodiment one makes is partially dark, and is partially yellow, and the present embodiment color development is very shallow and unstable; Hence one can see that, when Cadmium Sulphate and zirconyl chloride solution mass concentration surpass 45%, and the partially shallow and scarce Huang of the occlusion pigment color development that makes.Can cause solution acidity large when the A concentration of polymer solution is bigger than normal, when can causing side reaction, titration B solution reaction accelerates, in acid and the hydroxide radical of B solution or acid and sodium sulphite reaction, reaction causes the Cadmium Sulfide that generates and zirconium hydroxide to precipitate tailing off, finally cause product color development weak effect.
Embodiment four
The preparation method of the bright red ceramic pigment of parcel in the present embodiment comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate in molar ratio the water-soluble mass concentration that is mixed with of 1.4:0.15 ratio be molten night of A of 27%, mix;
2) again with sodium sulphite, metasilicate pentahydrate sodium, sodium hydroxide in molar ratio the 0.25:1.13:0.31 ratio be dissolved in water to be mixed with mass concentration be molten night of B of 15%, mix;
3) B solution is placed in the stirring reaction bucket, with the titration of A solution, carries out neutralization reaction when stirring, the reaction times is 5 hours, and after reaction is completed, the detection pH value is 8.4;
4) after reaction is completed, the work in-process that obtain are carried out press filtration, be dried to water ratio less than 4% under the temperature environment of 250 ℃;
5) dried work in-process are pulverized, fineness is controlled between the 400-500 order;
6) work in-process after pulverizing and mineralizer mix by the weight ratio of 100:5;
7) with the material that the mixes temperature lower calcination at 1030 ℃, with calcined material and 50% sulfuric acid by mass percentage 50:35 mix, soaked 30 hours, then be washed to neutrality, adding the ball mill ball milling, is 22 μ m-28 μ m until fineness reaches D90 again, and dry rear 325 mesh sieves of crossing are made finished product.
The colorant that the colorant that the present embodiment is made and embodiment one make carries out following detection contrast simultaneously:
1, fineness test
The colorant that embodiment one makes: D90:22.5
The present embodiment: D90:22.3
2, the color development ability detects
The basic glaze formula of the glaze colours that uses:
0.248K
2O 0.003Fe
2O
3 3.56Si
2O 0.021BaO
0.073Na
2O 0.504Al
2O
3 0.003ZnO 0.12CaO
Add massfraction in the parent glaze and be 3% synthetic colorant, temperature of glaze firing is 1300 ℃, and firing time is 70 minutes, soaking time 15-30 minute.
The data that record:
Embodiment one: L:75.19 a:6.46 b:70.20;
The present embodiment: L:73.06 a:7.58 b:73.89
By above-mentioned detected result contrast, the product color development that the present embodiment makes is partially deeply partially red partially more yellow than embodiment one, and the more smooth free of pinholes of glaze.when being high temperature due to product, Cadmium Sulfide forms through the zirconium silicate crystal parcel that generates, Cadmium Sulfide will decompose in the temperature that does not reach generation zirconium silicate crystal, cause zirconium silicate parcel Cadmium Sulfide can have defective, be difficult to wrap fully the color base Cadmium Sulfide, not wrapped Cadmium Sulfide color base can be attached to plane of crystal, can cause unstable or glaze used time of product color development that glaze is bubbled, can address this problem through the peracid bubble, by step 7) as can be known, the time of the present embodiment acid bubble is compared embodiment one lengthening, this more is conducive to acid and unnecessary not being wrapped the color base reaction that is attached to plane of crystal and being removed, solved the bubble problem of glaze used time, color development is purer.
Be below only the preferred embodiment of the present invention, should be pointed out that above-mentioned preferred implementation should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with the claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (9)
1. the preparation method of a zirconium silicate parcel cadmium yellow ceramic pigment, is characterized in that, comprises the steps:
1) with zirconium oxychloride and Cadmium Sulphate (1.3-1.5) in molar ratio: (0.13-0.15) water-solublely be mixed with the molten night of A that mass concentration is 27%-45%;
2) again with sodium sulphite and metasilicate pentahydrate sodium and sodium hydroxide (0.25-0.35) in molar ratio: (1.13-1.23): (0.31-0.35) water-solublely be mixed with the B solution that mass concentration is 7%-15%;
3) stir B solution, carry out neutralization reaction with the titration of A solution simultaneously, until pH value is 8.0～8.5 namely to complete reaction;
4) carry out press filtration after reaction is completed, then be dried to water ratio less than 4%, obtain dry thing;
5) dry thing is pulverized, making fineness is 400～500 orders;
6) mineralizer with the dry thing after the pulverizing of 100 weight parts and 3～5 weight parts mixes, temperature lower calcination at 1000 ℃-1050 ℃, obtain calcined material, be that 45%～55% sulfuric acid mixes with the calcined material of 45～55 weight parts and the concentration of 25～35 weight parts, soaked 20-48 hour, and be washed to neutrality, then being ground to fineness D90 is 22～28 μ m, dry again, obtain zirconium silicate parcel cadmium yellow ceramic pigment.
2. the preparation method of zirconium silicate parcel cadmium yellow ceramic pigment according to claim 1, is characterized in that, the reaction times of the neutralization reaction of step 3) is 4～6 hours.
3. the preparation method of zirconium silicate parcel cadmium yellow ceramic pigment according to claim 1, is characterized in that, the drying in step 4) is carried out in the temperature environment below 250 ℃.
4. the preparation method of zirconium silicate parcel cadmium yellow ceramic pigment according to claim 1, is characterized in that, described mineralizer is halogenide.
5. the preparation method of zirconium silicate according to claim 1 parcel cadmium yellow ceramic pigment, is characterized in that, described mineralizer is any one or the two or more mixture in lithium fluoride, sodium-chlor, Repone K, Sodium Fluoride.
6. the preparation method of zirconium silicate parcel cadmium yellow ceramic pigment according to claim 1, is characterized in that, being ground in step 6) adopts ball mill to carry out ball milling.
7. the preparation method of zirconium silicate parcel cadmium yellow ceramic pigment according to claim 1, is characterized in that, in step 6), the zirconium silicate parcel cadmium yellow ceramic pigment that obtains crossed 325 orders.
8. a zirconium silicate parcel cadmium yellow ceramic pigment, is characterized in that, described preparation method makes by claim 1～7 any one.
9. zirconium silicate as claimed in claim 8 wraps up the cadmium yellow ceramic pigment, it is characterized in that having following proterties:
Outward appearance: yellow powder; Lightness: 70≤L≤80; Form and aspect: 2≤a≤12; Form and aspect: 60≤b≤85; Granularity: D90 is 22 μ m～28 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310108577XA CN103145451A (en) | 2013-03-29 | 2013-03-29 | Zirconium silicate coated cadmium yellow ceramic pigment and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310108577XA CN103145451A (en) | 2013-03-29 | 2013-03-29 | Zirconium silicate coated cadmium yellow ceramic pigment and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103145451A true CN103145451A (en) | 2013-06-12 |
Family
ID=48543837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310108577XA Pending CN103145451A (en) | 2013-03-29 | 2013-03-29 | Zirconium silicate coated cadmium yellow ceramic pigment and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103145451A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396161A (en) * | 2013-08-02 | 2013-11-20 | 邵阳县彩鑫制釉有限公司 | Preparation method of zirconium silicon black ceramic pigment |
| CN104446653A (en) * | 2014-11-28 | 2015-03-25 | 深圳国瓷永丰源股份有限公司 | Underglaze pigment applicable to high-temperature ceramic biscuit and production technology of underglaze pigment |
| CN105000910A (en) * | 2015-05-29 | 2015-10-28 | 醴陵市科兴实业有限公司 | Acid-soaked cadmium-selenium contained acid pickle direct recycling method |
| CN105036803A (en) * | 2015-05-29 | 2015-11-11 | 醴陵市科兴实业有限公司 | Method for preparing gilvous occlusion pigment from cadmium-containing waste acid solution generated in acid pickling process |
| CN105254248A (en) * | 2015-10-19 | 2016-01-20 | 嘉善远大新型墙体有限公司 | Yellow concrete block and preparation method thereof |
| CN106752108A (en) * | 2016-12-02 | 2017-05-31 | 佛山市华意陶瓷颜料有限公司 | A kind of yellow cadmium system occlusion pigment, ceramic ink and preparation method thereof |
| CN115521070A (en) * | 2022-11-29 | 2022-12-27 | 广东大角鹿新材料有限公司 | Nano ultra-white overglaze, ceramic tile and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101786902A (en) * | 2010-03-04 | 2010-07-28 | 陕西科技大学 | Preparation method for extended red ZrSiO_4-Cd (S_xSe_(1-x)) pigment |
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
-
2013
- 2013-03-29 CN CN201310108577XA patent/CN103145451A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101786902A (en) * | 2010-03-04 | 2010-07-28 | 陕西科技大学 | Preparation method for extended red ZrSiO_4-Cd (S_xSe_(1-x)) pigment |
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
Non-Patent Citations (1)
| Title |
|---|
| 周杨帆等: "溶胶共沉淀法合成硅酸锆包裹硫硒化镉大红颜料", 《湘潭大学自然科学学报》, vol. 33, no. 1, 15 March 2011 (2011-03-15), pages 69 - 72 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396161A (en) * | 2013-08-02 | 2013-11-20 | 邵阳县彩鑫制釉有限公司 | Preparation method of zirconium silicon black ceramic pigment |
| CN104446653A (en) * | 2014-11-28 | 2015-03-25 | 深圳国瓷永丰源股份有限公司 | Underglaze pigment applicable to high-temperature ceramic biscuit and production technology of underglaze pigment |
| CN104446653B (en) * | 2014-11-28 | 2016-08-17 | 深圳国瓷永丰源股份有限公司 | It is applicable to ceramic high temperature element tire underglaze colour and paints pigment and manufacture craft thereof |
| CN105000910A (en) * | 2015-05-29 | 2015-10-28 | 醴陵市科兴实业有限公司 | Acid-soaked cadmium-selenium contained acid pickle direct recycling method |
| CN105036803A (en) * | 2015-05-29 | 2015-11-11 | 醴陵市科兴实业有限公司 | Method for preparing gilvous occlusion pigment from cadmium-containing waste acid solution generated in acid pickling process |
| CN105000910B (en) * | 2015-05-29 | 2018-04-03 | 醴陵市科兴实业有限公司 | A kind of acid soak is containing cadmium, the direct recoverying and utilizing method of selenium acid pickle |
| CN105254248A (en) * | 2015-10-19 | 2016-01-20 | 嘉善远大新型墙体有限公司 | Yellow concrete block and preparation method thereof |
| CN106752108A (en) * | 2016-12-02 | 2017-05-31 | 佛山市华意陶瓷颜料有限公司 | A kind of yellow cadmium system occlusion pigment, ceramic ink and preparation method thereof |
| CN106752108B (en) * | 2016-12-02 | 2018-10-30 | 佛山市华意陶瓷颜料有限公司 | A kind of yellow cadmium system occlusion pigment, ceramic ink and preparation method thereof |
| CN115521070A (en) * | 2022-11-29 | 2022-12-27 | 广东大角鹿新材料有限公司 | Nano ultra-white overglaze, ceramic tile and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103145451A (en) | Zirconium silicate coated cadmium yellow ceramic pigment and preparation method thereof | |
| CN102031023A (en) | Calcined kaolin-based compound titanium dioxide and preparation method thereof | |
| CN102515853B (en) | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment | |
| CN101851437B (en) | Pyrophyllite-based composite titanium white powder and preparation method thereof | |
| CN110204927A (en) | A kind of ash ceramic pigment color and preparation method thereof | |
| CN104119720A (en) | Red pigment capable of reflecting near infrared radiation | |
| CN103275523A (en) | Orange pigment for food packaging plastic and preparation method thereof | |
| CN104830099B (en) | Coated silica-bismuth vanadate-barium sulfate high-brightness yellow pigment preparation method | |
| CN108070280A (en) | A kind of preparation method of silicon dioxide microsphere-titanium dioxide composite powder pigment | |
| CN102627478B (en) | Method for preparing yellow pigment by using commonly used color development for replacing rare-earth element praseodymium and vanadium color development | |
| CN108017936B (en) | Preparation method of spherical composite superfine yellow ceramic pigment | |
| CN103359763A (en) | Chemical preparation method for spherical hollow alumina powder for producing gemstone by using flame fusion method | |
| CN113479895A (en) | Method for preparing superfine zirconium silicate and zirconium silicate-based coating pigment by one-step precipitation method | |
| CN110204926B (en) | Vanadium-zirconium blue ceramic pigment, vanadium-zirconium blue ceramic ink and preparation method thereof | |
| CN110182818B (en) | Calcium-chromium garnet green pigment and preparation method thereof | |
| CN104892030B (en) | A kind of preparation method of nanometer praseodymium yellow ceramic pigment | |
| CN103159505B (en) | Process for preparing zirconium-cadmium-selenium series colorant from recycled cadmium-containing wastewater | |
| CN103193510A (en) | Packaged red ceramic pigment and preparation method thereof | |
| CN101429053B (en) | Process for producing ferrozirconium red material | |
| CN108690377A (en) | A kind of pearlescent pigment and preparation method thereof with thousand pure gold effects | |
| CN102875196B (en) | Agate red ceramic pigment and liquid-phase preparation method thereof | |
| CN110105792A (en) | A kind of nanometer transparent ferric oxide red colorant and preparation method thereof | |
| KR101440473B1 (en) | Method for preparing plate-shaped alumina | |
| CN108250804B (en) | Nano vanadium-zirconium blue ceramic pigment and preparation method thereof | |
| CN102795890A (en) | Chrome-carried tin oxide violet ceramic pigment and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130612 |