Ammonia burst size additive and preparation method thereof in a kind of reduction cigarette smoke
Technical field
The present invention relates to a kind of NH in the selectivity reducing cigarette main flume that has
3The adsorbent of burst size.
Background technology
Along with the progress of society, people improve constantly the attention rate of self health, and China further strengthens Harm reduction techniques and falls burnt dynamics as the signatories to a treaty of " Framework Convention on Tobacco Control ", is related to the survival and development of China's tobacco business.Show according to international tobacco research organization statistics, by 2011, the composition of having identified in cigarette smoke surpassed kind more than 5000, and wherein 99.4% composition is harmless.2009, the cigarette smoke harmfulness index research by Zhengzhou tobacco research institute takes the lead and carried out Chinese-style cigarette filtered out 7 kinds of representative compositions as cigarette Evaluation of Harmfulness index in 29 kinds of harmful components of cigarette mainstream flue gas, and ammonia is wherein one.
Ammonia not only affects the sucking quality of cigarette, also can stimulate vision and the respiratory system of human body, and long-term suction meeting causes more serious harm to human body.Therefore, the research that reduces ammonia burst size in cigarette smoke to improve the cigarette quality, to improve the smoking property of cigarette security significant.
So far, launch around its assay method and formation mechanism about the research overwhelming majority of ammonia in flue gas.The research that both at home and abroad ammonia in cigarette smoke is reduced technology seldom, is mainly to realize falling ammonia by the means that reduce tar, selectively falls the ammonia DeGrain.
Summary of the invention
Given this, the object of the invention is to provide the functionalization adsorbent of ammonia burst size in a kind of selectivity reducing cigarette main flume.
For solving above technical problem, technical scheme provided by the invention is, on the one hand, ammonia burst size additive in a kind of reduction cigarette smoke is provided, spread loads alkaline earth metal chloride on mesoporous silicon, the mass percent that load accounts for total amount is not more than 40%, and the mesoporous silicon aperture is 2-50nm, and specific area is not less than 300m
2/ g, granularity is the 40-80 order.
Preferably, to account for the mass percent of total amount be 25% in described load.
Preferably, described alkaline earth metal compound is CaCl
2
Preferably, described alkaline earth metal compound is MgCl
2
Preferably, described alkaline earth metal compound is SrCl
2
On the other hand, the present invention also provides the preparation method of ammonia burst size additive in above-mentioned reduction cigarette smoke, takes alkaline earth metal compound and is dissolved in appropriate deionized water, stirs to form uniform solution; In compound, the mass percent of alkaline earth metal compound is not more than 40%, takes 40-80 order specific area for being not less than 300-m
2Then the mesoporous silicon of/g stirs, and places under room temperature to allow alkaline earth metal compound fully load on mesoporous silicon outer surface and inner duct in 12h hour, then puts into 110 ℃ of dry 24h of baking oven, and cool to room temperature namely obtains described additive.
Preferably, take 750g CaCl
2Be dissolved in appropriate deionized water, stir and form uniform solution; CaCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains described additive.
Preferably, take 750gMgCl
2Be dissolved in appropriate deionized water, stir and form uniform solution; MgCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow MgCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains described additive.
Preferably, take the SrCl of 750g
2Be dissolved in appropriate deionized water, stir and form uniform solution; SrCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow SrCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains described additive.
Compared with prior art, a technical scheme in technique scheme has following advantage:
But 1, simple, the with low cost industrial applications of technique of the present invention is fallen the ammonia effect remarkable.
2, the filter stick that has added additive of the present invention is applied to cigarette, from resulting result, can effectively reduce the burst size of ammonia in cigarette smoke, wherein functional mesoporous silicon materials all reduce significantly vapor phase ammonia, and grain phase ammonia is also had in various degree reduction.Mesoporous silicon load optimised quantity is 25%, and the duct will be seriously stopped up in excessive interpolation, reduces the specific area of material, thereby loses the duct advantage of mesoporous silicon.Additive of the present invention on the cigarette organoleptic quality substantially without impact, nontoxic, can satisfy the processing technology of binary compound bar, aspect low harm cigarette processing, application prospect is being arranged.
The binary compound filter candle that adopts additive of the present invention to make is composited by doping acetate fiber section and common acetate fiber section.The additive acetate fiber section is to be dispersed in by additive that loose acetate fibres is intrafascicular to be formed, and the additive addition is 2-30mg.
Common acetate fiber section and doping acetate fiber section are compounded to form binary compound filter candle, the common acetate fiber section of compound tense and add adsorbent acetate fiber section alternative arrangement, wherein common acetate fiber section is at the end of filter stick, the doping acetate fiber section namely contacts the pipe tobacco end at the front end of filter stick.
The specific embodiment
Ammonia burst size additive in the described reduction cigarette smoke of the present embodiment is spread loads CaCl on mesoporous silicon
2, MgCl
2Or SrCl
2, the mass percent that load accounts for total amount is not more than 40%, and the mesoporous silicon aperture is 2-50nm, and specific area is not less than 300m
2/ g, granularity is the 40-80 order.
Embodiment 1
Take 150g CaCl
2Be dissolved in appropriate deionized water, stir and form uniform solution; CaCl in compound
2Mass percent be 5%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2850g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 1.
The functional mesoporous silicon additive of table 1 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 2
Take 300 CaCl
2Be dissolved in appropriate deionized water, stir and form uniform solution; CaCl in compound
2Mass percent be 10%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2700g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 2.
The functional mesoporous silicon additive of table 2 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 3
Take the CaCl of 450g
2Be dissolved in the deionized water of 3L, stir and form uniform solution; CaCl in compound
2Mass percent be 15%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2550g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 3.
The functional mesoporous silicon additive of table 3 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 4
Take the CaCl of 750g
2Be dissolved in appropriate deionized water, stir and form uniform solution; CaCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 4.
The functional mesoporous silicon additive of table 4 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 5
Take the CaCl of 1050g
2Be dissolved in the deionized water of 3L, stir and form uniform solution; CaCl in compound
2Mass percent be 35%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 1950g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 5.
The functional mesoporous silicon additive of table 5 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 6
Take the CaCl of 1200g
2Dissolve in appropriate deionized water, stir and form uniform solution; CaCl in compound
2Mass percent be 40%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 1800g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 6.
The functional mesoporous silicon additive of table 6 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 7
Take the CaCl of 750g
2Be dissolved in appropriate deionized water, stir and form uniform solution; CaCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow CaCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 7.
The functional mesoporous silicon additive of table 7 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 8
Take the MgCl of 750g
2Be dissolved in appropriate deionized water, stir and form uniform solution; MgCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow MgCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 8.
The functional mesoporous silicon additive of table 8 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Embodiment 9
Take the SrCl of 750g
2Be dissolved in appropriate deionized water, stir and form uniform solution; SrCl in compound
2Mass percent be 25%, take 40-80 order specific area and be about 300m
2Then the mesoporous silicon 2250g of/g stirs, and places under room temperature to allow SrCl in 12h hour
2Fully load on mesoporous silicon outer surface and inner duct, then put into 110 ℃ of dry 24h of baking oven, cool to room temperature obtains functional mesoporous silicon materials 9.
The functional mesoporous silicon additive of table 9 is to vapor phase ammonia, grain phase ammonia burst size situation in cigarette mainstream flue gas
。
Be below only the preferred embodiment of the present invention, should be pointed out that above-mentioned preferred embodiment should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with the claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.