CN103129202B - Polyvinyl alcohol image photographic paper - Google Patents
Polyvinyl alcohol image photographic paper Download PDFInfo
- Publication number
- CN103129202B CN103129202B CN201310091883.7A CN201310091883A CN103129202B CN 103129202 B CN103129202 B CN 103129202B CN 201310091883 A CN201310091883 A CN 201310091883A CN 103129202 B CN103129202 B CN 103129202B
- Authority
- CN
- China
- Prior art keywords
- weight portion
- polyvinyl alcohol
- base material
- pva
- printing paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims abstract description 68
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 68
- 239000000463 material Substances 0.000 claims abstract description 35
- 238000003384 imaging method Methods 0.000 claims abstract description 28
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 22
- 239000011780 sodium chloride Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000007639 printing Methods 0.000 claims description 31
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 28
- 125000000129 anionic group Chemical group 0.000 claims description 15
- 229920005646 polycarboxylate Polymers 0.000 claims description 15
- 239000005995 Aluminium silicate Substances 0.000 claims description 14
- 239000002174 Styrene-butadiene Substances 0.000 claims description 14
- 235000012211 aluminium silicate Nutrition 0.000 claims description 14
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 14
- 229920000126 latex Polymers 0.000 claims description 14
- 239000011115 styrene butadiene Substances 0.000 claims description 14
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- 239000013530 defoamer Substances 0.000 claims description 11
- 239000004816 latex Substances 0.000 claims description 10
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 10
- 150000002171 ethylene diamines Chemical class 0.000 claims description 9
- 229920001131 Pulp (paper) Polymers 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000009288 screen filtration Methods 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- 238000010030 laminating Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Images
Landscapes
- Paper (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention belongs to the technical field of photographic paper, and in particular discloses polyvinyl alcohol image photographic paper. The body paper structurally comprises a base material and an ink absorbing imaging layer arranged on one surface or two surfaces of the base material, wherein the thickness of the ink absorbing imaging layer is 25-40g/m<2>, and the ink absorbing imaging layer is composed of PVA (Polyvinyl Alcohol), propylene glycol, ethylenediamine and sodium chloride. As the ink absorbing imaging layer of the polyvinyl alcohol image photographic paper is directly prepared from PVA which does not need to be formed into a water solution through a laminating process, the polyvinyl alcohol image photographic paper has the advantages of simple preparation process and low production cost.
Description
Technical field
The invention belongs to printing paper technical field, relate to a kind of polyvinyl alcohol image printing paper that advertisement, making video are used that is applicable to.
Background technology
Be applicable to the former paper structure of printing paper that advertisement, making video comprise that inkjet printing is used comprise by pure wood pulp, be prepared into, have that whiteness is high, smoothness is high and apparent sophistication is high and form without the base material of dust point and the PE film and the blotting imaging layer that are arranged at its one or both sides.Wherein said blotting imaging layer consists of nanoscale alundum (Al2O3) powder layer or consists of water miscible polyvinyl alcohol (PVA) material, because polyvinyl alcohol is a kind of nontoxic and hold labile material, is therefore widely used.But when using polyvinyl alcohol to prepare blotting imaging layer, the aqueous solution blade coating that must be prepared into concentration and be 10% left and right can be realized and filming on base material, must be through baking operation after filming; Therefore the preparation process of printing paper body paper not only complexity the more important thing is that energy consumption has caused greatly the high and inefficient defect of production cost.
Summary of the invention
Object of the present invention is exactly that providing a kind of can directly drench by polyvinyl alcohol (PVA) the polyvinyl alcohol image printing paper that forms blotting imaging layer on the base material of printing paper body paper.
Realizing the technical scheme that above-mentioned purpose of the present invention adopts is:
A polyvinyl alcohol image printing paper, includes base material and the blotting imaging layer that is arranged at these base material one or both sides; Wherein said blotting imaging layer thickness is 25-40 grams/m, and consists of the sodium chloride of propane diols, 10-15 weight portion ethylenediamines and 3-8 weight portions of 100 weight portion PVA, 10-12 weight portions.
In addition, the additional technical feature that forms above-mentioned polyvinyl alcohol image printing paper also comprises:
---between described base material and described blotting imaging layer, be disposed with thickness and be the PE rete that the pure wood pulp layer of 20-40 grams/m and thickness are 30-50 grams/m;
---between described PE rete and the pure wood pulp layer of described base material, be provided with thickness and be 15-20 grams/m, and the drag leveling course being formed by the anionic polycarboxylate of 400 weight portion kaolin, 180-220 weight portion calcium carbonate, 100-120 weight portion carboxylic styrene butadiene latexs, 18-25 weight portion PVA, 1.8-2.4 weight portion defoamers, 1.0-1.5 weight portion removers and 6-9 weight portions;
---between described base material and blotting imaging layer, be provided with thickness and be the PE rete of 30-50 grams/m;
---between described PE rete and base material, be provided with thickness and be 15-20 grams/m, and the drag leveling course being formed by the anionic polycarboxylate of 400 weight portion kaolin, 180-220 weight portion calcium carbonate, 100-120 weight portion carboxylic styrene butadiene latexs, 18-25 weight portion PVA, 1.8-2.4 weight portion defoamers, 1.0-1.5 weight portion removers and 6-9 weight portions;
---described in strike off layered material preparation method comprise the following steps:
PVA is heated at the temperature of 90-96 ℃, dissolve, and utilizes mixer to stir to form glue, utilizing 180-250 object screen filtrations to form dispersion liquids; Then, kaolin, calcium carbonate and anionic polycarboxylate are joined to stirring and dissolving in the water of stirred vessel and form the solution that concentration is 40-45%, then add carboxylic styrene butadiene latex, PVA dispersion liquid in solution after, stir again, add respectively subsequently remover and defoamer, and stir respectively 15 minutes, utilize 180-250 object screen filtrations to remove coarse grain.
A kind of polyvinyl alcohol image printing paper provided by the present invention compared with prior art, have the following advantages: one, owing to forming the sodium chloride formation of the blotting imaging layer of this image printing paper by propane diols, 10-15 weight portion ethylenediamines and 5 weight portions of 100 weight portion PVA, 10-12 weight portions, make PVA just can directly by film technique, complete blotting imaging layer without the formation aqueous solution and prepare, have advantages of that preparation technology's simple production cost is low; Its two, between the base material that forms printing paper and blotting imaging layer, be provided with the PE rete of water proof function, the problem that in the time of therefore can effectively avoiding on blotting imaging layer a large amount of ink-jet, the phase body paper of picture there will be direct gauffer to be out of shape; They are three years old, be provided with drag leveling course forming between the blotting imaging layer of printing paper or PE rete and base material, can realize the low threshold that forms image phase paper base material, without use completely expensive that by pure wood pulp, be prepared into, have that whiteness is high, smoothness is high and apparent sophistication is high and put without dust the base material that pure wood fibre forms, this base material can be replaced by the brown paper that has simple process to produce completely, can greatly reduce the production cost of image printing paper Normal juice;
Accompanying drawing explanation
Fig. 1 is the cross section structure schematic diagram of one side polyvinyl alcohol image printing paper;
Fig. 2 is the cross section structure schematic diagram of the second polyvinyl alcohol image printing paper;
Fig. 3 is the cross section structure schematic diagram of the third polyvinyl alcohol image printing paper.
The specific embodiment
Below in conjunction with accompanying drawing, structure and the use principle of polyvinyl alcohol image printing paper provided by the present invention are described in further detail:
Fig. 1,2 and 3 is depicted as the cross section structure schematic diagram of three kinds of one side polyvinyl alcohol image printing paper provided by the invention.The blotting imaging layer 2 that it is 25-40 grams/m that the structure that forms this polyvinyl alcohol image printing paper comprises by the thickness consisting of PVA, propane diols, ethylenediamine and sodium chloride forming as body paper base material 1 and film technique forms; Moisture wherein forms impact to picture body paper base material 1 when preventing 2 ink-jet of blotting imaging layer, and at base material 1 and 2 of blotting imaging layers, being provided with thickness is as shown in Figure 2 the PE rete of 30-50 grams/m.When adopting no calender operation brown paper done base material 1 cheaply as shown in Figure 3, first on brown paper is done a side of base material 1, set gradually thickness and be the pure wood pulp layer 5 of 20-40 grams/m and thickness and be after 15-20 grams/m and the drag leveling course 4 that formed by kaolin, calcium carbonate, carboxylic styrene butadiene latex, PVA, defoamer, remover and anionic polycarboxylate, PE rete 3 and blotting imaging layer 2 are being set.The one side polyvinyl alcohol image printing paper of said structure can not arrange PE rete as required, and drag leveling course is directly set between blotting imaging layer 2 and base material.
The polyvinyl alcohol image printing paper of said structure can arrange drag leveling course, PE rete and blotting imaging layer in two sides of base material, makes it to become two-sided polyvinyl alcohol image printing paper.When using brown paper to do base material, the pure wood pulp layer 5 that blade coating thickness is 20-40 grams/m on its side, to improve its firmness.
Being prepared as of blotting imaging layer that forms above-mentioned polyvinyl alcohol image printing paper will
The sodium chloride of the PVA particle of 100 weight portions, the propane diols of 10 weight portions, 14 weight portion ethylenediamines and 6 weight portions;
The sodium chloride of the PVA particle of 100 weight portions, the propane diols of 10.5 weight portions, 12 weight portion ethylenediamines and 5 weight portions;
The sodium chloride of the PVA particle of 100 weight portions, the propane diols of 11 weight portions, 13 weight portion ethylenediamines and 4 weight portions;
The sodium chloride of the PVA particle of 100 weight portions, the propane diols of 12 weight portions, 10 weight portion ethylenediamines and 7.5 weight portions;
The sodium chloride of the PVA particle of 100 weight portions, the propane diols of 11.5 weight portions, 11 weight portion ethylenediamines and 3 weight portions; Or
The sodium chloride mixing and stirring of the PVA particle of 100 weight portions, the propane diols of 11 weight portions, 15 weight portion ethylenediamines and 8 weight portions directly in extruder at the temperature of 110-125 ℃ extrudate flow be extended down to be combined with each other on base material, PE rete or drag leveling course and form polyvinyl alcohol image printing paper.
The composition (weight portion) that forms above-mentioned polyvinyl alcohol image printing paper drag leveling course is:
Kaolin 400, calcium carbonate 200, anionic polycarboxylate 8, carboxylic styrene butadiene latex 110, PVA 20, defoamer 2.2, remover 6;
Kaolin 400, calcium carbonate 190, anionic polycarboxylate 7, carboxylic styrene butadiene latex 115, PVA 18, defoamer 2.0, remover 9;
Kaolin 400, calcium carbonate 180, anionic polycarboxylate 6, carboxylic styrene butadiene latex 105, PVA 24, defoamer 2.4, remover 7;
Kaolin 400, calcium carbonate 210, anionic polycarboxylate 9, carboxylic styrene butadiene latex 100, PVA 22, defoamer 1.8, remover 8;
Kaolin 400, calcium carbonate 220, anionic polycarboxylate 8, carboxylic styrene butadiene latex 120, PVA 19, defoamer 2.0, remover 6; Or
Kaolin 400, calcium carbonate 200, anionic polycarboxylate 7, carboxylic styrene butadiene latex 110, PVA 22, defoamer 2.1, remover 8.Wherein, use
Defoamer can be selected n-butanol, ethanol or tbp;
Remover can be selected calcium stearate, polyethers-F68 or zinc stearate.Its preparation technology is:
First, preparation is heated to polyvinyl alcohol (PVA) to dissolve at the temperature of 90-96 ℃, and the rotating speed stirring at low speed of utilizing mixer to be controlled at 4.5-6.0r/min forms glue, is utilizing 180-250 object screen filtrations to form PVA dispersion liquids; Then, kaolin, calcium carbonate and anionic polycarboxylate are joined to stirring and dissolving in the water of stirred vessel and form the solution that concentration is 40-45%, add again carboxylic styrene butadiene latex, PVA dispersion liquid in solution after, stir, add respectively subsequently remover and defoamer, and stir respectively 15 minutes, utilize 180-250 object screen filtrations to remove coarse grain.
In present patent application description, PVA is the abbreviation abbreviation of high molecular weight water soluble polymer polyvinyl alcohol, and " anionic polycarboxylate " is about to usually said " DC dispersant ".
Claims (5)
1. a polyvinyl alcohol image printing paper, is characterized in that: comprise base material and the blotting imaging layer that is arranged at this base material single or double; Wherein said blotting imaging layer thickness is 25-40 grams/m, and consists of the sodium chloride of propane diols, 10-15 weight portion ethylenediamines and 3-8 weight portions of 100 weight portion PVA, 10-12 weight portions; Between described base material and described blotting imaging layer, be disposed with thickness and be the PE rete that the pure wood pulp layer of 20-40 grams/m and thickness are 30-50 grams/m.
2. a kind of polyvinyl alcohol image printing paper according to claim 1, it is characterized in that: between described PE rete and the pure wood pulp layer of described base material, be provided with thickness and be 15-20 grams/m, and the drag leveling course being formed by the anionic polycarboxylate of 400 weight portion kaolin, 180-220 weight portion calcium carbonate, 100-120 weight portion carboxylic styrene butadiene latexs, 18-25 weight portion PVA, 1.8-2.4 weight portion defoamers, 1.0-1.5 weight portion removers and 6-9 weight portions.
3. a kind of polyvinyl alcohol image printing paper according to claim 1, is characterized in that: between described base material and blotting imaging layer, be provided with thickness and be the PE rete of 30-50 grams/m.
4. a kind of polyvinyl alcohol image printing paper according to claim 3, it is characterized in that: between described PE rete and base material, be provided with thickness and be 15-20 grams/m, and the drag leveling course being formed by the anionic polycarboxylate of 400 weight portion kaolin, 180-220 weight portion calcium carbonate, 100-120 weight portion carboxylic styrene butadiene latexs, 18-25 weight portion PVA, 1.8-2.4 weight portion defoamers, 1.0-1.5 weight portion removers and 6-9 weight portions.
5. according to a kind of polyvinyl alcohol image printing paper described in claim 2 or 4, it is characterized in that: described in strike off layered material preparation method comprise the following steps:
PVA is heated at the temperature of 90-96 ℃, dissolve, and utilizes mixer to stir to form glue, utilizing 180-250 object screen filtrations to form dispersion liquids; Then, kaolin, calcium carbonate and anionic polycarboxylate are joined to stirring and dissolving in the water of stirred vessel and form the solution that concentration is 40-45%, then add carboxylic styrene butadiene latex, PVA dispersion liquid in solution after, stir again, add respectively subsequently remover and defoamer, and stir respectively 15 minutes, utilize 180-250 object screen filtrations to remove coarse grain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310091883.7A CN103129202B (en) | 2012-11-13 | 2013-03-21 | Polyvinyl alcohol image photographic paper |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210452858 | 2012-11-13 | ||
| CN201210452858.2 | 2012-11-13 | ||
| CN201310091883.7A CN103129202B (en) | 2012-11-13 | 2013-03-21 | Polyvinyl alcohol image photographic paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103129202A CN103129202A (en) | 2013-06-05 |
| CN103129202B true CN103129202B (en) | 2014-04-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310091883.7A Expired - Fee Related CN103129202B (en) | 2012-11-13 | 2013-03-21 | Polyvinyl alcohol image photographic paper |
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| Country | Link |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106671635A (en) * | 2016-06-29 | 2017-05-17 | 安徽文峰特种纸业有限公司 | Preparation method of polyvinyl alcohol coating applied to photographic paper |
| CN108705873A (en) * | 2018-04-08 | 2018-10-26 | 温州创佳影像材料有限公司 | One kind tearing not rotten duplex printing RC printing paper and its production technology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1500655A (en) * | 2002-11-15 | 2004-06-02 | 富士胶片株式会社 | Ink-jet recording sheet |
| JP2007015316A (en) * | 2005-07-11 | 2007-01-25 | Oji Paper Co Ltd | Sheet for inkjet recording |
| CN102218907A (en) * | 2010-03-29 | 2011-10-19 | 富士胶片株式会社 | Image forming method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2028016B1 (en) * | 2007-08-24 | 2011-03-23 | FUJIFILM Corporation | Recording medium, method for producing the same, and inkjet recording method using the recording medium |
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2013
- 2013-03-21 CN CN201310091883.7A patent/CN103129202B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1500655A (en) * | 2002-11-15 | 2004-06-02 | 富士胶片株式会社 | Ink-jet recording sheet |
| JP2007015316A (en) * | 2005-07-11 | 2007-01-25 | Oji Paper Co Ltd | Sheet for inkjet recording |
| CN102218907A (en) * | 2010-03-29 | 2011-10-19 | 富士胶片株式会社 | Image forming method |
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| Publication number | Publication date |
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| CN103129202A (en) | 2013-06-05 |
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