CN103114471A - Method for synthesizing multi-functional color fixing agent of silk fabrics - Google Patents
Method for synthesizing multi-functional color fixing agent of silk fabrics Download PDFInfo
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- CN103114471A CN103114471A CN2013100418605A CN201310041860A CN103114471A CN 103114471 A CN103114471 A CN 103114471A CN 2013100418605 A CN2013100418605 A CN 2013100418605A CN 201310041860 A CN201310041860 A CN 201310041860A CN 103114471 A CN103114471 A CN 103114471A
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Abstract
The invention discloses a method for synthesizing multi-functional color fixing agent of silk fabrics. The method comprises the following steps: step 1): adding two parts of diethylenetriamine and one part of triethylene tetramine to a three-neck flask, and stirring; and after the temperature reaches 60 DEG C, dropping 3.5 parts of ethyl acrylate, wherein the temperature is between 65 DEG C to 75 DEG C during the dropping process, and the reaction time is 3 hours; step 2): dropping 3 parts of epoxy chloropropane via a constant-pressure feeder, and dropping 8 parts of distilled water at the same time, wherein all the dropping operations are finished in one hour, the temperature is between 70 DEG C to 80 DEG C, and the reaction time is 3 hours; and step 3): adding the right amount of initiator potassium peroxodisulfate, wherein the temperature is between 75 DEG C to 85 DEG C, and the reaction time is 4 hours; and after the temperature is reduced to 40 DEG C, adjusting the pH value to 6-7 via 30% acetum, and then obtaining the multi-functional color fixing agent. The method disclosed by the invention has short production process, can easily control the technological conditions, and has less effect on feels of fabrics after use.
Description
Technical field
The present invention relates to a kind of color-fixing agent, be specifically related to the synthetic method of the multi-functional color-fixing agent of a kind of silk fabric.
Background technology
Common color-fixing agent production procedure is longer, and process conditions are loaded down with trivial details, and are wayward, has aborning noxious material and exists.
Summary of the invention
For addressing the above problem, the present invention proposes the synthetic method of the multi-functional color-fixing agent of a kind of silk fabric, production procedure of the present invention is shorter, and process regulation is easy, and the feel impact on fabric after using is less.
For realizing above-mentioned technical purpose, reach above-mentioned technique effect, the present invention is achieved through the following technical solutions:
The synthetic method of the multi-functional color-fixing agent of a kind of silk fabric comprises the following steps:
Step 1) adds 2 parts of diethylenetriamines in there-necked flask, 1 part of triethylene tetramine also stirs, and drips the ethyl acrylate of 3.5 parts when temperature is raised to 60 ℃, maintains the temperature between 65 ℃～75 ℃ reaction 3h in the dropping process;
Step 2) drip the epoxychloropropane of 3 parts with the constant voltage feeder, and drip simultaneously 8 parts of distilled water, all drip in 1h, maintain the temperature between 70 ℃～80 ℃, reaction 3h;
Step 3) adds appropriate initiator potassium persulfate, maintains the temperature between 75 ℃～85 ℃ to react 4h, after being cooled to 40 ℃, regulates pH value to 6～7 with 30% acetum, obtains multi-functional color-fixing agent.
Further, in described step 1), the time for adding of ethyl acrylate is 30 minutes.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention compares with traditional color-fixing agent, does not contain the harmful substances such as formaldehyde in multi-functional color-fixing agent synthesis material and building-up process, also formaldehydeless generation in use, and production procedure is shorter, and process regulation is easy.Technique for applying is simple aborning, and the silk fabric after processing is except there being good colour fixation, and washing is difficult for fading, and has crease resistance preferably, and after using, the feel impact on fabric is less.
The specific embodiment
The synthetic method of the multi-functional color-fixing agent of a kind of silk fabric comprises the following steps:
Step 1) adds 2 parts of diethylenetriamines in there-necked flask, 1 part of triethylene tetramine also stirs, and drips the ethyl acrylate of 3.5 parts when temperature is raised to 60 ℃, maintains the temperature between 65 ℃～75 ℃ reaction 3h in the dropping process;
Step 2) drip the epoxychloropropane of 3 parts with the constant voltage feeder, and drip simultaneously 8 parts of distilled water, all drip in 1h, maintain the temperature between 70 ℃～80 ℃, reaction 3h;
Step 3) adds appropriate initiator potassium persulfate, maintains the temperature between 75 ℃～85 ℃ to react 4h, after being cooled to 40 ℃, regulates pH value to 6～7 with 30% acetum, obtains multi-functional color-fixing agent.
Further, in described step 1), the time for adding of ethyl acrylate is 30 minutes.
The operation principle of the present embodiment is as follows:
The present invention is applicable to silk fabric crepe de Chine, the fixing finish of fabric after the acid dyeing of habotai, and after arranging, the silk fabric dry fastness generally can reach 4 grades or 4～5 grades (5 grades are best); Fastness to wet rubbing generally can reach 4 grades, and the part weak acid dye can reach 4～5 grades; Dyeing silk fabric after processing not only has good colour fixation, also has wrinkle-proof effect preferably, and take the habotai fabric as example, wrinkle resistant grade can be brought up to 3～4 grades by untreated 2 grades of left and right, and less on the feel impact.
Multi-functional color-fixing agent technique for applying is infusion process: color-fixing agent 5～20g/L(selects according to fabric characteristics and the dyeing degree of depth), bath raio (weight ratio of fabric and water) 1:20, temperature, 50～60 ℃, time 20～30min.
Claims (2)
1. the synthetic method of the multi-functional color-fixing agent of silk fabric is characterized in that: comprise the following steps:
Step 1) adds 2 parts of diethylenetriamines in there-necked flask, 1 part of triethylene tetramine also stirs, and drips the ethyl acrylate of 3.5 parts when temperature is raised to 60 ℃, maintains the temperature between 65 ℃～75 ℃ reaction 3h in the dropping process;
Step 2) drip the epoxychloropropane of 3 parts with the constant voltage feeder, and drip simultaneously 8 parts of distilled water, all drip in 1h, maintain the temperature between 70 ℃～80 ℃, reaction 3h;
Step 3) adds appropriate initiator potassium persulfate, maintains the temperature between 75 ℃～85 ℃ to react 4h, after being cooled to 40 ℃, regulates pH value to 6～7 with 30% acetum, obtains multi-functional color-fixing agent.
2. the synthetic method of the multi-functional color-fixing agent of a kind of silk fabric according to claim 1, it is characterized in that: in described step 1), the time for adding of ethyl acrylate is 30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100418605A CN103114471A (en) | 2013-02-04 | 2013-02-04 | Method for synthesizing multi-functional color fixing agent of silk fabrics |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100418605A CN103114471A (en) | 2013-02-04 | 2013-02-04 | Method for synthesizing multi-functional color fixing agent of silk fabrics |
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| CN103114471A true CN103114471A (en) | 2013-05-22 |
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| CN2013100418605A Pending CN103114471A (en) | 2013-02-04 | 2013-02-04 | Method for synthesizing multi-functional color fixing agent of silk fabrics |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103643567A (en) * | 2013-12-06 | 2014-03-19 | 成路凯尔服装（苏州）有限公司 | Synthesis method of multifunctional silk fabric fixing agent |
| CN104452367A (en) * | 2014-11-28 | 2015-03-25 | 周正英 | Printing, dyeing and fixation aid for cashmere fabric |
| CN107142754A (en) * | 2017-06-01 | 2017-09-08 | 合肥智慧龙图腾知识产权股份有限公司 | A kind of coloring agent of super imitative cotton real silk fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260625A (en) * | 2008-04-24 | 2008-09-10 | 刘国平 | Nanometer formaldehyde-free dye-fixing agent and method for making same |
| CN101824135A (en) * | 2010-04-13 | 2010-09-08 | 江苏工业学院 | Preparation method and application of terminated-type cation water-borne polyurethane color fixing agent |
| CN102887989A (en) * | 2011-07-18 | 2013-01-23 | 杨海翔 | Novel formaldehyde-free fixing agent |
-
2013
- 2013-02-04 CN CN2013100418605A patent/CN103114471A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260625A (en) * | 2008-04-24 | 2008-09-10 | 刘国平 | Nanometer formaldehyde-free dye-fixing agent and method for making same |
| CN101824135A (en) * | 2010-04-13 | 2010-09-08 | 江苏工业学院 | Preparation method and application of terminated-type cation water-borne polyurethane color fixing agent |
| CN102887989A (en) * | 2011-07-18 | 2013-01-23 | 杨海翔 | Novel formaldehyde-free fixing agent |
Non-Patent Citations (3)
| Title |
|---|
| 许磊: "无甲醛固色剂DK的应用研究", 《高职论丛》, no. 03, 15 September 2007 (2007-09-15), pages 18 - 20 * |
| 许磊等: "活性染料无甲醛固色剂X-1的合成与应用", 《纺织科技进展》, no. 05, 30 October 2005 (2005-10-30), pages 24 - 25 * |
| 许磊等: "真丝织物无甲醛固色剂M09的合成与应用", 《丝绸》, vol. 48, no. 10, 31 October 2011 (2011-10-31), pages 11 - 13 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103643567A (en) * | 2013-12-06 | 2014-03-19 | 成路凯尔服装（苏州）有限公司 | Synthesis method of multifunctional silk fabric fixing agent |
| CN104452367A (en) * | 2014-11-28 | 2015-03-25 | 周正英 | Printing, dyeing and fixation aid for cashmere fabric |
| CN107142754A (en) * | 2017-06-01 | 2017-09-08 | 合肥智慧龙图腾知识产权股份有限公司 | A kind of coloring agent of super imitative cotton real silk fabric and preparation method thereof |
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Application publication date: 20130522 |