CN103113763B - Method for modifying clay by using organic silicon micro-emulsion - Google Patents
Method for modifying clay by using organic silicon micro-emulsion Download PDFInfo
- Publication number
- CN103113763B CN103113763B CN201310060783.8A CN201310060783A CN103113763B CN 103113763 B CN103113763 B CN 103113763B CN 201310060783 A CN201310060783 A CN 201310060783A CN 103113763 B CN103113763 B CN 103113763B
- Authority
- CN
- China
- Prior art keywords
- clay
- organosilicon emulsion
- stir
- revs
- silicone oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention provides a method for modifying clay by using an organic silicon micro-emulsion. The method comprising the following steps of: preparing the organic silicon micro-emulsion through mechanical emulsification; fully mixing clay with the micro-emulsion through high-speed stirring and atomization; and performing heat treatment to obtain modified clay. By adopting the method, the surface polarity of clay can be changed to ensure that a super-hydrophobic layer is formed on the surface of the clay, the compatibility of the clay with a polymer is improved, and the water resistance, weatherability and mechanical properties of a clay-polymer composite material are improved. The method has positive significances for realizing efficient utilization of clay resources and promoting high performance of the clay-polymer composite material.
Description
Technical field
The present invention relates to clay alteration field, a kind of specifically method of organosilicon emulsion modified clay, has broad prospect of application in fields such as clay mineral recycling, clay-polymer composites.
Background technology
Clay is the aggregate of clay mineral, is made up of, and contains the impurity such as quartz, feldspar, mica and vitriol, sulfide, carbonate multiple hydrosilicate and a certain amount of aluminum oxide, alkalimetal oxide and alkaline earth metal oxide.The particle of clay mineral is tiny, is everlasting in colloid size range, is crystal or noncrystal, and great majority are sheets, and minority is tubulose, bar-shaped.Clay resource is abundant, with low cost, is one of ideal filler of polymer matrix composites.Clay has unique crystal layer overlay structure, and the atom on laminate interacts with strong covalent linkage, and interlayer is with intermolecular forces effect.Due to Intermolecular Forces a little less than, the mode such as under certain condition, some polar molecules (as water molecules) can be by adsorbing, insert, sandwich, suspension, pillared, embedding enters interlayer and does not destroy its laminate structure.But between crystal layer, the existence of large quantity of moisture is unfavorable for that monomer or polymkeric substance insert between clay layer, therefore, realize the application of clay in polymer matrix composites, must carry out intercalation modifying to clay.
Silicone oil is often referred to the linear polysiloxanes product that keeps liquid state under room temperature, has good consistency with most of monomers and polymkeric substance.Due to the wetting ability between clay seam, silicone oil macromole is difficult to directly enter.Silicone oil microemulsion is the dispersion liquid that silicone oil forms in water, and silicone oil particle diameter is wherein very tiny, and generally at 10-100nm, what have is even less than 10nm, is conducive to the intercalation modifying of clay.By silicone oil microemulsion, clay is carried out to modification, realized compound on molecular level of polymkeric substance and clay particle, greatly increased the interfacial interaction of polymkeric substance and clay, make polymer matrix composite there is remarkable mechanical property.Up to now, there is no the relevant report of organosilicon emulsion modified clay.
Summary of the invention
The invention provides a kind of method of organosilicon emulsion modified clay, object is the consistency improving in clay and polymeric matrix, strengthen the interaction between clay and polymkeric substance, improve the mechanical property of polymer-based carbon clay composite material and give the water resistance that clay-polymer composites is good.
The present invention is by the following technical solutions:
A method for organosilicon emulsion modified clay, comprises the following steps:
Step 1, under 1000～3000 revs/min of stir speed (S.S.)s by tensio-active agent and silicone oil 1:8～1:2 mix and blend 10～100 minutes in mass ratio, then divide the distilled water that adds silicone oil quality 150～550% for 4～6 times, obtain organosilicon emulsion;
Step 2, in stirring tank, add clay, wherein stirring tank temperature is 10～80 DEG C, stir speed (S.S.) is 350～2500 revs/min, the organosilicon emulsion obtaining in step 1 is evenly joined in the clay of high speed dispersion simultaneously, the clay wherein adding and organosilicon emulsion mass ratio are 0.45:1～5.5:1, treat that organosilicon emulsion adds complete, continue to stir 0.5～2 hour, after discharging, obtain organosilicon emulsion modified clay through thermal treatment, wherein 80～200 DEG C of thermal treatment temps, heat treatment time is 1～5 hour.
Further, described tensio-active agent is for being ionogenic surfactant or nonionic surface active agent, or the mixing of two class tensio-active agents; Ionogenic surfactant comprises one or more of sodium laurylsulfonate, Dodecyl trimethyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, and nonionic surface active agent comprises one or more of the smooth monostearate of sorb, sorbitan monooleate, polyoxyethylene sorbitan oleic acid ester, polyoxyethylene sorbitan stearate, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene.
Further, described silicone oil is one or more in methyl-silicone oil, ethyl silicon oil, phenyl silicone oil, amido silicon oil, hydroxy silicon oil, silicone oil of carboxyl.
Further, in the organosilicon emulsion preparation process described in step 1, add the timed interval of distilled water is 20～60 minutes at every turn.
Further, clay described in step 2 comprises one or more in attapulgite, kaolin, montmorillonite soil, illite soil, wilkinite, cleans in advance and skim upper strata impurity before use in water, at 100～150 DEG C, dries, grind, cross 100～500 mesh sieves.
Further, the mode that adds of organosilicon emulsion described in step 2 is atomized spray.
Beneficial effect of the present invention: method provided by the invention can change the surface polarity of clay, makes surface of clay form super-hydrophobic layer, improves itself and the consistency of polymkeric substance, water tolerance, weathering resistance and the mechanical property of raising clay-polymer composites.The present invention, to realizing the efficient utilization of clay resource, promotes the high performance of clay-polymer composites to have positive effect.
Embodiment:
Adopt the mode of embodiment to be described further organosilicon emulsion modified clay method of the present invention below, according to following embodiment, can better understand the present invention.But the described concrete material proportion of embodiment, processing condition and result thereof be only for the present invention is described, and should can not limit the present invention described in claims yet.
Embodiment 1
Under 2000 revs/min of stir speed (S.S.)s, by 2.5g sodium laurylsulfonate and 10g ethyl silicon oil mix and blend 20 minutes, then dividing and adding total amount for 6 times was the distilled water of 40g, and every minor tick 40 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 100 DEG C, dry, grind, cross 100 mesh sieves and obtain kaolin powder; In stirring tank, add 50g kaolin powder, at 30 DEG C, stir with 350 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1.5 hours, discharging, at 160 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 2 hours.
Embodiment 2
Under 1800 revs/min of stir speed (S.S.)s, by 2.5g sodium laurylsulfonate, the smooth monostearate of 2.5g sorb and 10g ethyl silicon oil mix and blend 30 minutes, then dividing and adding total amount for 4 times was the distilled water of 40g, and every minor tick 50 minutes, obtains organosilicon emulsion.Kaolin, wilkinite are cleaned respectively and skim upper strata impurity in water, at 100 DEG C, dry, grind, cross 100 mesh sieves, obtain kaolin powder and bentonite in powder.In stirring tank, add 50g kaolin powder and 25g bentonite in powder, at 55 DEG C, stir with 500 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1.5 hours, discharging, at 200 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 1 hour.
Embodiment 3
Under 2600 revs/min of stir speed (S.S.)s, by 2g fatty alcohol-polyoxyethylene ether and 15g amido silicon oil mix and blend 40 minutes, then dividing and adding total amount for 6 times was the distilled water of 30g, and with interval for the second time 20 minutes, 30 minutes, all the other intervals, obtained organosilicon emulsion for the first time.Montmorillonite soil and attapulgite are cleaned and skim upper strata impurity in water, at 150 DEG C, dry, grind, cross 500 mesh sieves, obtain kaolin powder and bentonite in powder.In stirring tank, add 50g montmorillonite soil powder and 50g attapulgite powder, at 30 DEG C, stir with 2000 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1.5 hours, discharging, at 100 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 5 hours.
Embodiment 4
Under 1500 revs/min of stir speed (S.S.)s by 0.5g dodecyl benzyl dimethyl ammonium chloride, 1g castor oil polyoxyethylene ether, 1.5g alkylphenol polyoxyethylene and 20g silicone oil of carboxyl mix and blend 30 minutes, then dividing and adding total amount for 6 times is the distilled water of 55g, add-on is 5g for the first time, be 10g each time later, every minor tick 40 minutes, obtains organosilicon emulsion.Illite soil is cleaned and skimmed in water upper strata impurity, at 150 DEG C, dry, grind, cross 100 mesh sieves, obtain illite soil powder.In stirring tank, add 100g illite soil powder, at 80 DEG C, stir with 800 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 120 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 5
Under 3000 revs/min of stir speed (S.S.)s by 0.5g sodium laurylsulfonate, 2.5g sorbitan monooleate, 2g polyoxyethylene sorbitan oleic acid ester, 10g hydroxy silicon oil and 10g ethyl silicon oil mix and blend 80 minutes, then divide 6 times and add 60g distilled water, every minor tick 40 minutes, obtains organosilicon emulsion.Attapulgite is cleaned in water and skim upper strata impurity, at 120 DEG C, dry, grind, cross 100 mesh sieves and obtain attapulgite powder.In stirring tank, add 400g attapulgite powder, at 75 DEG C, stir with 1500 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1 hour, discharging, at 120 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 6
Under 2000 revs/min of stir speed (S.S.)s by 0.5g Dodecyl trimethyl ammonium chloride, the smooth monostearate of 2g sorb, 2g polyoxyethylene sorbitan stearate, 5g phenyl silicone oil and 10g ethyl silicon oil mix and blend 100 minutes, then divide 5 times and add 60g distilled water, add-on is 5g for the first time, add-on is 10g for the second time, all the other are 15g each time, with interval for the second time 40 minutes, all the other intervals were 30 minutes, obtain organosilicon emulsion for the first time.Wilkinite is cleaned in water and skim upper strata impurity, at 120 DEG C, dry, grind, cross 200 mesh sieves and obtain bentonite in powder.In stirring tank, add 200g bentonite in powder, at 60 DEG C, stir with 1000 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 200 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 2 hours.
Embodiment 7
Under 1200 revs/min of stir speed (S.S.)s, by 2.5g alkylphenol polyoxyethylene and 20g phenyl silicone oil mix and blend 30 minutes, then divide 5 times and add 35g distilled water, every minor tick 40 minutes, obtains organosilicon emulsion.Kaolin and montmorillonite soil are cleaned and skim upper strata impurity in water, at 120 DEG C, dry, grind, cross 400 mesh sieves and obtain kaolin powder and montmorillonite soil powder.In stirring tank, add 200g kaolin powder and 100g montmorillonite soil powder, at 50 DEG C, stir with 2500 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 120 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 5 hours.
Embodiment 8
Under 2000 revs/min of stir speed (S.S.)s by 2.5g castor oil polyoxyethylene ether and 20g amido silicon oil mix and blend 20 minutes, then divide 5 times and add 70g distilled water, primary add-on is 10g, and all the other are 15g each time, every minor tick 30 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 130 DEG C, dry, grind, cross 200 mesh sieves and obtain kaolin powder.In stirring tank, add 200g kaolin powder, at 80 DEG C, stir with 800 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 2 hours, discharging, at 180 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 9
Under 1000 revs/min of stir speed (S.S.)s by 5g sodium laurylsulfonate, 10g amido silicon oil and 10g methyl-silicone oil mix and blend 80 minutes, then divide 4 times and add 35g distilled water, add-on is 5g for the first time, and all the other are 10g each time, every minor tick 40 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 120 DEG C, dry, grind, cross 200 mesh sieves and obtain kaolin powder.In stirring tank, add 200g kaolin powder, at 10 DEG C, stir with 300 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 160 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 5 hours.
Embodiment 10
Under 2000 revs/min of stir speed (S.S.)s, by 2g sodium laurylsulfonate and 15g hydroxy silicon oil mix and blend 10 minutes, then divide 5 times and add 80g distilled water, every minor tick 20 minutes, obtains organosilicon emulsion.Attapulgite is cleaned in water and skim upper strata impurity, at 140 DEG C, dry, grind, cross 100 mesh sieve attapulgite powders.In stirring tank, add 60g attapulgite powder, at 30 DEG C, stir with 1000 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 2 hours, discharging, at 180 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 2 hours.
Embodiment 11
Under 1500 revs/min of stir speed (S.S.)s, by 1g Dodecyl trimethyl ammonium chloride, 2.5g castor oil polyoxyethylene ether and 20g amido silicon oil mix and blend 20 minutes, then divide 4 times and add 60g distilled water, every minor tick 30 minutes, obtains organosilicon emulsion.Attapulgite is cleaned in water and skim upper strata impurity, at 120 DEG C, dry, grind, cross 200 mesh sieves and obtain attapulgite powder.In stirring tank, add 40g attapulgite powder, at 70 DEG C, stir with 800 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 180 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 12
Under 2500 revs/min of stir speed (S.S.)s, by 2.5g castor oil polyoxyethylene ether and 20g methyl-silicone oil mix and blend 20 minutes, then divide 6 times and add 30g distilled water, every minor tick 60 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 120 DEG C, dry, grind, cross 500 mesh sieve kaolin powders.In stirring tank, add 100g kaolin powder, at 80 DEG C, stir with 1000 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1 hour, discharging, at 80 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 5 hours.
Embodiment 13
Under 2500 revs/min of stir speed (S.S.)s, by 5g alkylphenol polyoxyethylene, 10g ethyl silicon oil and 10g methyl-silicone oil mix and blend 20 minutes, then divide 5 times and add 60g distilled water, every minor tick 50 minutes, obtains organosilicon emulsion.Attapulgite is cleaned in water and skim upper strata impurity, at 130 DEG C, dry, grind, cross 200 mesh sieves and obtain attapulgite powder.In stirring tank, add 100g attapulgite powder, at 20 DEG C, stir with 500 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1 hour, discharging, at 80 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 1 hour.
Embodiment 14
Under 2200 revs/min of stir speed (S.S.)s by 1g alkylphenol polyoxyethylene, 1.5g fatty alcohol-polyoxyethylene ether, 10g ethyl silicon oil and 10g methyl-silicone oil mix and blend 20 minutes, then divide 6 times and add 60g distilled water, every minor tick 50 minutes, obtains organosilicon emulsion.To in kaolin water, clean and skim upper strata impurity, at 130 DEG C, dry, grind, cross 200 mesh sieves and obtain kaolin powder.In stirring tank, add 100g kaolin powder, at 20 DEG C, stir with 500 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 120 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 15
Under 2500 revs/min of stir speed (S.S.)s by 1g dodecyl benzyl dimethyl ammonium chloride, 1g alkylphenol polyoxyethylene, 1g fatty alcohol-polyoxyethylene ether, 10g ethyl silicon oil and 10g methyl-silicone oil mix and blend 20 minutes, then divide 6 times and add 55g distilled water, every minor tick 30 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 130 DEG C, dry, grind, cross 200 mesh sieves and obtain kaolin powder.In stirring tank, add 100g kaolin powder, at 80 DEG C, stir with 1000 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1.5 hours, discharging, at 105 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 5 hours.
Embodiment 16
Under 2300 revs/min of stir speed (S.S.)s by 0.5g dodecyl benzyl dimethyl ammonium chloride, 1g castor oil polyoxyethylene ether, 1.5g alkylphenol polyoxyethylene and 20g silicone oil of carboxyl mix and blend 30 minutes, then divide 6 times and add 55g distilled water, add-on is 5g for the first time, be 10g each time later, every minor tick 40 minutes, obtains organosilicon emulsion.Attapulgite is cleaned in water and skim upper strata impurity, at 110 DEG C, dry, grind, cross 300 mesh sieves and obtain attapulgite powder.In stirring tank, add 100g attapulgite powder, at 80 DEG C, stir with 1000 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 2 hours, discharging, at 135 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 17
Under 2800 revs/min of stir speed (S.S.)s, by 2g sodium laurylsulfonate and 15g ethyl silicon oil mix and blend 20 minutes, then divide 4 times and add 40g distilled water, every minor tick 40 minutes, obtains organosilicon emulsion.Kaolin, attapulgite, wilkinite and illite soil are cleaned and skim upper strata impurity in water, at 110 DEG C, dry, grind, cross 100 mesh sieves and obtain kaolin powder, attapulgite powder, bentonite in powder and illite soil powder.In stirring tank, add 10g kaolin powder, 10g attapulgite powder, 10g bentonite in powder and 40g illite soil powder stir with 500 revs/min of speed at 60 DEG C; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 2 hours, discharging, at 160 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 3 hours.
Embodiment 18
Under 2800 revs/min of stir speed (S.S.)s, by 2.5g sodium laurylsulfonate, 2.5g methyl-silicone oil and 2.5g ethyl silicon oil mix and blend 30 minutes, then divide 4 times and add 25g distilled water, every minor tick 30 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 150 DEG C, dry, grind, cross 300 mesh sieves and obtain kaolin powder.In stirring tank, add 50g kaolin powder, at 50 DEG C, stir with 800 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1 hour, discharging, at 200 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 2 hours.
Embodiment 19
Under 2800 revs/min of stir speed (S.S.)s, by 1.5g sodium laurylsulfonate, 0.5g Dodecyl trimethyl ammonium chloride and 10g ethyl silicon oil mix and blend 20 minutes, then divide 5 times and add 50g distilled water, every minor tick 60 minutes, obtains organosilicon emulsion.Kaolin is cleaned in water and skim upper strata impurity, at 100 DEG C, dry, grind, cross 100 mesh sieves and obtain kaolin powder.In stirring tank, add 40g kaolin powder, at 20 DEG C, stir with 350 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 1 hour, discharging, at 80 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 2 hours.
Embodiment 20
Under 3000 revs/min of stir speed (S.S.)s, by 5g sodium laurylsulfonate and 10g ethyl silicon oil mix and blend 20 minutes, then divide 6 times and add 30g distilled water, every minor tick 40 minutes, obtains organosilicon emulsion.Illite soil is cleaned and skimmed in water upper strata impurity, at 120 DEG C, dry, grind, cross 100 mesh sieves and obtain illite soil powder.In stirring tank, add 50g illite soil powder, at 30 DEG C, stir with 350 revs/min of speed; The organosilicon emulsion atomized spray of above-mentioned preparation is added in the clay of stirring, treat that organosilicon emulsion adds complete, continue to stir 0.5 hour, discharging, at 160 DEG C, thermal treatment can obtain organosilicon emulsion modified clay in 5 hours.
Claims (5)
1. a method for organosilicon emulsion modified clay, comprises the following steps:
Step 1, under 1000～3000 revs/min of stir speed (S.S.)s by tensio-active agent and silicone oil 1:8～1:2 mix and blend 10～100 minutes in mass ratio, then divide the distilled water that adds silicone oil quality 150～550% for 4～6 times, obtain organosilicon emulsion; Described tensio-active agent is ionogenic surfactant or nonionic surface active agent, or the mixing of two class tensio-active agents; Ionogenic surfactant comprises one or more of sodium laurylsulfonate, Dodecyl trimethyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, and nonionic surface active agent comprises one or more of the smooth monostearate of sorb, sorbitan monooleate, polyoxyethylene sorbitan oleic acid ester, polyoxyethylene sorbitan stearate, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene;
Step 2, in stirring tank, add clay, wherein stirring tank temperature is 10～80 DEG C, stir speed (S.S.) is 350～2500 revs/min, the organosilicon emulsion obtaining in step 1 is evenly joined in the clay of high speed dispersion simultaneously, the clay wherein adding and organosilicon emulsion mass ratio are 0.45:1～5.5:1, treat that organosilicon emulsion adds complete, continue to stir 0.5～2 hour, after discharging, obtain organosilicon emulsion modified clay through thermal treatment, wherein 80～200 DEG C of thermal treatment temps, heat treatment time is 1～5 hour.
2. the method for organosilicon emulsion modified clay according to claim 1, is characterized in that, described silicone oil is one or more in methyl-silicone oil, ethyl silicon oil, phenyl silicone oil, amido silicon oil, hydroxy silicon oil, silicone oil of carboxyl.
3. the method for organosilicon emulsion modified clay according to claim 1, is characterized in that, in the organosilicon emulsion preparation process described in step 1, add the timed interval of distilled water is 20～60 minutes at every turn.
4. the method for organosilicon emulsion modified clay according to claim 1, it is characterized in that, clay described in step 2 comprises one or more mixing in attapulgite, kaolin, montmorillonite soil, illite soil, wilkinite, before use, in water, clean in advance and skim upper strata impurity, at 100～150 DEG C, dry, grind, cross 100～500 mesh sieves.
5. the method for organosilicon emulsion modified clay according to claim 1, is characterized in that, the mode that adds of organosilicon emulsion described in step 2 is atomized spray.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310060783.8A CN103113763B (en) | 2013-02-26 | 2013-02-26 | Method for modifying clay by using organic silicon micro-emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310060783.8A CN103113763B (en) | 2013-02-26 | 2013-02-26 | Method for modifying clay by using organic silicon micro-emulsion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103113763A CN103113763A (en) | 2013-05-22 |
| CN103113763B true CN103113763B (en) | 2014-08-20 |
Family
ID=48412186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310060783.8A Expired - Fee Related CN103113763B (en) | 2013-02-26 | 2013-02-26 | Method for modifying clay by using organic silicon micro-emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103113763B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104275213B (en) * | 2013-07-08 | 2016-09-14 | 中国科学院大连化学物理研究所 | There is the preparation method of the amine bridging organic silicon nano spherical particles of hydrophobic performance |
| CN104448950A (en) * | 2014-11-06 | 2015-03-25 | 中国科学院合肥物质科学研究院 | Preparation method of hydrophobic attapulgite |
| CN104559786B (en) * | 2014-12-24 | 2017-04-19 | 中国科学院合肥物质科学研究院 | Preparation method of hydrophobic self-cleaning coating |
| CN106280376A (en) * | 2016-08-30 | 2017-01-04 | 韦荣群 | A kind of ageing-resistant composite based on modified alta-mud |
| CN106518032B (en) * | 2016-11-25 | 2018-04-06 | 贵州欧玛陶瓷有限责任公司 | A kind of water-permeable brick and preparation method thereof |
| CN106915752A (en) * | 2017-04-12 | 2017-07-04 | 明光市国星凹土有限公司 | One kind increase hydrophobic method of attapulgite |
| CN108250454A (en) * | 2018-01-05 | 2018-07-06 | 芜湖维软新材料有限公司 | A kind of preparation method of silicone oil emulsion |
| CN110698809A (en) * | 2019-11-28 | 2020-01-17 | 青岛中新华美塑料有限公司 | Anti-aging and anti-impact composite material and preparation method thereof |
| CN115777704B (en) * | 2023-02-08 | 2023-04-28 | 潍坊市种子有限公司 | Drought-resistant seed coating agent and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5952095A (en) * | 1996-12-06 | 1999-09-14 | Amcol International Corporation | Intercalates and exfoliates formed with long chain (C10 +) monomeric organic intercalant compounds; and composite materials containing same |
| CN102627873A (en) * | 2012-03-27 | 2012-08-08 | 南京信息工程大学 | Method for modifying attapulgite clay |
-
2013
- 2013-02-26 CN CN201310060783.8A patent/CN103113763B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5952095A (en) * | 1996-12-06 | 1999-09-14 | Amcol International Corporation | Intercalates and exfoliates formed with long chain (C10 +) monomeric organic intercalant compounds; and composite materials containing same |
| CN102627873A (en) * | 2012-03-27 | 2012-08-08 | 南京信息工程大学 | Method for modifying attapulgite clay |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103113763A (en) | 2013-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103113763B (en) | Method for modifying clay by using organic silicon micro-emulsion | |
| CN102874825B (en) | Compound modification method for clay | |
| CN103787605B (en) | Modification method of rubber particles and modified rubber concrete | |
| CN104710661A (en) | carboxy terminated nitrile rubber/graphene nanocomposite and preparation method thereof | |
| CN103525099B (en) | Compound asphalt emulsifier containing Gemini surface active agent | |
| CN108440207A (en) | A kind of composite soil conditioner and preparation method thereof suitable for Coal Mine soil | |
| CN105968777A (en) | Antistatic composite nano material film and preparation method thereof | |
| CN106633195B (en) | Nano-cellulose/clay transparent nano-composite material and preparation method thereof | |
| CN103077765A (en) | Composite conducting material and preparation method thereof | |
| CN103194934A (en) | Preparation method of paper making sizing agent formed by emulsification of flaky solid particles | |
| CN102720067A (en) | Spinning oil for polyvinyl alcohol fiber in civil works | |
| CN108409984A (en) | A kind of method that Fast synchronization prepares lignin nanoparticle and carbon quantum dot | |
| CN104710660A (en) | Preparation method of carbon nano tube intercalated montmorillonite reinforced oil-filled latex co-coagulating rubber | |
| CN103881728A (en) | Planting soil improvement material for coastal chlorine salt soft soil matrix | |
| CN110358315A (en) | A kind of preparation method of core-shell structure epoxy resin modified asphalt lotion | |
| CN102516626A (en) | Antistatic waste plastic and preparation method thereof | |
| CN108912580A (en) | The preparation method of copper nanometer rods enhancing pitch planted roof root resistance material | |
| CN106006775B (en) | A kind of dedicated sewage-treating agent of rubber processing and preparation method thereof | |
| CN109181095A (en) | A kind of antistatic polypropylene material and preparation method thereof | |
| CN108795106A (en) | A kind of activated earth and preparation method thereof | |
| CN104130593B (en) | Calcium carbonate of a kind of hydrophobic oleophilic oil surface modification and preparation method thereof | |
| CN103290832B (en) | Hydrophobic sand preparation method adopting wax and sand as raw materials | |
| CN105153714A (en) | Animal and plant-based nano-liquid barrier material and preparation method thereof | |
| CN110684263A (en) | Degradable film material and preparation method thereof | |
| CN109749646A (en) | A kind of antibacterial Single layer nonwoven cloth rubber belt |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: NANTONG MATERIAL ENGINEERING TECHNOLOGY RESEARCH I Free format text: FORMER OWNER: INSTITUTE OF MATERIAL ENGINEERING TECHNOLOGY OF NANTONG NANJING UNIVERSITY Effective date: 20150420 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 226000 NANTONG, JIANGSU PROVINCE TO: 226019 NANTONG, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20150420 Address after: 226019 Jiangsu Province, Nantong City Chongchuan District Chongchuan Road No. 58, building 1, room 1002 Patentee after: Nantong Nanjing University Material Engineering Technology Research Institute Address before: Jiangsu province Nantong City Road 226000, No. 58, Nantong science and Technology Park Building 1, 9 floor Patentee before: Institute of Material Engineering Technology of Nantong, Nanjing University |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140820 Termination date: 20210226 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |