CN103103816A - Embossing printing paste of pile fabric and preparation method - Google Patents
Embossing printing paste of pile fabric and preparation method Download PDFInfo
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- CN103103816A CN103103816A CN2012105396059A CN201210539605A CN103103816A CN 103103816 A CN103103816 A CN 103103816A CN 2012105396059 A CN2012105396059 A CN 2012105396059A CN 201210539605 A CN201210539605 A CN 201210539605A CN 103103816 A CN103103816 A CN 103103816A
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Abstract
The invention discloses an embossing printing paste of a pile fabric. The embossing printing paste comprises the following components in parts by weight: 1.8 to 2.2 parts of fatty alcohol-polyoxyethylene ether, 9.8 to 10.3 parts of dimethylacrylicacid tetraethylene glycol ester, 340 to 350 parts of butyl acrylate, 70 to 72 parts of ethyl acrylate, 41 to 43 parts of acrylonitrile, 18 to 20 parts of itaconic acid, 1.7 to 2 parts of ammonium persulfate, 530 to 580 parts of deionized water, and 18 to 21 parts of thickening agent. The invention also provides a preparation method of the embossing printing paste of the pile fabric. The preparation method comprises the following technological steps: (1) emulsifying; (3) initiating polymerization reaction; and (3) thickening. According to the embossing printing paste of the pile fabric and the preparation method, the embossing printing paste is high in transparence, free from yellowing at high temperature, excellent in firmness, soft in hand feel, bright in color and free from formaldehyde and APEO (Alkylphenol Ethoxylates), so that the environment protection requirement is met, and the production process is simple.
Description
Technical field
The present invention relates to the printing paste field, be specifically related to a kind of pile fabrics embossing slurry and preparation method.
Background technology
Pile fabrics comprises the multiple types such as textile corduroy, polyester raschel blanket, coral suede.Pile fabrics has the uniqueness of self, and the stamp deep processing can be merged aesthetic on fabric, makes it to become a complete stamp suede series products, thereby improves the fabric class, increases added value.The embossing special printing quality that to be pile fabrics have through stamp oven dry set with special printing paste, technological process is: the stamp → baking of embossing slurry to eighty per cant dried → 30-70 ton calender temperature at 100-120 ℃ of calendering → brushing → finished product.Fabric through embossing reflects third dimension and sense modelled after an antique, and concave-convex effect is very outstanding, and sunk decorative pattern clear-cut fineness is good, presents gorgeous gloss, and outstanding fine hair gloss is soft, gives people with different visual effects.It is good that this just requires embossing slurry product that stamp uses to have transparency, and high temperature is xanthochromia not, and fastness is good, and feel is soft, and is bright-colored, formaldehydeless, meet environmental requirement without APEO.At present on embossing slurry market, the use of opinion is arranged, as the TX product of BASF AG, but result of use and imperfect, also there are no the open source information of correlation technique.
Summary of the invention
The object of the present invention is to provide a kind of pile fabrics embossing slurry and preparation method, transparency is good, and high temperature is xanthochromia not, and fastness is good, and feel is soft, and is bright-colored, and is formaldehydeless, meet environmental requirement without APEO, and production technology is simple.
For achieving the above object, the invention provides a kind of pile fabrics embossing slurry, its composition and content are:
Fatty alcohol-polyoxyethylene ether 1.8-2.2 weight portion, dimethacrylate TEG ester 9.8-10.3 weight portion, butyl acrylate 340-350 weight portion, ethyl acrylate 70-72 weight portion, acrylonitrile 41-43 weight portion, itaconic acid 18-20 weight portion, ammonium persulfate 1.7-2 weight portion, deionized water 530-580 weight portion, thickener 18-21 weight portion.
For achieving the above object, the present invention also provides the preparation method of above-mentioned pile fabrics embossing slurry, comprises following processing step:
(1) emulsification: add fatty alcohol-polyoxyethylene ether 1.8-2.2 weight portion, dimethacrylate TEG ester 9.8-10.3 weight portion, butyl acrylate 340-350 weight portion, ethyl acrylate 70-72 weight portion, acrylonitrile 41-43 weight portion, itaconic acid 18-20 weight portion, deionized water 500-550 weight portion in the stainless steel still, stirring and emulsifying 20 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount and add in reactor, be warming up to 78 ℃-81 ℃, the mixed liquor that adds initiator ammonium persulfate 1.16 weight portions and deionized water 15 weight portions, 78 ℃-81 ℃ reactions 10 minutes, then drip remaining emulsion at 78 ℃ of-81 ℃ of temperature, drip simultaneously ammonium persulfate 0.54-0.84 weight portion and deionized water 15 weight portion mixed liquors, dropwised in 1-2 hour, 78 ℃-81 ℃ insulations 2-3 hour, then being cooled to 35 ℃-45 ℃, is 25% ammoniacal liquor adjust pH 7 ± 0.3 with mass percent concentration;
(3) thickening: add thickener 18-21 weight portion, the stirring thickening is even, filters discharging and gets product.
Advantage of the present invention and beneficial effect are: a kind of pile fabrics embossing slurry and preparation method, and transparency is good, and high temperature is xanthochromia not, and fastness is good, and feel is soft, and is bright-colored, formaldehydeless, meet environmental requirement without APEO, and production technology is simple.
The specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.Following examples only are used for technical scheme of the present invention more clearly is described, and can not limit protection scope of the present invention with this.
Embodiment 1
A kind of pile fabrics embossing slurry, its composition and content are:
Fatty alcohol-polyoxyethylene ether 2 weight portions, dimethacrylate TEG ester 10 weight portions, butyl acrylate 345 weight portions, ethyl acrylate 71 weight portions, acrylonitrile 42 weight portions, itaconic acid 19 weight portions, ammonium persulfate 1.9 weight portions, deionized water 550 weight portions, thickener 20 weight portions.
The preparation method of above-mentioned pile fabrics embossing slurry comprises following processing step:
(1) emulsification: add fatty alcohol-polyoxyethylene ether 2 weight portions, dimethacrylate TEG ester 10 weight portions, butyl acrylate 345 weight portions, ethyl acrylate 71 weight portions, acrylonitrile 42 weight portions, itaconic acid 19 weight portions, deionized water 520 weight portions in the stainless steel still, stirring and emulsifying 20 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount and add in reactor, be warming up to 79 ℃, the mixed liquor that adds initiator ammonium persulfate 1.16 weight portions and deionized water 15 weight portions, 79 ℃ of reactions 10 minutes, then drip remaining emulsion at 79 ℃ of temperature, drip simultaneously ammonium persulfate 0.74 weight portion and deionized water 15 weight portion mixed liquors, 1.5 hour dropwise, 79 ℃ of insulations 2.5 hours, then being cooled to 40 ℃, is 25% ammoniacal liquor adjust pH 7.1 with mass percent concentration;
(3) thickening: add thickener 20 weight portions, the stirring thickening is even, filters discharging and gets product.
Embodiment 2
A kind of pile fabrics embossing slurry, its composition and content are:
Fatty alcohol-polyoxyethylene ether 1.8 weight portions, dimethacrylate TEG ester 9.8 weight portions, butyl acrylate 340 weight portions, ethyl acrylate 70 weight portions, acrylonitrile 41 weight portions, itaconic acid 18 weight portions, ammonium persulfate 1.7 weight portions, deionized water 530 weight portions, thickener 18 weight portions.
The preparation method of above-mentioned pile fabrics embossing slurry comprises following processing step:
(1) emulsification: add fatty alcohol-polyoxyethylene ether 1.8 weight portions, dimethacrylate TEG ester 9.8 weight portions, butyl acrylate 340 weight portions, ethyl acrylate 70 weight portions, acrylonitrile 41 weight portions, itaconic acid 18 weight portions, deionized water 500 weight portions in the stainless steel still, stirring and emulsifying 20 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount and add in reactor, be warming up to 78 ℃, the mixed liquor that adds initiator ammonium persulfate 1.16 weight portions and deionized water 15 weight portions, 78 ℃ of reactions 10 minutes, then drip remaining emulsion at 78 ℃ of temperature, drip simultaneously ammonium persulfate 0.54 weight portion and deionized water 15 weight portion mixed liquors, dropwised in 1 hour, 78 ℃ of insulations 2 hours, then be cooled to 35 ℃, be 25% ammoniacal liquor adjust pH 6.7 with mass percent concentration;
(3) thickening: add thickener 18 weight portions, the stirring thickening is even, filters discharging and gets product.
Embodiment 3
A kind of pile fabrics embossing slurry, its composition and content are:
Fatty alcohol-polyoxyethylene ether 2.2 weight portions, dimethacrylate TEG ester 10.3 weight portions, butyl acrylate 350 weight portions, ethyl acrylate 72 weight portions, acrylonitrile 43 weight portions, itaconic acid 20 weight portions, ammonium persulfate 2 weight portions, deionized water 580 weight portions, thickener 21 weight portions.
The preparation method of above-mentioned pile fabrics embossing slurry comprises following processing step:
(1) emulsification: add fatty alcohol-polyoxyethylene ether 2.2 weight portions, dimethacrylate TEG ester 10.3 weight portions, butyl acrylate 350 weight portions, ethyl acrylate 72 weight portions, acrylonitrile 43 weight portions, itaconic acid 20 weight portions, deionized water 550 weight portions in the stainless steel still, stirring and emulsifying 20 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount and add in reactor, be warming up to 81 ℃, the mixed liquor that adds initiator ammonium persulfate 1.16 weight portions and deionized water 15 weight portions, 81 ℃ of reactions 10 minutes, then drip remaining emulsion at 81 ℃ of temperature, drip simultaneously ammonium persulfate 0.84 weight portion and deionized water 15 weight portion mixed liquors, dropwised in 2 hours, 81 ℃ of insulations 3 hours, then be cooled to 45 ℃, be 25% ammoniacal liquor adjust pH 7.3 with mass percent concentration;
(3) thickening: add thickener 21 weight portions, the stirring thickening is even, filters discharging and gets product.
The above is only the preferred embodiment of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (2)
1. a pile fabrics embossing slurry, is characterized in that, its composition and content are:
Fatty alcohol-polyoxyethylene ether 1.8-2.2 weight portion, dimethacrylate TEG ester 9.8-10.3 weight portion, butyl acrylate 340-350 weight portion, ethyl acrylate 70-72 weight portion, acrylonitrile 41-43 weight portion, itaconic acid 18-20 weight portion, ammonium persulfate 1.7-2 weight portion, deionized water 530-580 weight portion, thickener 18-21 weight portion.
2. the preparation method of pile fabrics embossing slurry claimed in claim 1, is characterized in that, comprises following processing step:
(1) emulsification: add fatty alcohol-polyoxyethylene ether 1.8-2.2 weight portion, dimethacrylate TEG ester 9.8-10.3 weight portion, butyl acrylate 340-350 weight portion, ethyl acrylate 70-72 weight portion, acrylonitrile 41-43 weight portion, itaconic acid 18-20 weight portion, deionized water 500-550 weight portion in the stainless steel still, stirring and emulsifying 20 minutes is made emulsion;
(2) initiated polymerization: get 20% of emulsion total amount and add in reactor, be warming up to 78 ℃-81 ℃, the mixed liquor that adds initiator ammonium persulfate 1.16 weight portions and deionized water 15 weight portions, 78 ℃-81 ℃ reactions 10 minutes, then drip remaining emulsion at 78 ℃ of-81 ℃ of temperature, drip simultaneously ammonium persulfate 0.54-0.84 weight portion and deionized water 15 weight portion mixed liquors, dropwised in 1-2 hour, 78 ℃-81 ℃ insulations 2-3 hour, then being cooled to 35 ℃-45 ℃, is 25% ammoniacal liquor adjust pH 7 ± 0.3 with mass percent concentration;
(3) thickening: add thickener 18-21 weight portion, the stirring thickening is even, filters discharging and gets product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012105396059A CN103103816A (en) | 2012-12-14 | 2012-12-14 | Embossing printing paste of pile fabric and preparation method |
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| CN2012105396059A CN103103816A (en) | 2012-12-14 | 2012-12-14 | Embossing printing paste of pile fabric and preparation method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103526595A (en) * | 2013-10-23 | 2014-01-22 | 合肥聚合辐化技术有限公司 | Active pigment resin printing imitation binder and preparation method for same |
| CN107630284A (en) * | 2017-10-31 | 2018-01-26 | 宿迁市神龙家纺有限公司 | A kind of elastic force embossing warp knitted blanket and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102619102A (en) * | 2012-04-06 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
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- 2012-12-14 CN CN2012105396059A patent/CN103103816A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102619102A (en) * | 2012-04-06 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103526595A (en) * | 2013-10-23 | 2014-01-22 | 合肥聚合辐化技术有限公司 | Active pigment resin printing imitation binder and preparation method for same |
| CN107630284A (en) * | 2017-10-31 | 2018-01-26 | 宿迁市神龙家纺有限公司 | A kind of elastic force embossing warp knitted blanket and preparation method thereof |
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Application publication date: 20130515 |