CN103102803A - Aromatic hydrocarbon free antiseptic flow of metal structure - Google Patents
Aromatic hydrocarbon free antiseptic flow of metal structure Download PDFInfo
- Publication number
- CN103102803A CN103102803A CN2012105396947A CN201210539694A CN103102803A CN 103102803 A CN103102803 A CN 103102803A CN 2012105396947 A CN2012105396947 A CN 2012105396947A CN 201210539694 A CN201210539694 A CN 201210539694A CN 103102803 A CN103102803 A CN 103102803A
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- China
- Prior art keywords
- aromatic hydrocarbons
- flow process
- metal construction
- anticorrosion
- anticorrosion flow
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- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses an aromatic hydrocarbon free antiseptic flow of a metal structure. The flow comprises the following steps of: mixing the components such as siloxane, a solvent, silicon dioxide particles, a rare earth compound, deionized water, a catalyst, carbon fiber and polyimide, and curing the components; then filtering the cured mixture; spraying, brush coating or dipping on the surface of a base material; and forming a coating on the surface of the base material after deposition to realize surface antiseptic treatment.
Description
Technical field
The present invention relates to a kind of metal construction without the anticorrosion flow process of aromatic hydrocarbons, relate in particular to a kind of metal structure surface that is applicable to, have the coating method of the environmental protection coating material of excellent gloss and mechanical and physical performance and aromatic free solvent.
Background technology
In modern industry and daily life, corrosion of metal is seen everywhere, and the destruction of the forms such as crevice corrosion, stress corrosion and corrosion fatigue that especially occur in the storage vessel of a fuel oil dangerization product is caused great potential safety hazard for people's lives.
The metal protection method that adopts at present can roughly be divided three classes: a class is to carry out anodic oxidation treatment, namely form the anode oxide film of one deck tens micron thickness in the metallic surface, but because the anode oxidation process power consumption is large, and electrolyte solution is seriously polluted, be difficult to process, use its application to be restricted; Equations of The Second Kind is chemical conversion film, being about to metal parts is immersed in the solution of definite composition, rely at a certain temperature chemical reaction to form one deck chemical conversion film, now most widely used is the oxidation of chromic salt chemistry, but chromic salt is a kind of carcinogenic toxicant, and the world environments protective tissue has proposed restriction and used chromic salt and other to contain chromate compound; The 3rd class is organic coating, namely applies one deck organic coating in the metallic surface, with outward appearance and the physical and chemical performance that improves metal.People begin rare earth element is used in the aseptic technic of metallic surface in recent years.
The rare-earth conversion coatings film technique develops into today, and people have carried out a large amount of improvement to various film-forming process, and the performance of film also is improved.At present the rare-earth conversion coatings technology is mainly immersion treatment, and this technological operation is simple, be easy to safeguard; But its drawback is, the long period of soaking process treatment time is oversize, and formed rete is thinner and relatively poor with the sticking power of base material.Find through long-term exploratory development, add strong oxidizer in soaking solution, as H
2O
2, KMnO
4, (NH
4)
2S
2O
8Etc. strong oxide compound, rate of film build is improved greatly, the treatment time shortens dramatically, and the treatment soln temperature is not high yet simultaneously, can at room temperature use.But make the less stable for the treatment of process due to the existence of strong oxidizer.
The problem that exists in order to solve the rare-earth conversion coatings treatment process, the present invention proposes a kind of improved protective system coating method.This method anticorrosion with low cost, remarkable in economical benefits can be carried out normal temperature and be spread, and coating processes is simple, and solution is environment friendly and pollution-free.
Summary of the invention
The objective of the invention is for the deficiencies in the prior art part, provide a kind of environment protection metal structure without the anticorrosion flow process of aromatic hydrocarbons, in order to solve the protection against corrosion difficult problem of the surfaces externally and internally applications such as steel, aluminium, especially aluminium alloy, and coating aromatic free solvent, do not contain strong oxidizer, without poisonous pigment, be fit to various constructional methods, application is not subject to seasonal restrictions, and construction technology is simple and convenient, and technical costs is cheap, good environmental protection.
The present invention is achieved by the following technical solutions:
(1) prepare following component (mass parts):
A vinyltriethoxysilane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 6-10 of d cerium;
E deionized water 5-25;
F acetic acid 4-6;
G carbon fiber 5-7;
H polyimide 1-3;
(2) with carrying out maturation process after above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after deposition, realize the surface anticorrosion processing.
Embodiment
The present invention relates to metal construction without the anticorrosion flow process of aromatic hydrocarbons, carry out maturation process after the various components of protective system are mixed, then the mixture after slaking is filtered, then spray, brush or be immersed in substrate surface, form coating at substrate surface after deposition, realize the surface anticorrosion processing.
Described SiO
2The particle diameter of particle is the 50-100 nanometer.
Described maturation process is standing 50-60 hour at normal temperatures.
Described base material is steel or aluminium, preferred aluminium alloy.
Heat in deposition process after spraying, brushing or dipping, Heating temperature is to heat 1 minute to 1 hour at 50 ℃ to 150 ℃ temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush forms coating at substrate surface.
Protective system coating method disclosed by the invention is simple, convenient, quick, reliable, and raw material is cheap, this method can be simply in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of substrate material, substantially need not to carry out other adjustment on equipment, is the Eco-power production technique of a kind of height.
The below elaborates with embodiment to the present invention, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) prepare following component (mass parts):
A vinyltriethoxysilane 1;
B propyl alcohol 40;
C SiO
2Particle 1;
The oxide compound 6 of d cerium;
E deionized water 5;
F acetic acid 4;
G carbon fiber 5;
H polyimide 1;
(2) with carrying out maturation process after above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after deposition, realize the surface anticorrosion processing.
Embodiment 2
(1) prepare following component (mass parts):
A vinyltriethoxysilane 10;
B propyl alcohol 60;
C SiO
2Particle 5;
The oxide compound 10 of d cerium;
E deionized water 25;
F acetic acid 6;
G carbon fiber 7;
H polyimide 3;
(2) with carrying out maturation process after above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after deposition, realize the surface anticorrosion processing.
Embodiment 3
(1) prepare following component (mass parts):
A vinyltriethoxysilane 5;
B propyl alcohol 50;
C SiO
2Particle 3;
The oxide compound 8 of d cerium;
E deionized water 15;
F acetic acid 5;
G carbon fiber 6;
H polyimide 2;
(2) with carrying out maturation process after above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after deposition, realize the surface anticorrosion processing.
Claims (9)
- Metal construction without the anticorrosion flow process of aromatic hydrocarbons, comprising:(1) prepare following component (mass parts):A vinyltriethoxysilane 1-10;B propyl alcohol 40-60;C SiO 2Particle 1-5;The oxide compound 6-10 of d cerium;E deionized water 5-25;F acetic acid 4-6;G carbon fiber 5-7;H polyimide 1-3;(2) with carrying out maturation process after the said components mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after deposition, realize the surface anticorrosion processing.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that described SiO 2The particle diameter of particle is the 50-100 nanometer.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, described maturation process is standing 50-60 hour at normal temperatures.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, described base material is steel or aluminium.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, described base material is aluminium alloy.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, heat in described deposition process, Heating temperature is 50 ℃ to 150 ℃, 1 minute to 1 hour heat-up time.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, described coat-thickness is 1 micron to 10 microns.
- According to claim 7 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, described coat-thickness is 1 micron to 5 microns.
- According to claim 1 metal construction without the anticorrosion flow process of aromatic hydrocarbons, it is characterized in that, adopt spraying in described step (2) or the method for brushing forms coating at substrate surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105396947A CN103102803A (en) | 2012-12-14 | 2012-12-14 | Aromatic hydrocarbon free antiseptic flow of metal structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105396947A CN103102803A (en) | 2012-12-14 | 2012-12-14 | Aromatic hydrocarbon free antiseptic flow of metal structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103102803A true CN103102803A (en) | 2013-05-15 |
Family
ID=48311017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105396947A Pending CN103102803A (en) | 2012-12-14 | 2012-12-14 | Aromatic hydrocarbon free antiseptic flow of metal structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103102803A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717930A (en) * | 2009-12-25 | 2010-06-02 | 华烁科技股份有限公司 | Environment-friendly nano water-based silane treatment agent capable of improving anti-corrosion performance of metal surface |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for hot forming and process for the production thereof |
-
2012
- 2012-12-14 CN CN2012105396947A patent/CN103102803A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717930A (en) * | 2009-12-25 | 2010-06-02 | 华烁科技股份有限公司 | Environment-friendly nano water-based silane treatment agent capable of improving anti-corrosion performance of metal surface |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for hot forming and process for the production thereof |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130515 |