CN103102213A - Preparation method of special long-term slow-release compound fertilizer for wheat - Google Patents
Preparation method of special long-term slow-release compound fertilizer for wheat Download PDFInfo
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- CN103102213A CN103102213A CN2012105743711A CN201210574371A CN103102213A CN 103102213 A CN103102213 A CN 103102213A CN 2012105743711 A CN2012105743711 A CN 2012105743711A CN 201210574371 A CN201210574371 A CN 201210574371A CN 103102213 A CN103102213 A CN 103102213A
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Abstract
The invention discloses a preparation method of a special long-term slow-release compound fertilizer for wheat, and belongs to a mixture of a plurality of fertilizers and components without special fertilizer effects. The special long-term slow-release compound fertilizer is characterized by comprising the following materials in parts by weight: 21-47 parts of urea, 8-15 parts of ammonium sulfate, 10-30 parts of potassium sulphate, 20-35 parts of mixed phosphorus fertilizer, 0.1-0.5 part of iron, manganese, boron, copper, zinc and molybdenum additives, 6-12 parts of a granulation additive, and a proper amount of water. The preparation method comprises the following steps of (1) preparing compound of potash fertilizer and nitrogenous fertilizer; (2) preparing the mixed phosphorus fertilizer; (3) preparing mixed particles of each component of the compound fertilizer; (4) coating stearic acid; (5) applying a modified zeolite powder material; (6) screening, metering, quality checking, and packaging after the fertilizer is qualified. The preparation method of the special long-term slow-release compound fertilizer for wheat, which is overall in nutrition and excellent in slow-release property, and can fully meet the requirements of the wheat on nutrients, exerts the efficacy of the fertilizer to the maximal extent, can improve the yield of the wheat, can improve the quality, saves the resources and protects the environment is provided.
Description
Technical field
The present invention is the preparation method of the sustained-release long-acting compound fertilizer of a grow wheat special use.Belong to multiple fertilizer with without the mixture of special fertilizer efficiency component.
Background technology
Wheat is important food crop and cash crop, has statistics to show, its output and cultivated area are only second to paddy rice, occupy the second place of the world.Occupy critical role in the people's livelihood and national economy.Effectively utilize the Limited Land resource, the yield and quality that improves wheat crop is people's direction of making great efforts and eternal problem.
The nutritive element that Growth of Wheat need to absorb is kind more than 20 nearly, mainly contains nitrogen, phosphorus, three kinds of macroelement of potassium; The major elements such as Calcium Magnesium Sulphur and iron, manganese, boron, copper.The trace element such as zinc, molybdenum.These nutritive elements mainly provide by soil from fertilizer.
The high-quality nitrogenous fertilizer that urea is nitrogenous height, fertilizer efficiency is fast, consumption is large.But, urea in use, easily run off by approach such as volatilization, leaching, decomposition and runoffs, cause the fertilizer efficiency utilization ratio not high, according to statistics, the this season utilization ratio only has 30% left and right, and this has not only caused the waste of chemical fertilizer, and the environment of depending on for existence for mankind such as atmosphere, water body soil.
Chinese patent application number 201110021688.8 " biodegradable coated ureas " of Shikefeng Chemical Industry Co., Ltd.'s application have successfully solved the above problem that urea nitrogenous fertilizer exists, the stearic acid that utilization can be degraded under the soil microorganisms effect is as the coated fertilizer of nitrogenous fertilizer urea, provide a kind of coated fertilizer biodegradable, pollution-free, can improve again the biodegradable coated urea product of the utilization ratio of fertilizer.But it is a kind of high-quality nitrogenous fertilizer, and nutritive ingredient is single, can not be as the slow release fertilizer that is suitable for wheat planting and uses.
Phosphorus is the important composition element of cytoplasmic biomolecule, is also the requisite a kind of element of plant-growth.Phosphatic rock is the main raw mineral materials of making phosphate fertilizer and extracting phosphorus and compound thereof; But make the P in phosphate fertilizer requirement phosphatic rock
2O
5〉=28%; Extract the phosphatic rock P that phosphorus and compound thereof require
2O
5Content higher.
And along with the development of phosphorus chemical product and Phosphate Fertilizer Industry, the ground phosphate rock requirement increases sharply, and the higher-grade phosphate rock resource is deficient.The mode of production that only depends on rich phosphorus ore can not meet the demands.In this case, the exploitation of the phosphatic rock resource that grade is not high, no matter for economizing on resources, or protection of the environment is all significant.
In sum, there is following deficiency in fertilizer specially for wheat material of the prior art:
1.. the multilayer coating, complex manufacturing, investment is large, production cost is high.
2. coated fertilizer hard degradation, life-time service can bring negative impact to soil; Even soil is polluted, affect the quality of agricultural-food.
3. the main nutrient elements proportioning in fertilizer is unreasonable, and the fertilizer efficiency utilization ratio is low.
4. lack necessary middle amount or trace element, the hypotrophy face affects the raising of output and wheat quality.
4. utilization rate of nitrogen fertilizer is low, waste resource, contaminate environment.
5. the preparation method of the sustained-release long-acting compound fertilizer of wheat special use is also rare.
Summary of the invention
The object of the invention is to avoid above-mentioned weak point of the prior art; and provide a kind of comprehensive nutrition; sustained release performance is excellent; can fully satisfy wheat to the demand of nutrient; bring into play to greatest extent the effect of fertilizer; can improve wheat yield and can improve again its quality, namely economize on resources, again the preparation method of the sustained-release long-acting compound fertilizer of the wheat special use of protection of the environment.
Purpose of the present invention can reach by following measure:
The preparation method of the sustained-release long-acting compound fertilizer of wheat special use of the present invention is characterized in that being made by following raw material according to the mass fraction meter:
Urea 21~47
Ammonium sulfate 8~15
Vitriolate of tartar 10~30
Mixed phosphorus fertilizer 20~35
Iron, manganese, boron, copper, zinc, molybdenum additives 0.1~0.5
Granulation aid 6~12
Water is appropriate
Wherein:
Described mixed phosphorus fertilizer is composited by diammonium phosphate, fused(calcium magnesium)phosphate and floats, its mass percent for example under:
Diammonium phosphate 30~50
Fused(calcium magnesium)phosphate 25~40
Floats 20~45
Described floats are P
2O
5The low grade rock phosphate of content between 10%~20%;
Described granulation aid is mixed by the bauxitic clay powder of 50%~75% wilkinite and 25%~50% and is formed;
Its preparation method comprises the steps:
1.. the preparation of potash fertilizer, nitrogenous fertilizer mixture
At first after urea 21~47 weight part heating and meltings, add ammonium sulfate 8~15 weight parts and vitriolate of tartar 10~30 weight parts to mix, make the potash fertilizer, the nitrogenous fertilizer mixture that contain potassium, sulphur, ammonium, standby;
2.. the mixed phosphorus fertilizer preparation
A. the preparation of floats
To contain P
2O
510%~20% phosphatic rock grinds, the fineness of floats is controlled 100 orders ± 10, and is standby;
B. mix
With floats 20~45 weight part mixings of diammonium phosphate 30~50 weight parts, fused(calcium magnesium)phosphate 25~40 weight parts and step a preparation, standby;
3.. the preparation of each component composite grain of compound manure
Mixed phosphorus fertilizer 20~35 weight parts that 2. potash fertilizer, nitrogenous fertilizer mixture and the step that 1. step is prepared prepare, iron, manganese, boron, copper.Zinc, molybdenum additives 0.1~0.5 weight part mix evenly, add granulating agent 6~12 weight parts, and water is appropriate.Utilize traditional tablets press with each component mixing granulation of described compound manure, standby;
4.. stearic acid is filmed
Stearic consumption is 0.6%~1.2% of each component composite grain quality of compound manure of 3. preparing of step, and coating method is as follows:
A.. the stearic preparation of melting
Coating after according to the formula accurate-metering, in input stearic acid fusion tank, is heated to molten state with stearic acid, and is standby;
B.. coating
3. each component composite grain of compound manure for preparing according to formula accurate-metering step, melting stearic acid with step a preparation carries out spraying outside particle in drum-type mixing granulation machine, makes the composite grain outside surface form coating as far as possible uniformly, warm air drying, room temperature wind are cooling, standby; Processing condition are as follows:
The warm air drying temperature is not higher than 80 ℃
The cooling draught temperature is not higher than 50 ℃;
5.. modified zeolite powder powder body material face powder
A. the face powder preparation of mixed powder
According to Magnesium Stearate 1.5%~3.0%, the proportioning raw materials of zeolite powder 97%~98.5% accurately takes respectively each component of raw material, mixes, and grinding flour is controlled powder fineness and crossed 120 mesh sieves, and is standby;
B. the coating of applying powder
The mixed powder consumption of step a preparation is controlled at each component composite grain face powder of every 1000kg compound manure 10~15kg;
6.. screening, metering, quality test, qualified rear packing makes the preparation method of the sustained-release long-acting compound fertilizer of wheat special use; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour.
Crop growth is except demand N, P, K nutritive element, and S, Ca are also that demand is large and are that plant generates indispensable nutritive element.Sulphur is the important composition that consists of protein, and calcium is being brought into play irreplaceable vital role to the rudiment of plant seed and the growth of organ.S, Ca element enter the compound manure component, all can produce positively effect at plant growth, prevention and elimination of disease and pests and improvement soil aspect many.
Element sulphur in composition of raw materials of the present invention adds with the form of soluble sulphate, and large percentage, and the fourth-largest nutritive element that plant growth is necessary is for wheat directly provides the sulphur nutrient.Phosphatic rock component in the formula mixed phosphorus fertilizer provides calcium constituent simultaneously except containing phosphoric, with other components in composition of raw materials, compatibility is good, is suitable for wheat growth.To improving output and the quality of wheat.Made contribution.
Purpose of the present invention can also reach by following measure:
The preparation method of the sustained-release long-acting compound fertilizer of wheat special use of the present invention is characterized in that being made by following raw material according to the mass fraction meter:
Urea 30~45
Ammonium sulfate 10~15
Vitriolate of tartar 10~30
Mixed phosphorus fertilizer 10~30
Iron, manganese, boron, copper.Zinc, molybdenum additives 0.1~0.5
Granulation aid 6~12
Water is appropriate
Wherein:
Described mixed phosphorus fertilizer is composited by diammonium phosphate, fused(calcium magnesium)phosphate and floats, its mass percent for example under:
Diammonium phosphate 35~45
Fused(calcium magnesium)phosphate 20~30
Floats 30~35.
It is preferred technical scheme.
The preparation method of the sustained-release long-acting compound fertilizer of wheat special use of the present invention is characterized in that being made by following raw material according to the mass fraction meter:
Urea 30
Ammonium sulfate 18
Vitriolate of tartar 22
Mixed phosphorus fertilizer 22
Iron, manganese, boron, copper.Zinc, molybdenum additives 0.5
Granulation aid 7.5
Water is appropriate
Wherein:
Described mixed phosphorus fertilizer is composited by diammonium phosphate, fused(calcium magnesium)phosphate and floats, its mass percent for example under:
Diammonium phosphate 45
Fused(calcium magnesium)phosphate 20
Floats 35
It is a preferred technical scheme.
Sustained-release long-acting compound fertilizer according to the wheat special use of preparation method's preparation of the sustained-release long-acting compound fertilizer of wheat special use of the present invention is characterized in that product reaches following technical indicator:
Application process according to the sustained-release long-acting compound fertilizer of the wheat special use of preparation method's preparation of the sustained-release long-acting compound fertilizer of wheat special use of the present invention is characterized in that trench digging imposes on below the earth's surface, base fertilizer: 40~50Kg/ mu; Topdress: 20~30Kg/ mu.
The preparation method of the sustained-release long-acting compound fertilizer of wheat special use of the present invention has following positively effect compared to existing technology:
1. a kind of comprehensive nutrition is provided; sustained release performance is excellent, can fully satisfy wheat to the demand of nutrient, brings into play to greatest extent the effect of fertilizer; can improve wheat yield and can improve again its quality, namely economize on resources, again the preparation method of the sustained-release long-acting compound fertilizer of the wheat special use of protection of the environment.
2. individual layer coating, generating process is simple, low equipment investment, production cost is low.
3. coated fertilizer can be degraded under the soil microorganisms effect, has avoided the pollution of coated fertilizer to edatope.
4. the main nutrient elements reasonable ratio in fertilizer, the element sulphur in composition of raw materials adds with the form of soluble sulphate, and large percentage, and the fourth-largest nutritive element that plant growth is necessary is for wheat directly provides the sulphur nutrient.The fertilizer efficiency utilization ratio is high, improves output and the quality of wheat.
5. adopt the raw material of low grade as fertilizer sources.The higher-grade phosphate rock resource of saves valuable.The while protection of the environment.
6. because of chloride ion-containing not, be used for the fertilizer specially for wheat material, have the effect of increasing production and improying productivity.Average mu volume increase 5.3%~12.4%.
Embodiment
The present invention will now be further detailed embodiment:
Embodiment 1
The sustained-release long-acting compound fertilizer for preparing in accordance with the following steps the wheat special use
Its preparation method comprises the steps:
1.. the preparation of potash fertilizer, nitrogenous fertilizer mixture
At first after urea 30 weight part heating and meltings, add ammonium sulfate 18 weight parts and vitriolate of tartar 22 weight parts to mix, make the potash fertilizer, the nitrogenous fertilizer mixture that contain potassium, sulphur, ammonium, standby;
2.. the mixed phosphorus fertilizer preparation
A. the preparation of floats
To contain P
2O
510%~20% phosphatic rock grinds, the fineness of floats is controlled 100 orders ± 10, and is standby;
B. mix
With the floats 35 weight part mixings of diammonium phosphate 45 weight parts, fused(calcium magnesium)phosphate 20 weight parts and step a preparation, standby;
3.. the preparation of each component composite grain of compound manure
Mixed phosphorus fertilizer 22 weight parts that 2. potash fertilizer, nitrogenous fertilizer mixture and the step that 1. step is prepared prepare, iron, manganese, boron, copper.Zinc, molybdenum additives 0.5 weight part mix evenly, add granulating agent 7.5 weight parts, and water is appropriate.Utilize traditional tablets press with each component mixing granulation of described compound manure, standby;
4.. stearic acid is filmed
Stearic consumption is 0.6%~1.2% of each component composite grain quality of compound manure of 3. preparing of step, and coating method is as follows:
A.. the stearic preparation of melting
Coating after according to the formula accurate-metering, in input stearic acid fusion tank, is heated to molten state with stearic acid, and is standby;
B.. coating
3. each component composite grain of compound manure for preparing according to formula accurate-metering step, melting stearic acid with step a preparation carries out spraying outside particle in drum-type mixing granulation machine, makes the composite grain outside surface form coating as far as possible uniformly, warm air drying, room temperature wind are cooling, standby; Processing condition are as follows:
The warm air drying temperature is not higher than 80 ℃
The cooling draught temperature is not higher than 50 ℃;
5.. modified zeolite powder powder body material face powder
A. the face powder preparation of mixed powder
According to Magnesium Stearate 1.5%~3.0%, the proportioning raw materials of zeolite powder 97%~98.5% accurately takes respectively each component of raw material, mixes, and grinding flour is controlled powder fineness and crossed 120 mesh sieves, and is standby;
B. the coating of applying powder
The mixed powder consumption of step a preparation is controlled at every 1000kg granular urea face powder 10~15kg;
6.. screening, metering, quality test, qualified rear packing makes the sustained-release long-acting compound fertilizer of wheat special use; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour;
Product reaches following technical indicator:
N constituent content % 〉=12
P
2O
5Content % 〉=6
K
2O content % 〉=8
Grain graininess mm 2~4.75mm
Moisture content wt%≤2.0.
Embodiment 2~embodiment 7
Method and step according to embodiment 1 prepare the sustained-release long-acting compound fertilizer of wheat special use according to the composition of raw materials of table 1
Table 1
The sustained-release long-acting compound fertilizer product particle outward appearance that makes the wheat special use is mellow and full, the product free from extraneous odour;
Product reaches following technical indicator:
Claims (5)
1. the preparation method of the sustained-release long-acting compound fertilizer of a grow wheat special use is characterized in that being made by following raw material according to the mass fraction meter:
Urea 21~47
Ammonium sulfate 8~15
Vitriolate of tartar 10~30
Mixed phosphorus fertilizer 20~35
Iron, manganese, boron, copper.Zinc, molybdenum additives 0.1~0.5
Granulation aid 6~12
Water is appropriate
Wherein:
Described mixed phosphorus fertilizer is composited by diammonium phosphate, fused(calcium magnesium)phosphate and floats, its mass percent for example under:
Diammonium phosphate 30~50
Fused(calcium magnesium)phosphate 25~40
Floats 20~45
Described floats are P
2O
5The low grade rock phosphate of content between 10%~20%;
Described granulation aid is mixed by the bauxitic clay powder of 50%~75% wilkinite and 25%~50% and is formed;
Its preparation method comprises the steps:
1.. the preparation of potash fertilizer, nitrogenous fertilizer mixture
At first after urea 21~47 weight part heating and meltings, add ammonium sulfate 8~15 weight parts and vitriolate of tartar 10~30 weight parts to mix, make the potash fertilizer, the nitrogenous fertilizer mixture that contain potassium, sulphur, ammonium, standby;
2.. the mixed phosphorus fertilizer preparation
A. the preparation of floats
To contain P
2O
510%~20% phosphatic rock grinds, the fineness of floats is controlled 100 orders ± 10, and is standby;
B. mix
With floats 20~45 weight part mixings of diammonium phosphate 30~50 weight parts, fused(calcium magnesium)phosphate 25~40 weight parts and step a preparation, standby;
3.. the preparation of each component composite grain of compound manure
Mixed phosphorus fertilizer 20~35 weight parts that 2. potash fertilizer, nitrogenous fertilizer mixture and the step that 1. step is prepared prepare, iron, manganese, boron, copper.Zinc, molybdenum additives 0.1~0.5 weight part mix evenly, add granulating agent 6~12 weight parts, and water is appropriate.Utilize traditional tablets press with each component mixing granulation of described compound manure, standby;
4.. stearic acid is filmed
Stearic consumption is 0.6%~1.2% of each component composite grain quality of compound manure of 3. preparing of step, and coating method is as follows:
A.. the stearic preparation of melting
Coating after according to the formula accurate-metering, in input stearic acid fusion tank, is heated to molten state with stearic acid, and is standby;
B.. coating
3. each component composite grain of compound manure for preparing according to formula accurate-metering step, melting stearic acid with step a preparation carries out spraying outside particle in drum-type mixing granulation machine, makes the composite grain outside surface form coating as far as possible uniformly, warm air drying, room temperature wind are cooling, standby; Processing condition are as follows:
The warm air drying temperature is not higher than 80 ℃
The cooling draught temperature is not higher than 50 ℃;
5.. modified zeolite powder powder body material face powder
A. the face powder preparation of mixed powder
According to Magnesium Stearate 1.5%~3.0%, the proportioning raw materials of zeolite powder 97%~98.5% accurately takes respectively each component of raw material, mixes, and grinding flour is controlled powder fineness and crossed 120 mesh sieves, and is standby;
B. the coating of applying powder
The mixed powder consumption of step a preparation is controlled at each component composite grain face powder of every 1000kg compound manure 10~15kg;
6.. screening, metering, quality test, qualified rear packing makes the preparation method of the sustained-release long-acting compound fertilizer of wheat special use; The products obtained therefrom particle appearance is mellow and full, the product free from extraneous odour.
2. according to claim 1 the preparation method of sustained-release long-acting compound fertilizer of wheat special use is characterized in that being made by following raw material according to the mass fraction meter:
Urea 30~45
Ammonium sulfate 10~15
Vitriolate of tartar 10~30
Mixed phosphorus fertilizer 10~30
Iron, manganese, boron, copper.Zinc, molybdenum additives 0.1~0.5
Granulation aid 6~12
Water is appropriate
Wherein:
Described mixed phosphorus fertilizer is composited by diammonium phosphate, fused(calcium magnesium)phosphate and floats, its mass percent for example under:
Diammonium phosphate 35~45
Fused(calcium magnesium)phosphate 20~30
Floats 30~35.
3. according to claim 1 the preparation method of sustained-release long-acting compound fertilizer of wheat special use is characterized in that being made by following raw material according to the mass fraction meter:
Urea 30
Ammonium sulfate 18
Vitriolate of tartar 22
Mixed phosphorus fertilizer 22
Iron, manganese, boron, copper.Zinc, molybdenum additives 0.5
Granulation aid 7.5
Water is appropriate
Wherein:
Described mixed phosphorus fertilizer is composited by diammonium phosphate, fused(calcium magnesium)phosphate and floats, its mass percent for example under:
Diammonium phosphate 45
Fused(calcium magnesium)phosphate 20
Floats 35.
4. according to the sustained-release long-acting compound fertilizer of the wheat special use of preparation method's preparation of the sustained-release long-acting compound fertilizer of the wheat special use of claim 1, it is characterized in that product reaches following technical indicator:
N constituent content % 〉=12
P
2O
5Content % 〉=6
K
2O content % 〉=8
Grain graininess mm 2~4.75mm
Moisture content wt%≤2.0.
5. according to the application process of the sustained-release long-acting compound fertilizer of the wheat special use of preparation method's preparation of the sustained-release long-acting compound fertilizer of the wheat special use of claim 1, it is characterized in that trench digging imposes on below the earth's surface, base fertilizer: 40~50Kg/ mu; Topdress: 20~30Kg/ mu.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103351211A (en) * | 2013-06-07 | 2013-10-16 | 安徽金阳环保肥业有限公司 | Machine-applied controlled-release fertilizer special for winter wheat and preparation method thereof |
CN103539499A (en) * | 2013-10-08 | 2014-01-29 | 界首市昊坤农作物种植专业合作社 | Special foliage fertilizer for wheat |
CN103601549A (en) * | 2013-10-31 | 2014-02-26 | 界首市聚丰家庭农场 | Wheat composite fertilizer suitable for Huaibei Plain |
CN104355798A (en) * | 2014-10-23 | 2015-02-18 | 左中军 | Fertilizer applied during wheat heading |
CN104355755A (en) * | 2014-11-17 | 2015-02-18 | 淮北市三丰肥业有限公司 | Blended formulated fertilizer for wheat |
CN106396962A (en) * | 2016-09-12 | 2017-02-15 | 巢湖春友种业科技有限公司 | Calcium-rich nutrition fertilizer for wheat planting and method for preparing calcium-rich nutrition fertilizer |
CN106748016A (en) * | 2016-12-02 | 2017-05-31 | 河南力浮科技有限公司 | A kind of production method of wheat special controlled release seed dressing composite fertilizer |
CN108821888A (en) * | 2018-08-28 | 2018-11-16 | 海南莲华生态文化股份有限公司 | A kind of compound fertilizer formula of water lily |
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CN1803734A (en) * | 2006-01-18 | 2006-07-19 | 山东农业大学 | Production method of dedicated substrate sustained release fertilizer for wheat by weathered coal |
CN201678604U (en) * | 2010-05-04 | 2010-12-22 | 安徽省司尔特肥业股份有限公司 | Special composite particle slow release fertilizer for wheat |
CN101830762B (en) * | 2010-05-27 | 2011-05-11 | 山东金正大生态工程股份有限公司 | Special nutritional meal fertilizer for wheat |
CN102093144A (en) * | 2011-01-19 | 2011-06-15 | 施可丰化工股份有限公司 | Biodegradable coated urea |
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CN1803734A (en) * | 2006-01-18 | 2006-07-19 | 山东农业大学 | Production method of dedicated substrate sustained release fertilizer for wheat by weathered coal |
CN201678604U (en) * | 2010-05-04 | 2010-12-22 | 安徽省司尔特肥业股份有限公司 | Special composite particle slow release fertilizer for wheat |
CN101830762B (en) * | 2010-05-27 | 2011-05-11 | 山东金正大生态工程股份有限公司 | Special nutritional meal fertilizer for wheat |
CN102093144A (en) * | 2011-01-19 | 2011-06-15 | 施可丰化工股份有限公司 | Biodegradable coated urea |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103351211A (en) * | 2013-06-07 | 2013-10-16 | 安徽金阳环保肥业有限公司 | Machine-applied controlled-release fertilizer special for winter wheat and preparation method thereof |
CN103539499A (en) * | 2013-10-08 | 2014-01-29 | 界首市昊坤农作物种植专业合作社 | Special foliage fertilizer for wheat |
CN103601549A (en) * | 2013-10-31 | 2014-02-26 | 界首市聚丰家庭农场 | Wheat composite fertilizer suitable for Huaibei Plain |
CN104355798A (en) * | 2014-10-23 | 2015-02-18 | 左中军 | Fertilizer applied during wheat heading |
CN104355755A (en) * | 2014-11-17 | 2015-02-18 | 淮北市三丰肥业有限公司 | Blended formulated fertilizer for wheat |
CN106396962A (en) * | 2016-09-12 | 2017-02-15 | 巢湖春友种业科技有限公司 | Calcium-rich nutrition fertilizer for wheat planting and method for preparing calcium-rich nutrition fertilizer |
CN106748016A (en) * | 2016-12-02 | 2017-05-31 | 河南力浮科技有限公司 | A kind of production method of wheat special controlled release seed dressing composite fertilizer |
CN108821888A (en) * | 2018-08-28 | 2018-11-16 | 海南莲华生态文化股份有限公司 | A kind of compound fertilizer formula of water lily |
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